Updated on 2026/01/09

写真a

 
SHIRATORI YOSUKE
 
Organization
Institute of Integrated Research Laboratory for Zero-Carbon Energy Specially Appointed Professor
Title
Specially Appointed Professor
Contact information
メールアドレス
External link

Degree

  • Dr. Sc. ( 2000.3   Ritsumeikan University )

Research Interests

  • Secondary-battery materials

  • Environmental energy materials

  • Water-based quasi-solid-state battery

  • Materials chemistry

  • Electroceramics

  • Carbon nanotube

  • Physical chemistry

Research Areas

  • Nanotechnology/Materials / Composite materials and interfaces  / Water-based quasi-solid-state battery

  • Environmental Science/Agriculture Science / Environmental materials and recycle technology  / Water-based quasi-solid-state battery

  • Nanotechnology/Materials / Fundamental physical chemistry  / Surface enhanced Raman spectroscopy

  • Nanotechnology/Materials / Structural materials and functional materials  / Carbon nanotube

  • Nanotechnology/Materials / Inorganic compounds and inorganic materials chemistry  / Artificial photosynthesis

  • Nanotechnology/Materials / Inorganic compounds and inorganic materials chemistry  / Lead-free piezoceramics

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Education

  • Ritsumeikan University   Graduate School of Science and Engineering   Science and Engineering Major

    1998.4 - 2000.3

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    Country: Japan

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Research History

  • Institute of Science Tokyo   Laboratory for Zero-Carbon Energy   Specially Appointed Professor

    2025.6

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  • Fujifilm Corporation   Analytical Technology Center   Senior researcher

    2011.10 - 2025.5

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    Country:Japan

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  • The University of Tokyo   The Graduate School of Engineering Department of Chemical System Engineering   Specially appointed assistant professor

    2006.12 - 2011.9

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    Country:Japan

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  • Helmholtz Association Research Center Juelich   Institute for solid state research   Researcher   Humboldt researcher

    2003.3 - 2006.11

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Professional Memberships

Papers

  • Borate‐Water‐Based 3D‐Slime Interface Quasi‐Solid Electrolytes for Li‐ion Batteries Reviewed

    Yosuke Shiratori, Kenta Watanabe, Kengo Saito, Ryota Sato, Yukihiro Okuno, Shintaro Yasui

    Advanced Materials   2025.7

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    Authorship:Lead author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)   Publisher:Wiley  

    Abstract

    The development of solid‐state batteries (SSBs) that do not use hazardous materials as electrolytes and are not flammable is progressing rapidly, however the production of sulfide‐based SSBs requires strict low‐dew‐point control due to their high reactivity with atmospheric moisture and the concern of generating hydrogen sulfide, and several issues remain in terms of the cost and recyclability. Thus, low‐cost facile materials and low‐CO2‐emission processes are necessary. With regard to oxide‐type SSBs, which are attracting attention for their safety, there are issues with manufacturing suitability, as high‐temperature sintering of oxide solid electrolyte particles is required. A new quasi‐solid‐state (QSS) electrolyte with 3D‐ionic conduction and adhesive interfaces by combining amorphous Li2B4O7 and water (3D‐Slime Interface Solid Electrolyte: 3D‐SLISE) is synthesized without stringent dew point control and sintering. Electrode and electrolyte slurries containing 3D‐SLISE are applied to current‐collecting foils in air, naturally dried, and used to construct battery laminates. 3D‐SLISE‐QSSBs (LiCoO2 cathode/3D‐SLISE with 7 wt.% bound‐water/Li4Ti5O12 or TiNb2O7 anodes) maintain several hundred cycles of charge/discharge as a 2.35 V lithium‐ion battery. The 3D‐SLISE‐QSSB technology can promote the use of safe and low‐cost batteries, eliminate the need for a dry room during manufacturing, and enable direct recycling of active materials.

    DOI: 10.1002/adma.202505649

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  • Raman scattering studies on nanocrystalline BaTiO3 Part I—isolated particles and aggregates Reviewed

    Y. Shiratori, C. Pithan, J. Dornseiffer, R. Waser

    Journal of Raman Spectroscopy   38 ( 10 )   1288 - 1299   2007.6

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    Authorship:Lead author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)   Publisher:Wiley  

    Abstract

    BaTiO3 powders with various crystallite sizes, which were prepared through microemulsion‐mediated synthesis, were thoroughly studied by Raman spectroscopy. Clear evidence for the presence of the tetragonal phase was found for ultrafine powders with an average crystallite size above 30 nm. The lifetime of phonons that are specifically assigned to the tetragonal phase decreased with decreasing crystallite size below a critical size of 100 nm. In particles as fine as 100 nm, the short mean free path of phonons, mainly due to internal pressure, causes decoupling of the coupled A1 (TO) phonons and a diffuse phase transition behaviour (TC = 115 °C). Coupled A1(TO) phonons, which give a spectral dip at around 180 cm−1 and a lesser extent of diffuseness, were revealed for powders consisting of particles as large as 0.17 µm (TC = 123 °C). Further coarsening upon annealing induced the formation of aggregates, resulting in the shift of phase transition points to higher temperatures for the rhombohedral to orthorhombic and the orthorhombic to tetragonal transitions and to lower temperatures for the tetragonal to cubic transition, respectively. Phase stability in powders is discussed by considering possible factors such as internal pressure in isolated particles and internal stress in aggregates. Copyright © 2007 John Wiley & Sons, Ltd.

    DOI: 10.1002/jrs.1764

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  • Polymorphism in Micro-, Submicro-, and Nanocrystalline NaNbO3 Reviewed

    Yosuke Shiratori, Arnaud Magrez, Jürgen Dornseiffer, Franz-Hubert Haegel, Christian Pithan, Rainer Waser

    The Journal of Physical Chemistry B   109 ( 43 )   20122 - 20130   2005.10

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    Authorship:Lead author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/jp052974p

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  • An epitaxial La2CuO4 thin film photocathode for water splitting under visible light Reviewed

    Hiroyuki Kobayashi, Yosuke Shiratori, Masahiro Orita, Taro Yamada, Akihiko Kudo, Kazunari Domen

    Journal of Applied Physics   134 ( 3 )   2023.7

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:AIP Publishing  

    A semiconductive oxide, La2CuO4 (LCO), was investigated as a potential material to compose photocathode for sunlight-driven hydrogen evolution by splitting water. LCO, despite involving partially filled Cu 3d orbitals, behaves as a semiconductor and absorbs visible light on the bandgap formed by significant Coulomb repulsion between the electronic orbitals. An epitaxial LCO film was grown on a SrRuO3/SrTiO3 (SRO/STO) single-crystal substrate by pulsed laser deposition to obtain a photocathodic specimen for water photo-splitting. An LCO photocathode dressed with a Pt cocatalyst for hydrogen evolution (Pt/LCO/SRO/STO) exhibited a cathodic photocurrent with a density of 0.4 mA cm−2 at 0 VRHE under simulated AM1.5 G sunlight. This photocathode responded to incident light up to 800 nm, which is one of the longest wavelengths so far reported for an oxide photoelectrode. Together with a counter-electrode for oxygen evolution, the Pt/LCO/SRO/STO photocathode generated hydrogen with the expected H2 : O2 = 2 : 1 stoichiometric ratio with a Faradaic efficiency of approximately 80%.

    DOI: 10.1063/5.0145967

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  • One second growth of carbon nanotube arrays on a glass substrate by pulsed-current heating Reviewed

    Kotaro Sekiguchi, Koji Furuichi, Yosuke Shiratori, Suguru Noda

    Carbon   50 ( 6 )   2110 - 2118   2012.5

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Elsevier BV  

    DOI: 10.1016/j.carbon.2011.12.062

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  • Tailoring the Morphology of Carbon Nanotube Assemblies Using Microgradients in the Catalyst Thickness Reviewed

    Yosuke Shiratori, Koji Furuichi, Yoshiko Tsuji, Hisashi Sugime, Suguru Noda

    Japanese Journal of Applied Physics   50 ( 9R )   095101 - 095101   2011.9

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)   Publisher:IOP Publishing  

    In addition to the structural control of individual carbon nanotubes (CNTs), the morphological control of their assemblies is crucial to realize miniaturized CNT devices. Microgradients in the thickness of catalyst are used to enrich the variety of available self-organized morphologies of CNTs. Microtrenches were fabricated in gate/spacer/cathode trilayers using a conventional self-aligned top-down process and catalyst exhibiting a microgradient in its thickness was formed on the cathode by sputter deposition through gate slits. CNTs, including single-walled CNTs, of up to 1 µm in length were grown within 5–15 s by chemical vapor deposition. The tendency of thin CNTs to aggregate caused interactions between CNTs with different growth rates, yielding various morphologies dependent on the thickness of the catalyst. The field emission properties of several types of CNT assemblies were evaluated. The ability to produce CNTs with tailored morphologies by engineering the spatial distribution of catalysts will enhance their performance in devices.

    DOI: 10.1143/jjap.50.095101

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    Other Link: https://iopscience.iop.org/article/10.1143/JJAP.50.095101/pdf

  • Nanocomposite thin films for miniaturized multi-layer ceramic capacitors prepared from barium titanate nanoparticle based hybrid solutions Reviewed

    Theodor Schneller, Sandip Halder, Rainer Waser, Christian Pithan, Jürgen Dornseiffer, Yosuke Shiratori, Lothar Houben, Narayanan Vyshnavi, Subhasish B. Majumder

    Journal of Materials Chemistry   21 ( 22 )   7953 - 7965   2011

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry (RSC)  

    DOI: 10.1039/c1jm10607d

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  • Combinatorial Evaluation for Field Emission Properties of Carbon Nanotubes Part II: High Growth Rate System Reviewed

    Yosuke Shiratori, Suguru Noda

    The Journal of Physical Chemistry C   114 ( 30 )   12938 - 12947   2010.7

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    Authorship:Lead author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/jp103378c

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  • A Simple Combinatorial Method Aiding Research on Single-Walled Carbon Nanotube Growth on Substrates Reviewed

    Suguru Noda, Hisashi Sugime, Kei Hasegawa, Kazunori Kakehi, Yosuke Shiratori

    Japanese Journal of Applied Physics   49 ( 2S )   02BA02 - 02BA02   2010.2

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    Authorship:Last author   Language:English   Publishing type:Research paper (scientific journal)   Publisher:IOP Publishing  

    Establishing fabrication methods of carbon nanotubes (CNTs) is essential to realize many applications expected for CNTs. Catalytic growth of CNTs on substrates by chemical vapor deposition (CVD) is promising for direct fabrication of CNT devices, and catalyst nanoparticles play a crucial role in such growth. We have developed a simple method called “combinatorial masked deposition (CMD)”, in which catalyst particles of a given series of sizes and compositions are formed on a single substrate by annealing gradient catalyst layers formed by sputtering through a mask. CMD enables preparation of hundreds of catalysts on a wafer, growth of single-walled CNTs (SWCNTs), and evaluation of SWCNT diameter distributions by automated Raman mapping in a single day. CMD helps determinations of the CVD and catalyst windows realizing millimeter-tall SWCNT forest growth in 10 min, and of growth curves for a series of catalysts in a single measurement when combined with real-time monitoring. A catalyst library prepared using CMD yields various CNTs, ranging from individuals, networks, spikes, and to forests of both SWCNTs and multi-walled CNTs, and thus can be used to efficiently evaluate self-organized CNT field emitters, for example. The CMD method is simple yet effective for research of CNT growth methods.

    DOI: 10.1143/jjap.49.02ba02

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    Other Link: https://iopscience.iop.org/article/10.1143/JJAP.49.02BA02/pdf

  • Efficient field emission from triode-type 1D arrays of carbon nanotubes Reviewed

    Yosuke Shiratori, Koji Furuichi, Yoshiko Tsuji, Hisashi Sugime, Suguru Noda

    Nanotechnology   20 ( 47 )   475707 - 475707   2009.10

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    Authorship:Lead author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)   Publisher:IOP Publishing  

    DOI: 10.1088/0957-4484/20/47/475707

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  • 12.3: 1‐Second Implementation of CNT‐Emitter Arrays on Glasses for BLUs Reviewed

    Koji Furuichi, Yosuke Shiratori, Kotaro Sekiguchi, Hisashi Sugime, Suguru Noda

    SID Symposium Digest of Technical Papers   40 ( 1 )   139 - 141   2009.6

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Wiley  

    Abstract

    We realized simple fabrication of carbon nanotube field emitters for backlight units. Carbon nanotubes were directly grown on cathode lines patterned on low‐strain glasses by atmospheric pressure CVD with pulse electrical heating of cathodes for 1 second. Field emission current density was as high as 5.6 mA/cm2 at 3.3 V/μm.

    DOI: 10.1889/1.3256566

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  • Two-Dimensional Combinatorial Investigation of Raman and Fluorescence Enhancement in Silver and Gold Sandwich Substrates Reviewed

    T. W. H. Oates, Y. Shiratori, S. Noda

    The Journal of Physical Chemistry C   113 ( 22 )   9588 - 9594   2009.5

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/jp900436a

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  • Combinatorial Evaluation for Field Emission Properties of Carbon Nanotubes Reviewed

    Yosuke Shiratori, Hisashi Sugime, Suguru Noda

    The Journal of Physical Chemistry C   112 ( 46 )   17974 - 17982   2008.10

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    Authorship:Lead author   Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/jp807078h

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  • Pressure-Induced Phase Transitions in Micro-, Submicro-, and Nanocrystalline NaNbO3 Reviewed

    Yosuke Shiratori, Arnaud Magrez, Minoru Kato, Kunihiro Kasezawa, Christian Pithan, Rainer Waser

    The Journal of Physical Chemistry C   112 ( 26 )   9610 - 9616   2008.6

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    Authorship:Lead author, Corresponding author   Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/jp801234g

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  • Field Emission Properties of Single-Walled Carbon Nanotubes with a Variety of Emitter Morphologies Reviewed

    Yosuke Shiratori, Koji Furuichi, Suguru Noda, Hisashi Sugime, Yoshiko Tsuji, Zhengyi Zhang, Shigeo Maruyama, Yukio Yamaguchi

    Japanese Journal of Applied Physics   47 ( 6R )   4780 - 4780   2008.6

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)   Publisher:IOP Publishing  

    DOI: 10.1143/jjap.47.4780

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    Other Link: https://iopscience.iop.org/article/10.1143/JJAP.47.4780/pdf

  • Temperature-induced Phase Transitions in Micro-, Submicro-, and Nanocrystalline NaNbO3 Reviewed

    Yosuke Shiratori, Arnaud Magrez, Werner Fischer, Christian Pithan, Rainer Waser

    The Journal of Physical Chemistry C   111 ( 50 )   18493 - 18502   2007.11

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    Authorship:Lead author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/jp0738053

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  • Raman scattering studies on nanocrystalline BaTiO3 Part II—consolidated polycrystalline ceramics Reviewed

    Y. Shiratori, C. Pithan, J. Dornseiffer, R. Waser

    Journal of Raman Spectroscopy   38 ( 10 )   1300 - 1306   2007.6

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    Authorship:Lead author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)   Publisher:Wiley  

    Abstract

    BaTiO3 dense ceramics with different grain sizes from 5.6 µm down to 35 nm were thoroughly studied by Raman spectroscopy. The temperature characteristics of optical phonons were compared with those obtained for powders. The micrograined ceramic revealed the well‐known spectrum profiles and transitions, typical for bulk BaTiO3. On the other hand, the Raman spectra obtained for a nanograined ceramic with an average grain size of 35 nm revealed a tetragonally distorted pure BaTiO3 phase showing a diffused phase transition behaviour with respect to temperature. Abnormality of phonon damping characteristics for the nanograined ceramic was demonstrated through comparison with powders with various crystallite sizes and the micrograined ceramic. The Curie temperature of the nanograined ceramic was estimated to be 105 °C from the temperature characteristic of a sharp peak at 307 cm−1, which is one of the most specific tetragonal features for bulk BaTiO3. In the present study, local stabilization of the tetragonal phase in ultra‐fine grains was experimentally demonstrated from comparison between the Raman spectroscopic results for powders and ceramics prepared through microemulsion‐mediated synthesis. Rather long phonon mean free paths can exist even in such ultra‐fine grains, but the phonon characteristics originating from various grains are diffused mainly because of the effect of internal stress. Copyright © 2007 John Wiley & Sons, Ltd.

    DOI: 10.1002/jrs.1763

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  • Noncentrosymmetric phase of submicron NaNbO3 crystallites Reviewed

    Y. Shiratori, A. Magrez, K. Kasezawa, M. Kato, S. Röhrig, F. Peter, C. Pithan, R. Waser

    Journal of Electroceramics   19 ( 4 )   273 - 280   2007.2

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    Authorship:Lead author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)   Publisher:Springer Science and Business Media LLC  

    DOI: 10.1007/s10832-007-9032-7

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    Other Link: http://link.springer.com/article/10.1007/s10832-007-9032-7/fulltext.html

  • Preparation, Processing, and Characterization of Nano‐Crystalline BaTiO3 Powders and Ceramics Derived from Microemulsion‐Mediated Synthesis Reviewed

    C. Pithan, Y. Shiratori, R. Waser, J. Dornseiffer, F.‐H. Haegel

    Journal of the American Ceramic Society   89 ( 9 )   2908 - 2916   2006.6

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Wiley  

    Monodisperse and nanocrystalline BaTiO3 powders of different stoichiometries were synthesized through the hydrolytic decomposition of mixed metal alkoxide solutions with water‐in‐oil microemulsions as reaction media. The method allows a tailor‐made preparation of powder particles as small as 10 nm in average. Characterization with respect to purity, morphology, and behavior upon annealing was conducted in order to determine appropriate processing conditions for the preparation of pure, dense nanocrystalline ceramics. As a result, ceramics with a mean grain size as small as 35 nm were achieved. Raman spectroscopy revealed for the first time local tetragonality in pure nanocrystalline bulk BaTiO3‐ceramics with such a fine microstructure.

    DOI: 10.1111/j.1551-2916.2006.01144.x

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  • Microemulsion mediated synthesis of nanocrystalline BaTiO3: possibilities, potential and perspectives Reviewed

    Christian Pithan, Theodor Schneller, Yosuke Shiratori, Subhasish Basu Majumder, Franz-Hubert Haegel, Jürgen Dornseiffer, Rainer Waser

    International Journal of Materials Research   97 ( 5 )   499 - 507   2006.5

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Walter de Gruyter GmbH  

    Abstract

    The present study gives an overview on the potential, possibilities and perspectives that the synthesis of functional materials, such as BaTiO3, with microemulsions as the reaction medium offers. Well defined nanocrystalline particles in the form of powders for further ceramic processing, as well as stable colloidal dispersions for the preparation of coatings may be obtained. The paper describes the formation, phase behaviour and stabilization of microemulsions and related water/oil/surfactant systems that may be used as a nanoreactor during particle formation. The reaction principles of microemulsion mediated synthesis are outlined and some examples of structural aspects, revealing size effects in these systems are implemented using advanced characterization techniques, such as Raman spectroscopy. Finally, the preparation of mesoscopic layers, covering the thickness gap between thin film and thick film technology, is demonstrated.

    DOI: 10.3139/146.101264

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    Other Link: https://www.degruyterbrill.com/document/doi/10.3139/146.101264/pdf

  • Nanocrystalline Lead Free Piezoceramic (K x Na 1‐x )NbO 3 Derived from Microemulsion Mediated Synthesis International coauthorship International journal

    Christian Pithan, Yosuke Shiratori, Arnauld Magrez, Jürgen Dornseiffer, Franz‐Hubert Haegel

    Ceramic Transactions Series   41 - 50   2006.3

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    Language:English   Publisher:Wiley  

    DOI: 10.1002/9781118408186.ch5

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  • Consolidation, Microstructure and Crystallography of Dense NaNbO<sub>3</sub> Ceramics with Ultra-Fine Grain Size Reviewed

    Christian PITHAN, Yosuke SHIRATORI, Arnaud MAGREZ, Shao-Bo MI, J&uuml, rgen DORNSEIFFER, Rainer WASER

    Journal of the Ceramic Society of Japan   114 ( 1335 )   995 - 1000   2006

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Ceramic Society of Japan  

    DOI: 10.2109/jcersj.114.995

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  • Influence of impurities on the conductivity of composites in the system (3YSZ)1−x–(MgO)x Reviewed

    Y. Shiratori, F. Tietz, H.J. Penkalla, J.Q. He, Y. Shiratori, D. Stöver

    Journal of Power Sources   148   32 - 42   2005.9

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Elsevier BV  

    DOI: 10.1016/j.jpowsour.2005.01.036

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  • Microemulsion mediated synthesis of nanocrystalline (Kx,Na1−x)NbO3 powders Reviewed

    Christian Pithan, Yosuke Shiratori, Jürgen Dornseiffer, Franz-Hubert Haegel, Arnaud Magrez, Rainer Waser

    Journal of Crystal Growth   280 ( 1-2 )   191 - 200   2005.6

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Elsevier BV  

    DOI: 10.1016/j.jcrysgro.2005.03.038

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  • Particle size effect on the crystal structure symmetry of K0.5Na0.5NbO3 Reviewed

    Yosuke Shiratori, Arnaud Magrez, Christian Pithan

    Journal of the European Ceramic Society   25 ( 12 )   2075 - 2079   2005.1

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    Authorship:Lead author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)   Publisher:Elsevier BV  

    DOI: 10.1016/j.jeurceramsoc.2005.03.012

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  • Vertically aligned carbon nanotubes produced by radio-frequency plasma-enhanced chemical vapor deposition at low temperature and their growth mechanism Reviewed

    Y. Shiratori, H. Hiraoka, M. Yamamoto

    Materials Chemistry and Physics   87 ( 1 )   31 - 38   2004.9

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    Authorship:Lead author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)   Publisher:Elsevier BV  

    DOI: 10.1016/j.matchemphys.2004.03.017

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  • Phase transformation of KNaNb2O6 induced by size effect Reviewed

    Yosuke Shiratori, Arnaud Magrez, Christian Pithan

    Chemical Physics Letters   391 ( 4-6 )   288 - 292   2004.6

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    Authorship:Lead author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)   Publisher:Elsevier BV  

    DOI: 10.1016/j.cplett.2004.05.024

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  • Giant field amplification in tungsten nanowires Reviewed

    A.G. Umnov, Y. Shiratori, H. Hiraoka

    Applied Physics A: Materials Science & Processing   77 ( 1 )   159 - 161   2003.6

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Springer Science and Business Media LLC  

    DOI: 10.1007/s00339-003-2077-9

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    Other Link: http://link.springer.com/article/10.1007/s00339-003-2077-9/fulltext.html

  • One-step formation of aligned carbon nanotube field emitters at 400 °C Reviewed

    Y. Shiratori, H. Hiraoka, Y. Takeuchi, S. Itoh, M. Yamamoto

    Applied Physics Letters   82 ( 15 )   2485 - 2487   2003.4

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    Authorship:Lead author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)   Publisher:AIP Publishing  

    Fabrication of field emitters by the radio-frequency plasma-enhanced chemical vapor deposition of vertically aligned carbon nanotubes (CNT) on soda-lime glass is reported. CNT was produced at 400 °C by the control of the collision energy of carbonic cations to a substrate through a dc bias voltage. The CNTs produced in this work were of a cup-stacked type and had catalyst particles on the top. The CNT emitters formed by our method were integrated into triode-type microcathodes and showed field-emission properties suitable for display applications.

    DOI: 10.1063/1.1566803

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  • Raman Study of Hydration Effect on Conformational Equilibria of Haloacetones Reviewed

    Yosuke Shiratori, Yoshiaki Nanba, Minoru Kato, Yoshihiro Taniguchi

    Bulletin of the Chemical Society of Japan   76 ( 3 )   501 - 507   2003.3

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)   Publisher:Oxford University Press (OUP)  

    Abstract

    The conformational equilibria of chloroacetone and bromoacetone in various solvents were investigated using temperature and pressure-tuning Raman spectroscopy. Three conformational equilibria of gauche←→trans, gauche←→trans′ (trans conformer whose halogen atom forms hydrogen bonds with water), and trans←→trans′ were observed in water. Thermodynamic quantities between the conformers of both haloacetones in various solvents were evaluated from the temperature and pressure dependence of the Raman intensities of the C–X (X: Cl and Br) stretching modes. The effects of the substitution of halogen atoms were observed in the enthalpy and volume differences between the conformers in water. From the present results together with the previous results for fluoroacetone, a good correlation between the conformational thermodynamics for haloacetones in water and the polarizabilities of the halogen atoms was shown.

    DOI: 10.1246/bcsj.76.501

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  • Synthesis of multishell fullerenes by laser vaporization of composite carbon targets Reviewed

    V. Z. Mordkovich, Yosuke Shiratori, H. Hiraoka, Yoshimasa Takeuchi

    Physics of the Solid State   44 ( 4 )   603 - 606   2002.4

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Pleiades Publishing Ltd  

    DOI: 10.1134/1.1470536

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    Other Link: http://link.springer.com/article/10.1134/1.1470536/fulltext.html

  • Formation of multishell fullerenes from vaporized carbons Reviewed

    V. Z. Mordkovich, Yosuke Shiratori, Hiroyuki Hiraoka, Yasumasa Takeuchi, Morinobu Endo

    Molecular Crystals and Liquid Crystals   386 ( 1 )   103 - 107   2002.1

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Informa UK Limited  

    DOI: 10.1080/713738811

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  • A path to larger yields of multishell fullerenes Reviewed

    V. Z. Mordkovich, Yosuke Shiratori, H. Hiraoka, A. G. Umnov, Yoshimasa Takeuchi

    Carbon   39 ( 12 )   1938 - 1941   2001

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  • Raman study on conformational equilibria of fluoroacetone in aqueous solutions Reviewed

    Yosuke Shiratori, Minoru Kato, Yoshihiro Taniguchi

    Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy   56 ( 9 )   1693 - 1701   2000.8

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)   Publisher:Elsevier BV  

    DOI: 10.1016/s1386-1425(00)00226-2

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  • Solvent effect on Raman spectra of conformational key bands of chloroacetone and bromoacetone Reviewed

    Yosuke Shiratori, Minoru Kato, Yoshihiro Taniguchi

    Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy   55 ( 13 )   2659 - 2670   1999.11

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)   Publisher:Elsevier BV  

    DOI: 10.1016/s1386-1425(99)00086-4

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Presentations

  • Borate-Water-Based 3D-Slime Interface Solid Electrolytes for Li-ion Batteries

    Yosuke Shiratori, Shintaro Yasui

    Pacifichem 2025  2025.12 

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    Event date: 2025.12

    Language:English   Presentation type:Oral presentation (general)  

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  • 四ホウ酸リチウムを母相とした水系準固体電解質の化学的ロバスト性

    白鳥洋介, 安井伸太郎

    第66回 電池討論会  2025.11 

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    Event date: 2025.11

    Language:Japanese   Presentation type:Oral presentation (general)  

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  • Tailoring carbon nanotube assemblies for electronics applications Invited International conference

    Y. Shiratori, K. Sekiguchi, K. Furuichi, S. Noda

    The 4th International Symposium on Functional Materials (ISFM2011)  2011.8 

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    Language:English   Presentation type:Oral presentation (invited, special)  

    Venue:Sendai   Country:Japan  

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  • Polymorphism in multi- scaled NaNbO3 crystallites Invited International coauthorship International conference

    Y. Shiratori, A. Magrez, C. Pithan, R. Waser, W. Fischer, M. Kato, K. Kasezawa

    Electroceramics XI  2008.9 

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    Language:English   Presentation type:Oral presentation (invited, special)  

    Venue:Manchester   Country:United Kingdom  

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  • Size-tuned design and piezoactivity in lead-free nanoceramics Invited International coauthorship International conference

    Y. Shiratori, C. Pithan

    International Symposium on Integrated Functionalities (ISIF) 2010  2010.6 

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    Language:English   Presentation type:Oral presentation (invited, special)  

    Venue:San Juan   Country:Puerto Rico  

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  • Spectroscopic characterization of nanosized polar oxides Invited International coauthorship International conference

    Y. Shiratori

    German-Japanese Workshop on Nanocrystalline Dielectric Materials  2005.5 

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    Language:English   Presentation type:Symposium, workshop panel (nominated)  

    Venue:Niigata   Country:Japan  

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  • Sub-second growth of carbon nanotube arrays on conventional glasses and their field emission properties International conference

    Y. Shiratori, K. Sekiguchi, S. Noda

    The 12th International Conference on the Science and Application of Nanotubes (NT11)  2011.7 

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    Language:English   Presentation type:Oral presentation (general)  

    Venue:Cambridge   Country:United Kingdom  

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  • 顕微ラマン分光法による誘電体結晶の局所構造解析 Invited

    白鳥 洋介, 和田 大我

    日本セラミックス協会 第27回秋季シンポジウム  2014.9  公益社団法人 日本セラミックス協会

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    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:鹿児島   Country:Japan  

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  • Field emission properties of morphologically-controlled single-walled carbon nanotubes and their combinatorial evaluation International conference

    Y. Shiratori, K. Furuichi, S. Noda, H. Sugime, Y. Tsuji, Z. Zhang, S. Maruyama, Y. Yamaguchi

    The 9th International Conference on the Science and Application of Nanotubes (NT08)  2008.6 

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    Language:English   Presentation type:Oral presentation (general)  

    Venue:Montpellier   Country:France  

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  • Combinatorial study on self-organization of single-walled carbon nanotubes and tailoring field electron emitters Invited International conference

    Y. Shiratori

    INRS seminar at Institut national de la recherche scientifique – Énergie Matérriaux Télécommunications  2010.7 

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    Language:English   Presentation type:Public lecture, seminar, tutorial, course, or other speech  

    Venue:Quebec   Country:Canada  

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  • Size effect on the phase transformation of K0.5Na0.5NbO3 International coauthorship International conference

    Y. Shiratori, A. Magrez, C. Pithan

    Electroceramics IX  2004.6 

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    Language:English   Presentation type:Oral presentation (general)  

    Venue:Cherbourg   Country:France  

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  • Size-induced phase transformation of NaNbO3 prepared through microemulsion mediated synthesis: comparison with the case of (K0.50,Na0.50)NbO International coauthorship International conference

    Y. Shiratori, A. Magrez, C. Pithan, R. Waser

    European Congress on Advanced Materials and Processes (EUROMAT 2005)  2005.9 

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    Language:English   Presentation type:Oral presentation (general)  

    Venue:Prague   Country:Czech Republic  

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  • Noncentrosymmetry of NaNbO3 induced by particle size International coauthorship International conference

    Y. Shiratori, A. Magrez, K. Kasezawa, M. Kato, C. Pithan, R. Waser

    Piezoceramics for end-users II  2006.3 

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    Language:English   Presentation type:Oral presentation (general)  

    Venue:Lillehammer   Country:Norway  

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Industrial property rights

  • 固体電解質及び全固体リチウムイオン二次電池

    白鳥 洋介, 齋藤 健吾, 渡辺 健太, 佐藤 亮太, 安井 伸太郎

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    Applicant:富士フイルム株式会社, 国立大学法人東京科学大学

    Application no:特願2023-201370  Date applied:2023.11

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  • 全固体リチウムイオン二次電池及び全固体リチウムイオン二次電池の製造方法

    白鳥 洋介, 齋藤 健吾, 渡辺 健太, 安井 伸太郎, 東海林 雅俊

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    Applicant:富士フイルム株式会社, 国立大学法人東京工業大学

    Application no:PCT/JP2023/020287  Date applied:2023.5

    Announcement no:WO/2023/234351  Date announced:2023.12

    Country of applicant:Foreign country  

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  • 活物質の回収方法

    白鳥 洋介

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    Applicant:富士フイルム株式会社

    Application no:PCT/JP2023/020301  Date applied:2023.5

    Announcement no:WO/2023/234357  Date announced:2023.12

    Country of applicant:Foreign country  

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  • 全固体リチウムイオン二次電池及び全固体リチウムイオン二次電池の製造方法

    白鳥 洋介, 渡辺 健太, 齋藤 健吾, 安井 伸太郎, 東海林 雅俊, 奥野 幸洋

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    Applicant:富士フイルム株式会社, 国立大学法人東京科学大学

    Application no:PCT/2024/524911  Date applied:2023.5

    Announcement no:WO/2023/234352  Date announced:2023.12

    Country of applicant:Foreign country  

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  • リチウム系固体電解質、リチウム系固体電解質の製造方法、修飾正極活物質、修飾負極活物質、全固体二次電池、全固体二次電池用電極シート、固体電解質シート、全固体二次電池用電極

    白鳥 洋介, 安井 伸太郎, 奥野 幸洋, 齋藤 健吾, 渡辺 健太

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    Application no:PCT/JP2023/019713  Date applied:2023.5

    Announcement no:WO/2023/234209  Date announced:2023.12

    Country of applicant:Foreign country  

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  • 酸化物固体電解質、バインダ、固体電解質層、活物質、電極、全固体二次電池

    白鳥 洋介, 奥野 幸洋, 安井 伸太郎

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    Applicant:富士フイルム株式会社, 国立大学法人東京科学大学

    Application no:JP2021044020  Date applied:2021.12

    Announcement no:WO/2022/118868  Date announced:2022.6

    Patent/Registration no:特許7510650 

    Country of applicant:Foreign country  

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  • リチウム系固体電解質、無機固体電解質、リチウム系固体電解質の製造方法、修飾正極活物質、修飾負極活物質、全固体二次電池、全固体二次電池用電極シート、固体電解質シート、全固体二次電池用電極

    白鳥 洋介, 奥野 幸洋, 安井 伸太郎, 齋藤 健吾, 渡辺 健太

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    Applicant:富士フイルム株式会社, 国立大学法人東京科学大学

    Application no:JP2021044047  Date applied:2021.12

    Patent/Registration no:特許7634240 

    Country of applicant:Foreign country  

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  • 固体電解質含有分散物、全固体リチウムイオン二次電池、及び全固体リチウムイオン二次電池の製造方法

    佐藤 亮太, 渡辺 健太, 白鳥 洋介, 齋藤 健吾

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    Applicant:富士フイルム株式会社

    Application no:特願2024-218574  Date applied:2024.12

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  • 全固体リチウムイオン二次電池及び全固体リチウムイオン二次電池の製造方法

    白鳥 洋介, 安井 伸太郎, 奥野 幸洋, 白石 康晴, 齋藤 健吾, 渡辺 健太, 高橋 昭裕

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    Applicant:富士フイルム株式会社, 国立大学法人東京科学大学

    Application no:PCT/JP2023/020285  Date applied:2023.5

    Announcement no:WO/2023/234349  Date announced:2023.12

    Country of applicant:Foreign country  

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  • 捲回型全固体リチウムイオン二次電池及び捲回型全固体リチウムイオン二次電池の製造方法

    白鳥 洋介, 安井 伸太郎, 白石 康晴, 齋藤 健吾, 渡辺 健太, 高橋 昭裕

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    Applicant:富士フイルム株式会社, 国立大学法人東京科学大学

    Application no:PCT/2024/524909  Date applied:2023.5

    Announcement no:WO/2023/234350  Date announced:2023.12

    Country of applicant:Foreign country  

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  • ナトリウム系固体電解質、ナトリウム系固体電解質の製造方法、修飾正極活物質、修飾負極活物質、固体二次電池、固体二次電池用電極シート、固体電解質シート、固体二次電池用電極

    奥野 幸洋, 安井 伸太郎, 白鳥 洋介, 齋藤 健吾, 渡辺 健太

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    Applicant:富士フイルム株式会社, 国立大学法人東京科学大学

    Application no:PCT/JP2023/019752  Date applied:2023.5

    Announcement no:WO/2023/234219  Date announced:2023.12

    Country of applicant:Foreign country  

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  • 複合体、リチウムイオン伝導体、全固体リチウムイオン二次電池、全固体リチウムイオン二次電池用電極シート、四ホウ酸リチウム

    奥野 幸洋, 白鳥 洋介, 安井 伸太郎, 伊藤 満

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    Applicant:富士フイルム株式会社, 国立大学法人東京科学大学

    Application no:JP2021010433  Date applied:2021.3

    Announcement no:WO/2021/193204 

    Patent/Registration no:特許7377502 

    Country of applicant:Foreign country  

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  • 積層構造体及びそれを備えた圧電素子、積層構造体の製造方法、評価方法

    新川 高見, 大崎 龍介, 白鳥 洋介

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    Applicant:富士フイルム株式会社

    Application no:特願2015-144138  Date applied:2015.7

    Announcement no:特開2017-028062  Date announced:2017.2

    Patent/Registration no:特許6494031 

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  • パターン状電子源の製造方法、パターン状電子源

    野田 優, 白鳥 洋介

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    Applicant:国立大学法人 東京大学

    Application no:特願2010-133888  Date applied:2010.6

    Announcement no:特開2011-258502  Date announced:2011.12

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  • 面発光装置

    野田 優, 古市 考次, 白鳥 洋介

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    Applicant:国立大学法人 東京大学, 大日本スクリーン製造株式会社

    Application no:特願2008-278873  Date applied:2008.10

    Announcement no:特開2010-108723  Date announced:2010.5

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  • フィールドエミッション装置、ならびに、その製造方法

    野田 優, 古市 考次, 白鳥 洋介, 辻 佳子, 杉目 恒志

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    Application no:特願2008-089078  Date applied:2008.3

    Announcement no:特開2009-245672  Date announced:2009.10

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  • カーボンナノチューブの製造方法

    平岡 弘之, 白鳥 洋介, 山本 雅英, 伊藤 茂生, 縄巻 健司

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    Applicant:株式会社国際基盤材料研究所, 双葉電子工業株式会社

    Application no:特願2001-333529  Date applied:2001.9

    Announcement no:特開2003-095625  Date announced:2003.4

    Patent/Registration no:特許3725063 

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  • カーボンナノチューブの改質方法、カーボンナノチューブ及び電子放出源

    平岡 弘之, 白鳥 洋介, 山本 雅英, 伊藤 茂生, 縄巻 健司

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    Applicant:株式会社国際基盤材料研究所, 双葉電子工業株式会社

    Application no:特願2001-304186  Date applied:2001.8

    Announcement no:特開2003-063814  Date announced:2003.3

    Patent/Registration no:特許4863590 

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  • Process for the preparation of piezoelectric sodium niobate

    Christian Pithan, Yosuke Shiratori, Arnaud Magrez, Jürgen Dornseiffer

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    Applicant:Forschungszentrum Jülich GmbH (Research Center Juelich, Germany)

    Application no:DE102005038411 

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Awards

  • FUJIFILM Top Technology Prize (CTO賞)

    2018.3   富士フイルム株式会社   人工光合成技術の開発

    白鳥 洋介

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  • Lindau Nobel Laureate Meetings Humboldt Foundation selected participant

    2005.6   Council for the Lindau Nobel Laureate Meetings   Research on environmentally friendly lead-free piezoelectric ceramics

    Yosuke Shiratori

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Research Projects

  • ダイレクトリサイクルによる活物質循環型水系固体電池の創成

    Grant number:JPMJCR25S4  2025.10 - 2031.9

    JST  CREST 

    安井伸太郎

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    Authorship:Collaborating Investigator(s) (not designated on Grant-in-Aid) 

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  • 大気ハンドリング可能な汎用的で安全性を備えた酸化物全固体Li電池の開発

    Grant number:21502135-0  2022.2 - 2024.3

    NEDO  官民による若手研究者発掘支援事業 (若サポ) 

    安井伸太郎

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    Authorship:Collaborating Investigator(s) (not designated on Grant-in-Aid) 

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  • 焼結フリー高イオン伝導酸化物固体電解質の開発

    2020.11 - 2022.3

    科学技術振興機構  産学が連携した研究開発成果の展開 研究成果展開事業 研究成果最適展開支援プログラム(A-STEP) トライアウト トライアウト 

    安井 伸太郎

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    Authorship:Collaborating Investigator(s) (not designated on Grant-in-Aid)  Grant type:Competitive

    最有力技術である硫化物系電解質の最大の弱点は大気下における不安定性であり、水分と反応して硫化水素を発生するために安全面に関して懸念されている。酸化物は大気下で合成され、安定性は抜群であるためにこの問題を解決する唯一の方法であるが、しかしながらそのイオン伝導度は硫化物系電解質と比べて低い。さらに硫化物系固体電解質は材料自身の柔らかさより加工性もよい。酸化物材料に足りない加工性およびイオン伝導度に関して、新材料である非晶質リチウム化合物を用いて硫化物に近いイオン伝導並びに凌駕する加工性を付与し、焼結フリーというプロセスコスト面にも優しい固体酸化物電解質を開発する。

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    J-GLOBAL

  • Multi-scaled evaluation for self-organized carbon nanotube electron emitters

    Grant number:21760003  2009 - 2010

    Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research  Grant-in-Aid for Young Scientists (B)

    SHIRATORI Yosuke

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    Grant amount:\4550000 ( Direct Cost: \3500000 、 Indirect Cost:\1050000 )

    Control of self-organized morphologies of carbon nanotubes (CNTs) was aimed to apply them for electron emitters in field emission (FE) type light emitting elements. In order to form CNT emitters with moderate spacing and number density desirable for an efficient electron source, FE properties ranging from self-organized CNT emitters to macroscopic device properties were systematically studied. Through the multi-scaled evaluation ; control of CNT growth and optimization of device structures, the preparation condition to fulfill their FE properties was highly improved. It is expected that the findings obtained are applied for the processes tolerable for a variety of conventional substrates.

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Media Coverage

  • リチウムイオン 発火しない"スライム電池" TV or radio program

    テレビ東京  ブレイクスルー  2025.12

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  • 水に混ぜてリサイクルする電池 Newspaper, magazine

    日本経済新聞社  日本経済新聞  2025.8

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  • 3D-SLISE: a quasi-solid electrolyte for safer and greener lithium-ion batteries Internet

    Linkedin Corporation  Linkedin  2025.8

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  • 燃えにくくリサイクルも楽なリチウムイオン電池。東京科学大が開発 Internet

    LINEヤフー株式会社  Yahoo! JAPANニュース  2025.8

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  • 「スライム」が電池の未来を変える?東京科学大学が開発した革新的電解質「3D-SLISE」が安全・高速充電・循環型電池経済の未来を可能に Internet

    グルーオン・システムズ  XenoSpectrum  2025.8

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  • New slime-like electrolyte could make lithium-ion batteries safer and easy to recycle Internet

    Interesting Engineering, Inc.  INTERESTING ENGINEERING  2025.8

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  • 3D-SLISE: a quasi-solid electrolyte for safer and greener lithium-ion batteries Promotional material

    The American Association for the Advancement of Science (AAAS)  EurekAlert!  2025.8

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  • 世界初、大気下でつくる新しいリチウムイオン電池電解質 Promotional material

    国立大学法人 東京科学大学  Science Tokyoニュース  2025.8

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  • 東京科学大が新リチウム電池開発 製造簡素化・資源循環容易に Newspaper, magazine

    日刊工業新聞社  日刊工業新聞  2025.8

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    Author:Other 

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  • 水に混ぜリサイクルする電池開発 東京科学大、環境負荷低くコスト減 Newspaper, magazine

    日本経済新聞社  日本経済新聞  2025.7

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  • 全固体電池、塗って乾かす電解質 東京工業大学 Newspaper, magazine

    日本経済新聞社  日本経済新聞  2023.8

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  • 全固体電池、塗って乾かす電解質 Newspaper, magazine

    日本経済新聞社  日経産業新聞  2023.8

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