Reaction of a Triruthenium μ₃-Borylene Complex with Benzonitrile: Formation of a μ₃-η³-BCN Ring on a Cationic Ru₃ Plane via Photo-Induced Intramolecular Borylene Transfer 査読 国際誌

Takeshi Kaneko, Toshiro Takao

Organometallics   39 ( 4 )   593 - 604   2020年2月

Formation of a μ₃-Acetylide on a Ru₃ Cluster via Coupling of μ-Methylene with Isocyanide Accompanied by Elimination of Amine: A Model of Hydrogen-Assisted C–C Bond Formation on a Metal Surface 査読 国際誌

Hiroki Chikamori, Toshiro Takao

Organometallics   38 ( 14 )   2705 - 2709   2019年6月

Diruthenium complexes having a partially hydrogenated bipyridine ligand: plausible mechanism for the dehydrogenative coupling of pyridines at a diruthenium site 招待 査読 国際誌

Toshiro Takao, Takashi Kawashima, Ryo Nagae, Hideyuki Kanda, Wataru Watanabe

Faraday Discussions   220   249 - 268   2019年

Transformation of a μ₃-Benzyne Ligand into Phenol on a Cationic Triruthenium Cluster Supported by a μ₃-Sulfido Ligand 査読 国際誌

Hiroki Chikamori, Atsushi Tahara, Toshiro Takao

Organometallics   38 ( 2 )   527 - 535   2018年12月

Catalytic Hydrogenation of Benzonitrile by Triruthenium Clusters: Consecutive Transformations of Benzonitrile on the Face of a Ru₃ Plane 査読 国際誌

Toshiro Takao, Sachie Horikoshi, Takashi Kawashima, Sachio Asano, Yuta Takahashi, Akira Sawano, Hiroharu Suzuki

Organometallics   37 ( 10 )   1598 - 1614   2018年5月

Dehydrogenative Oxidation of Cyclic Amines on a Diruthenium Complex 査読 国際誌

Ryuichi Shimogawa, Ryosuke Fujita, Toshiro Takao, Hiroharu Suzuki

Organometallics   36 ( 10 )   1893 - 1896   2017年5月

Dehydrogenative Coupling of 4-Substituted Pyridines Catalyzed by a Trinuclear Complex of Ruthenium and Cobalt 査読 国際誌

Masahiro Nagaoka, Takashi Kawashima, Hiroharu Suzuki, Toshiro Takao

Organometallics   35 ( 14 )   2348 - 2360   2016年7月

Synthesis of cationic trinuclear heterobimetallic complexes of Ru and Fe containing μ- and μ3-ethylidyne ligands. Considerations on alkylidyne−alkylidyne coupling on a multimetallic site

Naoya Noguchi, Toshiro Takao

Journal of Organometallic Chemistry   2026年6月

Photo-Induced Hydrogenation of a Cationic Triruthenium Complex Capped by a μ3-η3-C3 Ring: Fluxional Behavior of Hydrides in a Cationic Triruthenium Diruthenaallyl Complex with an Agostic Ru–H–C Interaction

Toshiro Takao, Shiyu Zhou

Organometallics   2026年4月

Preparation of a series of heterobimetallic complexes containing bridging ethylidyne ligands by the reaction of diruthenium Bis(μ-ethylidyne) complex with 3d metal carbonyls: Alkylidyne−alkylidyne coupling reaction at the Ru2Fe site 査読 国際誌

Naoya Noguchi, Toshiro Takao

Journal of Organometallic Chemistry   1026   123497 - 123497   2025年2月

Synthesis of a 50-electron triangular ruthenium cluster containing a μ3-methylidyne ligand via the fragmentation of the Ru2 skeleton 査読 国際誌

Toshiro Takao, Shu Egawa, Takayuki Ochi, Takeshi Fukuyama

Journal of Organometallic Chemistry   1013   123157 - 123157   2024年6月

Skeletal Rearrangement of a μ–η²:η⁴-Hexatrienyl Ligand at a Diruthenium Site via a μ–η⁵-Ruthenacyclohexadienyl Intermediate 査読 国際誌

Toshiro Takao, Taiki Taniguchi, Yohei Tsurumaki

Organometallics   43 ( 8 )   866 - 878   2024年4月

Heterobimetallic Trihydrido Complex of Ruthenium and Rhodium Supported by Cyclopentadienyl Groups with Different Steric Demands 査読 国際誌

Toshiro Takao, Taichi Monoe, Ryuichi Shimogawa, Keigo Nakamura

Organometallics   42 ( 15 )   2087 - 2101   2023年7月

Photo-Induced Reaction of Cp*Ru(μ-H)₄RuCp* with Arenes Resulting in Irreversible Formation of μ-η²:η²-Cyclohexadiene Complexes 査読 国際誌

Ryuichi Shimogawa, Yuki Muroi, Naoya Noguchi, Gen-ichi Konishi, Toshiro Takao, Hiroharu Suzuki

Organometallics   41 ( 23 )   3750 - 3761   2022年11月

Mono- and Bis-cyclopentadienyl Complexes of Ruthenium and Osmium 招待 査読 国際誌

Toshiro Takao, Akiko Inagaki

Comprehensive Organometallic Chemistry IV   294 - 443   2022年8月

Syntheses and Properties of Triruthenium Polyhydrido Complexes Composed of 1,2,4-tri-tert-butylcyclopentadienyl and p-Cymene Ruthenium Units 査読 国際誌

Toshiro Takao, Hidenori Suzuki, Ryuichi Shimogawa

Organometallics   40 ( 9 )   1303 - 1313   2021年4月

Synthesis of Diruthenium μ-Chloromethylidyne Complex: C–C Bond Formation at the Bridging Carbon Atom via the Reduction of a μ-Chloromethylidyne Ligand 国際誌

Toshiro Takao, Koichi Seki

Organometallics   40 ( 4 )   467 - 471   2021年2月

Four-Electron Reduction of Dioxygen on a Metal Surface: Models of Dissociative and Associative Mechanisms in a Homogeneous System 査読 国際誌

Hajime Kameo, Shigeyoshi Sakaki, Yasuhiro Ohki, Naoki Uehara, Takuya Kosukegawa, Hiroharu Suzuki, Toshiro Takao

Inorganic Chemistry   60 ( 3 )   1550 - 1560   2020年11月

Reversible Transformation of a μ₃-η³-C₃ Ring into μ₃-η²-Ethyne and μ-Vinylidene Ligands at a Triruthenium Site upon Deprotonation and Protonation 査読 国際誌

Toshiro Takao, Koichi Seki

Organometallics   39 ( 24 )   4637 - 4644   2020年11月

Synthesis and site-dependent reactivity of a heterometallic dinuclear bis(μ-imido) complex of tungsten and ruthenium 査読 国際誌

Hiroyuki Tsuruda, Toshiro Takao

Journal of Organometallic Chemistry   919   121296 - 121296   2020年7月

Selective Synthesis of a Triruthenium Pentahydrido Complex with Mixed-Cp Ligands (C₅^tBu₃H₂ and C₅Me₅) and Its Transformation into Face-Capping Benzene Complexes: Fluxionality of a Face-Capping Benzene Ligand Induced by Oxidation 査読 国際誌

Ryuichi Shimogawa, Yohei Tsurumaki, Hidenori Suzuki, Toshiro Takao

Organometallics   38 ( 19 )   3824 - 3833   2019年9月

Synthesis and Properties of a Triruthenium Hydrido Complex Capped by a μ₃-Oxoboryl Ligand 査読 国際誌

Takeshi Kaneko, Hayato Ninagawa, Moe Matsuoka, Toshiro Takao

Organometallics   38 ( 9 )   2239 - 2249   2019年4月

Effect of ring size on the properties of μ3-Cycloalkyne complexes: Synthesis of triruthenium complexes containing a perpendicularly coordinated μ3-Allenyl ligand 査読 国際誌

Moeko Saito, Shuhei Kojima, Akiko Inagaki, Koichi Seki, Toshiro Takao

Journal of Organometallic Chemistry   885   7 - 20   2019年4月

Synthesis of a heterometallic spiked tetrahedral cluster of ruthenium and nickel containing multiple hydrido ligands and its degradation to a tetrahedral NiRu3 cluster 査読 国際誌

Takuya Kosukegawa, Toshiro Takao

Journal of Organometallic Chemistry   882   70 - 79   2019年3月

σ-Coordination of a P–H Bond at a Sterically Demanding Diruthenium Site: Tautomerization between Agostic μ-Phosphane and μ-Phosphanido Complexes via an η²-P–H Bond Cleavage 査読 国際誌

Ryuichi Shimogawa, Youhei Tsurumaki, Takuya Kuzutani, Toshiro Takao

Organometallics   37 ( 3 )   290 - 293   2018年1月

Preparation of Bis(μ₃-silylyne) Complexes via Consecutive Si–H Bond Cleavage at a Triruthenium Site 査読 国際誌

Hiroyuki Tsuruda, Yoshihiro Hayashi, Susumu Kawauchi, Toshiro Takao

Organometallics   36 ( 19 )   3774 - 3783   2017年9月

Synthesis of an Electron-Deficient Triruthenium Hydrido Complex Having a Bridging Carbonyl Ligand: Influence of a CO Ligand on the Properties and Reactivities of a Hydrido Cluster 査読 国際誌

Yuta Takahashi, Yumiko Nakajima, Hiroharu Suzuki, Toshiro Takao

Organometallics   36 ( 18 )   3539 - 3552   2017年8月

Half-sandwich Cyclopentadienyl Iridium Dichloride Monomer Cp^‡IrCl₂ (Cp^‡: 1,2,4-tri-tert-butylcyclopentadienyl) 査読 国際誌

Ryuichi Shimogawa, Toshiro Takao, Hiroharu Suzuki

Chemistry Letters   46 ( 2 )   197 - 199   2017年2月

Synthesis and characterisation of tetranuclear ruthenium polyhydrido clusters with pseudo-tetrahedral geometry 査読 国際誌

Hajime Kameo, Yutaka Ito, Ryuichi Shimogawa, Asuka Koizumi, Hiroki Chikamori, Junko Fujimoto, Hiroharu Suzuki, Toshiro Takao

Dalton Transactions   46 ( 17 )   5631 - 5643   2017年

Modified synthesis of mixed-ligand dinuclear Ru–Ir, Ru–Rh, and Ru–Ru polyhydride-bridged complexes, CpsRuH3ML (Cps = C5Me5 (Cp*), C5Bu3H2 (Cp‡); M = Rh, Ir, Ru; L = C5(CH3)5, C6H6, p-CH3C6H4CH(CH3)2) 査読 国際誌

Ryuichi Shimogawa, Toshiro Takao, Hiroharu Suzuki

Journal of Organometallic Chemistry   818   168 - 178   2016年9月

Synthesis of a Heterometallic Trinuclear Cluster of Ruthenium and Platinum with a Linear Alignment 査読 国際誌

Takuya Kuzutani, Yushi Torihata, Hiroharu Suzuki, Toshiro Takao

Organometallics   35 ( 15 )   2543 - 2556   2016年7月

Photolysis of triruthenium μ3-alkyne complexes capped by a μ3-oxo ligand 査読 国際誌

Takeshi Kaneko, Eisuke Murotani, Ryu-ichi Tenjimbayashi, Hiroharu Suzuki, Toshiro Takao

Journal of Organometallic Chemistry   812   167 - 176   2016年6月

Photoinduced Reactions of Diruthenium Tetrahydride Complexes: Carbon–Hydrogen Bond Cleavage of Tetrahydrofuran Leading to Bridging Cyclic Fischer-Type Carbene Complexes 査読 国際誌

Ryuichi Shimogawa, Gen-ichi Konishi, Toshiro Takao, Hiroharu Suzuki

Organometallics   35 ( 10 )   1446 - 1457   2016年3月

Versatile and highly efficient synthesis of diruthenium tetrahydride complex 査読 国際誌

Ryuichi Shimogawa, Toshiro Takao, Hiroharu Suzuki

Journal of Organometallic Chemistry   801   6 - 9   2016年1月

m3-h2:h2:h2-Coordination of Primary Silane on a Triruthenium Plane

Masahiro Nagaoka, Hiroyuki Tsuruda, Masa-aki Amako, HIROHARU SUZUKI, TOSHIRO TAKAO

Angew. Chem. Int. Ed.   Vol. 54 ( No. 49 )   2015年10月

μ₃‐η²:η²:η²‐Coordination of Primary Silane on a Triruthenium Plane 査読 国際誌

Masahiro Nagaoka, Hiroyuki Tsuruda, Masa‐aki Amako, Hiroharu Suzuki, Toshiro Takao

Angewandte Chemie International Edition   54 ( 49 )   14871 - 14874   2015年10月

Trinuclear μ₃-Silyl Complexes of Ruthenium and Group 9 Metals Having 3c-2e Interactions and Transformation of a μ₃-Silyl Complex of Ru₂Ir into μ-Silyl and μ₃-Silylene Complexes 査読 国際誌

Masahiro Nagaoka, Takanori Shima, Toshiro Takao, Hiroharu Suzuki

Organometallics   33 ( 24 )   7232 - 7240   2014年12月

Photochemical Reaction of Diruthenium Tetrahydride-Bridged Complexes with Carbon Dioxide: Insertion of CO₂ into a Ru–H Bond versus C═O Double-Bond Cleavage 査読 国際誌

Ryuichi Shimogawa, Toshiro Takao, Gen-ichi Konishi, Hiroharu Suzuki

Organometallics   33 ( 19 )   5066 - 5069   2014年8月

Activation of Linear Alkanes by a Hydrido Triruthenium Cluster and Associated Skeletal Rearrangements

Takao Toshiro, Suzuki Hiroharu

Bulletin of the Chemical Society of Japan   87 ( 4 )   443 - 458   2014年

Synthesis, Characterization, and Reactions of Ruthenium(II), -(III), and -(IV) Complexes with Sterically Demanding 1,2,4-Tri-tert-butylcyclopentadienyl Ligands 査読 国際誌

Ryuichi Shimogawa, Toshiro Takao, Hiroharu Suzuki

Organometallics   33 ( 1 )   289 - 301   2013年12月

A Triruthenium Complex Capped by a Triply Bridging Oxoboryl Ligand 査読

Takeshi Kaneko, Toshiro Takao, Hiroharu Suzuki

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   52 ( 45 )   11884 - 11887   2013年11月

Synthesis of a heterometallic trinuclear cluster of ruthenium and iridium containing a perpendicularly coordinated alkyne ligand and its dynamic behavior 査読

Masahiro Nagaoka, Takanori Shima, Toshiro Takao, Hiroharu Suzuki

Journal of Organometallic Chemistry   725   68 - 75   2013年2月

Intramolecular Borylene Transfer Leading to the Formation of a μ3-BC2 Ring on a Triruthenium Plane 査読

金子岳史, 諏訪仁史, 高尾俊郎, 鈴木寛治

Organometallics   32 ( 3 )   737 - 740   2013年2月

Complex Containing μ3-η2(||)-Ethyne and μ3-Methylidyne Ligands: Equilibrium of an Ethyne?Hydrido Complex with a Nonclassical μ3-Vinyl Complex 査読

田原淳士, 梶ヶ谷真奈, 高尾俊郎, 鈴木寛治

Organometallics   32 ( 1 )   260 - 271   2013年1月

Bimetallic Activation of 2-Alkanones through Photo-Induced α-Hydrogen Abstraction Mediated by a Dinuclear Tetrahydride Complex 査読

鈴木寛治, 下川隆一, 室井勇輝, 高尾俊郎, 大島 正人, 小西玄一

Angew. Chem. Int. Ed.   52 ( 6 )   1773 - 1776   2013年

Synthesis of a Heterometallic Trinuclear Cluster Containing Ruthenium and Cobalt and Its Reactivity with Internal Alkynes 査読

Masahiro Nagaoka, Toshiro Takao, Hiroharu Suzuki

ORGANOMETALLICS   31 ( 18 )   6547 - 6554   2012年9月

Synthesis of Triruthenium Complexes Containing a Triply Bridging Pyridyl Ligand and Its Transformations to Face-Capping Pyridine and Perpendicularly Coordinated Pyridyl Ligands 査読

Toshiro Takao, Takashi Kawashima, Hideyuki Kanda, Rei Okamura, Hiroharu Suzuki

ORGANOMETALLICS   31 ( 13 )   4817 - 4831   2012年7月

Formation of a Boraruthenacyclopentenyl Skeleton via B-C Bond Formation across a Triruthenium Plane 査読

Toshiro Takao, Hitoshi Suwa, Rei Okamura, Hiroharu Suzuki

ORGANOMETALLICS   31 ( 5 )   1825 - 1831   2012年3月

Skeletal rearrangement of hydrocarbyl ligands on a triruthenium core induced by chemical oxidation 査読

Toshiro Takao, Hiroharu Suzuki

COORDINATION CHEMISTRY REVIEWS   256 ( 5-8 )   695 - 708   2012年3月

Reactions of a Triruthenium Pentahydrido Complex with Imines Leading to the Formation of a Perpendicularly Coordinated Iminoacyl Ligand and the Scission of a C=N Bond on a Triruthenium Plane 査読

Hideyuki Kanda, Takashi Kawashima, Toshiro Takao, Hiroharu Suzuki

ORGANOMETALLICS   31 ( 5 )   1917 - 1926   2012年3月

Synthesis and Property of Diruthenium Complexes Containing Bridging Cyclic Diene Ligands and the Reaction of Diruthenium Tetrahydrido Complex with Benzene Forming a mu-eta(2):eta(2)-Cyclohexadiene Complex via Partial Hydrogenation on a Ru-2 Center 査読

Toshiro Takao, Nozomi Obayashi, Bo Zhao, Kazunori Akiyoshi, Hideki Omori, Hiroharu Suzuki

ORGANOMETALLICS   30 ( 18 )   5057 - 5067   2011年9月

Direct Arylation of a Cluster-Bound Alkyne Ligand with Benzene 査読

Toshiro Takao, Makoto Moriya, Mana Kajigaya, Hiroharu Suzuki

ORGANOMETALLICS   29 ( 21 )   4770 - 4773   2010年11月

Metathesis Reaction of Hydrocarbyl Ligands across the Triruthenium Plane 査読

Atsushi Tahara, Mana Kajigaya, Makoto Moriya, Toshiro Takao, Hiroharu Suzuki

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   49 ( 34 )   5898 - 5901   2010年

Arylation of Hydrocarbyl Ligands Formed from n-Alkanes through C-H Bond Activation of Benzene Using a Triruthenium Cluster 査読

Makoto Moriya, Atsushi Tahara, Toshiro Takao, Hiroharu Suzuki

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY   Vol. 2009 ( 23 )   3393 - 3397   2009年8月

三核ルテニウムクラスター上での炭化水素配位子の骨格転位

高尾 俊郎, 鈴木 寛治

有機合成化学協会誌   67 ( 5 )   475 - 485   2009年5月

Preparation and properties of diruthenium hydrido complexes having a bridging benzoquinone ligand: Formation of an alcohol adduct of a mu-eta(2):eta(2)-benzoquinone complex through hydrogen bonding 査読

Toshiro Takao, Kazunori Akiyoshi, Hiroharu Suzuki

ORGANOMETALLICS   27 ( 16 )   4199 - 4206   2008年8月

Insertion of acetylene and nitriles into a Ru-C bond of a dicationic triruthenium complex having a mu(3)-eta(3)-C-3 ring: Formation of six-membered ruthenacycles on a triruthenium core 査読

Toshiro Takao, Makoto Moriya, Hiroharu Suzuki

ORGANOMETALLICS   27 ( 6 )   1044 - 1054   2008年3月

Synthesis, structure, and property of a triruthenium cluster having a m-alkyl ligand: Transformation of a m3(^)-alkyne ligand into a m-alkyl ligand via a m3-vinylidene complex 査読

天神林隆一, 室谷英介, 竹森利郁, 高尾俊郎, 鈴木寛治

Journal of Organometallic Chemistry   Vol. 692   442 - 454   2008年1月

Introduction of a methoxy group into a hydrocarbyl ligand derived from a linear alkane on a triruthenium cluster via chemical oxidation 査読

Toshiro Takao, Makoto Moriya, Hiroharu Suzuki

ORGANOMETALLICS   27 ( 1 )   18 - 20   2008年1月

Dehydrogenative coupling of 4-substituted Pyridines catalyzed by diruthenium complexes 査読

Takashi Kawashima, Toshiro Takao, Hiroharu Suzuki

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   129 ( 36 )   11006 - +   2007年9月

Synthesis and structure of cationic triruthenium complexes containing an oxametallacycle: Reversible carbon-oxygen bond formation and scission on an electron-deficient triruthenium plane 査読

Makoto Moriya, Toshiro Takao, Hiroharu Suzuki

ORGANOMETALLICS   26 ( 7 )   1650 - 1657   2007年3月

Redox-induced reversible rearrangement of a dimetallaallyl ligand on the trinuclear cluster of ruthenium. Mechanistic aspects of formation of the face-capping mu(3)-C-3 ring on the triruthenium plane 査読

Toshiro Takao, Makoto Moriya, Hiroharu Suzuki

ORGANOMETALLICS   26 ( 6 )   1349 - 1360   2007年3月

Oxidation-induced rearrangement from a nido- to a closo-ruthenacyclopentadiene 査読

Toshiro Takao, Akiko Inagaki, Tsubomi Imamura, Hiroharu Suzuki

ORGANOMETALLICS   25 ( 23 )   5511 - 5514   2006年11月

Cleavage of the C-N Triple Bond on the Triruthenium Cluster: Synthesis and Structure of a Triruthenium Complex Containing a μ_3_-Nitrido Ligand

Takashi Kawashima, Toshiro Takao, Hiroharu Suzuki

Angew. Chem. Int. Ed.   45 ( 3 )   2006年

Synthesis and structure of a triruthenium complex containing a face-capping pyridine ligand 査読

Takashi Kawashima, Toshiro Takao, Hiroharu Suzuki

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   45 ( 45 )   7615 - 7618   2006年

Cleavage of the C-N Triple Bond on the Triruthenium Cluster: Synthesis and Structure of a Triruthenium Complex Containing a μ_3_-Nitrido Ligand 査読

高尾 俊郎

Angew. Chem. Int. Ed.   45 ( 3 )   485 - 488   2006年

Synthesis and Structure of a Triruthenium Complex Containing a Perpendicularly Coordinated μ_3_-η^2^:η^2^(⊥)-Nitrile Ligand, and Its Protonation to Yield a Perpendicularly Coordinated Iminoacyl Ligand 査読

Organometallics   24 ( 14 )   3371 - 3374   2005年7月

Substitution Reaction at a Bridging Silicon Ligand. Formation of a Bis(μ-Silylene) Complex Containing a Trifluoroacetoxyl Group, and Mechanistic Studies of the Site-exchange Process of the Hydride Ligands 査読

高尾 俊郎, 吉田 茂, 鈴木 寛治

Organometallics   24 ( 4 )   521 - 532   2005年2月

Synthesis, Structures, and Reactions of Coordinatively Unsaturated Trinuclear Ruthenium Polyhydrido Complexes, [{Ru(C_5_Me_5_)}_3_(μ-H)_6_](Y) (Y = BF_4_, CF_3_SO_3_, 1/2(SO_4_), C_6_H_5_CO_2_, CH_3_CO_2_, B(C_6_H_5_)_4_, PF_6_) and [{Ru(C_5_Me_5_)}_3_(μ-H)_3_(μ_3_-H)_2_]

Toshiro Takao

Bull. Chem. Soc. Jpn.   2005年

Synthesis, Structures, and Reactions of Coordinatively Unsaturated Trinuclear Ruthenium Polyhydrido Complexes, [{Ru(C5Me5)}3(.MU.-H)6](Y) (Y=BF4, CF3SO3, 1/2(SO4), C6H5CO2, CH3CO2, B(C6H5)4, PF6) and [{Ru(C5Me5)}3(.MU.-H)3(.MU.3-H)2]

Suzuki Hiroharu, Kakigano Takeaki, Tada Ken-ichi, Igarashi Minoru, Matsubara Kouki, Inagaki Akiko, Oshima Masato, Takao Toshiro

Bulletin of the Chemical Society of Japan   78 ( 1 )   67 - 87   2005年

Synthesis and characterization of triruthenium complexes containing a perpendicularly coordinated alkyne ligand 査読

T Takao, Y Takaya, E Murotani, RI Tenjimbayashi, H Suzuki

ORGANOMETALLICS   23 ( 26 )   6094 - 6096   2004年12月

Fluxional Behavior of a Perpendicularly Coordinated μ3-Alkyne ligand on a Triruthenium cluster. Synthesis and Structure of a μ_3_-η^2^:η^2^(⊥)-Cycloalkyne Complex 査読

Organometallics   23 ( 26 )   6094 - 6096   2004年12月

Fluxional behavior of a perpendicularly coordinated mu(3)-alkyne ligand on a triruthenium cluster. Synthesis and structure of a mu(3)-eta(2):eta(2)(perpendicular to)-cycloalkyne complex 査読

T Takao, S Kakuta, RI Tenjimbayashi, T Takemori, E Murotani, H Suzuki

ORGANOMETALLICS   23 ( 26 )   6090 - 6093   2004年12月

Successive Si-H/Si-C bond cleavage of tertiary silanes on diruthenium centers. Reactivities and fluxional behavior of the bis(m-silylene) complexes containing m-hydride ligands 査読

T Takao, MA Amako, H Suzuki

ORGANOMETALLICS   22 ( 19 )   3855 - 3876   2003年9月

Thermal skeletal rearrangement of a nido-ruthenacyclopentadiene complex involving reversible rupture and formation of a ruthenium-ruthenium bond

A Inagaki, T Takao, M Moriya, H Suzuki

ORGANOMETALLICS   22 ( 11 )   2196 - 2198   2003年5月

Bimetallic reductive C-C coupling reaction induced by chemical oxidation: Formation of a mu(3)-C-3 ring on a triruthenium cluster

T Takao, A Inagaki, E Murotani, T Imamura, H Suzuki

ORGANOMETALLICS   22 ( 7 )   1361 - 1363   2003年3月

Skeletal rearrangement of a C-2 unit on a triruthenium cluster. Synthesis of mu-ethylidene, mu 3-ethylidyne, and mu(3)-vinylidene complexes by the reaction of {Cp*Ru(mu-H)}(3)(mu(3)-H)(2) with acetylene 査読

T Takao, T Takemori, M Moriya, H Suzuki

ORGANOMETALLICS   21 ( 24 )   5190 - 5203   2002年11月

Reactions of diruthenium tetrahydride complex (eta(5)-C5Me5)Ru(mu-H)(4)Ru(eta(5)-C5Me5) with vinylsilanes: Formation of a mu-silylene complex via successive Si-H and Si-C bond cleavage of dimethylvinylsilane 査読

T Takao, MA Amako, H Suzuki

ORGANOMETALLICS   20 ( 16 )   3406 - 3422   2001年8月

Protonation of Bis-.MU.-diethylsilyl Complex {(C5Me5)Ru(.MU.-.ETA.2-HSiEt2)}2(.MU.-H)(H): Enhancement of Bonding Interaction between Bridging Silicon and Hydride Ligands.

Takao Toshiro, Yoshida Shigeru, Suzuki Hiroharu

Chemistry Letters   30 ( 11 )   1100 - 1101   2001年

SYNTHESIS, CHARACTERIZATION, AND REACTIVITIES OF DIRUTHENIUM COMPLEXES CONTAINING A MU-SILANE LIGAND AND STRUCTURAL STUDIES OF THE MU-SILANE COMPLEX [CP'RU(CO)](2)(MU-ETA(2)ETA(2)-H(2)SI(T)BU(2)) 査読

T TAKAO, S YOSHIDA, H SUZUKI, M TANAKA

ORGANOMETALLICS   14 ( 8 )   3855 - 3868   1995年8月

Insertion of Acetylene into The Ru-Si Bond of a Bis(μ-Silylene) Complex. Synthesis and Structure of a 2,5-Disilaruthenacyclopentene Complex 査読

高尾 俊郎, 鈴木 寛治, 田中 正子

Organometallics   13 ( 7 )   2554 - 2556   1994年7月

SYNTHESIS AND REACTIVITY OF DINUCLEAR MU-SILYL COMPLEXES OF RUTHENIUM HAVING 3-CENTER 2-ELECTRON RU-H-SI INTERACTIONS 査読

H SUZUKI, T TAKAO, M TANAKA, Y MOROOKA

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS   ( 6 )   476 - 478   1992年3月

Synthesis and Reactivities of Dinuclear μ-Silyl Complexes of Ruthenium having Three-center Two-electron Ru-H-Si Interactions. 査読

高尾 俊郎, 鈴木寛治, 田中 正子, 諸岡 良彦

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