2026/02/03 更新

写真a

アキタ ムネタカ
穐田 宗隆
AKITA MUNETAKA
所属
リサーチディベロップメント機構 特任教授
職名
特任教授
外部リンク

News & Topics

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学位

  • 工学修士 ( 京都大学 )

  • 理学博士 ( 大阪大学大学院 )

研究キーワード

  • 有機金属化学

  • 有機化学

  • フォトレドックス触媒

  • 有機光化学

  • 分子デバイス

研究分野

  • ナノテク・材料 / 無機・錯体化学  / 有機金属分子エレクトロニクス

  • ナノテク・材料 / 有機合成化学  / フォトレドックス触媒

  • ナノテク・材料 / 有機合成化学  / 有機金属化学

  • ライフサイエンス / 生物有機化学

学歴

  • 大阪大学大学院   理学研究科   高分子学専攻

    1981年4月 - 1984年3月

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    国名: 日本国

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  • 京都大学大学院   工学研究科   合成化学専攻

    1979年4月 - 1981年3月

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    国名: 日本国

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  • 京都大学   工学部   合成化学科

    1975年4月 - 1979年3月

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    国名: 日本国

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経歴

  • 東京科学大学   特任教授

    2024年10月 - 現在

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  • 東京工業大学   特任教授

    2024年9月

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  • 東京工業大学   名誉教授

    2022年4月

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  • -:東京工業大学 教授

    2002年4月

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  • -:東京工業大学 助教授

    1995年5月

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  • -:東京工業大学 助手

    1984年4月

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所属学協会

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論文

  • Dawn of photoredox catalysis

    Munetaka Akita

    PROCEEDINGS OF THE JAPAN ACADEMY SERIES B-PHYSICAL AND BIOLOGICAL SCIENCES   101 ( 5 )   274 - 301   2025年

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  • Controlling Redox and Wirelike Charge-Delocalization Properties of Dinuclear Mixed-Valence Complexes with MCp*(dppe) (M = Fe, Ru) Termini Bridged by Metalloporphyrin Linkers. 国際誌

    Masahito Murai, Masanori Ono, Yuya Tanaka, Munetaka Akita

    ACS organic & inorganic Au   4 ( 5 )   504 - 516   2024年10月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    Four dinuclear organometallic molecular wire complexes with diethynylmetalloporphyrin linkers 1 MM' , [5,15-bis{MCp*(dppe)ethynyl}-10,20-diarylporphinato]M' (Cp* = η5-C5Me5; dppe = 1,2-bis(diphenylphosphino)ethane; M/M' = Fe/Zn (1 FeZn ), Ru/Zn (1 RuZn ), Fe/Ni (1 FeNi ), Ru/Ni (1 RuNi ); aryl = 3,5-di-tert-butylphenyl), are synthesized and characterized by NMR, CV, UV-vis-NIR, and ESI-TOF mass spectrometry techniques. Electrochemical investigations combined with electronic absorption spectroscopic studies reveal strong interactions among the electron-donating, redox-active MCp*(dppe) termini and the metalloporphyrin moieties. The monocationic species of the four complexes obtained by chemical oxidation have been characterized as mixed-valence Class II/III or Class III compounds according to the Robin-Day classification despite the long molecular dimension (>1.5 nm), as demonstrated by their intense intervalence charge transfer bands (IVCT) in the near IR region. DFT calculations indicate large spin densities on the metalloporphyrin moieties. Furthermore, the wirelike performance can be finely tuned by coordination of appropriate nitrogen donors to the axial sites of the metalloporphyrin.

    DOI: 10.1021/acsorginorgau.4c00021

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  • Molecule-Electrode Interfaces Controlled by Bulky Long-Legged Ligands in Organometallic Molecular Wires

    Yuya Tanaka, Yeana Bae, Fumiya Ogasawara, Keita Suzuki, Shuji Kobayashi, Satoshi Kaneko, Shintaro Fujii, Tomoaki Nishino, Munetaka Akita

    Advanced Materials Interfaces   10 ( 11 )   2023年4月

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    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1002/admi.202202464

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  • A metal alkynyl molecular wire with PN ligands: Synthesis, isomerization, physical properties and single-molecule conductance

    Yuya Tanaka, Aki Okamoto, Shintaro Fujii, Tomoaki Nishino, Munetaka Akita

    Inorganica Chimica Acta   544   2023年1月

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    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1016/j.ica.2022.121211

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  • One-Electron Injection-triggered Radical Reaction of Alkyl Benzoates Promoted by 1,4-Bis(diphenylamino)benzene Photocatalysis

    Takashi Koike, Ryo Okumura, Tomoki Kato, Manabu Abe, Munetaka Akita

    CHEMCATCHEM   2023年1月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1002/cctc.202201311

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  • Estimation of Electron Distribution over Dinuclear Organometallic Molecular Wires by “IR Tag” Analysis of Ancillary Acyl-Cp Ligands

    Yuya Tanaka, Hiroki Takahashi, Munetaka Akita

    ACS Organic & Inorganic Au   2022年8月

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    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1021/acsorginorgau.2c00005

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  • Assemblies of 1,4-Bis(diarylamino)naphthalenes and Aromatic Amphiphiles: Highly Reducing Photoredox Catalysis in Water

    Takashi Koike, Munetaka Akita, Yuki Hyodo, Keigo Takahashi, Youhei Chitose, Manabu Abe, Michito Yoshizawa

    Synlett   2022年7月

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    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1055/a-1652-2707

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  • Modular Redox Switching of Dinuclear Organometallic Molecular Junctions

    Yuya Tanaka, Naoki Morozumi, Tatsuhiko Ohto, Satoshi Kaneko, Yasuhisa Naitoh, Hirokazu Tada, Shintaro Fujii, Tomoaki Nishino, Munetaka Akita

    2022年2月

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    出版者・発行元:American Chemical Society (ACS)  

    Molecular switch is one of the essential functional units of molecular electronics. Here, we report development of new molecular switches based on the electron-rich diruthenium complexes with the (2,5-di-R-substituted 1,4-diethynylbenzene)diyl linkers. The dinuclear molecular switches, {µ-p-C≡C-(2,5-R2-C6H2)-C≡C}{Ru(dppe)2(C≡C-C6H4-p-SMe)}2 1R (R= OMe, H, CF3), with various substituents (R) on the bridging phenylene rings showed two successive reversible 1e-oxidation waves, indicating stability of 1e-oxidized mixed-valence species. The solid-state structure of [1H]+ showed the charge-localized Robin-Day class II nature, while that of [1OMe]+ revealed the fully charge-delocalized class III nature. These characters were also evident from the spectroscopic data in solutions. Single-molecule conductance measurements by the scanning tunneling microscope break junction method revealed a significant dependence of the conductance on R, i.e. 1OMe turned out to be >100-times more conductive than 1H and 1CF3, whereas the substituent effect of the monocationic complexes was within a fold-change of 2. As a result, the ON/OFF ratios (the ratios of the conductance of the cationic species [1R]+ to that of the neutral species 1R) were critically dependent on R (as large as 191 when R = CF3) and even reversed (0.4 when R = OMe). Furthermore, the neutral and monocationic complexes 1H and [1H]+ fabricated into the nanogap devices showed in situ ON/OFF switching behavior. The present study demonstrates not only the rare examples of the mixed-valence complexes which were subjected to the break junction measurements but also the first examples of molecular switch, the ON/OFF ratio of which was controlled by tuning the organic linker parts.

    DOI: 10.26434/chemrxiv-2022-xfrpb-v2

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  • Synthesis, structural characterization, and reactivity of a dinuclear cobalt(II) (μ-hydroxo)(μ-pyrazolato) complex based on a hydrotris(pyrazolyl)borate ligand

    Hidehito Komatsuzaki, Kazunari Ohira, Shun Tadokoro, Yuta Yamasaki, Hitomi Oouchi, Minoru Satoh, Tomohiro Agou, Yuya Tanaka, Munetaka Akita, Jun Nakazawa, Shiro Hikichi

    Inorganica Chimica Acta   527   120533 - 120533   2021年11月

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    掲載種別:研究論文(学術雑誌)   出版者・発行元:Elsevier BV  

    DOI: 10.1016/j.ica.2021.120533

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  • Organometallic Molecular Wires with Thioacetylene Backbones, trans-{RS-(C≡C)<inf>n</inf>}<inf>2</inf>Ru(phosphine)<inf>4</inf>: High Conductance through Non-Aromatic Bridging Linkers

    Atsushi Yashiro, Yuya Tanaka, Tomofumi Tada, Shintaro Fujii, Tomoaki Nishino, Munetaka Akita

    Chemistry - A European Journal   27 ( 37 )   9666 - 9673   2021年7月

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    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1002/chem.202100828

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  • Dimesitylborylethynylated Arenes: Unique Electronic and Photophysical Properties Caused by Ethynediyl (C≡C) Spacers

    Kentaro Mishiba, Yuya Tanaka, Munetaka Akita

    Chemistry – A European Journal   27 ( 17 )   5432 - 5438   2021年3月

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    掲載種別:研究論文(学術雑誌)   出版者・発行元:Wiley  

    DOI: 10.1002/chem.202004744

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    その他リンク: https://onlinelibrary.wiley.com/doi/full-xml/10.1002/chem.202004744

  • Cover Feature: Dimesitylborylethynylated Arenes: Unique Electronic and Photophysical Properties Caused by Ethynediyl (C≡C) Spacers (Chem. Eur. J. 17/2021)

    Kentaro Mishiba, Yuya Tanaka, Munetaka Akita

    Chemistry – A European Journal   27 ( 17 )   5308 - 5308   2021年3月

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    掲載種別:研究論文(学術雑誌)   出版者・発行元:Wiley  

    DOI: 10.1002/chem.202100132

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    その他リンク: https://onlinelibrary.wiley.com/doi/full-xml/10.1002/chem.202100132

  • Control of dominant conduction orbitals by peripheral substituents in paddle-wheel diruthenium alkynyl molecular junctions 査読

    Shiori Ogawa, Swarup Chattopadhyay, Yuya Tanaka, Tatsuhiko Ohto, Tomofumi Tada, Hirokazu Tada, Shintaro Fujii, Tomoaki Nishino, Munetaka Akita

    Chemical Science   12 ( 32 )   10871 - 10877   2021年

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    掲載種別:研究論文(学術雑誌)   出版者・発行元:Royal Society of Chemistry ({RSC})  

    DOI: 10.1039/D1SC02407H

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  • Simple generation of various α-monofluoroalkyl radicals by organic photoredox catalysis: modular synthesis of β-monofluoroketones

    Ryo Taniguchi, Naoki Noto, Seiya Tanaka, Keigo Takahashi, Sujan K. Sarkar, Ryoko Oyama, Manabu Abe, Takashi Koike, Munetaka Akita

    Chemical Communications   2021年

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    掲載種別:研究論文(学術雑誌)   出版者・発行元:Royal Society of Chemistry ({RSC})  

    DOI: 10.1039/D0CC08060H

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  • Single-molecule junctions of multinuclear organometallic wires: long-range carrier transport brought about by metal–metal interaction

    Yuya Tanaka, Yuya Kato, Kaho Sugimoto, Reo Kawano, Tomofumi Tada, Shintaro Fujii, Manabu Kiguchi, Munetaka Akita

    Chemical Science   12 ( 12 )   4338 - 4344   2021年

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    掲載種別:研究論文(学術雑誌)   出版者・発行元:Royal Society of Chemistry ({RSC})  

    DOI: 10.1039/D0SC06613C

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  • Transition Metal-Free Supramolecular Photoredox Catalysis in Water: A Phenoxazine Photocatalyst Encapsulated in V-Shaped Aromatic Amphiphiles

    Naoki Noto, Yuki Hyodo, Michito Yoshizawa, Takashi Koike, Munetaka Akita

    ACS CATALYSIS   10 ( 23 )   14283 - 14289   2020年12月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1021/acscatal.0c04221

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  • Laser Flash Photolysis Studies on Radical Monofluoromethylation by (Diarylamino)naphthalene Photoredox Catalysis: Long Lifetime of the Excited State is Not Always a Requisite. 査読 国際誌

    Naoki Noto, Keigo Takahashi, Shion Goryo, Akira Takakado, Koichi Iwata, Takashi Koike, Munetaka Akita

    The Journal of organic chemistry   85 ( 20 )   13220 - 13227   2020年10月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    Organic photoredox catalysis has become a useful tool for the development of metal-free radical reactions. Recently, we have reported that 1,4-bis(diphenylamino)naphthalene N serves as an efficient photoredox catalyst for radical monofluoromethylation with N-tosyl-S-monofluoromethyl-S-phenylsulfoximine 2. In this paper, we report the preparation and photo- and electrochemical properties of (diarylamino)naphthalene derivatives, 1,4-bis(di(p-tert-butylphenyl)amino)naphthalene 1a, 1,5-bis(di(p-tert-butylphenyl)amino)naphthalene 1b, and 1-(di(p-tert-butylphenyl)amino)naphthalene) 1c, as supported by density functional theory (DFT) and time-dependent-DFT calculations. In addition, their performance of photocatalysis has been evaluated by means of methoxy-monofluoromethylation of aromatic alkenes. Laser flash photolysis shows that the fluorescence of 1a in the excited state is efficiently quenched by 2 (quenching rate constant kq = ca. 2 × 109 M-1 s-1). Transient absorption spectroscopic analyses reveal that the excited species of 1a in the presence of 2 starts decreasing in ca. 100 ps, suggesting the occurrence of fast electron-transfer processes. These results lead to the unconventional concept for the catalyst design, that is, long lifetime of the excited state is not always a requisite for efficient photoredox catalysts.

    DOI: 10.1021/acs.joc.0c01999

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  • Single-Molecule Junction of a Cationic Rh(III) Polyyne Molecular Wire

    Yuya Tanaka, Kohei Ohmura, Shintaro Fujii, Tomofumi Tada, Manabu Kiguchi, Munetaka Akita

    Inorganic Chemistry   59 ( 18 )   13254 - 13261   2020年9月

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    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1021/acs.inorgchem.0c01609

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  • N-Doping of Polyaromatic Capsules: Small Cavity Modification Leads to Large Change in Host-Guest Interactions 査読

    Hiroki Dobashi, Lorenzo Catti, Yuya Tanaka, Munetaka Akita, Michito Yoshizawa

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   59 ( 29 )   11881 - 11885   2020年7月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1002/anie.202004168

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  • Recognition and Stabilization of Unsaturated Fatty Acids by a Polyaromatic Receptor 査読

    Keita Niki, Takahiro Tsutsui, Masahiro Yamashina, Munetaka Akita, Michito Yoshizawa

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   59 ( 26 )   10489 - 10492   2020年6月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1002/anie.202003253

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  • Anisotropic Contraction of a Polyaromatic Capsule and Its Cavity-Induced Compression Effect 査読

    Natsuki Kishida, Kyosuke Matsumoto, Yuya Tanaka, Munetaka Akita, Hidehiro Sakurai, Michito Yoshizawa

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   142 ( 21 )   9599 - 9603   2020年5月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1021/jacs.0c02932

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  • Energy transfer-driven regioselective synthesis of functionalized phenanthridines by visible-light Ir photocatalysis 査読

    Yuki Matsushita, Rika Ochi, Yuya Tanaka, Takashi Koike, Munetaka Akita

    ORGANIC CHEMISTRY FRONTIERS   7 ( 10 )   1243 - 1248   2020年5月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1039/d0qo00271b

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  • Fluoroalkanesulfinate Salts as Dual Fluoroalkyl and SO2 Sources: Atom-Economical Fluoroalkyl-Sulfonylation of Alkenes and Alkynes by Photoredox Catalysis 査読

    Seiya Tanaka, Yoshiki Nakayama, Yusuke Konishi, Takashi Koike, Munetaka Akita

    ORGANIC LETTERS   22 ( 7 )   2801 - 2805   2020年4月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1021/acs.orglett.0c00789

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  • Recognition and Stabilization of Unsaturated Fatty Acids by a Polyaromatic Receptor 査読

    Keita Niki, Takahiro Tsutsui, Masahiro Yamashina, Munetaka Akita, Michito Yoshizawa

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   2020年4月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1002/anie.202003253

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  • Photoluminescent properties and molecular structures of dinuclear gold(<scp>i</scp>) complexes with bridged diphosphine ligands: near-unity phosphorescence from 3XMMCT/3MC

    Masahisa Osawa, Sakie Soma, Mikio Hoshino, Yuya Tanaka, Munetaka Akita

    Dalton Transactions   49 ( 43 )   15204 - 15212   2020年

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    掲載種別:研究論文(学術雑誌)   出版者・発行元:Royal Society of Chemistry (RSC)  

    <p>Dinuclear gold(i) complexes with bridged diphosphine ligands display near-unity phosphorescence in the crystalline state at room-temperature.</p>

    DOI: 10.1039/d0dt03144e

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  • Polyaromatic nanocapsules as photoresponsive hosts in water 査読

    Lorenzo Catti, Natsuki Kishida, Tomokuni Kai, Munetaka Akita, Michito Yoshizawa

    Nature Communications   10 ( 1 )   2019年12月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1038/s41467-019-09928-x

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  • A Redox-Active Heterocyclic Capsule: Radical Generation, Oxygenation, and Guest Uptake/Release 査読

    Yoshiyuki Satoh, Lorenzo Catti, Munetaka Akita, Michito Yoshizawa

    Journal of the American Chemical Society   141 ( 31 )   12268 - 12273   2019年8月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1021/jacs.9b03419

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  • Keto-Difluoromethylation of Aromatic Alkenes by Photoredox Catalysis: Step-Economical Synthesis of alpha-CF2H-Substituted Ketones in Flow 査読

    Nakayama Yoshiki, Ando Gaku, Abe Manabu, Koike Takashi, Akita Munetaka

    ACS CATALYSIS   9 ( 7 )   6555 - 6563   2019年7月

  • Recent progress in photochemical radical di- and mono-fluoromethylation 査読

    Koike Takashi, Akita Munetaka

    ORGANIC & BIOMOLECULAR CHEMISTRY   17 ( 22 )   5413 - 5419   2019年6月

  • Organometallic radicals of iron and ruthenium: Similarities and dissimilarities of radical reactivity and charge delocalization

    Yuya Tanaka, Munetaka Akita

    Coordination Chemistry Reviews   388   334 - 342   2019年6月

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    掲載種別:研究論文(学術雑誌)   出版者・発行元:Elsevier BV  

    DOI: 10.1016/j.ccr.2019.02.036

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  • A Peanut-Shaped Polyaromatic Capsule: Solvent-Dependent Transformation and Electronic Properties of a Non-Contacted Fullerene Dimer 査読

    Kyosuke Matsumoto, Shunsuke Kusaba, Yuya Tanaka, Yoshihisa Sei, Munetaka Akita, Kazushi Aritani, Masa-aki Haga, Michito Yoshizawa

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   58 ( 25 )   8463 - 8467   2019年6月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1002/anie.201903117

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  • Visible-Light-Triggered Monofluoromethylation of Alkenes by Strongly Reducing 1,4-Bis(diphenylamino)naphthalene Photoredox Catalysis 査読

    Naoki Noto, Takashi Koike, Munetaka Akita

    ACS Catalysis   9 ( 5 )   4382 - 4387   2019年5月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:American Chemical Society ({ACS})  

    DOI: 10.1021/acscatal.9b00473

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  • A Polyaromatic Gemini Amphiphile That Assembles into a Well-Defined Aromatic Micelle with Higher Stability and Host Functions 査読

    Tomoya Nishioka, Kiyonori Kuroda, Munetaka Akita, Michito Yoshizawa

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   58 ( 20 )   6579 - 6583   2019年5月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1002/anie.201814624

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  • A polyaromatic receptor with high androgen affinity 査読

    Masahiro Yamashina, Takahiro Tsutsui, Yoshihisa Sei, Munetaka Akita, Michito Yoshizawa

    SCIENCE ADVANCES   5 ( 4 )   2019年4月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1126/sciadv.aav3179

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  • Open versus Closed Polyaromatic Nanocavity: Enhanced Host Abilities toward Large Dyes and Pigments 査読

    Takahiro Tsutsui, Shunsuke Kusaba, Masahiro Yamashina, Munetaka Akita, Michito Yoshizawa

    CHEMISTRY-A EUROPEAN JOURNAL   25 ( 17 )   4320 - 4324   2019年3月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1002/chem.201806409

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  • Dinuclear ruthenium acetylide complexes with diethynylated anthrahydroquinone and anthraquinone frameworks: a multi-stimuli-responsive organometallic switch 査読

    Yousuke Oyama, Reo Kawano, Yuya Tanaka, Munetaka Akita

    Dalton Transactions   2019年

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    掲載種別:研究論文(学術雑誌)   出版者・発行元:Royal Society of Chemistry ({RSC})  

    DOI: 10.1039/C9DT01255A

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  • Luminescence color alteration induced by trapped solvent molecules in crystals of tetrahedral gold(i) complexes: near-unity luminescence mixed with thermally activated delayed fluorescence and phosphorescence 査読

    Masahisa Osawa, Hiroto Yamayoshi, Mikio Hoshino, Yuya Tanaka, Munetaka Akita

    Dalton Transactions   48 ( 25 )   9094 - 9103   2019年

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    掲載種別:研究論文(学術雑誌)   出版者・発行元:Royal Society of Chemistry ({RSC})  

    DOI: 10.1039/C9DT01373C

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  • Synthesis and intramolecular electronic interactions of hexaarylbenzene bearing redox-active Cp*(dppe)Fe-C≡C- termini 査読

    Yuya Tanaka, Munetaka Akita

    Journal of Organometallic Chemistry   878   30 - 37   2018年12月

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    掲載種別:研究論文(学術雑誌)   出版者・発行元:Elsevier {BV}  

    DOI: 10.1016/j.jorganchem.2018.10.002

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  • A Pentacene‐based Nanotube Displaying Enriched Electro/Photochemical Activities 査読

    Kiyonori Kuroda, Kohei Yazaki, Yuya Tanaka, Munetaka Akita, Hayato Sakai, Taku Hasobe, Nikolai V. Tkachenko, Michito Yoshizawa

    Angewandte Chemie International Edition   2018年11月

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  • An Organometallic Molecular Wire Bearing a Manganese Porphyrin Linker: Coordination-driven Modulation of the Metal-Metal Interaction 査読

    Yuya Tanaka, Masanori Ono, Munetaka Akita

    Chemistry Letters   47 ( 10 )   1296 - 1299   2018年10月

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    掲載種別:研究論文(学術雑誌)   出版者・発行元:The Chemical Society of Japan  

    DOI: 10.1246/cl.180592

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  • Cramming versus threading of long amphiphilic oligomers into a polyaromatic capsule 査読

    Masahiro Yamashina, Shunsuke Kusaba, Munetaka Akita, Takashi Kikuchi, Michito Yoshizawa

    NATURE COMMUNICATIONS   9   2018年10月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1038/s41467-018-06458-w

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  • A monomeric manganese(II) catecholato complex: Synthesis, crystal structure, and reactivity toward molecular oxygen 査読

    Shin-ichiro Agake, Hidehito Komatsuzaki, Minoru Satoh, Tomohiro Agou, YuyaTanaka, Munetaka Akita, Jun Nakazawa, Shiro Hikichi

    Inorganica Chimica Acta   484   424 - 429   2018年9月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1016/j.ica.2018.09.013

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  • Strongly Reducing (Diarylamino)anthracene Catalyst for Metal-Free Visible-Light Photocatalytic Fluoroalkylation 査読

    Naoki Noto, Yuya Tanaka, Takashi Koike, Munetaka Akita

    ACS Catalysis   8 ( 10 )   9408 - 9419   2018年9月

  • "Doping" of Polyyne with an Organometallic Fragment Leads to Highly Conductive Metallapolyyne Molecular Wire 査読

    Tanaka Yuya, Kato Yuya, Tada Tomofumi, Fujii Shintaro, Kiguchi Manabu, Akita Munetaka

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   140 ( 32 )   10080 - 10084   2018年8月

  • Photoredox radical C-H oxygenation of aromatics with aroyloxylutidinium salts 査読

    Miyazawa Kazuki, Ochi Rika, Koike Takashi, Akita Munetaka

    ORGANIC CHEMISTRY FRONTIERS   5 ( 9 )   1406 - 1410   2018年5月

  • New Horizons of Photocatalytic Fluoromethylative Difunctionalization of Alkenes 査読

    Koike Takashi, Akita Munetaka

    CHEM   4 ( 3 )   409 - 437   2018年3月

  • Alkylation-, Heating-, and Doping-Induced Emission Enhancement of a Polyaromatic Tube in the Solid State 査読

    Kiyonori Kuroda, Masafumi Otsuki, Kohei Yazaki, Yoshihisa Sei, Munetaka Akita, Michito Yoshizawa

    CHEMISTRY-AN ASIAN JOURNAL   13 ( 5 )   515 - 519   2018年3月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1002/asia.201800034

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  • Hydrophilic Oligo(lactic acid)s Captured by a Hydrophobic Polyaromatic Cavity in Water 査読

    Shunsuke Kusaba, Masahiro Yamashina, Munetaka Akita, Takashi Kikuchi, Michito Yoshizawa

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   57 ( 14 )   3706 - 3710   2018年3月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1002/anie.201800432

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  • Encapsulation-induced emission enhancement (EIEE) of Eu(III)-complexes by aromatic micelles in water 査読

    Tomokuni Kai, Mai Kishimoto, Munetaka Akita, Michito Yoshizawa

    CHEMICAL COMMUNICATIONS   54 ( 8 )   956 - 959   2018年1月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1039/c7cc09450g

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  • Near-unity thermally activated delayed fluorescence efficiency in three- and four-coordinate Au(i) complexes with diphosphine ligands 査読

    Masahisa Osawa, Masa-aki Aino, Takaki Nagakura, Mikio Hoshino, Yuya Tanaka, Munetaka Akita

    Dalton Transactions   47 ( 25 )   8229   2018年

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    出版者・発行元:Royal Society of Chemistry ({RSC})  

    DOI: 10.1039/C8DT01097H

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  • Non-Radical Light-Controlled Polymerization of Styrene and Vinyl Ethers Catalyzed by an Iridium-Palladium Photocatalyst 査読

    Shinnosuke Kikuchi, Kazuma Saito, Munetaka Akita, Akiko Inagaki

    Organometallics   37   359 - 366   2018年

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    記述言語:英語  

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  • Side-Chain-Directed Dispersion of MoS2 Nanosheets by V-Shaped Polyaromatic Compounds 査読

    Atsushi Matsumoto, Keisuke Jono, Munetaka Akita, Michito Yoshizawa

    CHEMISTRY-AN ASIAN JOURNAL   12 ( 22 )   2889 - 2893   2017年11月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1002/asia.201701199

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  • Substituent Effect of the Bridging Ligand in the Trinuclear Ru Complexes on Photocatalytic Oxygenation of a Sulfide and Alkenes 査読

    Siwas Phungsripheng, Munetaka Akita, Akiko Inagaki

    INORGANIC CHEMISTRY   56 ( 21 )   12996 - 13006   2017年11月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1021/acs.inorgchem.7b01764

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  • Synthesis and charge delocalization property of multimetallic molecular wires with diethynylthiophene bridges 査読

    Kaho Sugimoto, Hidekazu Idei, Yuya Tanaka, Munetaka Akita

    JOURNAL OF ORGANOMETALLIC CHEMISTRY   847   121 - 131   2017年10月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1016/j.jorganchem.2017.02.033

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  • Metal-free di- and tri-fluoromethylation of alkenes realized by visible-light-induced perylene photoredox catalysis 査読

    Noto Naoki, Koike Takashi, Akita Munetaka

    CHEMICAL SCIENCE   8 ( 9 )   6375 - 6379   2017年9月

  • A Switchable Open/closed Polyaromatic Macrocycle that Shows Reversible Binding of Long Hydrophilic Molecules 査読

    Kohei Kurihara, Kohei Yazaki, Munetaka Akita, Michito Yoshizawa

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   56 ( 38 )   11360 - 11364   2017年9月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1002/anie.201703357

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    その他リンク: http://orcid.org/0000-0001-9356-0127

  • Exact mass analysis of sulfur clusters upon encapsulation by a polyaromatic capsular matrix 査読

    Sho Matsuno, Masahiro Yamashina, Yoshihisa Sei, Munetaka Akita, Akiyoshi Kuzume, Kimihisa Yamamoto, Michito Yoshizawa

    NATURE COMMUNICATIONS   8   2017年9月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1038/s41467-017-00605-5

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  • A polyaromatic nanocapsule as a sucrose receptor in water 査読

    Masahiro Yamashina, Munetaka Akita, Taisuke Hasegawa, Shigehiko Hayashi, Michito Yoshizawa

    SCIENCE ADVANCES   3 ( 8 )   2017年8月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1126/sciadv.1701126

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  • Polyaromatic molecular peanuts 査読

    Kohei Yazaki, Munetaka Akita, Soumyakanta Prusty, Dillip Kumar Chand, Takashi Kikuchi, Hiroyasu Sato, Michito Yoshizawa

    NATURE COMMUNICATIONS   8   2017年6月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1038/ncomms15914

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  • Photoredox-catalyzed oxytrifluoromethylation of allenes: stereoselective synthesis of 2-trifluoromethylated allyl acetates 査読

    Tomita Ren, Koike Takashi, Akita Munetaka

    CHEMICAL COMMUNICATIONS   53 ( 34 )   4681 - 4684   2017年4月

  • Photocatalytic Trifluoromethylthiolation of Aromatic Alkenes Associated with Hydroxylation and Alkoxylation 査読

    Li Yanjie, Koike Takashi, Akita Munetaka

    ASIAN JOURNAL OF ORGANIC CHEMISTRY   6 ( 4 )   445 - 448   2017年4月

  • Inorganic and Organometallic Molecular Wires for Single-Molecule Devices 査読

    Yuya Tanaka, Manabu Kiguchi, Munetaka Akita

    CHEMISTRY-A EUROPEAN JOURNAL   23 ( 20 )   4741 - 4749   2017年4月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1002/chem.201604812

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  • Inorganic and Organometallic Molecular Wires for Single-Molecule Devices 査読

    Yuya Tanaka, Manabu Kiguchi, Munetaka Akita

    CHEMISTRY-A EUROPEAN JOURNAL   23 ( 20 )   4740 - 4740   2017年4月

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  • A Polyaromatic Molecular Clip That Enables the Binding of Planar, Tubular, and Dendritic Compounds 査読

    Keisuke Jono, Akira Suzuki, Munetaka Akita, Ken Albrecht, Kimihisa Yamamoto, Michito Yoshizawa

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   56 ( 13 )   3570 - 3574   2017年3月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1002/ange.201612489

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  • Inside Back Cover: A Fully Charge-Delocalized Two-Dimensional Porphyrin System with Two Different Class III States (Chem. Eur. J. 9/2017) 査読

    Kentaro Mishiba, Masanori Ono, Yuya Tanaka, Munetaka Akita

    Chemistry - A European Journal   23 ( 9 )   2231   2017年2月

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    出版者・発行元:Wiley  

    DOI: 10.1002/chem.201605448

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  • A Fully Charge-Delocalized Two-Dimensional Porphyrin System with Two Different Class III States 査読

    Kentaro Mishiba, Masanori Ono, Yuya Tanaka, Munetaka Akita

    CHEMISTRY-A EUROPEAN JOURNAL   23 ( 9 )   2067 - 2076   2017年2月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1002/chem.201604455

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  • A pH-responsive molecular capsule with an acridine shell: catch and release of large hydrophobic compounds 査読

    Mai Kishimoto, Kei Kondo, Munetaka Akita, Michito Yoshizawa

    CHEMICAL COMMUNICATIONS   53 ( 8 )   1425 - 1428   2017年1月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1039/c6cc09094j

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  • フォトレドックス触媒反応

    穐田 宗隆, 小池 隆司

    ファルマシア   53 ( 9 )   865 - 869   2017年

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    記述言語:日本語   出版者・発行元:公益社団法人 日本薬学会  

    地球環境や資源開発の観点から、グリーンシステムの開発は急務である。事実上無尽蔵な太陽光(可視光)エネルギーを有効利用できる有機合成反応系の一つとして、2000年代後半以降急速に発展してきたフォトレドックス触媒作用について、原理の解説および筆者らの研究成果を中心に最近の研究動向について紹介する。この反応系では、光増感剤触媒の励起状態の一電子移動酸化還元特性に基づいて誘起されるラジカル反応が鍵となっている。

    DOI: 10.14894/faruawpsj.53.9_865

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  • Aminohydroxylation of olefins with iminopyridinium ylides by dual Ir photocatalysis and Sc(OTf)(3) catalysis 査読

    Miyazawa Kazuki, Koike Takashi, Akita Munetaka

    TETRAHEDRON   72 ( 48 )   7813 - 7820   2016年12月

  • Polycationic-Shelled Capsular and Tubular Nanostructures and Their Anionic–Guest Binding Properties 査読

    Yazaki K, Sei Y, Akita M, Yoshizawa M

    Chemistry - A European Journal   22 ( 49 )   17557 - 17561   2016年12月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1002/chem.201604384

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    その他リンク: http://orcid.org/0000-0001-9356-0127

  • Principles and Applications of Photoredox Catalysis: Trifluoromethylation and Beyond 査読

    Akita Munetaka, Koike Takashi

    JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN   74 ( 11 )   1036 - 1046   2016年11月

  • Fine Design of Photoredox Systems for Catalytic Fluoromethylation of Carbon-Carbon Multiple Bonds 査読

    Koike Takashi, Akita Munetaka

    ACCOUNTS OF CHEMICAL RESEARCH   49 ( 9 )   1937 - 1945   2016年9月

  • M2L4 coordination capsules with tunable anticancer activity upon guest encapsulation 査読

    Anife Ahmedova, Rositsa Mihaylova, Denitsa Momekova, Pavletta Shestakova, Silviya Stoykova, Joana Zaharieva, Masahiro Yamashina, Georgi Momekov, Munetaka Akita, Michito Yoshizawa

    DALTON TRANSACTIONS   45 ( 33 )   13214 - 13221   2016年9月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1039/c6dt01801g

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  • Recognition of Multiple Methyl Groups on Aromatic Rings by a Polyaromatic Cavity 査読

    Masahiro Yamashina, Sho Matsuno, Yoshihisa Sei, Munetaka Akita, Michito Yoshizawa

    CHEMISTRY-A EUROPEAN JOURNAL   22 ( 40 )   14147 - 14150   2016年9月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1002/chem.201603032

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  • Diastereoselective Synthesis of CF3- and CF2H-Substituted Spiroethers from Aryl-Fused Cycloalkenylalkanols by Photoredox Catalysis 査読

    Noto Naoki, Koike Takashi, Akita Munetaka

    JOURNAL OF ORGANIC CHEMISTRY   81 ( 16 )   7064 - 7071   2016年8月

  • Engineering Stacks of V-Shaped Polyaromatic Compounds with Alkyl Chains for Enhanced Emission in the Solid State 査読

    Shoya Sekiguchi, Kei Kondo, Yoshihisa Sei, Munetaka Akita, Michito Yoshizawa

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   55 ( 24 )   6906 - 6910   2016年6月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1002/anie.201602502

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  • Photocatalytic Oxygenation of Sulfide and Alkenes by Trinuclear Ruthenium Clusters 査読

    Siwas Phungsripheng, Kazuyuki Kozawa, Munetaka Akita, Akiko Inagaki

    INORGANIC CHEMISTRY   55 ( 8 )   3750 - 3758   2016年4月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1021/acs.inorgchem.5b02518

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  • Radical Pentafluorosulfanylphenylation of Styrenes by Photoredox Catalysis 査読

    Li Yanjie, Koike Takashi, Akita Munetaka

    SYNLETT   27 ( 5 )   736 - 740   2016年3月

  • Solubility Switching of Metallophthalocyanines and Their Larger Derivatives upon Encapsulation 査読

    Kei Kondo, Munetaka Akita, Michito Yoshizawa

    CHEMISTRY-A EUROPEAN JOURNAL   22 ( 6 )   1937 - 1940   2016年2月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1002/chem.201505036

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  • Anticancer Potencies of Pt-II- and Pd-II-linked M2L4 Coordination Capsules with Improved Selectivity 査読

    Anife Ahmedova, Denitsa Momekova, Masahiro Yamashina, Pavletta Shestakova, Georgi Momekov, Munetaka Akita, Michito Yoshizawa

    CHEMISTRY-AN ASIAN JOURNAL   11 ( 4 )   474 - 477   2016年2月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1002/asia.201501238

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  • Oxydifluoromethylation of Alkenes by Photoredox Catalysis: Simple Synthesis of CF2H-Containing Alcohols 査読

    Arai Yusuke, Tomita Ren, Ando Gaku, Koike Takashi, Akita Munetaka

    CHEMISTRY-A EUROPEAN JOURNAL   22 ( 4 )   1262 - 1265   2016年1月

  • Efficient Catalytic Epoxidation in Water by Axial N-Ligand-Free Mn-Porphyrins within a Micellar Capsule 査読

    Takumi Omagari, Akira Suzuki, Munetaka Akita, Michito Yoshizawa

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   138 ( 2 )   499 - 502   2016年1月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1021/jacs.5b11665

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  • An M2 L4 Molecular Capsule with a Redox Switchable Polyradical Shell. 査読

    Yazaki Kohei, Noda Shogo, Tanaka Yuya, Sei Yoshihisa, Akita Munetaka, Yoshizawa Michito

    Angewandte Chemie (International ed. in English)   55 ( 48 )   15031 - 15034   2016年

  • Organometallic molecular wires as versatile modules for energy-level alignment of the metal-molecule-metal junction 査読

    Sugimoto Kaho, Tanaka Yuya, Fujii Shintaro, Tada Tomofumi, Kiguchi Manabu, Akita Munetaka

    Chemical Communications   52 ( 34 )   5796 - 5799   2016年

  • Combination of organotrifluoroborates with photoredox catalysis marking a new phase in organic radical chemistry 査読

    Koike Takashi, Akita Munetaka

    ORGANIC & BIOMOLECULAR CHEMISTRY   14 ( 29 )   6886 - 6890   2016年

  • A versatile strategy for difunctionalization of carbon-carbon multiple bonds by photoredox catalysis 査読

    Koike Takashi, Akita Munetaka

    ORGANIC CHEMISTRY FRONTIERS   3 ( 10 )   1345 - 1349   2016年

  • A fluorescent molecular capsule with a flexible polyaromatic shell for the detection of monoterpene compounds in water 査読

    Akira Suzuki, Kei Kondo, Yoshihisa Sei, Munetaka Akita, Michito Yoshizawa

    CHEMICAL COMMUNICATIONS   52 ( 15 )   3151 - 3154   2016年

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1039/c5cc09647b

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  • Amphiphilic tribranched scaffolds with polyaromatic panels that wrap perylene stacks displaying unusual emissions 査読

    Akira Suzuki, Munetaka Akita, Michito Yoshizawa

    CHEMICAL COMMUNICATIONS   52 ( 65 )   10024 - 10027   2016年

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1039/c6cc04823d

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  • Trifluoromethylation of aromatic alkenes by visible-light-driven photoredox catalysis: Direct conversion of alkenes to 3-trifluoromethyl-1-propenyl and 1,3-bis(trifluoromethyl)-1-propenyl derivatives 査読

    Asano Masashi, Tomita Ren, Koike Takashi, Akita Munetaka

    JOURNAL OF FLUORINE CHEMISTRY   179   83 - 88   2015年11月

  • Photoredox-Catalyzed Stereoselective Conversion of Alkynes into Tetrasubstituted Trifluoromethylated Alkenes 査読

    Tomita Ren, Koike Takashi, Akita Munetaka

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   54 ( 44 )   12923 - 12927   2015年10月

  • C-C Bond Forming Reductive Elimination from Diarylplatinum Complexes Driven by Visible-Light-Mediated Photoredox Reactions 査読

    Yuichiro Shiba, Akiko Inagaki, Munetaka Akita

    ORGANOMETALLICS   34 ( 20 )   4844 - 4853   2015年10月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1021/om501080v

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  • A V-Shaped Polyaromatic Amphiphile: Solubilization of Various Nanocarbons in Water and Enhanced Photostability 査読

    Kei Kondo, Munetaka Akita, Takafumi Nakagawa, Yutaka Matsuo, Michito Yoshizawa

    CHEMISTRY-A EUROPEAN JOURNAL   21 ( 36 )   12741 - 12746   2015年9月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1002/chem.201501414

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  • Regiospecific Intermolecular Aminohydroxylation of Olefins by Photoredox Catalysis 査読

    Miyazawa Kazuki, Koike Takashi, Akita Munetaka

    CHEMISTRY-A EUROPEAN JOURNAL   21 ( 33 )   11677 - 11680   2015年8月

  • Anti-Diastereoselective Synthesis of CF3-Containing Spirooxazolines and Spirooxazines via Regiospecific Trifluoromethylative Spirocyclization by Photoredox Catalysis 査読

    Noto Naoki, Miyazawa Kazuki, Koike Takashi, Akita Munetaka

    ORGANIC LETTERS   17 ( 15 )   3710 - 3713   2015年8月

  • Sunlight-driven trifluoromethylation of olefinic substrates by photoredox catalysis: A green organic process 査読

    Akita Munetaka, Koike Takashi

    COMPTES RENDUS CHIMIE   18 ( 7 )   742 - 751   2015年7月

  • Preparation of Highly Fluorescent Host-Guest Complexes with Tunable Color upon Encapsulation 査読

    Masahiro Yamashina, Matthew M. Sartin, Yoshihisa Sei, Munetaka Akita, Satoshi Takeuchi, Tahei Tahara, Michito Yoshizawa

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   137 ( 29 )   9266 - 9269   2015年7月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1021/jacs.5b06195

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  • Anisotropic Expansion of an M2L4 Coordination Capsule: Host Capability and Frame Rearrangement 査読

    Masahiro Yamashina, Tsubasa Yuki, Yoshihisa Sei, Munetaka Akita, Michito Yoshizawa

    CHEMISTRY-A EUROPEAN JOURNAL   21 ( 11 )   4200 - 4204   2015年3月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1002/chem.201406445

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  • Synthesis and properties of diiron complexes with heteroaromatic linkers: An approach for modulation of organometallic molecular wire 査読

    Tanaka Yuya, Ishisaka Takuya, Koike Takashi, Akita Munetaka

    POLYHEDRON   86   105 - 110   2015年1月

  • Polyaromatic Nanocapsules Displaying Aggregation-Induced Enhanced Emissions in Water 査読

    Yusuke Okazawa, Kei Kondo, Munetaka Akita, Michito Yoshizawa

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   137 ( 1 )   98 - 101   2015年1月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1021/ja511463k

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  • Redox-economical radical generation from organoborates and carboxylic acids by organic photoredox catalysis 査読

    Chinzei Tatsuya, Miyazawa Kazuki, Yasu Yusuke, Koike Takashi, Akita Munetaka

    RSC ADVANCES   5 ( 27 )   21297 - 21300   2015年

  • Alkyl- and aryl-thioalkylation of olefins with organotrifluoroborates by photoredox catalysis 査読

    Li Yanjie, Miyazawa Kazuki, Koike Takashi, Akita Munetaka

    ORGANIC CHEMISTRY FRONTIERS   2 ( 4 )   319 - 323   2015年

  • Well-defined aqueous nanoassemblies from amphiphilic meta-terphenyls and their guest incorporation 査読

    Yusuke Okazawa, Kei Kondo, Munetaka Akita, Michito Yoshizawa

    CHEMICAL SCIENCE   6 ( 8 )   5059 - 5062   2015年

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1039/c5sc01545f

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  • Synthesis and wire-like performance of diruthenium molecular wire with a C equivalent to C-porphyrin-C equivalent to C linker 査読

    Tanaka Yuya, Ono Masanori, Akita Munetaka

    Journal of Porphyrins and Phthalocyanines   19 ( 1-3 )   442 - 450   2015年

  • Polyaromatic molecular tubes with a subnanometer pore and the guest-induced emission enhancement behavior 査読

    Keita Hagiwara, Masafumi Otsuki, Munetaka Akita, Michito Yoshizawa

    CHEMICAL COMMUNICATIONS   51 ( 52 )   10451 - 10454   2015年

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1039/c5cc02931g

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  • An aqueous molecular tube with polyaromatic frameworks capable of binding fluorescent dyes 査読

    Keita Hagiwara, Munetaka Akita, Michito Yoshizawa

    CHEMICAL SCIENCE   6 ( 1 )   259 - 263   2015年

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1039/c4sc02377c

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  • Recent progress in transition-metal-catalyzed trifluoromethylation of olefins using electrophilic CF3 reagents 査読

    Koike Takashi, Akita Munetaka

    JOURNAL OF FLUORINE CHEMISTRY   167   30 - 36   2014年11月

  • Micellar Polyaromatic Capsules: Enhanced Emissive Properties through Shell-Functionalization 査読

    Kei Kondo, Akira Suzuki, Munetaka Akita, Michito Yoshizawa

    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY   2014 ( 33 )   7389 - 7394   2014年11月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1002/ejoc.201403136

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  • Synthesis of C-1 symmetrical ansa-cyclopentadienylamidotitanium complexes and their application for living polymerization of propylene 査読

    Zhengguo Cai, Haihui Su, Yuushou Nakayama, Takeshi Shiono, Munetaka Akita

    JOURNAL OF ORGANOMETALLIC CHEMISTRY   770   136 - 141   2014年11月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1016/j.jorganchem.2014.08.019

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  • A polyaromatic molecular tube that binds long hydrocarbons with high selectivity 査読

    Kohei Yazaki, Yoshihisa Sei, Munetaka Akita, Michito Yoshizawa

    NATURE COMMUNICATIONS   5   2014年10月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1038/ncomms6179

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  • Hydroaminomethylation of Olefins with Aminomethyltrifluoroborate by Photoredox Catalysis 査読

    Miyazawa Kazuki, Koike Takashi, Akita Munetaka

    ADVANCED SYNTHESIS & CATALYSIS   356 ( 13 )   2749 - 2755   2014年9月

  • Safe storage of radical initiators within a polyaromatic nanocapsule 査読

    Masahiro Yamashina, Yoshihisa Sei, Munetaka Akita, Michito Yoshizawa

    NATURE COMMUNICATIONS   5   2014年8月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1038/ncomms5662

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  • Combining Photoredox-Catalyzed Trifluoromethylation and Oxidation with DMSO: Facile Synthesis of alpha-Trifluoromethylated Ketones from Aromatic Alkenes 査読

    Tomita Ren, Yasu Yusuke, Koike Takashi, Akita Munetaka

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   53 ( 28 )   7144 - 7148   2014年7月

  • Trifluoromethylation by Visible-Light-Driven Photoredox Catalysis 査読

    Koike Takashi, Akita Munetaka

    TOPICS IN CATALYSIS   57 ( 10-13 )   967 - 974   2014年6月

  • Direct C-H trifluoromethylation of di- and trisubstituted alkenes by photoredox catalysis 査読

    Tomita Ren, Yasu Yusuke, Koike Takashi, Akita Munetaka

    BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY   10   1099 - 1106   2014年5月

  • Organometallic Photocatalysis Promoted by Visible Light (Sunlight) : Photo-redox Catalysis and Difunctional Dinuclear Catalyst System 査読

    Akita Munetaka, Koike Takashi, Inagaki Akiko

    JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN   72 ( 5 )   538 - 547   2014年5月

  • A Solvato-Fluorochromic Macrocycle of Multiple Anthracene Fluorophores in Close Proximity 査読

    Zhiou Li, Yoshihisa Sei, Munetaka Akita, Michito Yoshizawa

    CHEMISTRY-AN ASIAN JOURNAL   9 ( 4 )   1016 - 1019   2014年4月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1002/asia.201301648

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  • Selective Host-Guest Interactions of a Transformable Coordination Capsule/Tube with Fullerenes 査読

    Norifumi Kishi, Munetaka Akita, Michito Yoshizawa

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   53 ( 14 )   3604 - 3607   2014年4月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1002/anie.201311251

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  • Synthesis of Highly Conjugated Dinuclear Ru Complexes Bridged by a Novel N2-N3 Ligand and Their Application in Photocatalytic Oxygenation of Sulfides 査読

    Kazuyuki Kozawa, Akiko Inagaki, Munetaka Akita

    CHEMISTRY LETTERS   43 ( 3 )   290 - 292   2014年3月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1246/cl.130966

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  • Synthesis of trinuclear Pd-Ru-Pd porphyrin complexes with axially ligated Pd centers. Prominent metal-to-ligand charge transfer band in the visible region 査読

    Yusuke Yasu, Akiko Inagaki, Munetaka Akita

    JOURNAL OF ORGANOMETALLIC CHEMISTRY   753   48 - 54   2014年3月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1016/j.jorganchem.2013.12.008

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  • Highly Regio- and Diastereoselective Synthesis of CF3-Substituted Lactones via Photoredox-Catalyzed Carbolactonization of Alkenoic Acids 査読

    Yasu Yusuke, Arai Yusuke, Tomita Ren, Koike Takashi, Akita Munetaka

    ORGANIC LETTERS   16 ( 3 )   780 - 783   2014年2月

  • Infrared Vibrational Spectroscopy of [Ru(bpy)(2)(bpm)](2+) and [Ru(bpy)(3)](2+) in the Excited Triplet State 査読

    Mukuta Tatsuhiko, Fukazawa Naoto, Murata Kei, Inagaki Akiko, Akita Munetaka, Tanaka Sei'ichi, Koshihara Shin-ya, Onda Ken

    Inorganic Chemistry   53 ( 5 )   2481 - 2490   2014年

  • Visible-light radical reaction designed by Ru- and Ir-based photoredox catalysis 査読

    Koike Takashi, Akita Munetaka

    INORGANIC CHEMISTRY FRONTIERS   1 ( 8 )   562 - 576   2014年

  • Visible-Light-Induced Redox Reactions by Ruthenium Photoredox Catalyst 査読

    Koike Takashi, Akita Munetaka

    RUTHENIUM IN CATALYSIS   48   371 - 395   2014年

  • Zinc-porphyrins functionalized with redox-active metal peripherals: Enhancement of d<inf>π</inf>-p<inf>π</inf> interaction leading to unique assembly and redox-triggered remote switching of fluorescence

    Masahito Murai, Manabu Sugimoto, Munetaka Akita

    Dalton Transactions   42   16108 - 16120   2013年12月

  • Visible-Light-Induced Photoredox Catalysis: An Easy Access to Green Radical Chemistry 査読

    Koike Takashi, Akita Munetaka

    SYNLETT   24 ( 19 )   2492 - 2505   2013年12月

  • Facile Catch and Release of Fullerenes Using a Photoresponsive Molecular Tube 査読

    Norifumi Kishi, Munetaka Akita, Motoshi Kamiya, Shigehiko Hayashi, Hsiu-Fu Hsu, Michito Yoshizawa

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   135 ( 35 )   12976 - 12979   2013年9月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1021/ja406893y

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  • Revelation of the Photoactive Species in the Photocatalytic Dimerization of alpha-Methylstyrene by a Dinuclear Ruthenium-Palladium Complex 査読

    Kei Murata, Akiko Inagaki, Munetaka Akita, Jean-Francois Halet, Karine Costuas

    INORGANIC CHEMISTRY   52 ( 14 )   8030 - 8039   2013年7月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1021/ic400666v

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  • Atroposelective Self-Assembly of a Molecular Capsule from Amphiphilic Anthracene Trimers 査読

    Akira Suzuki, Kei Kondo, Munetaka Akita, Michito Yoshizawa

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   52 ( 31 )   8120 - 8123   2013年7月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1002/anie.201302789

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  • Intermolecular Aminotrifluoromethylation of Alkenes by Visible-Light-Driven Photoredox Catalysis 査読

    Yasu Yusuke, Koike Takashi, Akita Munetaka

    ORGANIC LETTERS   15 ( 9 )   2136 - 2139   2013年5月

  • Syntheses, photophysical properties, and reactivities of novel bichromophoric Pd complexes composed of Ru(II)-polypyridyl and naphthyl moieties 査読

    Kei Murata, Mizuki Araki, Akiko Inagaki, Munetaka Akita

    DALTON TRANSACTIONS   42 ( 19 )   6989 - 7001   2013年

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1039/c3dt50266j

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  • A bowl-shaped organic host using bispyridine ligands: selective encapsulation of carbonyl guests in water 査読

    Kohei Yazaki, Norifumi Kishi, Munetaka Akita, Michito Yoshizawa

    CHEMICAL COMMUNICATIONS   49 ( 16 )   1630 - 1632   2013年

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1039/c3cc38869g

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  • Micelle-like Molecular Capsules with Anthracene Shells as Photoactive Hosts 査読

    Kei Kondo, Akira Suzuki, Munetaka Akita, Michito Yoshizawa

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   52 ( 8 )   2308 - 2312   2013年

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1002/anie.201208643

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  • Manganese(II) semiquinonato and manganese(III) catecholato complexes with tridentate ligand: Modeling the substrate-binding state of manganese-dependent catechol dioxygenase and reactivity with molecular oxygen 査読

    Hidehito Komatsuzaki, Akihiko Shiota, Shogo Hazawa, Muneaki Itoh, Noriko Miyamura, Nahomi Miki, Yoichi Takano, Jun Nakazawa, Akiko Inagaki, Munetaka Akita, Shiro Hikichi

    Chem. Asian. J.   8 ( 6 )   1115 - 1119   2013年

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1002/asia.201300029

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  • Visible-light-induced synthesis of a variety of trifluoromethylated alkenes from potassium vinyltrifluoroborates by photoredox catalysis 査読

    Yasu Yusuke, Koike Takashi, Akita Munetaka

    CHEMICAL COMMUNICATIONS   49 ( 20 )   2037 - 2039   2013年

  • Visible-light-induced hydroalkoxymethylation of electron-deficient alkenes by photoredox catalysis 査読

    Miyazawa Kazuki, Yasu Yusuke, Koike Takashi, Akita Munetaka

    CHEMICAL COMMUNICATIONS   49 ( 65 )   7249 - 7251   2013年

  • Visible Light-Induced Selective Generation of Radicals from Organoborates by Photoredox Catalysis 査読

    Yasu Yusuke, Koike Takashi, Akita Munetaka

    ADVANCED SYNTHESIS & CATALYSIS   354 ( 18 )   3414 - 3420   2012年12月

  • Visible-light-driven Oxidation of 1,3-Dicarbonyl Compounds via Catalytic Disproportionation of TEMPO by Photoredox Catalysis 査読

    Koike Takashi, Yasu Yusuke, Akita Munetaka

    CHEMISTRY LETTERS   41 ( 9 )   999 - 1001   2012年9月

  • Extended Fluorochromism of Anthracene Trimers with a meta-Substituted Triphenylamine or Triphenylphosphine Core 査読

    Zhiou Li, Hiromi Ishizuka, Yoshihisa Sei, Munetaka Akita, Michito Yoshizawa

    CHEMISTRY-AN ASIAN JOURNAL   7 ( 8 )   1789 - 1794   2012年8月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1002/asia.201200310

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  • Isostructural M2L4 Molecular Capsules with Anthracene Shells: Synthesis, Crystal Structures, and Fluorescent Properties 査読

    Zhiou Li, Norifumi Kishi, Kenji Yoza, Munetaka Akita, Michito Yoshizawa

    CHEMISTRY-A EUROPEAN JOURNAL   18 ( 27 )   8358 - 8365   2012年7月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1002/chem.201200155

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  • Theoretical Study on the Photocyclization Mechanism of Diarylethenes with Transition-Metal Substituents 査読

    Hatakeyama Makoto, Yokojima Satoshi, Shinoda Keiko, Koike Takashi, Akita Munetaka, Nakamura Shinichiro

    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN   85 ( 6 )   679 - 686   2012年6月

  • Photochromic Metal Complexes: Photoregulation of both the Nonlinear Optical and Luminescent Properties 査読

    Lucie Ordronneau, Hiroyuki Nitadori, Isabelle Ledoux, Anu Singh, J. A. Gareth Williams, Munetaka Akita, Veronique Guerchais, Hubert Le Bozec

    INORGANIC CHEMISTRY   51 ( 10 )   5627 - 5636   2012年5月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1021/ic2025457

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  • Color change of redox-active organometallic dithienylethene complexes by photochemical and redox processes 査読

    Li Huifang, Koike Takashi, Akita Munetaka

    DYES AND PIGMENTS   92 ( 2 )   854 - 860   2012年2月

  • Enhanced Photocatalytic Activity of alpha-Methylstyrene Oligomerization through Effective Metal-to-Ligand Charge-Transfer Localization on the Bridging Ligand 査読

    Hiroyuki Nitadori, Takeshi Takahashi, Akiko Inagaki, Munetaka Akita

    INORGANIC CHEMISTRY   51 ( 1 )   51 - 62   2012年1月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1021/ic200291t

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  • Photoswitching of the second-order nonlinearity of a tetrahedral octupolar multi DTE-based copper(I) complex 査読

    Hiroyuki Nitadori, Lucie Ordronneau, Julien Boixel, Denis Jacquemin, Abdou Boucekkine, Anu Singh, Munetaka Akita, Isabelle Ledoux, Veronique Guerchais, Hubert Le Bozec

    CHEMICAL COMMUNICATIONS   48 ( 84 )   10395 - 10397   2012年

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1039/c2cc34999j

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  • Sunlight-driven synthesis of gamma-diketones via oxidative coupling of enamines with silyl enol ethers catalyzed by [Ru(bpy)(3)](2+) 査読

    Yasu Yusuke, Koike Takashi, Akita Munetaka

    CHEMICAL COMMUNICATIONS   48 ( 43 )   5355 - 5357   2012年

  • Three-component Oxytrifluoromethylation of Alkenes: Highly Efficient and Regioselective Difunctionalization of C=C Bonds Mediated by Photoredox Catalysts 査読

    Yasu Yusuke, Koike Takashi, Akita Munetaka

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   51 ( 38 )   9567 - 9571   2012年

  • A tubular macrocycle from covalently linked anthracenes and meta-phenylene spacers 査読

    Keita Hagiwara, Yoshihisa Sei, Munetaka Akita, Michito Yoshizawa

    CHEMICAL COMMUNICATIONS   48 ( 62 )   7678 - 7680   2012年

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1039/c2cc31383a

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  • 3,5-Bis(diphenylphosphinoethyl)pyrazolate ligand (PNNPC2) and its dirhodium complexes: Comparison with related quadridentate dinucleating diphenylphosphinomethyl (PNNPPy) and phthalazine derivatives (PNNPPh) 査読

    Gondoh Akiko, Koike Takashi, Akita Munetaka

    INORGANICA CHIMICA ACTA   374 ( 1 )   489 - 498   2011年8月

  • An M2L4 Molecular Capsule with an Anthracene Shell: Encapsulation of Large Guests up to 1 nm 査読

    Norifumi Kishi, Zhiou Li, Kenji Yoza, Munetaka Akita, Michito Yoshizawa

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   133 ( 30 )   11438 - 11441   2011年8月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1021/ja2037029

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  • Higher-dimensional and Functional Molecular Wires: Toward Molecular Circuits 査読

    Yuya Tanaka, Munetaka Akita

    JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN   69 ( 8 )   864 - 876   2011年8月

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  • Photochromic Organometallics, A Stimuli-Responsive System: An Approach to Smart Chemical Systems 査読

    Munetaka Akita

    ORGANOMETALLICS   30 ( 1 )   43 - 51   2011年1月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1021/om100959h

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  • Photo- and electro-chromic organometallics with dithienylethene (DTE) linker, L2CpM-DTE-MCpL2: Dually stimuli-responsive molecular switch 査読

    Motoyama Keiko, Li Huifang, Koike Takashi, Hatakeyama Makoto, Yokojima Satoshi, Nakamura Shinichiro, Akita Munetaka

    DALTON TRANSACTIONS   40 ( 40 )   10643 - 10657   2011年

  • Making organometallic molecular wires via oxidative ligand coupling 査読

    Johno Keita, Tanaka Yuya, Koike Takashi, Akita Munetaka

    DALTON TRANSACTIONS   40 ( 32 )   8089 - 8091   2011年

  • Highly fluorescent M2L4 molecular capsules with anthracene shells 査読

    Zhiou Li, Norifumi Kishi, Kimiko Hasegawa, Munetaka Akita, Michito Yoshizawa

    CHEMICAL COMMUNICATIONS   47 ( 30 )   8605 - 8607   2011年

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1039/c1cc12946e

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  • Dirhodium Complexes Bridged by Bis(diphenylphosphino)phthalazine (PNNPPh): Central Ring Size and Charge Effects As Compared with the Pyrazolate Derivative (PNNPPy) 査読

    Yamaguchi Takafumi, Koike Takashi, Akita Munetaka

    ORGANOMETALLICS   29 ( 23 )   6493 - 6502   2010年12月

  • Coordination Properties of Organoborate Ligands - Steric Hindrance Around the Distal Boron Center Directs the Conformation of the Dialkylbis(imidazolyl)-borate Scaffold 査読

    Shiro Hikichi, Koyu Fujita, Yoshitaka Manabe, Munetaka Akita, Jun Nakazawa, Hidehito Komatsuzaki

    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY   ( 35 )   5529 - 5537   2010年12月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1002/ejic.201000629

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  • Tuning the Stability and Reactivity of Metal-bound Alkylperoxide by Remote Site Substitution of the Ligand 査読

    Shiro Hikichi, Chiho Kobayashi, Michito Yoshizawa, Munetaka Akita

    CHEMISTRY-AN ASIAN JOURNAL   5 ( 9 )   2086 - 2092   2010年9月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1002/asia.201000183

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  • Photocatalytic Styrene Polymerization by Novel Bichromophoric Pd Catalyst Having Long Excited-state Lifetime 査読

    Kei Murata, Masaharu Ito, Akiko Inagaki, Munetaka Akita

    CHEMISTRY LETTERS   39 ( 9 )   915 - 917   2010年9月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1246/cl.2010.915

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  • Reversible, Fine Performance Tuning of an Organometallic Molecular Wire by Addition, Ligand Replacement and Removal of Dicobalt Fragments 査読

    Tanaka Yuya, Koike Takashi, Akita Munetaka

    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY   ( 23 )   3571 - 3575   2010年8月

  • m × n Stacks of Discrete Aromatic Stacks in Solution 査読

    Yoshihiro Yamauchi, Yuya Hanaoka, Michito Yoshizawa, Munetaka Akita, Takahiro Ichikawa, Masafumi Yoshio, Takashi Kato, Makoto Fujita

    Journal of the American Chemical Society   132 ( 28 )   9555 - 9557   2010年7月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1021/ja103180z

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  • Engineering Double to Quintuple Stacks of a Polarized Aromatic in Confined Cavities 査読

    Yoshihiro Yamauchi, Michito Yoshizawa, Munetaka Akita, Makoto Fujita

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   132 ( 3 )   960 - 966   2010年1月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1021/ja904063r

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  • 2-Dimensional molecular wiring based on toroidal delocalization of hexaarylbenzene 査読

    Tanaka Yuya, Koike Takashi, Akita Munetaka

    CHEMICAL COMMUNICATIONS   46 ( 25 )   4529 - 4531   2010年

  • Photochromic Organometallics with a Dithienylethene (DTE) Bridge, [Y-C C-DTE-C C-y] (Y = {MCp*(dppe)}): Photoswitchable Molecular Wire (M = Fe) versus Dual Photo- and Ellectrochromism (M = Ru) 査読

    Tanaka Yuya, Ishisaka Takuya, Inagaki Akiko, Koike Takashi, Lapinte Claude, Akita Munetaka

    CHEMISTRY-A EUROPEAN JOURNAL   16 ( 16 )   4762 - 4776   2010年

  • Acetoxybis(imidazolyl)methylborate [B(Im(N-Me))(2)(OC(=O)Me)Me](-): Carboxylation of borane moiety of imidazolyl-based scorpionate 査読

    Koyu Fujita, Munetaka Akita, Shiro Hikichi

    INORGANICA CHIMICA ACTA   362 ( 12 )   4472 - 4479   2009年9月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1016/j.ica.2009.05.007

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  • Syntheses and photophysical properties of visible-light-absorbing Ru(II) polypyridyl complexes possessing (pyridylpyrazolyl) metal tethers 査読

    Tomohide Saita, Hiroyuki Nitadori, Akiko Inagaki, Munetaka Akita

    JOURNAL OF ORGANOMETALLIC CHEMISTRY   694 ( 19 )   3125 - 3133   2009年9月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1016/j.jorganchem.2009.05.024

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  • Regioregulated Syntheses of Poly(aminopyridine)s by Pd-catalyzed Amination Reactions 査読

    Kuwabara, Junpei, Mori, Hironori, Teratani, Takuya, Akita, Munetaka, Kanbara, Takaki

    MACROMOLECULAR RAPID COMMUNICATIONS   30 ( 12 )   997 - 1001   2009年6月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:WILEY-V C H VERLAG GMBH  

    DOI: 10.1002/marc.200900033

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  • Design, Synthesis, and Catalysis of Bio-inspired Immobilized Metallocomplex Catalyst 査読

    Shiro Hikichi, Mami Kaneko, Yasuyuki Miyoshi, Noritaka Mizuno, Koyu Fujita, Munetaka Akita

    TOPICS IN CATALYSIS   52 ( 6-7 )   845 - 851   2009年6月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1007/s11244-009-9232-2

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  • Chemical Stimuli Induced Phosphorescence Modulation of Secondary Thioamide-Based Pincer Platinum Complexes 査読

    Okamoto, Ken, Yamamoto, Takakazu, Akita, Munetaka, Wada, Akihide, Kanbara, Takaki

    ORGANOMETALLICS   28 ( 11 )   3307 - 3310   2009年6月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:AMER CHEMICAL SOC  

    DOI: 10.1021/om800894j

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  • Electronic and Magnetic Couplings in Free and pi-Coordinated 1,4-Diethynylnaphthalene-Bridged [Cp*(dppe)Fe](n+) (n=0, 1) Units 査読

    Tanaka Yuya, Shaw-Taberlet Jennifer A, Justaud Frederic, Cador Olivier, Roisnel Thierry, Akita Munetaka, Hamon Jean-Rene, Lapinte Claude

    Organometallics   28 ( 16 )   4656 - 4669   2009年

  • p-Diethynylbenzene-based molecular wires, Fe-C C-p-C6H2X2-C C-Fe [Fe = Fe(eta(5)-C5Me5)( dppe)]: Synthesis, substituent effects and unexpected formation of benzodifuran complex 査読

    Matsuura Yumi, Tanaka Yuya, Akita Munetaka

    Journal of Organometallic Chemistry   694 ( 12 )   1840 - 1847   2009年

  • Structural Characterization and Oxidation Activity of a Nickel(II) Alkylperoxo Complex 査読

    Shiro Hikichi, Hideho Okuda, Yoshiko Ohzu, Munetaka Akita

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   48 ( 1 )   188 - 191   2009年

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1002/anie.200804402

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  • Synthesis of Pd Complexes Directly Linked to the Light-Absorbing [(bpy)3Ru]2+ Unit and Their Photochemical Reactions toward Styrenes 査読

    Akiko Inagaki, Hiroki Nakagawa, Munetaka Akita, Keiichi Inoue, Makoto Sakai, Masaaki Fujii

    Dalton Transactions   ( 47 )   6709 - 6723   2008年4月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1039/b809020c

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  • Syntheses of novel di- and trinucleating ligands having a triethylbenzene core with N,N-bidentate tethers: their complexation toward Pd and Rh organometallic fragments 査読

    Gou Higashihara, Akiko Inagaki, Munetaka Akita

    DALTON TRANSACTIONS   ( 14 )   1888 - 1898   2008年

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1039/b713503c

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  • Chemistry of polycarbon species: from clusters to molecular devices 査読

    Akita Munetaka, Koike Takashi

    DALTON TRANSACTIONS   ( 27 )   3523 - 3530   2008年

  • Remarkable switching behavior of bimodally stimuli-responsive photochromic dithienylethenes with redox-active organometallic attachments 査読

    Motoyama Keiko, Koike Takashi, Akita Munetaka

    CHEMICAL COMMUNICATIONS   ( 44 )   5812 - 5814   2008年

  • Synthesis of pd complexes combined with photosensitizing of a ruthenium(II) polypyridyl moiety through a series of substituted bipyrimidine bridges. Substituent effect of the bridging ligand on the photocatalytic dimerization of alpha-methylstyrene 査読

    Akiko Inagaki, Shinichi Yatsuda, Shinichi Edure, Akiko Suzuki, Takeshi Takahashi, Munetaka Akita

    INORGANIC CHEMISTRY   46 ( 7 )   2432 - 2445   2007年4月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1021/ic0612909

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  • Electronic coupling in dimetallic complexes with pi-conjugated bridge 査読

    Min-Chul Chung, Ho-Geun Ahn, Chee-Hun Kwak, Munetaka Akita

    JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY   6 ( 11 )   3347 - 3350   2006年11月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1166/jnn.2006.007

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  • New aspects of the cobalt-dioxygen complex chemistry opened by hydrotris(pyrazoly)borate ligands (TpR): Unique properties of TpRCo-dioxygen complexes 査読

    Shiro Hikichi, Munetaka Akita, Yoshihiko Moro-oka

    Coordination Chemistry Reviews   198 ( 1 )   61 - 87   2000年

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Elsevier  

    DOI: 10.1016/S0010-8545(99)00232-5

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  • Novel monoanionic tripodal ligands: Methylbis(1-methylimidazol-2-yl)(pyrazol-1-yl)borate (= [MeB(ImN-Me)2(PzR)]-). Synthesis and structural characterization of their nickel complexes and carboxylate shift from nickel to boron 査読

    Koyu Fujita, Shiro Hikichi, Munetaka Akita, Yoshihiko Moro-oka

    Journal of the Chemical Society, Dalton Transactions   ( 2 )   117 - 119   2000年

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Royal Society of Chemistry  

    DOI: 10.1039/a908181j

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  • An entry to half-sandwich complexes of first row transition metals(Ni, Co, Mn) containing the Kläui tripodal ligand, LOMe: Synthesis and crystal structures of oligomeric, [LOMeM(μ-X)(L)]n(n = 2, 4), and monomeric complexes, LOMeM(L2)(X) 査読

    De-Qiang Ma, Shiro Hikichi, Munetaka Akita, Yoshihiko Moro-oka

    Journal of the Chemical Society, Dalton Transactions   ( 7 )   1123 - 1134   2000年

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1039/a909580b

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  • Oxidative C(sp3)-C(sp3) bond cleavage reaction of an isopropyl group to give an acetyl group upon O2-treatment of a labile cationic ruthenium species, [Tp(iPr)Ru(dppene)(OH2)]+ 査読

    Yoshiaki Takahashi, Shiro Hikichi, Munetaka Akita, Yoshihiko Moro-Oka

    Chemical Communications   ( 16 )   1491 - 1492   1999年8月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Royal Society of Chemistry  

    DOI: 10.1039/a904218k

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  • Specific C-C coupling of the labile diruthenium bridging methylene complex, Cp2Ru2(μ-CH2)(CO)2(MeCN), with diazoalkanes (R2C=N2) leading to alkenyl complexes, Cp2Ru2(μ-CH=CR2)(μ-H)(CO)2, and alkenes, CH2=CR2 査読

    Munetaka Akita, Ruimao Hua, Selby A.R. Knox, Yoshihiko Moro-Oka, Sadahiro Nakanishi, Michael I. Yates

    Journal of Organometallic Chemistry   569 ( 1-2 )   71 - 83   1998年10月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Elsevier  

    DOI: 10.1016/S0022-328X(98)00775-X

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  • Two isomeric structures of hydridoruthenium complexes supported by hydrotrispyrazolylborates, TpRRu(H)(1,5-cyclooctadiene): An octahedral structure with additional 3-center-2-electron Ru-H-B interaction is more stable than a square-pyramidal structure with a κ2-TpR ligand

    Yoshiaki Takahashi, Munetaka Akita, Shiro Hikichi, Yoshihiko Moro-oka

    Organometallics   17 ( 22 )   4884 - 4888   1998年10月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:American Chemical Society  

    DOI: 10.1021/om980363w

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  • First synthesis and structural characterization of dinuclear M(III) bis(mu-oxo) complexes of nickel and cobalt with hydrotris(pyrazolyl)borate ligand 査読

    S Hikichi, M Yoshizawa, Y Sasakura, M Akita, Y Moro-Oka

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   120 ( 40 )   10567 - 10568   1998年10月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

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  • X-ray structures of chiral (salen)manganese(III) complexes: Proof of pliability of the salen ligand

    R Irie, T Hashihayata, T Katsuki, M Akita, Y Moro-oka

    CHEMISTRY LETTERS   ( 10 )   1041 - 1042   1998年10月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1246/cl.1998.1041

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  • Reductive activation of dioxygen: A new concept for the catalytic oxidation 査読

    Munetaka Akita, Yoshihiko Moro-oka

    Catalysis Today   44 ( 1-4 )   183 - 188   1998年9月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Elsevier  

    DOI: 10.1016/S0920-5861(98)00189-8

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  • Reaction of ethynediyl, butadiynediyl and ethynyl iron complexes, (η5-C5R5)(CO)2Fe-(C≢C)n-X [X=Fe(η5-C5R5)(CO)2, H; R5=Me5, Me4Et; N=1, 2], with Fe2(CO)9 leading to polynuclear C2 and C4 complexes 査読

    Munetaka Akita, Min-Chul Chung, Masako Terada, Masanori Miyauti, Masako Tanaka, Yoshihiko Moro-oka

    Journal of Organometallic Chemistry   565 ( 1-2 )   49 - 62   1998年8月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Elsevier  

    DOI: 10.1016/S0022-328X(98)00442-2

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  • Characterization of a Dinuclear Mn(II) (μ-Hydroxo)(μ-Pyrazolato) Complex and Hydrolytic Equilibrium of the Bridging Pyrazolate Ligand 査読

    Hidehito Komatsuzaki, Shinobu Ichikawa, Shiro Hikichi, Munetaka Akita, Yoshihiko Moro-oka

    Inorg. Chem.   37 ( 14 )   3652 - +   1998年7月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

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  • Bio-inorganic approach to hydrocarbon oxidation 査読

    Yoshihiko Moro-oka, Munetaka Akita

    Catalysis Today   41 ( 4 )   327 - 338   1998年6月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Elsevier  

    DOI: 10.1016/S0920-5861(98)00023-6

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  • Aliphatic C-H bond oxygenation by the Co(II)OOX species with the hindered hydrotris(pyrazolyl)borate ligand (X = Co(II), alkyl, H) 査読

    Shiro Hikichi, Hidehito Komatsuzaki, Munetaka Akita, Yoshihiko Moro-oka

    Journal of the American Chemical Society   120 ( 19 )   4699 - 4710   1998年5月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1021/ja9720523

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  • Dioxygen activation by a novel manganese(II) thiolate complex with hydrotris(3,5-diisopropylpyrazol-1-yl)borate ligand 査読

    Hidehito Komatsuzaki, Yuichi Nagasu, Kantaro Suzuki, Takao Shibpasaki, Minoru Satoh, Fujio Ebina, Shiro Hikichi, Munetaka Akita, Yoshihiko Moro-oka

    Journal of the Chemical Society - Dalton Transactions   ( 4 )   511 - 512   1998年

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Royal Society of Chemistry  

    DOI: 10.1039/a708210j

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  • Synthesis, Structural Characterization, and Extradiol Oxygenation of Iron-Catecholato Complexes with Hydrotris(pyrazolyl)borate Ligands

    Tamako Ogihara, Shiro Hikichi, Munetaka Akita, Yoshihiko Moro-oka

    Inorganic Chemistry   37 ( 11 )   2614 - 2615   1998年

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:American Chemical Society  

    DOI: 10.1021/ic9716215

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  • Synthesis and structure determination of Rh-diene complexes with the hydridotris(3,5-diisopropylpyrazolyl)borate ligand, TpiprRh(diene) (diene = cod, nbd): Dependence of the v(B-H) values on the hapticity of the Tpipr ligand (κ2 VS κ3)

    Munetaka Akita, Keisuke Ohta, Yoshiaki Takahashi, Shiro Hikichi, Yoshihiko Moro-Oka

    Organometallics   16 ( 19 )   4121 - 4128   1997年9月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:American Chemical Society  

    DOI: 10.1021/om970352n

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  • Interconversion between methylene and methylidyne-hydride species on a tetraruthenium system 査読

    Munetaka Akita, Ruimao Hua, Yoshihiko Moro-Oka

    Journal of Organometallic Chemistry   539 ( 1-2 )   205 - 207   1997年7月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Elsevier  

    DOI: 10.1016/S0022-328X(97)00023-5

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  • Characterization of a μ-η2:η2-Peroxo Dinuclear Cobalt(II) Complex 査読

    Shiro Hikichi, Hidehito Komatsuzaki, Nobumasa Kitajima, Munetaka Akita, Masahiro Mukai, Teizo Kitagawa, Yoshihiko Moro-oka

    Inorg. Chem.   36 ( 3 )   266 - &   1997年1月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

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  • Synthesis and Characterization of the Benzoylformate Ferrous Complexes with the Hindered Tris(pyrazolyl)borate Ligand as a Structural Model for Mononuclear Non-Heme Iron Enzymes 査読

    Shiro Hikichi, Tamako Ogihara, Kiyoshi Fujisawa, Nobumasa Kitajima, Munetaka Akita, Yoshihiko Moro-oka

    Inorg. Chem.   36 ( 20 )   4539-4547   1997年

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    α-ケト酸鉄(II)錯体を合成し、構造決定した。核磁気共鳴により溶液内の挙動を詳細に検討した。

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  • Photochemical C-C coupling reaction of an iron acetylide complex [Fe(η5-C5Me5)(CO)2(C≡CPh)] with alk-1-ynes (RC≡CH) leading to cyclic compounds including paramagnetic iron(I) cyclopentadienone complexes [Fe(η5-C5Me 5)(η4-2-Ph-5-R-C5H2O)] 査読

    Munetaka Akita, Masako Terada, Yoshihiko Moro-oka

    Chemical Communications   ( 3 )   265 - 266   1997年

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Royal Society of Chemistry  

    DOI: 10.1039/a606836g

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  • Some additional aspects of versatile starting compounds for cationic organoiron complexes: Molecular structure of the aqua complex [(η5-C5Me4Et)Fe(CO)2(OH2)]BF4 and solution behavior of the THF complex [(η5-C5R5)Fe(CO)2(THF)]BF4 査読

    Munetaka Akita, Masako Terada, Masako Tanaka, Yoshihiko Morooka

    Journal of Organometallic Chemistry   510 ( 1-2 )   255 - 261   1996年3月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Elsevier  

    DOI: 10.1016/0022-328X(95)05918-F

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  • C-H and Si-C bond activation on diruthenium bridging methylene complexes: Evidence for reversible oxidative addition of Si-C(sp3) bonds 査読

    Ruimao Hua, Munetaka Akita, Yoshihiko Moro-oka

    Chemical Communications   ( 4 )   541 - 542   1996年

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Royal Society of Chemistry  

    DOI: 10.1039/CC9960000541

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  • Structure expansion of the mixed-metal dicarbide cluster core in [(μ3-CC-Fp)Ru3(μ-H)(CO9)] via direct radical and thermal coupling reactions leading to higher-nuclearity (μ-C2Hx)My cluster compounds (x = 0, 1; y = 7, 8), CpFeRu6(μ5-C2)(μ5-C 2H)(CO)... 査読

    Munetaka Akita, Hideki Hirakawa, Masako Tanaka, Yoshihiko Moro-oka

    Journal of Organometallic Chemistry   485 ( 1-2 )   C14 - C17   1995年1月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1016/0022-328X(94)05044-C

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  • 1,2-H Shift on Tetranuclear Ethynyl Complexes (μ4-C2H)(η5-C5R5)FeMCo2(CO)n(M = Fe, Ru; n = 10, 11; R = H, Me)1 査読

    Munetaka Akita, Hideki Hirakawa, Kohsuke Sakaki, Yoshihiko Moro-oka

    Organometallics   14 ( 6 )   2775 - 2780   1995年

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1021/om00006a025

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  • Deoxygenative Reduction of Dimolybdenum Carbonyl Complexes Mo2(η5-C5H4R')2(CO)4 by Hydrosilane Giving Trinuclear μ3-Methylidyne and μ3-Ethylidyne Complexes, (μ3-Cr)[Mo(η5-C5H4R')(co)2]3 (r, r' = h, CH3), and Analysis of the Rotational Processes of the Mo(η5-C5H4R')(CO)2 Moieties1 査読

    Munetaka Akita, Kazumi Noda, Yoshiaki Takahashi, Yoshihiko Moro-oka

    Organometallics   14 ( 11 )   5209 - 5220   1995年

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1021/om00011a044

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  • Formation of a Trinuclear μ3-Methylidyne Complex, (μ3-CH)[MoCp(CO)2]3, through Reduction of a CO Ligand in Cp2Mo2(CO)4 by a Hydrosilane 査読

    Munetaka Akita, Kazumi Noda, Yoshihiko Moro-oka

    Organometallics   13 ( 11 )   4145 - 4147   1994年11月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1021/om00023a008

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  • Unusual reactivities of (μ-η2:η2-FPCCH)Co2(CO)6 , the adducts of... 査読

    Munetaka Akita, Masako Terada, Naomi Ishii, Hideki Hirakawa, Yoshihiko Moro-oka

    Journal of Organometallic Chemistry   473 ( 1-2 )   175 - 186   1994年6月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1016/0022-328X(94)80118-5

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  • Reaction of the Metal-Substituted Vinylidene Complex Cp′(CO)2Mn[═C═(H)–Fp*] with Excess BuLi, Giving Acylated Dinuclear Bridging Alkenyl Complexes, Cp′MnCp*Fe[μ-CH═C(E)–C(═O)Bu](μ-CO)(CO)2 (E = H, Me): Confirmation of the Intramolecular 1,2-H Shift Mechanism Proposed for the Fluxional Process of the Cationic Diiron μ-Ethynyl Complexes [{(η5-C5R5)Fe(CO)2}2(μ-C≡C–H)]BF4 査読

    Munetaka Akita, Akio Takabuchi, Masako Terada, Naomi Ishii, Masako Tanaka, Yoshihiko Moro-oka

    Organometallics   13 ( 6 )   2516 - 2520   1994年6月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1021/om00018a056

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  • Transformation of the C2H Ligand in Fp*C≡CH (Fp* = (η5-C5Me5)Fe(CO)2] into Various C2 Functional Groups via an Iron-Substituted Vinylidene Complex, (η5-C5H4Me)Mn(CO)2[═C═C(H)Fp*]: Its Amphoteric Reactivities, Structural Comparisons Relevant to 1-Alkyne-to-Vinylidene Rearrangements, and Electronic Influences on Structures of Heterobimetallic Bridging Alkynyl Complexes [(η5-C5R5)M(CO)2]2(µ-C2R) 査読

    Munetaka Akita, Naomi Ishii, Akio Takabuchi, Masako Tanaka, Yoshihiko Moro-oka

    Organometallics   13 ( 1 )   258 - 268   1994年1月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1021/om00013a039

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  • Photochemical head-to-head (R H) vs. head-to-tail dimerization (R Ph) of iron acetylide complexes (η5-C5Me5)Fe(CO)2CCR leading to a dimetallacyclopentenone and a μ-vinylidene complex 査読

    Munetaka Akita, Shuichiro Sugimoto, Masako Terada, Yoshihiko Moro-oka

    Journal of Organometallic Chemistry   447 ( 1 )   103 - 106   1993年3月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1016/0022-328X(93)80278-J

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  • Synthesis and Characterization of (CP)2Mo2(CO)4(μ-η2:η2-FP—CC—H), Adducts of Ethynyliron Complexes to (CP)2Mo2(CO)4: Their Fluxional Behavior via Reversible 1-Alkyne-Vinylidene Ligand Interconversion on a Dinuclear System and Photochemical Decarbonylation Leading to the μ3-Vinylidenyl Complexes (CP)FeCp2Mo2(CO)4(μ-CO)(μ3-CCH) 査読

    Munetaka Akita, Shuichiro Sugimoto, Akio Takabuchi, Masako Tanaka, Yoshihiko Moro-oka

    Organometallics   12 ( 8 )   2925 - 2932   1993年

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1021/om00032a013

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  • Interaction of Iron Ethynyl and Ethynediyl Complexes with Cp2Ni2(CO)2: Formation of Tri- and Tetranuclear Adducts with a Multiply Bridging C2H Ligand 査読

    Munetaka Akita, Masako Terada, Masako Tanaka, Yoshihiko Moro-oka

    Organometallics   11 ( 10 )   3468 - 3472   1992年10月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1021/om00046a058

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  • Preparation, Characterization, and Sequential Transformation of Dicarbide Cluster Compounds with Permetalated Ethyne, Ethene, and Ethane Structures 査読

    Munetaka Akita, Shuichiro Sugimoto, Masako Tanaka, Yoshihiko Moro-oka

    Journal of the American Chemical Society   114 ( 19 )   7581 - 7582   1992年9月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1021/ja00045a051

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  • Interaction of Ethynyliron (Fp-C≡C-H and Fp*-C≡C-H) and Ethynediyldiiron Complexes (Fp*-C≡C-Fp*) with Co2(CO)8: Formation of a Cluster Compound Which Is Fluxional via a Metal-Metal Bond Scission and Recombination Process 査読

    Munetaka Akita, Masako Terada, Yoshihiko Moro-oka

    Organometallics   11 ( 5 )   1825 - 1830   1992年5月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1021/om00041a016

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  • Oxymethylation of Alkyliron Complex CpFe(CO)2-R with Hydrostannane and -silane, Leading to R-CH2OH Derivatives: Related Reactions of CpFe(CO)(L)-R and CpFe(CO)(L)-C(O)R Type Organoiron Complexes and the Molecular Structure of trans-CpFe(H)(CO)(SnPh3)2 査読

    Munetaka Akita, Tomoharu Oku, Masako Tanaka, Yoshihiko-Oka Moro

    Organometallics   10 ( 9 )   3080 - 3089   1991年9月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1021/om00055a021

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  • Oxidative Addition of Allylic Halides to Ruthenium(II) Compounds. Preparation, Reactions, and X-ray Crystallographic Structure of Ruthenium(IV)-Allyl Complexes 査読

    Hideo Nagashima, Katsunori Mukai, Yusuke Shiota, Keitaro Yamaguchi, Ken-Ichi Ara, Takahiko Fukahori, Hiroharu Suzuki, Munetaka Akita, Yoshihiko Moro-Oka, Kenji Itoh

    Organometallics   9 ( 3 )   799 - 807   1990年

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1021/om00117a041

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  • Preparation, Structure, and Divergent Fluxional Behavior of Cationic Dinuclear Iron Acetylides [Fp*2(C=C–R)]BF4 (R = H, Ph) 査読

    Munetaka Akita, Masako Tarada, Shuji Oyama, Yoshihiko Morooka

    Organometallics   9 ( 3 )   816 - 825   1990年

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1021/om00117a043

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  • Reactivities of ketene ligands on polymetallic systems 査読

    Munetaka Akita, Hitoshi Andoh, Osamu Mitani, Tomoharu Oku, Yoshihiko Moro-Oka

    Journal of molecular catalysis   56 ( 1 )   107 - 116   1989年

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1016/0304-5102(89)80176-2

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  • Crystal structures of Di-iron μ-η2-(C,C)-ketene complexes, [{Fe(η5-C5H5)(CO)2} 2(μ-CH2CO)] and [{Fe(η5-C5Me5)(CO)2} 2(μ-CH2CO)]. 査読

    Munetaka Akita, Atsuo Kondoh, Yoshihiko Moro-Oka

    Journal of the Chemical Society, Dalton Transactions   ( 6 )   1083 - 1087   1989年

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1039/DT9890001083

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  • Molecular structure of heterobimetallic μ-η&lt;sup&gt;2&lt;/sup&gt;-(C,C)-ketene complexes 査読

    Munetaka Akita, Atsuo Kondoh, Yoshihiko Moro-Oka

    Journal of the Chemical Society, Dalton Transactions   ( 8 )   1627 - 1630   1989年

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1039/DT9890001627

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  • One-pot synthesis of transition metal-substituted carboxylic acids 査読

    Munetaka Akita, Noboru Kakinuma, Yoshihiko Moro-oka

    Journal of Organometallic Chemistry   348 ( 1 )   91 - 94   1988年6月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1016/0022-328X(88)80342-5

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  • Metal-exchange reaction on cationic diiron μ-η2-(C,O)-enolate complexes 査読

    Munetaka Akita, Masako Terada, Yoshihiko Moro-oka

    Journal of Organometallic Chemistry   345 ( 1-2 )   C9 - C12   1988年5月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1016/0022-328X(88)80256-0

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  • Preparation of Homo- and Heterobimetallic μ-η2-(C,C)-Ketene Complexes, FpCH2COMLn, and Transformation of the Bridging Ketene Ligand into Various C2 Functional Groups 査読

    Munetaka Akita, Atsuo Kondoh, Takashi Kawahara, Takenobu Takaai, Yoshihiko Moro-oka

    Organometallics   7 ( 2 )   366 - 374   1988年

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1021/om00092a019

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▼全件表示

書籍等出版物

  • ハートウィグ有機遷移金属化学

    小宮三四郎, 穐田宗隆, 岩澤伸治( 担当: 共訳)

    東京化学同人  2014年4月 

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  • ハウスクロフト無機化学

    巽和行, 西原寛, 穐田宗隆, 酒井健( 担当: 共訳)

    東京化学同人  2012年3月 

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  • Polynuclear Iron Compounds: Compounds without Hydrocarbyl Ligands (Vol. 6, Chapter 3.2) in Comprehensive Organometallic Chemistry III

    Elsevier  2007年 

     詳細を見る

  • Polynuclear Iron Compounds: Compounds with Hydrocarbyl Ligands (Vol. 6, Chapter 3.1) in Comprehensive Organometallic Chemistry III

    Elsevier  2007年 

     詳細を見る

  • 生物無機化学

    三共出版  2005年 

     詳細を見る

  • Polynuclear Iron Compounds with Hydrocarbyl Ligands

    Pergamon  1995年 

     詳細を見る

  • Polynuclear Iron Compounds with Hydrocarbyl Ligands

    Pergamon  1995年 

     詳細を見る

▼全件表示

MISC

  • Dawn of photoredox catalysis

    Munetaka AKITA

    Proceedings of the Japan Academy, Series B   101 ( 5 )   274 - 301   2025年5月

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    出版者・発行元:Japan Academy  

    DOI: 10.2183/pjab.101.019

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  • Progress in Photocatalysis for Organic Chemistry

    Munetaka Akita, Paola Ceroni, Corey R. J. Stephenson, Géraldine Masson

    The Journal of Organic Chemistry   88 ( 10 )   6281 - 6283   2023年5月

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    出版者・発行元:American Chemical Society (ACS)  

    DOI: 10.1021/acs.joc.3c00812

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  • Visible‐Light‐Driven C-H Bond Functionalization of Amine Derivatives

    Munetaka Akita

    Handbook of CH-Functionalization   1 - 35   2022年10月

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    出版者・発行元:Wiley  

    Abstract

    Recent developments in CH bond functionalization of amine derivatives driven by visible‐light photoredox catalysis ( PRC ) are summarized. PRC promotes the generation of organic radicals via single‐electron transfer (SET) under mild reaction conditions. Functionalizations are categorized according to the four reactive intermediates generated by PRC : N‐centered radicals (aminium cation radicals and aminyl radicals) and C‐centered active species (iminium cations and α‐aminoalkyl radicals). The radical‐generating systems by PRC can be combined with other catalytic systems such as cross‐coupling and hydrogen atom transfer (HAT) to lead to more sophisticated dual and triple catalytic systems, which result in efficient functionalization of the hydrocarbyl substituents in amines. In addition to PRC , energy transfer and electron donor–acceptor complex have attracted increasing attention as alternative utilization methods of visible‐light energy. Reactions of relevant amide and imine derivatives are also included.

    DOI: 10.1002/9783527834242.chf0210

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    その他リンク: https://onlinelibrary.wiley.com/doi/full-xml/10.1002/9783527834242.chf0210

  • Carbon-rich organometallics: Application to molecular electronics

    Munetaka Akita, Yuya Tanaka

    Coordination Chemistry Reviews   461   214501 - 214501   2022年6月

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    出版者・発行元:Elsevier BV  

    DOI: 10.1016/j.ccr.2022.214501

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  • 可視光フォトレドックス触媒によるトリフルオロメチル化反応

    小池隆司, 穐田宗隆

    CSJ Current Review   ( 43 )   2022年

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  • Modern Synthetic Strategies for One-Electron Injection

    Takashi Koike, Munetaka Akita

    TRENDS IN CHEMISTRY   3 ( 5 )   416 - 427   2021年5月

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    記述言語:英語   掲載種別:書評論文,書評,文献紹介等  

    DOI: 10.1016/j.trechm.2021.02.006

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  • Photocatalytic introduction of fluorinated groups

    T. Koike, M. Akita

    Science of Synthesis   6   559 - 574   2018年1月

  • Cover Picture: Photocatalytic Trifluoromethylthiolation of Aromatic Alkenes Associated with Hydroxylation and Alkoxylation (Asian J. Org. Chem. 4/2017) 査読

    Yanjie Li, Takashi Koike, Munetaka Akita

    Asian Journal of Organic Chemistry   6 ( 4 )   347   2017年4月

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    出版者・発行元:Wiley  

    DOI: 10.1002/ajoc.201700003

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  • Two-dimensional Charge Delocalization of a Tetraruthenium Complex bearing a Nickel Porphyrin Ligand.

    TANAKA Yuya, MISHIBA Kentaro, ONO Masanori, AKITA Munetaka

    錯体化学会討論会講演要旨集   66th   80   2016年8月

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    記述言語:英語  

    J-GLOBAL

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  • 酸化還元活性なRuアセチリド置換基を有するNiポルフィリン錯体の酸化に伴う芳香族性の変化

    三柴健太郎, 田中裕也, 穐田宗隆

    日本化学会講演予稿集   95th ( 4 )   1102   2015年3月

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    記述言語:日本語  

    J-GLOBAL

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  • Synthesis and Property of Ni Porphyrin Molecular Junction Bearing Four Ru Centers

    MISHIBA Kentaro, TANAKA Yuya, AKITA Munetaka

    Symp Organomet Chem Jpn   61st   86   2014年9月

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    記述言語:英語  

    J-GLOBAL

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  • Trifluoromethylation by photoredox catalysis

    Munetaka Akita, Takashi Koike

    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY   248   2014年8月

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    記述言語:英語   掲載種別:研究発表ペーパー・要旨(国際会議)  

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  • メタロポルフィリン骨格を有する有機金属分子ワイヤーの合成と機能化

    田中裕也, 小野勝則, 三柴健太郎, 小池隆司, 穐田宗隆

    錯体化学会討論会講演要旨集   63rd   89   2013年10月

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    記述言語:日本語  

    J-GLOBAL

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  • 東京工業大学 資源化学研究所穐田(あきた)・吉沢 研究室 : かしこい分子を作る!

    穐田 宗隆, 吉沢 道人

    觸媒 = Catalyst   55 ( 3 )   180 - 180   2013年6月

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    記述言語:日本語  

    CiNii Books

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  • Wide-Ranging Host Capability of a Pd-II-Linked M2L4 Molecular Capsule with an Anthracene Shell

    Norifumi Kishi, Zhiou Li, Yoshihisa Sei, Munetaka Akita, Kenji Yoza, Jay S. Siegel, Michito Yoshizawa

    CHEMISTRY-A EUROPEAN JOURNAL   19 ( 20 )   6313 - 6320   2013年5月

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    記述言語:英語   掲載種別:書評論文,書評,文献紹介等  

    DOI: 10.1002/chem.201204010

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  • 機能性有機金属分子ワイヤーの合成とその可能性 (特集 もし『分子ワイヤー』とそのマテリアルが実用化されたら?)

    小池 隆司, 穐田 宗隆

    Material stage   12 ( 12 )   9 - 12   2013年3月

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    記述言語:日本語   出版者・発行元:技術情報協会  

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  • Visible-light promoted bimetallic catalysis

    Akiko Inagaki, Munetaka Akita

    COORDINATION CHEMISTRY REVIEWS   254 ( 11-12 )   1220 - 1239   2010年6月

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    記述言語:英語   掲載種別:書評論文,書評,文献紹介等  

    DOI: 10.1016/j.ccr.2009.11.003

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  • π共役架橋配位子を有する有機金属分子ワイヤー (特集 未来技術基盤としてのパイ電子科学)

    小池 隆司, 穐田 宗隆

    化学工業   60 ( 11 )   827 - 835   2009年11月

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    記述言語:日本語   出版者・発行元:化学工業社  

    CiNii Books

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  • Discrete stack of an odd number of polarized aromatic compounds revealing the importance of net vs. local dipoles

    Yoshihiro Yamauchi, Michito Yoshizawa, Munetaka Akita, Makoto Fujita

    PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA   106 ( 26 )   10435 - 10437   2009年6月

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  • Electrophilic Substitution of Thiophenes with Arylpalladium(II) and Platinum(II) Complexes: Mechanistic Studies on Palladium-Catalyzed CH Arylation of Thiophenes

    Atsushi Sugie, Hirotoshi Furukawa, Yuji Suzaki, Kohtaro Osakada, Munetaka Akita, Daiki Monguchi, Atsunori Mori

    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN   82 ( 5 )   555 - 562   2009年5月

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  • Spin Crossover by Encapsulation

    Kosuke Ono, Michito Yoshizawa, Munetaka Akita, Tatsuhisa Kato, Yoshihide Tsunobuchi, Shin-ichi Ohkoshi, Makoto Fujita

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   131 ( 8 )   2782 - +   2009年3月

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  • Photoinduced Oxyamination of Enamines and Aldehydes with TEMPO Catalyzed by [Ru(bpy)(3)](2+)

    Takashi Koike, Munetaka Akita

    CHEMISTRY LETTERS   38 ( 2 )   166 - 167   2009年2月

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  • Spin Crossover by Encapsulation

    K. Ono, M. Yoshizawa, M. Akita, T. Kato, Y. Tsunobuchi, S. Ohkoshi, M. Fujita

    J. Am. Chem. Soc.   131 ( 8 )   2782 - 2783   2009年

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  • Switchable trans窶田is interconversion of an amphiphilic anthracene trimer

    Junji Iwasa, Kosuke Ono, Makoto Fujita, Munetaka Akita, Michito Yoshizawa

    Chemical Communications   ( 38 )   5746 - 5748   2009年

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  • π 共役架橋配位子を有する有機金属分子ワイヤー

    小 池 隆 司, 穐田 宗隆

    化学工業 特 集 未来技術基盤としてのパイ電子科学   60 ( 11 )   11 - 19   2009年

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  • Switchable trans-cis interconversion of an amphiphilic anthracene trimer

    Junji Iwasa, Kosuke Ono, Makoto Fujita, Munetaka Akita, Michito Yoshizawa

    CHEMICAL COMMUNICATIONS   ( 38 )   5746 - 5748   2009年

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  • Electrophilic substitution of platinum(II) complexes with thiophene derivatives

    Atsunori Mori, Atsushi Sugie, Hirotoshi Furukawa, Yuji Suzaki, Kohtaro Osakada, Munetaka Akita

    CHEMISTRY LETTERS   37 ( 5 )   542 - 543   2008年5月

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  • Preparation and photochemical behavior of organoruthenium derivatives of photochromic dithienylethene (DTE):

    Kazunori Uchida, Akiko Inagaki, Munetaka Akita

    Organometallics   26 ( 20 )   5030 - 5041   2007年9月

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    記述言語:英語  

    DOI: 10.1021/om700537s

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  • Preparation and photochemical behavior of organoruthenium derivatives of photochromic dithienylethene (DTE): DTE-(RRuLm)(n) (RRuLm = (eta(6)-C6H5)Ru(eta(5)-C5Me5), (eta(6)-C6H5)RuCl2(PPh3), (eta(5)-C5Me4)Ru(CO)(2); n = 1, 2)

    Kazunori Uchida, Akiko Inagaki, Munetaka Akita

    ORGANOMETALLICS   26 ( 20 )   5030 - 5041   2007年9月

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  • Photo-activation of Pd-catalyzed Sonogashira coupling using a Ru/bipyridine complex as energy transfer agent

    Masahisa Osawa, Hidetada Nagai, Munetaka Akita

    DALTON TRANSACTIONS   ( 8 )   827 - 829   2007年2月

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  • Ruthenium and chromium complexes bearing pH-indicators as the eta(6)-arene ligand: Synthesis, characterization, and protonation behavior

    Miyuki Hirasa, Akiko Inagaki, Munetaka Akita

    JOURNAL OF ORGANOMETALLIC CHEMISTRY   692 ( 1-3 )   93 - 110   2007年1月

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  • C-C coupling of a permetalated ethene, (mu(4)-C=C)Ru-2(FeCp*)(2)(CO)(10), with alkynes, and isolation of a labile MeCN adduct, (mu(4)-C=C)Ru-2(FeCp*)(2)(CO)(8)(NCMe)(2)

    Gou Higashihara, Masako Terada, Akiko Inagaki, Munetaka Akita

    ORGANOMETALLICS   26 ( 2 )   439 - 444   2007年1月

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  • Redox-active polyiron complexes with tetra(ethynylphenyl) ethene and [2,2]paracyclophane spacers containing ethynylphenyl units: extension to higher dimensional molecular wire

    Yuya Tanaka, Takehiro Ozawa, Akiko Inagaki, Munetaka Akita

    DALTON TRANSACTIONS   ( 9 )   928 - 933   2007年

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  • A photoswitchable molecular wire with the dithienylethene (DTE) linker, (dppe)(g5-C5Me5)Fe窶鼎MC窶泥TE窶鼎MC窶擢e(g5-C5Me5)(dppe){

    Yuya Tanaka, Akiko Takao(Inagaki, MUNETAKA AKITA

    Chemical Communications   ( 11 )   1169 - 1171   2007年

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  • A photoswitchable molecular wire with the dithienylethene (DTE) linker, (dppe)(eta(5)-C5Me5)Fe-C C-DTE-C C-Fe(eta(5)-C5Me5)(dppe)

    Yuya Tanaka, Akiko Inagaki, Munetaka Akita

    CHEMICAL COMMUNICATIONS   ( 11 )   1169 - 1171   2007年

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  • Hydrogen bonding interaction between imidazolyl N-H group and peroxide: Stabilization of Mn(III)-peroxo complex Tp(iPr2)Mn(eta(2)-O2)(im(Me)H) (im(Me)H=2-methylimidazole)

    Udai P. Singh, Asish K. Sharma, Shiro Hikichi, Hidehito Komatsuzaki, Yoshihiko Moro-oka, Munetaka Akita

    INORGANICA CHIMICA ACTA   359 ( 13 )   4407 - 4411   2006年10月

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  • Synthesis of a series of diiron complexes based on a tetraethynylethene skeleton and related C-6-enediyne spacers, (dppe)Cp*Fe-C CC(R)=C(R) C C-FeCp*(dppe): Tunable molecular wires

    Munetaka Akita, Yuya Tanaka, Chie Naitoh, Takehiro Ozawa, Nobuhiko Hayashi, Makoto Takeshita, Akiko Inagaki, Min-Chul Chung

    ORGANOMETALLICS   25 ( 22 )   5261 - 5275   2006年10月

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    記述言語:英語   掲載種別:書評論文,書評,文献紹介等  

    DOI: 10.1021/om060403t

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  • Synthesis of a Series of Diiron Complexes Based on Tetraethynylethene Skeleton and Related C6-Endiyne Spacers, (dppe)Cp*Fe-C∫C-C(R)=C(R)-C∫C-FeCp*(dppe): Tunable Molecular Wires.

    AKITA Munetaka, TANAKA Yuya, NAITOH Chie, OZAWA Takehiro, HAYASHI Nobuhiko, TAKESHITA Makoto, INAGAKI Akiko, CHUNG Min‐Chul

    Organometallics   25 ( 22 )   5261 - 5275   2006年10月

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    記述言語:英語   掲載種別:書評論文,書評,文献紹介等  

    DOI: 10.1021/om060403t

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  • Chelation-Assisted Facile C-N Bond Oxidative Addition of Spironaphthoxazines Photochromic by Ru(h4-cycloocta-1,5-diene)(h6-naphthalene)

    Kaori Takano, Akiko, Inagaki, Munetaka Akita

    Chem. Lett.   35 ( 4 )   434 - 435   2006年4月

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  • Chelation-assisted facile C-N bond oxidative addition of spironaphthoxazines by Ru (eta(4)-cycloocta-1,5-diene)(eta(6)-naphthalene)

    Kaori Takano, Akiko Inagaki, Munetaka Akita

    CHEMISTRY LETTERS   35 ( 4 )   434 - 435   2006年4月

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  • Synthesis of a library of iridium-containing dinuclear complexes with bridging PNNN and PNNP ligands (BL), [LM(mu-BL)M ' L ']BF4. 1. Specific synthesis of isomeric heterodinuclear complexes with switched metal arrangements

    C Dubs, T Yamamoto, A Inagaki, M Akita

    ORGANOMETALLICS   25 ( 6 )   1344 - 1358   2006年3月

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  • Synthesis of a library of iridium-containing dinuclear complexes with bridging PNNN and PNNP ligands (BL), [LM(mu-BL)M ' L ']BF4. 2. Preparation, basic coordination properties, and reactivity of the carbonyl complexes

    C Dubs, T Yamamoto, A Inagaki, M Akita

    ORGANOMETALLICS   25 ( 6 )   1359 - 1367   2006年3月

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  • A new method for the conversion of allyl alcohol into pi-allyl species promoted by nucleophilic interaction with a CO ligand

    C Dubs, T Yamamoto, A Inagaki, M Akita

    CHEMICAL COMMUNICATIONS   ( 18 )   1962 - 1964   2006年

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  • Xenophilic Complexes Bearing a TpR Ligand, TpRM-MユLn [TpR= TpiPr2, Tp# (TpMe2,4-Br); M= Ni, Co, Fe, Mn; MユLn= Co(CO)4, Co(CO)3(PPh3), RuCp(CO)2]: The Two Metal Centers are Held Together not by Covalent Interaction but by Electrostatic Attraction.

    Kazuhiro Uehara, Shiro Hikichi Akiko Inagaki, Munetaka Akita

    Chem. A Eur. J.   11 ( 9 )   2788 - 2809   2005年4月

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    記述言語:英語   掲載種別:書評論文,書評,文献紹介等  

    DOI: 10.1002/chem.200401016

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  • Xenophilic complexes bearing a Tp(R) ligand, [Tp(R)M-M'L-n] [Tp(R) =Tp(iPr2), Tp(#) (Tp(Me2,4-Br)); M = Ni, Co, Fe, Mn; M'L-n =CO(CO)(4), CO(CO)(3)(PPh3), RuCp(CO)(2)]: The two metal centers are held together not by covalent interaction but by electrostatic attraction

    K Uehara, S Hikichi, A Inagaki, M Akita

    CHEMISTRY-A EUROPEAN JOURNAL   11 ( 9 )   2788 - 2809   2005年4月

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    記述言語:英語   掲載種別:書評論文,書評,文献紹介等  

    DOI: 10.1002/chem.200401016

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  • Polynuclear rhodium complexes with dinucleating PNNP ligand: Dynamic and diverse M center dot center dot center dot M interactions in [(mu-X)Rh-2(PNNP)(CO)(2)](n+) and [(mu(4)-X)Rh-4(PNNP)(2)(CO)(4)](n+) [X = H, O, C C-R, R-C C-R, C C, CH=CH2, SMe2; n=0, 1 : PNNP=3,5-bis(diphenylphosphinomethyl)pyrazolato]

    S Tanaka, C Dubs, A Inagaki, M Akita

    ORGANOMETALLICS   24 ( 1 )   163 - 184   2005年1月

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  • Polynuclear Rhodium Complexes with Dinucleating PNNP Ligand: Dynamic and Diverse M--M Interactions in [(m-X)Rh2(PNNP)(CO)2]n+ and [(m4-X)Rh4(PNNP)2(CO)4]n+ [X= H, O, CコC-R, R-CコC-R, CコC, CH=CH2, SMe2; n= 0, 1: PNNP= 3,5-bis(diphenylphosphinomethyl)pyra・・・

    TANAKA S, DUBS C, INAGAKI A, AKITA M

    Organometallics   24 ( 1 )   163 - 184   2005年1月

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  • Highly selective photo-catalytic dimerization of alpha-methylstyrene by a novel palladium complex with photosensitizing ruthenium(II) polypyridyl moiety

    A Inagaki, S Edure, S Yatsuda, M Akita

    CHEMICAL COMMUNICATIONS   ( 43 )   5468 - 5470   2005年

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  • Coordinatively unsaturated organometallic system based on Tp ligand: tetrahedral Tp(R)M-R ' and Tp(R)M-M ' L-n species

    M Akita

    JOURNAL OF ORGANOMETALLIC CHEMISTRY   689 ( 24 )   4540 - 4551   2004年11月

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  • Tetrakis(trimethylsilylbutadiynyl)ethene, C-18(SiMe3)(4): An extended two-dimensional pi-conjugated system consisting of eighteen carbon atoms

    T Ozawa, M Akita

    CHEMISTRY LETTERS   33 ( 9 )   1180 - 1181   2004年9月

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  • Oxygenation of a low valent rhodium complex, Tp(iPr2) Rh(dppe): sequential conversion of molecular oxygen into peroxo and hydroperoxo complexes and characterization of the peroxo species

    Y Takahashi, M Hashimoto, S Hikichi, Y Moro-oka, M Akita

    INORGANICA CHIMICA ACTA   357 ( 6 )   1711 - 1724   2004年4月

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  • Tetranuclear Complexes Based on Dynamic Metal-metal Linkage, [(μ_4_-X)Rh_4_(CO)_4_(PNNP)_2_] ^n+ ^ [X / n= R-CC / 1 (Acetylide), C_2_ / 0 (Dicarbide)]

    Shukichi Tanaka Christian Dubs Akiko, Inagaki, Munetaka Akita

    Organometallics   23 ( 3 )   317 - 319   2004年2月

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  • Tetranuclear complexes based on a dvnamic metal-metal linkage, [(mu 4-X)Rh-4(CO)(4)(PNNP)(2)](n+) (X/n = RC equivalent to C/1 (acetylide), C-2/0 (dicarbide))

    S Tanaka, C Dubs, A Inagaki, M Akita

    ORGANOMETALLICS   23 ( 3 )   317 - 319   2004年2月

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  • Oxygenation of a Series of Cationic Aquoruthenium Complexes, Tp^iPr2^Ru(OH_2_)_n_L_3-n_・CF_3_SO_3_(THF)_x_, Leading to Mono- and Dinuclear Aquo-hydroxo Complexes Supported by Unique Hydrogen Bonding Networks

    Yoshiaki Takahashi, Shiro Hikichi Yoshihiko Moro-oka, Munetaka Akita

    Polyhedron   23 ( 2-3 )   225 - 234   2004年1月

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  • Oxygenation of a series of cationic aquoruthenium complexes, Tp(iPr2)Ru(OH2)(n)L3-n center dot CF3SO3 center dot (THF)(x), leading to mono- and dinuclear aquo-hydroxo complexes supported by unique hydrogen bonding networks

    Y Takahashi, S Hikichi, Y Moro-oka, M Akita

    POLYHEDRON   23 ( 2-3 )   225 - 234   2004年1月

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  • Selective synthesis of isomeric heterodinuclear complexes with switched metal arrangements via proton-induced reversible metal migration

    C Dubs, A Inagaki, M Akita

    CHEMICAL COMMUNICATIONS   ( 23 )   2760 - 2761   2004年

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  • Selective synthesis of isomeric heterodinuclear complexes with switched metal arrangements via proton-induced reversible metal migration

    C Dubs, A Inagaki, M Akita

    CHEMICAL COMMUNICATIONS   ( 23 )   2760 - 2761   2004年

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  • Coordinatively Unsaturated Organometallic System Based on Tp ligand: Tetrahedral Tp^R^M-R' and Tp ^R ^M-M'L_n_ Species

    MUNETAKA AKITA

    J. Organomet. Chem.   689 ( 24 )   4540 - 4551   2004年

  • μ_4_-Dicarbyne Complex with a Dimetallacyclobutatriene Core: A New Binding Mode of C_2_ Species

    Masako Terada Gou Higashihara Akiko, Inagaki, Munetaka Akita

    Chem. Commun.   ( 24 )   2984 - 2985   2003年12月

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  • mu 4-dicarbyne complex with a dimetallacyclobutatriene core: A new binding mode of C-2 species

    M Terada, G Higashihara, A Inagaki, M Akita

    CHEMICAL COMMUNICATIONS   ( 24 )   2984 - 2985   2003年12月

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  • Interaction of Hydroperoxopalladium Complexes, (Tp^R^)(py)Pd-OOH, with Hydroxonickel and -cobalt Complexes, [(μ-OH)(MTp^R^)]_2_ (M= Ni, Co), Leading to Oxidative Dehydrogenation of the Saturated Hydrocarbyl Moiety in the Ancillary Ligand (Tp^iPr2^).

    Masato Kujime, Shiro Hikichi Munetaka Akita

    Dalton Trans.   ( 18 )   3506 - 3515   2003年9月

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  • Interaction of hydroperoxopalladium complexes, (Tp(R))(py)Pd-OOH, with hydroxo-nickel and -cobalt complexes, [(mu-OH)(MTp(R '))](2) (M = Ni, Co), leading to oxidative dehydrogenation of the saturated hydrocarbyl moiety in the ancillary ligand (Tp(iPr2))

    M Kujime, S Hikichi, M Akita

    DALTON TRANSACTIONS   ( 18 )   3506 - 3515   2003年9月

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  • Enolato-cobalt and -nickel Complexes Bearing Tp^iPr2^ Ligand, [Tp^iPr2^M(XCHY)]_n_ [Tp^iPr2^= Hydrotris(3,5-diisopropylpyrazolyl)borato; n= 1, 2], Obtained from Hydroxometal Complexes, (μ-OH)_2_(MTp^iPr2^)_2_, and Active Methylene Compounds, CH_2_XY.

    Masato Kujime, Shiro Hikichi Munetaka Akita

    Inorg. Chim. Acta   350   163 - 174   2003年7月

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  • Synthesis and characterization of enolato-cobalt and -nickel complexes bearing Tp(2)(iPr) ligand, [Tp(iPr2)M(XCHY)](n) [Tp(iPr2) = hydrotris(3,5-diisopropylpyrazolyl)borato; n=1, 2], obtained from hydroxometal complexes, (mu-OH)(2)(MTp(iPr2))(2), and active methylene compounds, CH2XY

    M Kujime, S Hikichi, M Akita

    INORGANICA CHIMICA ACTA   350   163 - 174   2003年7月

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  • Conversion of a hydroperoxo complex, (Tp(iPr2))(py)Pd-OOH, into a cyclic alkylperoxo complex, [HB(pz(iPr2))(2)(pz-3-CMe2-5-i-Pr)](py)Pd-OO, catalyzed by Cu(II) species [Tp(iPr2): Hydrotris(3,5-diisopropylpyrazolyl)borato]

    M Kujime, S Hikichi, M Akita

    CHEMISTRY LETTERS   32 ( 6 )   486 - 487   2003年6月

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  • Cluster compounds containing a linear carbon chain derived from polyynediyl and polyynyl complexes, Fp*-(C C)(n)-X [X = Fp*, H; Fp* = Fe(eta(5)-C5Me5)(CO)(2)]

    M Akita, A Sakurai, MC Chung, Y Moro-oka

    JOURNAL OF ORGANOMETALLIC CHEMISTRY   670 ( 1-2 )   2 - 10   2003年3月

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    記述言語:英語   掲載種別:書評論文,書評,文献紹介等  

    DOI: 10.1016/S0022-328X(02)02067-3

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  • Cluster Compounds Containing a Linear Carbon Chain Derived from Polyynediyl and Polyynyl Complexes, Fp*-(C≡C)_n_-X [X= Fp*, H; Fp*=Fe(η^5^-C_5_Me_5_)(CO)_2_]

    Munetaka Akita Aizoh, Sakurai Min-Chul Chung, Yoshihiko Moro-oka

    J. Organomet. Chem.   670 ( 1-2 )   2 - 10   2003年3月

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    記述言語:英語   掲載種別:書評論文,書評,文献紹介等  

    DOI: 10.1016/S0022-328X(02)02067-3

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  • Formal hydrogenation of a permetalated ethene, (mu(4)-C=C)Fe2Ru2(eta(5)-C5Me5)(2)(CO)(8)(dppm), via successive protonation-hydride reduction leading to C2Hn cluster compounds

    M Terada, M Akita

    ORGANOMETALLICS   22 ( 2 )   355 - 364   2003年1月

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  • Formal Hydrogenation of a Permetalated Ethene, (μ_4_-C=C)Fe_2_Ru_2_(η^5^-C_5_Me_5_)_2_(CO)_8_(dppm), via Successive Protonation-Hydride Reduction Leading to C_2_H_n_ Cluster Compounds

    Masako Terada, Munetaka Akita

    Organometallics   22 ( 2 )   355 - 364   2003年1月

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  • A peroxochromium complex, Tp(2)(iPr)Cr(O-2)(2), obtained by oxidative dehydrative condensation between a dihydroxochromium complex and H2O2 [Tp(2)(iPr) = hydrotris(3,5-diisopropylpyrazolyl)borato]

    K Sugawara, M Akita, M Akita

    DALTON TRANSACTIONS   ( 22 )   4346 - 4355   2003年

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  • Reactivity control of a dinuclear xenophilic species, Tp(#)Ni-RuCp(CO)(2), via spin crossover across a metal-metal bond [Tp(#): hydrotris(4-bromo-3,5-dimethylpyrazolyl)borato]

    K Uehara, S Hikichi, M Akita

    CHEMISTRY LETTERS   ( 12 )   1198 - 1199   2002年12月

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  • Reactivity control of a dinuclear xenophilic species, Tp(#)Ni-RuCp(CO)(2), via spin crossover across a metal-metal bond [Tp(#): hydrotris(4-bromo-3,5-dimethylpyrazolyl)borato]

    K Uehara, S Hikichi, M Akita

    CHEMISTRY LETTERS   ( 12 )   1198 - 1199   2002年12月

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  • Synthesis and characterization of a series of (Hydroperoxo)-, (Alkylperoxo)-, and (,mu-Peroxo)palladium complexes containing the hydrotris(3,5-diisopropylpyrazolyl)borato ligand (Tp(iPr2)): (Tp(iPr2))(py)Pd-OO-X [X = H, t-Bu, Pd(Tp(iPr2))(py)] and (Tp(iPr2))(py)Pd-(mu-K-1 : K 2-OO)-PdTp(iPr2)

    T Miyaji, M Kujime, S Hikichi, Y Moro-oka, M Akita

    INORGANIC CHEMISTRY   41 ( 20 )   5286 - 5295   2002年10月

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  • Synthesis and Characterization of a Series of Hydroperoxo-, Alkylperoxo- and μ-Peroxo-palladium Complexes Containing Hydrotris(3,5-diisopropylpyrazolyl)borato Ligand (Tp^iPr2^), (Tp^iPr2^)(py)Pd-OO-X [X= H, t-Bu, Pd(Tp^iPr2^)(py)] and (Tp^iPr2^)(py)Pd-・・・

    Masato Kujime, Shiro Hikichi Munetaka Akita

    Inorg. Chem.   41 ( 20 )   5286 - 5295   2002年10月

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  • Synthesis and characterization of coordinatively unsaturated alkynyl- and aryl-cobalt complexes with 15 valence electrons, Tp(iPr2)Co-R, bearing the hydrotris(3,5-diisopropylpyrazolyl)borato ligand (Tp(iPr2))

    S Yoshimitsu, S Hikichi, M Akita

    ORGANOMETALLICS   21 ( 18 )   3762 - 3773   2002年9月

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  • Inorganic chemistry based on Tp ligands - From dioxygen complexes to organometallic systems

    Munetaka Akita, Shiro Hikichi

    Bulletin of the Chemical Society of Japan   75 ( 8 )   1657 - 1679   2002年8月

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    記述言語:英語  

    DOI: 10.1246/bcsj.75.1657

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  • Inorganic chemistry based on Tp Ligands - From dioxygen complexes to organometallic systems

    M Akita, S Hikichi

    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN   75 ( 8 )   1657 - 1679   2002年8月

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    記述言語:英語   掲載種別:書評論文,書評,文献紹介等  

    DOI: 10.1246/bcsj.75.1657

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  • Selective synthesis, characterization, and configurational flexibility of the coordinatively unsaturated metal center of half-sandwich type complexes with the less-hindered hydrotris(3, 5-dimethyl-4-X-1-pyrazolyl)borate ligands [Tp(Me2,X)M(II)(kappa(2)-O,O '-L)] (M = Ni, Co; L = NO3, OAc; X = Me, H, Br)

    S Hikichi, Y Sasakura, M Yoshizawa, Y Ohzu, Y Moro-oka, M Akita

    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN   75 ( 6 )   1255 - 1262   2002年6月

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  • Selective Synthesis, Characterization, and Configurational Flexibility of the Coordinatively Unsaturated Metal Center of Half-sandwich Type Complexes with the Less-Hindered Hydrotris(3,5-dimethyl-4-X-1-pyrazolyl)borate Ligands [Tp^Me2,X^M^II^(κ^2^-O,O-・・・

    Shiro Hikichi Yasuyuki, Sasakura Michito Yoshizawa Yoshiko Ohzu Yoshihiko Moro-oka Munetaka Akita

    Bull. Chem. Soc. Japan   75 ( 6 )   1255 - 1262   2002年6月

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  • New soluble pi-conjugated tetrathiafulvalene (TTF) polymers bearing long alkyl side chains: Preparation by organometallic polycondensation, structure and chemical properties of the polymers

    T Yamamoto, T Sasaki, T Yanagida, T Shimizu, Yamaguchi, I, M Akita, S Sasaki, T Fukuda, H Matsuda

    MOLECULAR CRYSTALS AND LIQUID CRYSTALS   381   101 - 112   2002年

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  • New soluble pi-conjugated tetrathiafulvalene (TTF) polymers bearing long alkyl side chains: Preparation by organometallic polycondensation, structure and chemical properties of the polymers

    T Yamamoto, T Sasaki, T Yanagida, T Shimizu, Yamaguchi, I, M Akita, S Sasaki, T Fukuda, H Matsuda

    MOLECULAR CRYSTALS AND LIQUID CRYSTALS   381   101 - 112   2002年

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  • Highly labile cationic tris-acetonitrile complexes, [Tp(R)M(NCMe)(3)]OTf (M = Ni, Co; Tp(R):: hydrotrispyrazolylborato, R = Ph, Me and iPr(2)): versatile precursors for Tp(R)-containing nickel and cobalt complexes

    K Uehara, S Hikichi, M Akita

    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS   ( 18 )   3529 - 3538   2002年

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  • Di- and tri-valent chlorochromium complexes bearing hydrotris(3,5-diisopropylpyrazolyl)borato ligand (Tp(iPr2)), Tp(iPr2)CrCl(n)(L) (n=1, 2) and [Tp(iPr2)Cr(mu-Cl)](2): flexible coordination behavior of the Tp(iPr2) ligand and reduction features of Cr(II) species

    K Sugawara, S Hikichi, M Akita

    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS   ( 23 )   4514 - 4524   2002年

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  • Structural characterization and intramolecular aliphatic C-H oxidation ability of M-III (mu-O)(2)M-III complexes of Ni and Co with the hydrotris-(3,5-dialkyl-4-X-pyrazolyl)borate ligands Tp(Me2,X) (X = Me, H, Br) and Tp(iPr2)

    S Hikichi, M Yoshizawa, Y Sasakura, H Komatsuzaki, Y Moro-oka, M Akita

    CHEMISTRY-A EUROPEAN JOURNAL   7 ( 23 )   5011 - +   2001年12月

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    記述言語:英語   掲載種別:書評論文,書評,文献紹介等  

    DOI: 10.1002/1521-3765(20011203)7:23<5011::AID-CHEM5011>3.0.CO;2-C

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  • Structural Characterization and Intramolecular Aliphatic C-H Oxidation Ability of M(III)(μ-O)_2_M(III) Complexes of Ni and Co with Hydrotris(3,5-diaklylpyrazolyl)borate Ligands Tp^Me2,X^ (X= Me, H, Br) and Tp^iPr2^

    Shiro Hikichi Michito Yoshizawa, Yasuyuki Sasakura, Hidehito Komatsuzaki Yoshihiko Moro-oka Munetaka Akita

    Chemistry - A European Journal   7 ( 23 )   5011 - +   2001年12月

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    記述言語:英語   掲載種別:書評論文,書評,文献紹介等  

    DOI: 10.1002/1521-3765(20011203)7:23<5011::AID-CHEM5011>3.0.CO;2-C

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  • Rational synthesis and reversible metal-metal bond scission of heterobimetallic xenophilic complexes containing an unsupported, polar metal-metal bond, Tp(iPr2)M-CO(CO)(3)L (M = Ni, Co, Fe, Mn; L = CO, PPh3)

    K Uehara, S Hikichi, M Akita

    ORGANOMETALLICS   20 ( 24 )   5002 - 5004   2001年11月

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  • Dichloromethane activation by chlorochromium(II) complexes with Tp(2)(iPr): Generation of an electrophilic Cr-methylene species without the action of an external Cl-abstraction reagent

    K Sugawara, S Hikichi, M Akita

    CHEMISTRY LETTERS   ( 11 )   1094 - 1095   2001年11月

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  • Dichloromethane activation by chlorochromium(II) complexes with Tp(2)(iPr): Generation of an electrophilic Cr-methylene species without the action of an external Cl-abstraction reagent

    K Sugawara, S Hikichi, M Akita

    CHEMISTRY LETTERS   ( 11 )   1094 - 1095   2001年11月

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  • N/O- and C-bound (enolato)palladium complexes with hydrotris(pyrazolyl)borato ligands (Tp(R): R = iPr(2), Me-2) obtained via dehydrative condensation between the hydroxo complexes Tp(R)Pd(Py)OH and active methylene compounds: Factors determining the isomer distribution and dimerization of cyano compounds

    M Kujime, S Hikichi, M Akita

    ORGANOMETALLICS   20 ( 19 )   4049 - 4060   2001年9月

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  • C- and N/O-bound Enolatopalladium Complexes with Hydrotrispyrazolylborato Ligands (Tp^R^: R= iPr2 and Me2) Obtained via Dehydrative Condensation Between the Hydroxo Complexes, Tp^R^Pd(py)-OH, and Active Methylene Compounds: Factors Determining the Isom・・・

    Masato Kujime, Shiro Hikichi Munetaka Akita

    Organometallics   20 ( 19 )   4049 - 4060   2001年9月

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  • Tetrahedral, highly coordinatively unsaturated 14e (Fe) and 15e (Co) hydrocarbyl complexes bearing hydrotris(pyrazolyl)borato ligands (Tp(R ')), Tp(R ')M-R (M = Fe, Co, Ni)

    N Shirasawa, TT Nguyet, S Hikichi, Y Moro-oka, M Akita

    ORGANOMETALLICS   20 ( 16 )   3582 - 3598   2001年8月

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  • Nucleophilic Addition to the η^2^-Alkyne Ligand in [CpFe(CO)_2_(η^2^-R-C≡C-R)]^+^. Dependence of the Alkenyl Product Stereochemistry on the Basicity of the Nucleophile

    Munetaka Akita, Satoshi Kakuta, Shuichiro Sugimoto, Masako Terada, Masako Tanaka, Yoshihiko Moro-oka

    Organometallics   20 ( 13 )   2736 - 2750   2001年6月

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  • Nucleophilic addition to the eta(2)-alkyne ligand in [CpFe(CO)(2)(eta(2)-R-C C-R)](+). Dependence of the alkenyl product stereochemistry on the basicity of the nucleophile

    M Akita, S Kakuta, S Sugimoto, M Terada, M Tanaka, Y Moro-oka

    ORGANOMETALLICS   20 ( 13 )   2736 - 2750   2001年6月

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  • Higher Nuclearity Fe,Ru-Mixed Metal Dicarbide Cluster Compounds Derived from Ethynediyldiiron Complex, (η^5^-C_5_Me_5_)(CO)_2_Fe-C≡C-Fe(η^5^-C_5_Me_5_)(CO)_2_

    Munetaka Akita Shuichiro Sugimoto, Hideki Hirakawa, Shin-ichi Kato, Masako Terada, Masako Tanaka, Yoshihiko Moro-oka

    Organometallics   20 ( 8 )   1555 - 1568   2001年4月

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  • Higher nuclearity Fe,Ru mixed-metal dicarbide cluster compounds derived from ethynediyldiiron complex (eta(5)-C5Me5)(CO)(2)Fe-C C-Fe(eta(5)-C5Me5)(CO)(2)

    M Akita, S Sugimoto, H Hirakawa, S Kato, M Terada, M Tanaka, Y Moro-oka

    ORGANOMETALLICS   20 ( 8 )   1555 - 1568   2001年4月

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  • Synthesis and dehydrative condensation of monomeric hydroxoruthenium complexes with hydrotris(3,5-diisopropylpyrazolyl)borate ligand, Tp(2)(iPr)Ru(L-2)-OH (L-2 = dppe, bipy)

    M Akita, Y Takahashi, S Hikichi, Y Moro-oka

    INORGANIC CHEMISTRY   40 ( 1 )   169 - +   2001年1月

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  • Synthesis and dehydrative condensation of monomeric hydroxoruthenium complexes with hydrotris(3,5-diisopropylpyrazolyl)borate ligand, Tp(2)(iPr)Ru(L-2)-OH (L-2 = dppe, bipy)

    M Akita, Y Takahashi, S Hikichi, Y Moro-oka

    INORGANIC CHEMISTRY   40 ( 1 )   169 - +   2001年1月

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  • Photochemical C-H bond activation of diruthenium bridging alkylidene complexes: Interligand H-exchange on Cp_2_Ru_2_(μ-CH_2_)(μ-CHR)(CO)_2_ (R= H, Me)

    Munetaka Akita, Hideki Musashi Sadahiro Nakanishi Yoshihiko Moro-oka

    J. Organomet. Chem.   617 ( 1 )   254 - 260   2001年1月

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  • Photochemical C-H bond activation of diruthenium bridging alkylidene complexes: Interligand H-exchange on Cp2Ru2(mu-CH2)(mu-CHR)(CO)(2) (R = H, Me)

    M Akita, H Musashi, S Nakanishi, Y Moro-oka

    JOURNAL OF ORGANOMETALLIC CHEMISTRY   617 ( 1 )   254 - 260   2001年1月

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  • [(mu(4)-H)Rh-4(PNNP)(2)(CO)(4)](+): A novel hydride bridging mode

    S Tanaka, M Akita

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   40 ( 15 )   2865 - 2867   2001年

  • [(μ_4_-H)[Rh_4_(PNNP)_2_(CO)_4_]^+^ A Novel Hydride Bridging Mode

    Shukichi Tanaka, Munetaka Akita

    Angew. Chem. Int. Ed. in Engl.   40 ( 15 )   2865 - 2867   2001年

  • Characterization of a dinuclear Mn(II) tri(mu-carboxylato) complex with the hindered hydrotris(3,5-diisopropyl-1-pyrazolyl)borate (=Tp(iPr2)) ligand: intramolecular hydrogen bonding interaction between the protonated Tp(iPr2) and Mn-coordinating carboxylate ligands

    UP Singh, R Singh, S Hikichi, M Akita, Y Moro-oka

    INORGANICA CHIMICA ACTA   310 ( 2 )   273 - 278   2000年12月

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  • Characterization of a dinuclear Mn(II) tri(μ-carboxylato) complex with the hindered hydrotris(3,5-diisopropyl-1-pyrazolyl)borate (= Tp^iPr2^) ligand: intramolecular hydrogen bonding interaction between the protonated Tp^iPr2^ and Mn-coordinating carbox・・・

    Udai P. Singh, Rajender Singh Shiro Hikichi Munetaka Akita, Yoshihiko. Moro-oka

    Inorganica Chimica Acta   310 ( 2 )   273 - 278   2000年12月

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  • Synthesis and structural comparison of Tp(iPr)2Rh[cis-1,2-bis(diphenylphosphino)ethene]: Factors determining hapticity (kappa(2) vs kappa(3)) of the Tp(iPr)2 ligand in Tp(iPr)2Rh(diphosphine) complexes

    M Akita, M Hashinoto, S Hikichi, Y Moro-oka

    ORGANOMETALLICS   19 ( 18 )   3744 - 3747   2000年9月

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  • Synthesis and dehydrative condensation of square-planar mono- and dinuclear hydroxopalladium complexes with the hydrotris(3,5-diisopropylpyrazolyl)borato ligand (Tp(2)(iPr)), Tp(2)(iPr)(Py)Pd-OH, and (mu-OH)(2){PdTp(2)(iPr)(H2O)}(2)

    M Akita, T Miyaji, N Muroga, C Mock-Knoblauch, W Adam, S Hikichi, Y Moro-oka

    INORGANIC CHEMISTRY   39 ( 10 )   2096 - 2102   2000年5月

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  • Synthesis and Dehydrative Condensation of Square-planar Mono- and Dinuclear Hydroxopalladium Complexes with the Hydrotris(3,5-diisopropylpyrazolyl)borato Ligand (Tp^iPr2^), Tp^iPr2^(py)Pd-OH and (μ-OH)_2_{PdTp^iPr2^(H_2_O)}_2_

    Munetaka Akita Taichi Miyaji Nobuyuki, Muroga Cordula Mock-Knoblauch Shiro Hikichi Waldemar Adam Yoshihiko Moro-oka

    Inorg. Chem.   39 ( 10 )   2096 - 2102   2000年5月

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  • An approach to the O-2 activating mononuclear non-heme Fe enzymes: structural characterization of Fe(II)-acetato complex and formation of alkylperoxoiron(III) species with the highly hindered hydrotris(3-tert-butyl-5-isopropyl-1-pyrazolyl)borate

    T Ogihara, S Hikichi, M Akita, T Uchida, T Kitagawa, Y Moro-oka

    INORGANICA CHIMICA ACTA   297 ( 1-2 )   162 - 170   2000年1月

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  • An entry to half-sandwich complexes of first row transition metals (Ni, Co, Mn) containing the Klaeui tripodal ligand, LOMe: Synthesis and crystal structures of oligomeric, [LOMeM(m-X)(L)]n (n= 2, 4), and monomeric complexes, LOMeM(L2)(X)

    De-qiang Ma, Shiro Hikichi Munetaka Akita, Yoshihiko Moro-oka

    J. Chem. Soc., Dalton Trans   ( 7 )   1123 - 1134   2000年

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  • Formation of novel conjugated polycarbon-metal systems via metal migration on a M-C≡C-C≡C-M linkage

    Munetaka Akita, Min-Chul Chung Aizoh, Sakurai Yoshihiko Moro-oka

    J. Chem. Soc., Chem. Commun.   ( 14 )   1285 - 1286   2000年

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  • Synthesis and structural characterization of a new class of organoborato ligands containing imidazolyl functional groups [MeB(ImN-Me)2(X)]-

    Koyu Fujita Shiro Hikichi Munetaka Akita, Yoshihiko Moro-oka

    J. Chem. Soc., Dalton Trans.   ( 8 )   1255 - 1260   2000年

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  • Synthesis and structural characterization of a new class of organoborato ligands containing imidazolyl functional groups [MeB(ImN-Me)2(X)]-

    Koyu Fujita Shiro Hikichi Munetaka Akita, Yoshihiko Moro-oka

    J. Chem. Soc., Dalton Trans.   ( 8 )   1255 - 1260   2000年

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  • Formation of novel conjugated polycarbon-metal systems via metal migration on a M-C C-C C-M linkage

    M Akita, MC Chung, A Sakurai, Y Moro-oka

    CHEMICAL COMMUNICATIONS   ( 14 )   1285 - 1286   2000年

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  • Novel monoanionic tripodal ligands methylbis(1-methyl-2-imidazolyl)(1-pyrazolyl)borate (= [MeB(ImN-Me)2(PzR)]-): Synthesis and structural characterization of their nickel complexes and carboxylate shift from nickel to boron

    Koyu Fujita Shiro Hikichi Munetaka Akita, Yoshihiko Moro-oka

    J. Chem. Soc., Dalton Trans.   ( 2 )   117 - 119   2000年

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  • An entry to half-sandwich complexes of first row transition metals (Ni, Co, Mn) containing the Klaeui tripodal ligand, LOMe: Synthesis and crystal structures of oligomeric, [LOMeM(m-X)(L)]n (n= 2, 4), and monomeric complexes, LOMeM(L2)(X)

    De-qiang Ma, Shiro Hikichi Munetaka Akita, Yoshihiko Moro-oka

    J. Chem. Soc., Dalton Trans   ( 7 )   1123 - 1134   2000年

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  • Novel monoanionic tripodal ligands methylbis(1-methyl-2-imidazolyl)(1-pyrazolyl)borate (= [MeB(ImN-Me)2(PzR)]-): Synthesis and structural characterization of their nickel complexes and carboxylate shift from nickel to boron

    Koyu Fujita Shiro Hikichi Munetaka Akita, Yoshihiko Moro-oka

    J. Chem. Soc., Dalton Trans.   ( 2 )   117 - 119   2000年

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  • Conformational analysis of cationic (R,S)- and (R,R)-(salen)manganese complexes possessing axial chirality as a chiral element based on X-ray crystallography: An explanation of the effect of apical ligand on enantioselection by (salen)manganese catalyst

    T Hashihayata, T Punniyamurthy, R Irie, T Katsuki, M Akita, Y Moro-oka

    TETRAHEDRON   55 ( 51 )   14599 - 14610   1999年12月

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  • Conformational analysis of cationic (R,S)- and (R,R)-(salen)manganese complexes possessing axial chirality as a chiral element based on X-ray crystallography: An explanation of the effect of apical ligand on enantioselection by (salen)manganese catalyst

    T Hashihayata, T Punniyamurthy, R Irie, T Katsuki, M Akita, Y Moro-oka

    TETRAHEDRON   55 ( 51 )   14599 - 14610   1999年12月

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  • Synthesis and characterisation of Fe,Co-mixed metal polynuclear complexes with C4H and C-4 ligands derived from butadiynyl (X = H) and butadiynediyl iron complexes (X = Fp*), Fp*-C C-C C-X [Fp* = (eta(5)-C5Me5)Fe(CO)(2)]: Transformation of the C-4(H) cluster frameworks via valence isomerization and 1,2-H shift of the carbon linkages

    MC Chung, A Sakurai, M Akita, Y Moro-oka

    ORGANOMETALLICS   18 ( 23 )   4684 - 4691   1999年11月

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  • Synthesis and Characterization of Fe,Co-Mixed Metal Polynuclear Complexes with C4H and C4 Ligands Derived From Butadiynyl (X= H) and Butadiynediyl Iron Complexes (X= Fp*), Fp*-CコC-CコC-X [Fp*= (h5-C5Me5)Fe(CO)2]: Transformation of the C4(H) Cluster Fram・・・

    Min-Chul Chung Aizoh, Sakurai Munetaka Akita, Yoshihiko Moro-oka

    Organometallics   18 ( 23 )   4684 - 4691   1999年11月

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  • Conversion of molecular oxygen into a hydroperoxo species by ring- opening protonation of a cyclic η2-peroxo intermediate: Characterization of the η2-peroxo and hydroperoxo complexes

    Yoshiaki Takahashi, Mariko Hashimoto, Shiro Hikichi, Munetaka Akita, Yoshihiko Moro-oka

    Angewandte Chemie - International Edition   38 ( 20 )   3074 - 3077   1999年10月

  • Conversion of Molecular Oxygen into a Hydroperoxo Species via Ring Opening Protonation of a Cyclic η^2^-Peroxide Intermediate: Characterization of the η^2^-Peroxide and Hydroperoxo Complexes Obtained by Oxygenation of a Rh(I) Complex in the Presence of・・・

    Yoshiaki Takahashi, Mariko Hashimoto, Shiro Hikichi Munetaka Akita, Yoshihiko Moro-oka

    Angew. Chem. Int. Ed. in Engl   38 ( 20 )   3074 - 3077   1999年10月

  • Oxygenation of saturated hydrocarbyl groups in the dinuclear Ni(III) bis(mu-oxo) complexes with the hydrotris(pyrazolyl)borate ligands Tp(R) (R = Me-3 and Pr-2(i))

    S Hikichi, M Yoshizawa, Y Sasakura, H Komatsuzaki, M Akita, Y Moro-oka

    CHEMISTRY LETTERS   ( 9 )   979 - 980   1999年9月

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  • A transition metal-hydroperoxo complex stabilized by hydrogen-bonding interaction: The first example of a hydroperoxopalladium species characterized by X-ray crystallography, (kappa(2)-Tp(iPr))Pd(PPh3)(OOH) [Tp(iPr) = hydrotris(3,5-diisopropylpyrazolyl)borato]

    M Akita, T Miyaji, S Hikichi, Y Moro-oka

    CHEMISTRY LETTERS   ( 8 )   813 - 814   1999年8月

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  • Synthesis of a series of rhodium complexes, Tp(iPr)Rh(I)L(2) and Tp(iPr)Rh(III)(X)(Y)(MeCN), with the hydridotris(3,5-diisopropylpyrazolyl)borato ligand (Tp(iPr)) from a versatile precursor, (kappa(3)-Tp(iPr))Rh(coe)(MeCN), and dependence of kappa(2)-kappa(3) interconversion rate of the Tp(iPr) ligand on the chelate ring size

    K Ohta, M Hashimoto, Y Takahashi, S Hikichi, M Akita, Y Moro-oka

    ORGANOMETALLICS   18 ( 16 )   3234 - 3240   1999年8月

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  • Synthesis of a Series of Rhodium Complexes, TpiPrRhIL2 and TpiPrRhIII(X)(Y)(MeCN), with Hydrotris(3,5-diisopropyl-pyrazolyl)borato Ligand (TpiPr) from the Versatile Precursor, (k3-TpiPr)Rh(coe)(MeCN), and Dependence of the k2-k3 Interconversion Rate of・・・

    Keisuke Ohta, Mariko Hashimoto, Yoshiaki Takahashi Shiro Hikichi Munetaka Akita, Yoshihiko Moro-oka

    Organometallics   18 ( 16 )   3234 - 3240   1999年8月

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  • Synthesis and characterization of the dodecahexaynediyldiiron complex, Fp*-(C C)(6)-Fp* [Fp*= Fe(eta(5)-C5Me5)(CO)(2)], the longest structurally characterized polyynediyl complex

    A Sakurai, M Akita, Y Moro-oka

    ORGANOMETALLICS   18 ( 16 )   3241 - 3244   1999年8月

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  • Synthesis and Characterization of the Dodecahexaynediyldiiron Complex, Fp*-(CコC)6-Fp* [Fp*= Fe(h5-C5Me5)(CO)2], the Longest Structurally Characterized Polyynediyl Complex

    Aizoh Sakurai, Munetaka Akita, Yoshihiko Moro-oka

    Organometallics   18 ( 16 )   3241 - 3244   1999年8月

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  • Coordinatively unsaturated species with an agostic C-H interaction, [(kappa(4)-Tp(iPr))Ru(dppe)]OSO2CF3, and its addition reaction

    Y Takahashi, S Hikichi, M Akita, Y Moro-oka

    ORGANOMETALLICS   18 ( 14 )   2571 - 2573   1999年7月

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  • Why do (R,R)- and (R,S)-(salen)manganese(III) complexes show different substrate-specificity? The role of an apical aqua ligand

    T Punniyamurthy, R Irie, T Katsuki, M Akita, Y Moro-oka

    SYNLETT   ( 7 )   1049 - 1052   1999年7月

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  • Why do (R,R)- and (R,S)-(salen)manganese(III) complexes show different substrate-specificity? The role of an apical aqua ligand

    T Punniyamurthy, R Irie, T Katsuki, M Akita, Y Moro-oka

    SYNLETT   ( 7 )   1049 - 1052   1999年7月

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  • The first evidence for activation of exogenous O-2 on a vanadium(IV) center: synthesis and characterization of a peroxo vanadium(V) complex with hydrotris(3,5-diisopropylpyrazol-1-yl)borate

    M Kosugi, S Hikichi, M Akita, Y Moro-oka

    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS   ( 9 )   1369 - 1371   1999年5月

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  • Inter- and Intramolecular Hydrogen-bonding Interaction of Hydroxo Groups and Steric Effect of Alkyl Substituents on Pyrazolyl Rings in TpR Ligands: Synthesis and Structural Characterization of Chloro-, Acetylacetonato- and Hydroxo Complexes of VO2+ wit・・・

    Masahiro Kosugi, Shiro Hikichi Munetaka Akita, Yoshihiko Moro-oka

    Inorg. Chem.   38 ( 11 )   2567 - 2578   1999年5月

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  • Inter- and intramolecular hydrogen-bonding interaction of hydroxo groups and steric effect of alkyl substituents on pyrazolyl rings in Tp(R) ligands: Synthesis and structural characterization of chloro-, acetylacetonato-, and hydroxo complexes of VO2+ with Tp(Pri2) and Tp(Me2) ligands

    M Kosugi, S Hikichi, M Akita, Y Moro-oka

    INORGANIC CHEMISTRY   38 ( 11 )   2567 - 2578   1999年5月

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  • Thermally stable coordinatively unsaturated alkyl complexes resistant to beta-hydride elimination: Tp(iPr)M-CH2CH3 (M = Co, Fe)

    N Shirasawa, M Akita, S Hikichi, Y Moro-Oka

    CHEMICAL COMMUNICATIONS   ( 5 )   417 - 418   1999年3月

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  • Synthesis and crystal structures of mononuclear half-sandwich complexes of Ni and Co containing Klaui's tripodal ligand, [M{kappa(3)-(eta(5)-C5H5)Co[P(=O)(OCH3)(2)](3)}(kappa(2)-NO3)(L)] (M = Ni or Co)

    M Akita, DQ Ma, S Hikichi, Y Moro-oka

    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS   ( 6 )   987 - 996   1999年3月

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  • Synthesis and crystal structures of mononuclear half-sandwich complexes of Ni and Co containing Klaui's tripodal ligand, [M{kappa(3)-(eta(5)-C5H5)Co[P(=O)(OCH3)(2)](3)}(kappa(2)-NO3)(L)] (M = Ni or Co)

    M Akita, DQ Ma, S Hikichi, Y Moro-oka

    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS   ( 6 )   987 - 996   1999年3月

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  • Photochemical C-H bond activation of the diruthenium bridging methylene complex, Cp2Ru2(mu-CH2)(2)(CO)(2): insertion of norbornadienes into the methylene C-H bond and unprecedented intramolecular H-D exchange between the two methylene units

    M Akita, S Nakanishi, H Musashi, Y Moro-oka

    CHEMICAL COMMUNICATIONS   ( 2 )   145 - 146   1999年1月

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  • Facile CコC bond cleavage of polyynediyldiiron complexes, Fp*-(CコC)n-Fp* [Fp*= Fe(h5-C5Me5)(CO)2; n= 3, 4], with Fe2(CO)9 leading to bis(m3-alkylidyne) complexes, Fp*-CコC-m3-C-Fe3(CO)9-m3-C-(CコC)n-2-Fp*.

    Munetaka Akita Aizoh, Sakurai Yoshihiko Moro-oka

    J. Chem. Soc., Chem. Commun.   ( 1 )   101 - 102   1999年1月

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  • Photochemical C-H bond activation of the diruthenium bridging methylene complex, Cp2Ru2(mu-CH2)(2)(CO)(2): insertion of norbornadienes into the methylene C-H bond and unprecedented intramolecular H-D exchange between the two methylene units

    M Akita, S Nakanishi, H Musashi, Y Moro-oka

    CHEMICAL COMMUNICATIONS   ( 2 )   145 - 146   1999年1月

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  • Facile C C bond cleavage of polyynediyldiiron complexes, Fp*-(C C)(n)-Fp* [Fp*=Fe(eta(5)-C5Me5)(CO)(2), n = 3, 4], with Fe-2(CO)(9) leading to bis(mu(3)-alkylidyne) complexes, Fp*-C C-mu(3)-C-Fe-3(CO)(9)-mu(3)-C-(C C)(n-2)-Fp*

    M Akita, A Sakurai, Y Moro-oka

    CHEMICAL COMMUNICATIONS   ( 1 )   101 - 102   1999年1月

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  • Synthesis and Characterization of the Dodecahexaynediyldiiron Complex, Fp*-(CコC)6-Fp* [Fp*= Fe(h5-C5Me5)(CO)2], the Longest Structurally Characterized Polyynediyl Complex

    Aizoh Sakurai, Munetaka Akita, Yoshihiko Moro-oka

    Organometallics   18 ( 16 )   3241 - 3244   1999年

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  • ヒドロトリス(ピラゾリル)ボレートを配位子とする金属錯体の化学-酸素錯体を中心に-

    穐田宗隆, 引地史郎, 諸岡良彦

    有機合成化学協会誌   57 ( 7 )   619 - 628   1999年

  • 14e η┣D11┫D1-Hydrocarbyliron complexes supported by hydrotris(3,5-diisopropylpyrazolyl)borate : The allyl complex prefers a highly coordinatively unsaturated 14e η┣D11┫D1-structure to a 16e η┣D13┫D1-structure

    MUNETAKA AKITA

    Journal of Chemal Society, Chemical Communications   ( 9 )   973 - 974   1998年5月

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  • Systematic synthesis of a series of hydroperoxo-, alkylperoxo-and μ-peroxopalladium complexes supported by the hydrotris(3,5-diisopropylpyrazolyl)borate ligand(Tp┣D1iPr┫D1), Tp┣D1iPr┫D1Pd(py)-OOX[X=PdTp┣D1iPr┫D1(py), H. Bu┣D1+┫D1], via dehydrative cond・・・

    MUNETAKA AKITA

    Journal of Chemal Society, Chemical Communications   ( 9 )   1005 - 1006   1998年5月

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  • 14e eta(1)-hydrocarbyliron complexes supported by hydrotris(3,5-diisopropylpyrazolyl)borate: The allyl complex prefers a highly coordinatively unsaturated 14e eta(1)-structure to a 16e eta(3)-structure

    M Akita, N Shirasawa, S Hikichi, Y Moro-Oka

    CHEMICAL COMMUNICATIONS   ( 9 )   973 - 974   1998年5月

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  • Systematic synthesis of a series of hydroperoxo-, alkylperoxo- and mu-peroxo-palladium complexes supported by the hydrotris(3,5-diisopropylpyrazolyl)borate ligand (Tp(iPr)), Tp(iPr)Pd(py)-OOX [X = PdTp(iPr)(py), H, Bu-t], via dehydrative condensation of a hydroxo complex, Tp(iPr)Pd(py)-OH

    M Akita, T Miyaji, S Hikichi, Y Moro-oka

    CHEMICAL COMMUNICATIONS   ( 9 )   1005 - 1006   1998年5月

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  • Synthesis of Various Cationic Ruthenium-Aqua Complexes with the Hydrotris(3, 5-diisopropylpyrazolyl)borate Ligand, Tp┣D1iPr┫D1Ru(OH┣D22┫D2)┣D22┫D2(L)┣D23-n┫D2(CF┣D23┫D2SO┣D23┫D2)(THF)┣D2x┫D2, and Their Structures Supported by Hydrogen-Bonding Networks

    MUNETAKA AKITA

    Inorganic Chemistry   37 ( 13 )   3186 - 3194   1998年

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  • Reaction of Ethynediyl, Butadiynediyl and Ethynyl Iron Complexes, Fp┣D1*┫D1-(C≡C)┣D2n┫D2--X[X=Fp┣D1*┫D1, H ; n=1,2 ; Fp┣D1*┫D1=Fe(η┣D15┫D1-C┣D25┫D2Me┣D25┫D2)(CO)┣D22┫D2], with Fe┣D22┫D2(CO)┣D29┫D2 Leading to Polynuclear C┣D22┫D2 and C┣D24┫D2 Complexes

    MUNETAKA AKITA

    Journal of Organometallic Chemistry   565   49   1998年

  • Reaction of Ethynediyl, Butadiynediyl and Ethynyl Iron Complexes, Fp┣D1*┫D1-(C≡C)┣D2n┫D2--X[X=Fp┣D1*┫D1, H ; n=1,2 ; Fp┣D1*┫D1=Fe(η┣D15┫D1-C┣D25┫D2Me┣D25┫D2)(CO)┣D22┫D2], with Fe┣D22┫D2(CO)┣D29┫D2 Leading to Polynuclear C┣D22┫D2 and C┣D24┫D2 Complexes

    MUNETAKA AKITA

    Journal of Organometallic Chemistry   565   49   1998年

  • Synthesis of Various Cationic Ruthenium-Aqua Complexes with the Hydrotris(3, 5-diisopropylpyrazolyl)borate Ligand, Tp┣D1iPr┫D1Ru(OH┣D22┫D2)┣D22┫D2(L)┣D23-n┫D2(CF┣D23┫D2SO┣D23┫D2)(THF)┣D2x┫D2, and Their Structures Supported by Hydrogen-Bonding Networks

    MUNETAKA AKITA

    Inorganic Chemistry   37 ( 13 )   3186 - 3194   1998年

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  • Chemistry of μ-η22-Peroxo Dimetal Complexes: A Bioinorganic Model Triggers a New Trend of Transition Metal Peroxo Species 招待

    Munetaka Akita, Kiyoshi Fujisawa, Shiro Hikichi, Yoshihiko Moro-oka

    Res. Chem. Intermed.   24   291-307   1998年

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    記述言語:英語   掲載種別:記事・総説・解説・論説等(学術雑誌)  

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  • Synthesis and reactivity of labile MeCN adducts of diruthenium bis(mu-methylene) species, Cp2Ru2(mu-CH2)(2)(CO)(n)(MeCN)(2-n) (n = 1, 2): Reaction with H sources, H-X (X = SiR3, SnR3, H), and C-C coupling with alkynes and diazoalkanes

    M Akita, R Hua, S Nakanishi, M Tanaka, Y Morooka

    ORGANOMETALLICS   16 ( 25 )   5572 - 5584   1997年12月

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  • Synthesis and Reactivity of Labile MeCN Adducts of Diruthenium Bis(μ-methylene)Species, Cp┣D22┫D2Ru┣D22┫D2(μ-CH┣D22┫D2)┣D22┫D2(CO)n(MeCN)┣D22-n┫D2(n=1,2) : Reaction with H-sources, H-X(X=SiR┣D23┫D2, SnR┣D23┫D2, H), and C-C Coupling with Alkyne and Diaz・・・

    MUNETAKA AKITA

    Organometallics   16 ( 25 )   5572 - 5584   1997年12月

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  • Synthesis and structural characterization of a tetrahedral sp(3) carbide cluster compound

    Y Takahashi, M Akita, Y Morooka

    CHEMICAL COMMUNICATIONS   ( 16 )   1557 - 1558   1997年8月

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  • Synthesis and structural characterization of a tetrahedral sp(3) carbide cluster compound

    Y Takahashi, M Akita, Y Morooka

    CHEMICAL COMMUNICATIONS   ( 16 )   1557 - 1558   1997年8月

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  • Synthesis and Structure Determination of Linear Conjugated Polyynyl and Polyynediyl Iron Complexes, Fp┣D1*┫D1-(C≡C)┣D2n┫D2-X[X=H(n=1,2) ; X=Fp┣D1*┫D1(n=1,2,4) ; Fp┣D1*┫D1=(η┣D15┫D1-C┣D25┫D2Me┣D25┫D2)Fe(CO)┣D22┫D2]

    MUNETAKA AKITA

    Organometallics   16 ( 22 )   4882 - 4888   1997年

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  • Synthesis and Structure Determination of Linear Conjugated Polyynyl and Polyynediyl Iron Complexes, Fp┣D1*┫D1-(C≡C)┣D2n┫D2-X[X=H(n=1,2) ; X=Fp┣D1*┫D1(n=1,2,4) ; Fp┣D1*┫D1=(η┣D15┫D1-C┣D25┫D2Me┣D25┫D2)Fe(CO)┣D22┫D2]

    MUNETAKA AKITA

    Organometallics   16 ( 22 )   4882 - 4888   1997年

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  • Synthesis of Diiron Bridging Allenylidene Complexes Cp┣D1*┫D1┣D22┫D2Fe┣D22┫D2(μ-C=C=CR┣D11┫D1R┣D12┫D1)(μ-CO)(CO)┣D22┫D2(Cp┣D1*┫D1=η┣D15┫D1-C┣D25┫D2Me┣D25┫D2) via Nucleophilic Addition to Diiron Ethynediyl Complex (μ-C≡C)[FeCp┣D1*┫D1(CO)┣D22┫D2]┣D22┫D2 ・・・

    MUNETAKA AKITA

    Organometallics   16   2392   1997年

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    Synthesis of Diiron Bridging Allenylidene Complexes Cp┣D1*┫D1┣D22┫D2Fe┣D22┫D2(μ-C=C=CR┣D11┫D1R┣D12┫D1)(μ-CO)(CO)┣D22┫D2(Cp┣D1*┫D1=η┣D15┫D1-C┣D25┫D2Me┣D25┫D2) via Nucleophilic Addition to Diiron Ethynediyl Complex (μ-C≡C)[FeCp┣D1*┫D1(CO)┣D22┫D2]┣D22┫D2 and Their Convers

    DOI: 10.1021/om961104e

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  • Synthesis of Diiron Bridging Allenylidene Complexes Cp┣D1*┫D1┣D22┫D2Fe┣D22┫D2(μ-C=C=CR┣D11┫D1R┣D12┫D1)(μ-CO)(CO)┣D22┫D2(Cp┣D1*┫D1=η┣D15┫D1-C┣D25┫D2Me┣D25┫D2) via Nucleophilic Addition to Diiron Ethynediyl Complex (μ-C≡C)[FeCp┣D1*┫D1(CO)┣D22┫D2]┣D22┫D2 ・・・

    MUNETAKA AKITA

    Organometallics   16   2392   1997年

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    Synthesis of Diiron Bridging Allenylidene Complexes Cp┣D1*┫D1┣D22┫D2Fe┣D22┫D2(μ-C=C=CR┣D11┫D1R┣D12┫D1)(μ-CO)(CO)┣D22┫D2(Cp┣D1*┫D1=η┣D15┫D1-C┣D25┫D2Me┣D25┫D2) via Nucleophilic Addition to Diiron Ethynediyl Complex (μ-C≡C)[FeCp┣D1*┫D1(CO)┣D22┫D2]┣D22┫D2 and Their Convers

    DOI: 10.1021/om961104e

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  • Deoxygenative Reduction of Diruthenium Carbonyl Complexes(η5-C5H4R)2Ru2(μ-CO)(CO)2 with Hydrosilanes Leading to Bridging Methylene Complexes (η5-C5H4R)2Ru2(μ-CH2)n(μ-CO)2-n(CO)2(n=1,2 ; R=H, CH3)

    MUNETAKA AKITA

    Organometallics   15 ( 10 )   2548 - 2553   1996年5月

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  • Deoxygenative reduction of diruthenium carbonyl complexes (eta(5)-C(5)H(4)R)(2)Ru-2(mu-CO)(2)(CO)(2) with hydrosilanes leading to bridging methylene complexes (eta(5)-C(5)H(4)R)(2)Ru-2(mu-CH2)(n)(mu-CO)(2-n)(CO)(2) (n=1, 2; R=H, CH3)

    M Akita, RM Hua, T Oku, Y Morooka

    ORGANOMETALLICS   15 ( 10 )   2548 - 2553   1996年5月

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講演・口頭発表等

  • Photoinduced Oxidative Coupling Reaction Using Tris(bipyridyl)ruthenium(II) complex

    The 23rd International Conference on Organometallic Chemistry  2008年 

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    会議種別:ポスター発表  

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  • Photoinduced Oxidative Coupling Reaction Using Tris(bipyridyl)ruthenium(II) complex

    The 23rd International Conference on Organometallic Chemistry  2008年 

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    会議種別:ポスター発表  

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受賞

  • Inorganic Chemistry Frontiers Outstanding Paper Awards 2014–2023

    2025年2月   中国化学会・イギリス王立化学会  

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  • 文部科学大臣表彰 科学技術省(研究部門)

    2022年4月   文部科学省   文部科学大臣表彰 科学技術省(研究部門)

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  • The Japanese Photochemistry Association Special Lectureship Award

    2021年9月   光化学協会  

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  • イギリス王立化学会フェロー

    2009年9月   イギリス王立化学会  

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  • 触媒学会奨励賞

    1996年   触媒学会  

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    受賞国:日本国

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共同研究・競争的資金等の研究課題

  • 有機金属光化学

    2002年

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    資金種別:競争的資金

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  • organometallic photochemistry

    2002年

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    資金種別:競争的資金

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  • organometallic molecular wire

    1999年

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    資金種別:競争的資金

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  • 有機金属分子ワイヤー

    1999年

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    資金種別:競争的資金

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  • 遷移金属・炭素複合錯体の合成研究

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    資金種別:競争的資金

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  • 遷移金属・酸素錯体の合成研究

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    資金種別:競争的資金

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  • 一酸化炭素の脱酸素還元反応

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    資金種別:競争的資金

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  • Deoxygenative reduction of CO

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    資金種別:競争的資金

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  • Synthetic study of transition metalcarbon complexes

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    資金種別:競争的資金

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  • Synthetic study of transition metaldioxygen complexes

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    資金種別:競争的資金

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