Reaction of a Triruthenium μ₃-Borylene Complex with Benzonitrile: Formation of a μ₃-η³-BCN Ring on a Cationic Ru₃ Plane via Photo-Induced Intramolecular Borylene Transfer Reviewed International journal

Takeshi Kaneko, Toshiro Takao

Organometallics   39 ( 4 )   593 - 604   2020.2

Formation of a μ₃-Acetylide on a Ru₃ Cluster via Coupling of μ-Methylene with Isocyanide Accompanied by Elimination of Amine: A Model of Hydrogen-Assisted C–C Bond Formation on a Metal Surface Reviewed International journal

Hiroki Chikamori, Toshiro Takao

Organometallics   38 ( 14 )   2705 - 2709   2019.6

Diruthenium complexes having a partially hydrogenated bipyridine ligand: plausible mechanism for the dehydrogenative coupling of pyridines at a diruthenium site Invited Reviewed International journal

Toshiro Takao, Takashi Kawashima, Ryo Nagae, Hideyuki Kanda, Wataru Watanabe

Faraday Discussions   220   249 - 268   2019

Transformation of a μ₃-Benzyne Ligand into Phenol on a Cationic Triruthenium Cluster Supported by a μ₃-Sulfido Ligand Reviewed International journal

Hiroki Chikamori, Atsushi Tahara, Toshiro Takao

Organometallics   38 ( 2 )   527 - 535   2018.12

Catalytic Hydrogenation of Benzonitrile by Triruthenium Clusters: Consecutive Transformations of Benzonitrile on the Face of a Ru₃ Plane Reviewed International journal

Toshiro Takao, Sachie Horikoshi, Takashi Kawashima, Sachio Asano, Yuta Takahashi, Akira Sawano, Hiroharu Suzuki

Organometallics   37 ( 10 )   1598 - 1614   2018.5

Dehydrogenative Oxidation of Cyclic Amines on a Diruthenium Complex Reviewed International journal

Ryuichi Shimogawa, Ryosuke Fujita, Toshiro Takao, Hiroharu Suzuki

Organometallics   36 ( 10 )   1893 - 1896   2017.5

Dehydrogenative Coupling of 4-Substituted Pyridines Catalyzed by a Trinuclear Complex of Ruthenium and Cobalt Reviewed International journal

Masahiro Nagaoka, Takashi Kawashima, Hiroharu Suzuki, Toshiro Takao

Organometallics   35 ( 14 )   2348 - 2360   2016.7

Synthesis of cationic trinuclear heterobimetallic complexes of Ru and Fe containing μ- and μ3-ethylidyne ligands. Considerations on alkylidyne−alkylidyne coupling on a multimetallic site

Naoya Noguchi, Toshiro Takao

Journal of Organometallic Chemistry   2026.6

Photo-Induced Hydrogenation of a Cationic Triruthenium Complex Capped by a μ3-η3-C3 Ring: Fluxional Behavior of Hydrides in a Cationic Triruthenium Diruthenaallyl Complex with an Agostic Ru–H–C Interaction

Toshiro Takao, Shiyu Zhou

Organometallics   2026.4

Preparation of a series of heterobimetallic complexes containing bridging ethylidyne ligands by the reaction of diruthenium Bis(μ-ethylidyne) complex with 3d metal carbonyls: Alkylidyne−alkylidyne coupling reaction at the Ru2Fe site Reviewed International journal

Naoya Noguchi, Toshiro Takao

Journal of Organometallic Chemistry   1026   123497 - 123497   2025.2

Synthesis of a 50-electron triangular ruthenium cluster containing a μ3-methylidyne ligand via the fragmentation of the Ru2 skeleton Reviewed International journal

Toshiro Takao, Shu Egawa, Takayuki Ochi, Takeshi Fukuyama

Journal of Organometallic Chemistry   1013   123157 - 123157   2024.6

Skeletal Rearrangement of a μ–η²:η⁴-Hexatrienyl Ligand at a Diruthenium Site via a μ–η⁵-Ruthenacyclohexadienyl Intermediate Reviewed International journal

Toshiro Takao, Taiki Taniguchi, Yohei Tsurumaki

Organometallics   43 ( 8 )   866 - 878   2024.4

Heterobimetallic Trihydrido Complex of Ruthenium and Rhodium Supported by Cyclopentadienyl Groups with Different Steric Demands Reviewed International journal

Toshiro Takao, Taichi Monoe, Ryuichi Shimogawa, Keigo Nakamura

Organometallics   42 ( 15 )   2087 - 2101   2023.7

Photo-Induced Reaction of Cp*Ru(μ-H)₄RuCp* with Arenes Resulting in Irreversible Formation of μ-η²:η²-Cyclohexadiene Complexes Reviewed International journal

Ryuichi Shimogawa, Yuki Muroi, Naoya Noguchi, Gen-ichi Konishi, Toshiro Takao, Hiroharu Suzuki

Organometallics   41 ( 23 )   3750 - 3761   2022.11

Mono- and Bis-cyclopentadienyl Complexes of Ruthenium and Osmium Invited Reviewed International journal

Toshiro Takao, Akiko Inagaki

Comprehensive Organometallic Chemistry IV   294 - 443   2022.8

Syntheses and Properties of Triruthenium Polyhydrido Complexes Composed of 1,2,4-tri-tert-butylcyclopentadienyl and p-Cymene Ruthenium Units Reviewed International journal

Toshiro Takao, Hidenori Suzuki, Ryuichi Shimogawa

Organometallics   40 ( 9 )   1303 - 1313   2021.4

Synthesis of Diruthenium μ-Chloromethylidyne Complex: C–C Bond Formation at the Bridging Carbon Atom via the Reduction of a μ-Chloromethylidyne Ligand International journal

Toshiro Takao, Koichi Seki

Organometallics   40 ( 4 )   467 - 471   2021.2

Four-Electron Reduction of Dioxygen on a Metal Surface: Models of Dissociative and Associative Mechanisms in a Homogeneous System Reviewed International journal

Hajime Kameo, Shigeyoshi Sakaki, Yasuhiro Ohki, Naoki Uehara, Takuya Kosukegawa, Hiroharu Suzuki, Toshiro Takao

Inorganic Chemistry   60 ( 3 )   1550 - 1560   2020.11

Reversible Transformation of a μ₃-η³-C₃ Ring into μ₃-η²-Ethyne and μ-Vinylidene Ligands at a Triruthenium Site upon Deprotonation and Protonation Reviewed International journal

Toshiro Takao, Koichi Seki

Organometallics   39 ( 24 )   4637 - 4644   2020.11

Synthesis and site-dependent reactivity of a heterometallic dinuclear bis(μ-imido) complex of tungsten and ruthenium Reviewed International journal

Hiroyuki Tsuruda, Toshiro Takao

Journal of Organometallic Chemistry   919   121296 - 121296   2020.7

Selective Synthesis of a Triruthenium Pentahydrido Complex with Mixed-Cp Ligands (C₅^tBu₃H₂ and C₅Me₅) and Its Transformation into Face-Capping Benzene Complexes: Fluxionality of a Face-Capping Benzene Ligand Induced by Oxidation Reviewed International journal

Ryuichi Shimogawa, Yohei Tsurumaki, Hidenori Suzuki, Toshiro Takao

Organometallics   38 ( 19 )   3824 - 3833   2019.9

Synthesis and Properties of a Triruthenium Hydrido Complex Capped by a μ₃-Oxoboryl Ligand Reviewed International journal

Takeshi Kaneko, Hayato Ninagawa, Moe Matsuoka, Toshiro Takao

Organometallics   38 ( 9 )   2239 - 2249   2019.4

Effect of ring size on the properties of μ3-Cycloalkyne complexes: Synthesis of triruthenium complexes containing a perpendicularly coordinated μ3-Allenyl ligand Reviewed International journal

Moeko Saito, Shuhei Kojima, Akiko Inagaki, Koichi Seki, Toshiro Takao

Journal of Organometallic Chemistry   885   7 - 20   2019.4

Synthesis of a heterometallic spiked tetrahedral cluster of ruthenium and nickel containing multiple hydrido ligands and its degradation to a tetrahedral NiRu3 cluster Reviewed International journal

Takuya Kosukegawa, Toshiro Takao

Journal of Organometallic Chemistry   882   70 - 79   2019.3

σ-Coordination of a P–H Bond at a Sterically Demanding Diruthenium Site: Tautomerization between Agostic μ-Phosphane and μ-Phosphanido Complexes via an η²-P–H Bond Cleavage Reviewed International journal

Ryuichi Shimogawa, Youhei Tsurumaki, Takuya Kuzutani, Toshiro Takao

Organometallics   37 ( 3 )   290 - 293   2018.1

Preparation of Bis(μ₃-silylyne) Complexes via Consecutive Si–H Bond Cleavage at a Triruthenium Site Reviewed International journal

Hiroyuki Tsuruda, Yoshihiro Hayashi, Susumu Kawauchi, Toshiro Takao

Organometallics   36 ( 19 )   3774 - 3783   2017.9

Synthesis of an Electron-Deficient Triruthenium Hydrido Complex Having a Bridging Carbonyl Ligand: Influence of a CO Ligand on the Properties and Reactivities of a Hydrido Cluster Reviewed International journal

Yuta Takahashi, Yumiko Nakajima, Hiroharu Suzuki, Toshiro Takao

Organometallics   36 ( 18 )   3539 - 3552   2017.8

Half-sandwich Cyclopentadienyl Iridium Dichloride Monomer Cp^‡IrCl₂ (Cp^‡: 1,2,4-tri-tert-butylcyclopentadienyl) Reviewed International journal

Ryuichi Shimogawa, Toshiro Takao, Hiroharu Suzuki

Chemistry Letters   46 ( 2 )   197 - 199   2017.2

Synthesis and characterisation of tetranuclear ruthenium polyhydrido clusters with pseudo-tetrahedral geometry Reviewed International journal

Hajime Kameo, Yutaka Ito, Ryuichi Shimogawa, Asuka Koizumi, Hiroki Chikamori, Junko Fujimoto, Hiroharu Suzuki, Toshiro Takao

Dalton Transactions   46 ( 17 )   5631 - 5643   2017

Modified synthesis of mixed-ligand dinuclear Ru–Ir, Ru–Rh, and Ru–Ru polyhydride-bridged complexes, CpsRuH3ML (Cps = C5Me5 (Cp*), C5Bu3H2 (Cp‡); M = Rh, Ir, Ru; L = C5(CH3)5, C6H6, p-CH3C6H4CH(CH3)2) Reviewed International journal

Ryuichi Shimogawa, Toshiro Takao, Hiroharu Suzuki

Journal of Organometallic Chemistry   818   168 - 178   2016.9

Synthesis of a Heterometallic Trinuclear Cluster of Ruthenium and Platinum with a Linear Alignment Reviewed International journal

Takuya Kuzutani, Yushi Torihata, Hiroharu Suzuki, Toshiro Takao

Organometallics   35 ( 15 )   2543 - 2556   2016.7

Photolysis of triruthenium μ3-alkyne complexes capped by a μ3-oxo ligand Reviewed International journal

Takeshi Kaneko, Eisuke Murotani, Ryu-ichi Tenjimbayashi, Hiroharu Suzuki, Toshiro Takao

Journal of Organometallic Chemistry   812   167 - 176   2016.6

Photoinduced Reactions of Diruthenium Tetrahydride Complexes: Carbon–Hydrogen Bond Cleavage of Tetrahydrofuran Leading to Bridging Cyclic Fischer-Type Carbene Complexes Reviewed International journal

Ryuichi Shimogawa, Gen-ichi Konishi, Toshiro Takao, Hiroharu Suzuki

Organometallics   35 ( 10 )   1446 - 1457   2016.3

Versatile and highly efficient synthesis of diruthenium tetrahydride complex Reviewed International journal

Ryuichi Shimogawa, Toshiro Takao, Hiroharu Suzuki

Journal of Organometallic Chemistry   801   6 - 9   2016.1

m3-h2:h2:h2-Coordination of Primary Silane on a Triruthenium Plane

Masahiro Nagaoka, Hiroyuki Tsuruda, Masa-aki Amako, HIROHARU SUZUKI, TOSHIRO TAKAO

Angew. Chem. Int. Ed.   Vol. 54 ( No. 49 )   2015.10

μ₃‐η²:η²:η²‐Coordination of Primary Silane on a Triruthenium Plane Reviewed International journal

Masahiro Nagaoka, Hiroyuki Tsuruda, Masa‐aki Amako, Hiroharu Suzuki, Toshiro Takao

Angewandte Chemie International Edition   54 ( 49 )   14871 - 14874   2015.10

Trinuclear μ₃-Silyl Complexes of Ruthenium and Group 9 Metals Having 3c-2e Interactions and Transformation of a μ₃-Silyl Complex of Ru₂Ir into μ-Silyl and μ₃-Silylene Complexes Reviewed International journal

Masahiro Nagaoka, Takanori Shima, Toshiro Takao, Hiroharu Suzuki

Organometallics   33 ( 24 )   7232 - 7240   2014.12

Photochemical Reaction of Diruthenium Tetrahydride-Bridged Complexes with Carbon Dioxide: Insertion of CO₂ into a Ru–H Bond versus C═O Double-Bond Cleavage Reviewed International journal

Ryuichi Shimogawa, Toshiro Takao, Gen-ichi Konishi, Hiroharu Suzuki

Organometallics   33 ( 19 )   5066 - 5069   2014.8

Activation of Linear Alkanes by a Hydrido Triruthenium Cluster and Associated Skeletal Rearrangements

Takao Toshiro, Suzuki Hiroharu

Bulletin of the Chemical Society of Japan   87 ( 4 )   443 - 458   2014

Synthesis, Characterization, and Reactions of Ruthenium(II), -(III), and -(IV) Complexes with Sterically Demanding 1,2,4-Tri-tert-butylcyclopentadienyl Ligands Reviewed International journal

Ryuichi Shimogawa, Toshiro Takao, Hiroharu Suzuki

Organometallics   33 ( 1 )   289 - 301   2013.12

A Triruthenium Complex Capped by a Triply Bridging Oxoboryl Ligand Reviewed

Takeshi Kaneko, Toshiro Takao, Hiroharu Suzuki

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   52 ( 45 )   11884 - 11887   2013.11

Synthesis of a heterometallic trinuclear cluster of ruthenium and iridium containing a perpendicularly coordinated alkyne ligand and its dynamic behavior Reviewed

Masahiro Nagaoka, Takanori Shima, Toshiro Takao, Hiroharu Suzuki

Journal of Organometallic Chemistry   725   68 - 75   2013.2

Intramolecular Borylene Transfer Leading to the Formation of a mu(3)-BC2 Ring on a Triruthenium Cluster Reviewed

Takeshi Kaneko, Hitoshi Suwa, Toshiro Takao, Hiroharu Suzuki

ORGANOMETALLICS   32 ( 3 )   737 - 740   2013.2

Synthesis and Dynamic Properties of a Triruthenium Complex Containing mu(3)-eta(2)(parallel to)-Ethyne and mu(3)-Methylidyne Ligands: Equilibrium of an Ethyne-Hydrido Complex with a Nonclassical mu(3)-Vinyl Complex Reviewed

Atsushi Tahara, Mana Kajigaya, Toshiro Takao, Hiroharu Suzuki

ORGANOMETALLICS   32 ( 1 )   260 - 271   2013.1

Bimetallic Activation of 2-Alkanones through Photo-Induced alpha-Hydrogen Abstraction Mediated by a Dinuclear Ruthenium Tetrahydride Complex Reviewed

Hiroharu Suzuki, Ryuichi Shimogawa, Yuki Muroi, Toshiro Takao, Masato Oshima, Gen-ichi Konishi

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   52 ( 6 )   1773 - 1776   2013

Synthesis of a Heterometallic Trinuclear Cluster Containing Ruthenium and Cobalt and Its Reactivity with Internal Alkynes Reviewed

Masahiro Nagaoka, Toshiro Takao, Hiroharu Suzuki

ORGANOMETALLICS   31 ( 18 )   6547 - 6554   2012.9

Synthesis of Triruthenium Complexes Containing a Triply Bridging Pyridyl Ligand and Its Transformations to Face-Capping Pyridine and Perpendicularly Coordinated Pyridyl Ligands Reviewed

Toshiro Takao, Takashi Kawashima, Hideyuki Kanda, Rei Okamura, Hiroharu Suzuki

ORGANOMETALLICS   31 ( 13 )   4817 - 4831   2012.7

Formation of a Boraruthenacyclopentenyl Skeleton via B-C Bond Formation across a Triruthenium Plane Reviewed

Toshiro Takao, Hitoshi Suwa, Rei Okamura, Hiroharu Suzuki

ORGANOMETALLICS   31 ( 5 )   1825 - 1831   2012.3

Skeletal rearrangement of hydrocarbyl ligands on a triruthenium core induced by chemical oxidation Reviewed

Toshiro Takao, Hiroharu Suzuki

COORDINATION CHEMISTRY REVIEWS   256 ( 5-8 )   695 - 708   2012.3

Reactions of a Triruthenium Pentahydrido Complex with Imines Leading to the Formation of a Perpendicularly Coordinated Iminoacyl Ligand and the Scission of a C=N Bond on a Triruthenium Plane Reviewed

Hideyuki Kanda, Takashi Kawashima, Toshiro Takao, Hiroharu Suzuki

ORGANOMETALLICS   31 ( 5 )   1917 - 1926   2012.3

Synthesis and Property of Diruthenium Complexes Containing Bridging Cyclic Diene Ligands and the Reaction of Diruthenium Tetrahydrido Complex with Benzene Forming a mu-eta(2):eta(2)-Cyclohexadiene Complex via Partial Hydrogenation on a Ru-2 Center Reviewed

Toshiro Takao, Nozomi Obayashi, Bo Zhao, Kazunori Akiyoshi, Hideki Omori, Hiroharu Suzuki

ORGANOMETALLICS   30 ( 18 )   5057 - 5067   2011.9

Direct Arylation of a Cluster-Bound Alkyne Ligand with Benzene Reviewed

Toshiro Takao, Makoto Moriya, Mana Kajigaya, Hiroharu Suzuki

ORGANOMETALLICS   29 ( 21 )   4770 - 4773   2010.11

Metathesis Reaction of Hydrocarbyl Ligands across the Triruthenium Plane Reviewed

Atsushi Tahara, Mana Kajigaya, Makoto Moriya, Toshiro Takao, Hiroharu Suzuki

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   49 ( 34 )   5898 - 5901   2010

Arylation of Hydrocarbyl Ligands Formed from n-Alkanes through C-H Bond Activation of Benzene Using a Triruthenium Cluster Reviewed

Makoto Moriya, Atsushi Tahara, Toshiro Takao, Hiroharu Suzuki

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY   Vol. 2009 ( 23 )   3393 - 3397   2009.8

Skeletal Rearrangement of a Hydrocarbyl Moiety on a Triruthenium Cluster

TAKAO Toshiro, SUZUKI Hiroharu

Journal of Synthetic Organic Chemistry, Japan   67 ( 5 )   475 - 485   2009.5

Preparation and properties of diruthenium hydrido complexes having a bridging benzoquinone ligand: Formation of an alcohol adduct of a mu-eta(2):eta(2)-benzoquinone complex through hydrogen bonding Reviewed

Toshiro Takao, Kazunori Akiyoshi, Hiroharu Suzuki

ORGANOMETALLICS   27 ( 16 )   4199 - 4206   2008.8

Insertion of acetylene and nitriles into a Ru-C bond of a dicationic triruthenium complex having a mu(3)-eta(3)-C-3 ring: Formation of six-membered ruthenacycles on a triruthenium core Reviewed

Toshiro Takao, Makoto Moriya, Hiroharu Suzuki

ORGANOMETALLICS   27 ( 6 )   1044 - 1054   2008.3

Synthesis, structure, and property of a triruthenium cluster having a m-alkyl ligand: Transformation of a m3(^)-alkyne ligand into a m-alkyl ligand via a m3-vinylidene complex Reviewed

Ryu-ichi Tenjimbayashi, Eisuke Murotani, Toshifumi Takemori, TOSHIRO TAKAO, Hiroharu Suzuki

Journal of Organometallic Chemistry   Vol. 692   442 - 454   2008.1

Introduction of a methoxy group into a hydrocarbyl ligand derived from a linear alkane on a triruthenium cluster via chemical oxidation Reviewed

Toshiro Takao, Makoto Moriya, Hiroharu Suzuki

ORGANOMETALLICS   27 ( 1 )   18 - 20   2008.1

Dehydrogenative coupling of 4-substituted Pyridines catalyzed by diruthenium complexes Reviewed

Takashi Kawashima, Toshiro Takao, Hiroharu Suzuki

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   129 ( 36 )   11006 - +   2007.9

Synthesis and structure of cationic triruthenium complexes containing an oxametallacycle: Reversible carbon-oxygen bond formation and scission on an electron-deficient triruthenium plane Reviewed

Makoto Moriya, Toshiro Takao, Hiroharu Suzuki

ORGANOMETALLICS   26 ( 7 )   1650 - 1657   2007.3

Redox-induced reversible rearrangement of a dimetallaallyl ligand on the trinuclear cluster of ruthenium. Mechanistic aspects of formation of the face-capping mu(3)-C-3 ring on the triruthenium plane Reviewed

Toshiro Takao, Makoto Moriya, Hiroharu Suzuki

ORGANOMETALLICS   26 ( 6 )   1349 - 1360   2007.3

Oxidation-induced rearrangement from a nido- to a closo-ruthenacyclopentadiene Reviewed

Toshiro Takao, Akiko Inagaki, Tsubomi Imamura, Hiroharu Suzuki

ORGANOMETALLICS   25 ( 23 )   5511 - 5514   2006.11

Cleavage of the C-N Triple Bond on the Triruthenium Cluster: Synthesis and Structure of a Triruthenium Complex Containing a μ_3_-Nitrido Ligand

Takashi Kawashima, Toshiro Takao, Hiroharu Suzuki

Angew. Chem. Int. Ed.   45 ( 3 )   2006

Synthesis and structure of a triruthenium complex containing a face-capping pyridine ligand Reviewed

Takashi Kawashima, Toshiro Takao, Hiroharu Suzuki

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   45 ( 45 )   7615 - 7618   2006

Cleavage of the C N bond on a triruthenium cluster: Synthesis and structure of a triruthenium complex containing a mu(3)-nitrido ligand Reviewed

T Kawashima, T Takao, H Suzuki

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   45 ( 3 )   485 - 488   2006

Synthesis and structure of a triruthenium complex containing a perpendicularly coordinated mu(3)-eta(2):eta(2)(perpendicular to)-nitrile ligand and its protonation to yield a perpendicularly coordinated iminoacyl ligand Reviewed

T Takao, T Kawashima, K Matsubara, H Suzuki

ORGANOMETALLICS   24 ( 14 )   3371 - 3374   2005.7

Substitution reactions at a bridging silicon ligand. Formation of a bis(mu-silylene) complex containing a trifluoroacetoxy group. Mechanistic studies of the site-exchange process of the hydride ligands Reviewed

T Takao, S Yoshida, H Suzuki

ORGANOMETALLICS   24 ( 4 )   521 - 532   2005.2

Synthesis, Structures, and Reactions of Coordinatively Unsaturated Trinuclear Ruthenium Polyhydrido Complexes, [{Ru(C_5_Me_5_)}_3_(μ-H)_6_](Y) (Y = BF_4_, CF_3_SO_3_, 1/2(SO_4_), C_6_H_5_CO_2_, CH_3_CO_2_, B(C_6_H_5_)_4_, PF_6_) and [{Ru(C_5_Me_5_)}_3_(μ-H)_3_(μ_3_-H)_2_]

Toshiro Takao

Bull. Chem. Soc. Jpn.   2005

Synthesis, Structures, and Reactions of Coordinatively Unsaturated Trinuclear Ruthenium Polyhydrido Complexes, [{Ru(C5Me5)}3(.MU.-H)6](Y) (Y=BF4, CF3SO3, 1/2(SO4), C6H5CO2, CH3CO2, B(C6H5)4, PF6) and [{Ru(C5Me5)}3(.MU.-H)3(.MU.3-H)2]

Suzuki Hiroharu, Kakigano Takeaki, Tada Ken-ichi, Igarashi Minoru, Matsubara Kouki, Inagaki Akiko, Oshima Masato, Takao Toshiro

Bulletin of the Chemical Society of Japan   78 ( 1 )   67 - 87   2005

Synthesis and characterization of triruthenium complexes containing a perpendicularly coordinated alkyne ligand Reviewed

T Takao, Y Takaya, E Murotani, RI Tenjimbayashi, H Suzuki

ORGANOMETALLICS   23 ( 26 )   6094 - 6096   2004.12

Synthesis and characterization of triruthenium complexes containing a perpendicularly coordinated alkyne ligand Reviewed

T Takao, Y Takaya, E Murotani, RI Tenjimbayashi, H Suzuki

ORGANOMETALLICS   23 ( 26 )   6094 - 6096   2004.12

Fluxional behavior of a perpendicularly coordinated mu(3)-alkyne ligand on a triruthenium cluster. Synthesis and structure of a mu(3)-eta(2):eta(2)(perpendicular to)-cycloalkyne complex Reviewed

T Takao, S Kakuta, RI Tenjimbayashi, T Takemori, E Murotani, H Suzuki

ORGANOMETALLICS   23 ( 26 )   6090 - 6093   2004.12

Successive Si-H/Si-C bond cleavage of tertiary silanes on diruthenium centers. Reactivities and fluxional behavior of the bis(m-silylene) complexes containing m-hydride ligands Reviewed

T Takao, MA Amako, H Suzuki

ORGANOMETALLICS   22 ( 19 )   3855 - 3876   2003.9

Thermal skeletal rearrangement of a nido-ruthenacyclopentadiene complex involving reversible rupture and formation of a ruthenium-ruthenium bond

A Inagaki, T Takao, M Moriya, H Suzuki

ORGANOMETALLICS   22 ( 11 )   2196 - 2198   2003.5

Bimetallic reductive C-C coupling reaction induced by chemical oxidation: Formation of a mu(3)-C-3 ring on a triruthenium cluster

T Takao, A Inagaki, E Murotani, T Imamura, H Suzuki

ORGANOMETALLICS   22 ( 7 )   1361 - 1363   2003.3

Skeletal rearrangement of a C-2 unit on a triruthenium cluster. Synthesis of mu-ethylidene, mu 3-ethylidyne, and mu(3)-vinylidene complexes by the reaction of {Cp*Ru(mu-H)}(3)(mu(3)-H)(2) with acetylene Reviewed

T Takao, T Takemori, M Moriya, H Suzuki

ORGANOMETALLICS   21 ( 24 )   5190 - 5203   2002.11

Reactions of diruthenium tetrahydride complex (eta(5)-C5Me5)Ru(mu-H)(4)Ru(eta(5)-C5Me5) with vinylsilanes: Formation of a mu-silylene complex via successive Si-H and Si-C bond cleavage of dimethylvinylsilane Reviewed

T Takao, MA Amako, H Suzuki

ORGANOMETALLICS   20 ( 16 )   3406 - 3422   2001.8

Protonation of Bis-.MU.-diethylsilyl Complex {(C5Me5)Ru(.MU.-.ETA.2-HSiEt2)}2(.MU.-H)(H): Enhancement of Bonding Interaction between Bridging Silicon and Hydride Ligands.

Takao Toshiro, Yoshida Shigeru, Suzuki Hiroharu

Chemistry Letters   30 ( 11 )   1100 - 1101   2001

SYNTHESIS, CHARACTERIZATION, AND REACTIVITIES OF DIRUTHENIUM COMPLEXES CONTAINING A MU-SILANE LIGAND AND STRUCTURAL STUDIES OF THE MU-SILANE COMPLEX [CP'RU(CO)](2)(MU-ETA(2)ETA(2)-H(2)SI(T)BU(2)) Reviewed

T TAKAO, S YOSHIDA, H SUZUKI, M TANAKA

ORGANOMETALLICS   14 ( 8 )   3855 - 3868   1995.8

INSERTION OF ACETYLENE INTO THE RU-SI BOND OF A BIS(MU-SILYLENE) COMPLEX - SYNTHESIS AND STRUCTURE OF A 2,5-DISILARUTHENACYCLOPENTENE COMPLEX Reviewed

T TAKAO, H SUZUKI, M TANAKA

ORGANOMETALLICS   13 ( 7 )   2554 - 2556   1994.7

SYNTHESIS AND REACTIVITY OF DINUCLEAR MU-SILYL COMPLEXES OF RUTHENIUM HAVING 3-CENTER 2-ELECTRON RU-H-SI INTERACTIONS Reviewed

H SUZUKI, T TAKAO, M TANAKA, Y MOROOKA

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS   ( 6 )   476 - 478   1992.3

Synthesis and reactivity of dinuclear μ-silyl complexes of ruthenium having three-centre two-electron Ru-H-Si interactions Reviewed

Hiroharu Suzuki, Toshiro Takao, Masako Tanaka, Yoshihiko Moro-Oka

Journal of the Chemical Society, Chemical Communications   ( 6 )   476 - 478   1992

三重架橋メチリジン配位子を有する 50 電子カチオン性ルテニウ ム三核錯体の合成及び反応性

江川 周, 高尾 俊郎

日本化学会第103春季年会  2023.3  日本化学会

二重芳香族性 Ru2C2コアをもつ二核ルテニウムビス架橋エチリジ ン錯体の反応性

野口 尚弥, 高尾 俊郎

日本化学会第103春季年会  2023.3  日本化学会

レニウムと9族金属からなる二核ポリヒドリド錯体の合成と反応性

松澤慎司, 長岡正宏, 高尾俊郎

第67回有機金属化学討論会  2021.9  近畿化学協会

ジカチオン性ベンザイン三核ルテニウム錯体とアンモニアとの反応によるC-N結合の形成

甲斐雅隆, 高尾俊郎

第67回有機金属化学討論会  2021.9  近畿化学協会

ビス架橋アルキリジン錯体のRu2C2コアの二重芳香族性と架橋アルキリジン配位子間のカップリング反応

高尾俊郎, 関晃一

第67回有機金属化学討論会  2021.9  近畿化学協会

Control over the Reactivity of a Polyhydrido Cluster via Subtle Interaction with Alcohol

Grant number：19550058  2007 - 2010

Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research  Grant-in-Aid for Scientific Research (C)

TAKAO Toshiro

Reaction Chemistry of Transition Metal Clusters

Grant number：18105002  2006 - 2010

Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research  Grant-in-Aid for Scientific Research (S)

SUZUKI Hiroharu

Precision Designing of Multinuclear Transition Metal Complexes

Grant number：18064007  2006 - 2009

Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research  Grant-in-Aid for Scientific Research on Priority Areas

SUZUKI Hiroharu, TAKAO Toshiro

Reduction and Synthetic Application of Dinitrogen Mediated by Metal Polyhydrido Clusters

Grant number：15205009  2003 - 2005

Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research  Grant-in-Aid for Scientific Research (A)

SUZUKI Hiroharu, TAKAO Toshiro

Inorganica Chimica Acdta International contribution

Role(s)： Peer review

Elsevier  2025.1

Organometallics

Role(s)： Peer review

American Chemical Society  2024.12

New Journal of Chemistry

Role(s)： Peer review

Royal Society of Chemistry  2024.11

Organometallics

Role(s)： Peer review

American Chemical Socety  2024.10 - 2024.11

Elsevier Journal of Molecular Structure

Role(s)： Peer review

Elsevier  2024.8

Angewandte Chemie International Edition

Role(s)： Peer review

Wiley  2024.8

Inorganica Chimica Acta

Role(s)： Peer review

Elsevier  2024.8

New Journal of Chemistry

Role(s)： Peer review

Royal Society of Chemistry  2024.7

Elsevier Journal of Molecular Structure

Role(s)： Peer review

Elsevier  2024.6 - 2024.7

Journal of the American Chemical Society

Role(s)： Peer review

American Chemical Society  2024.6 - 2024.7

ACS Omega

Role(s)： Peer review

American Chemical Society  2024.5