LAX phases: A family of novel stable layered materials, informatics‐based discovery Reviewed

Ehsan Alibagheri, Mohammad Khazaei, Mehdi Estili, Alireza Seyfi, Hiroshi Mizoguchi, Kaoru Ohno, Hideo Hosono, S. Mehdi Vaez Allaei

InfoMat   12664/1 - 11   2025.2

Ammonia Decomposition Catalyzed by Co Nanoparticles Encapsulated in Rare Earth Oxide Reviewed

Hiroshi Mizoguchi, Shunqin Luo, Masato Sasase, Masaaki Kitano, Hideo Hosono

J. Phys. Chem. Lett.   16   796 - 801   2025.1

Exploration of heterogeneous catalyst for molecular hydrogen ortho‐para conversion Invited Reviewed

Hideki Abe, Hiroshi Mizoguchi, Ryuto Eguchi, Hideo Hosono

Exploration   2023.12

Ammonia Cracking Catalyzed by Ni Nanoparticles Confined in the Framework of CeO₂ Support Reviewed

Hiroshi Mizoguchi, Yuta Osawa, Masato Sasase, Naoki Ohashi, Masaaki Kitano, Hideo Hosono

The Journal of Physical Chemistry Letters   14   9516 - 9520   2023.10

Hydride Anion Substitution Boosts Thermoelectric Performance of Polycrystalline SrTiO 3 via Simultaneous Realization of Reduced Thermal Conductivity and High Electronic Conductivity Reviewed

Xinyi He, Seiya Nomoto, Takehito Komatsu, Takayoshi Katase, Terumasa Tadano, Suguru Kitani, Hideto Yoshida, Takafumi Yamamoto, Hiroshi Mizoguchi, Keisuke Ide, Hidenori Hiramatsu, Hitoshi Kawaji, Hideo Hosono, Toshio Kamiya

Advanced Functional Materials   2023.4

Unique Conduction Band Minimum of Semiconductors Possessing a Zincblende-Type Framework Reviewed

Mizoguchi, H., Park, S.-W., Katase, T., Yu, J., Wang, J., Hosono, H.

Inorganic Chemistry   61 ( 27 )   2022.6

Electronic Structures of Group III–V Element Haeckelite Compounds: A Novel Family of Semiconductors, Dirac Semimetals, and Topological Insulators Reviewed

Khazaei, M., Ranjbar, A., Kang, Y.-G., Liang, Y., Khaledialidusti, R., Bae, S., Raebiger, H., Wang, V., Han, M.J., Mizoguchi, H., Bahramy, M.S., K{\"u}hne, T.D., Belosludov, R.V., Ohno, K., Hosono, H.

Advanced Functional Materials   32 ( 20 )   2110930 - 2110930   2022.5

Superior catalytic performance of intermetallic CaPt₂ nanoparticles supported on titanium group oxides in hydrogenation of ketones to alcohols Reviewed

Yasukazu Kobayashi, Shohei Tada, Masaru Kondo, Kakeru Fujiwara, Hiroshi Mizoguchi

Chemical Communications   58 ( 30 )   4795 - 4798   2022

Intermetallic YIr₂ nanoparticles with negatively charged Ir active sites for catalytic hydrogenation of cyclohexanone to cyclohexanol Reviewed

Yasukazu Kobayashi, Shohei Tada, Masaru Kondo, Kakeru Fujiwara, Hiroshi Mizoguchi

Catalysis Science and Technology   12 ( 10 )   3088 - 3093   2022

A View on Formation Gap in Transition Metal Hydrides and Its Collapse Reviewed

Mizoguchi, H., Park, S.-W., Hosono, H.

Journal of the American Chemical Society   143 ( 30 )   11345 - 11348   2021.8

Origin of Metallic Nature of Na₃N

Mizoguchi, H., Park, S.-W., Katase, T., Vazhenin, G.V., Kim, J., Hosono, H.

Journal of the American Chemical Society   143 ( 1 )   69 - 72   2021.1

Chemical route to prepare nickel supported on intermetallic Ti₆Si₇Ni₁₆nanoparticles catalyzing CO methanation Reviewed

Kobayashi, Y., Tada, S., Mizoguchi, H.

Nanoscale   13 ( 39 )   16533 - 16542   2021

Twinning by Merohedry and Thermal Expansion of Zeolitic Clathrasil Deca-dodecasil 3R Reviewed

Koichi Kajihara, Hirohiko Kato, Ryo Takahashi, Kiyoshi Kanamura, Hiroshi Mizoguchi, Yukiko Namatame, Hiroyasu Sato

INORGANIC CHEMISTRY   59 ( 8 )   5600 - 5609   2020.4

On the Origin of the Negative Thermal Expansion Behavior of YCu Reviewed

Mizoguchi, H., Bang, J., Inoshita, T., Kamiya, T., Hosono, H.

Inorganic Chemistry   58 ( 17 )   11819 - 11827   2019.9

Hydrogen-Insertion-Induced Itinerant Ferromagnetism in Zr₂CoH_4.8 with Co Chains Reviewed

Mizoguchi, H., Matsuishi, S., Park, S.-W., Hosono, H.

Journal of Physical Chemistry C   123 ( 24 )   14964 - 14968   2019.6

Zeolitic Intermetallics: LnNiSi (Ln = La–Nd) Reviewed

Hiroshi Mizoguchi, Sang-Won Park, Kazuhisa Kishida, Masaaki Kitano, Junghwan Kim, Masato Sasase, Takashi Honda, Kazutaka Ikeda, Toshiya Otomo, Hideo Hosono

Journal of the American Chemical Society   141 ( 8 )   3376 - 3379   2019.2

High Electron Density on Ru in Intermetallic YRu2: The Application to Catalyst for Ammonia Synthesis Reviewed

Takaya Ogawa, Yasukazu Kobayashi, Hiroshi Mizoguchi, Masaaki Kitano, Hitoshi Abe, Tomofumi Tada, Yoshitake Toda, Yasuhiro Niwa, Hideo Hosono

The Journal of Physical Chemistry C   122 ( 19 )   10468 - 10475   2018.5

Transformation of the Chromium Coordination Environment in LaCrAsO Induced by Hydride Doping: Formation of La₂Cr₂As₂O_yH_x Reviewed

Park, S.-W., Mizoguchi, H., Hiraka, H., Ikeda, K., Otomo, T., Hosono, H.

Inorganic Chemistry   56 ( 22 )   13642 - 13645   2017.11

Cubic Fluorite-Type CaH2 with a Small Bandgap Reviewed

Hiroshi Mizoguchi, SangWon Park, Takashi Honda, Kazutaka Ikeda, Toshiya Otomo, Hideo Hosono

Journal of the American Chemical Society   139 ( 33 )   11317 - 11320   2017.8

The Unique Electronic Structure of Mg₂Si: Shaping the Conduction Bands of Semiconductors with Multicenter Bonding Invited Reviewed

Mizoguchi, H., Muraba, Y., Fredrickson, D.C., Matsuishi, S., Kamiya, T., Hosono, H.

Angewandte Chemie - International Edition   56 ( 34 )   10135 - 10139   2017.8

Hydride-Based Electride Material, LnH₂ (Ln = La, Ce, or Y) Reviewed

Mizoguchi, H., Okunaka, M., Kitano, M., Matsuishi, S., Yokoyama, T., Hosono, H.

Inorganic Chemistry   55 ( 17 )   8833 - 8838   2016.9

An Anti CuO2-type Metal Hydride Square Net Structure in Ln(2)M(2)As(2)H(x) (Ln=La or Sm, M=Ti, V, Cr, or Mn) Reviewed

Hiroshi Mizoguchi, SangWon Park, Haruhiro Hiraka, Kazutaka Ikeda, Toshiya Otomo, Hideo Hosono

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   54 ( 10 )   2932 - 2935   2015.3

New LaMAsH_x (M = Co, Ni, or Cu) arsenides with covalent M-H chains Reviewed

Mizoguchi, H., Park, S., Hiraka, H., Ikeda, K., Otomo, T., Hosono, H.

Journal of the American Chemical Society   136 ( 50 )   17390 - 17393   2014.12

Hydrothermal crystal growth and structure determination of double hydroxides LiSb(OH)₆, BaSn(OH)₆, and SrSn(OH)₆ Reviewed

Mizoguchi, H., Bhuvanesh, N.S.P., Kim, Y.-I., Ohara, S., Woodward, P.M.

Inorganic Chemistry   53 ( 19 )   10570 - 10577   2014.10

Magnetic structure and electromagnetic properties of LnCrAsO with a ZrCuSiAs-type structure (Ln = La, Ce, Pr, and Nd) Reviewed

Park, S.-W., Mizoguchi, H., Kodama, K., Shamoto, S.-I., Otomo, T., Matsuishi, S., Kamiya, T., Hosono, H.

Inorganic Chemistry   52 ( 23 )   13363 - 13368   2013.12

Electrical and optical properties of Sb-doped BaSnO₃ Reviewed

Mizoguchi, H., Chen, P., Boolch, , P., Ksenofontov, V., Felser, C., Barnes, P.W., Woodward, P.M.

Chemistry of Materials   25 ( 19 )   3858 - 3866   2013.10

Superconductivity in Defective Pyrite-Type Iridium Chalcogenides Ir(x)Ch(2) (Ch = Se and Te) Reviewed

Yanpeng Qi, Satoru Matsuishi, Jiangang Guo, Hiroshi Mizoguchi, Hideo Hosono

PHYSICAL REVIEW LETTERS   109 ( 21 )   2012.11

Superconductivity in a PbFCl-type pnictide: NbSiAs Reviewed

Gihun Ryu, Sung Wng Kim, Hiroshi Mizoguchi, Satoru Matsuishi, Hideo Hosono

EPL   99 ( 2 )   2012.7

Superconductivity in la T _MBN and La ₃ T _M2B ₂N ₃ (T _M = transition metal) synthesized under high pressure Reviewed

Imamura, N., Mizoguchi, H., Hosono, H.

Journal of the American Chemical Society   134 ( 5 )   2516 - 2519   2012.2

Optical constants and crystal chemical parameters of Sc ₂W ₃O ₁₂ Reviewed

Shannon, R.D., Medenbach, O., Mizoguchi, H., Subramanian, M.A., Fischer, R.X.

Materials Research Bulletin   47 ( 2 )   235 - 238   2012.2

Angle-resolved photoemission spectroscopy of Co-based boride superconductor LaCo _1.73Fe _0.27B ₂

Nakayama, K., Ieki, E., Tanaka, Y., Sato, T., Takahashi, T., Kuroda, T., Mizoguchi, H., Kim, S.W., Hosono, H.

Physical Review B - Condensed Matter and Materials Physics   86 ( 1 )   2012

Undulating layers in a new rhodate network: Structure of Bi _1.4CuORh₅O₁₀ Reviewed

Mizoguchi, H., Michiue, Y., Sleight, A.W., Subramanian, M.A.

Inorganic Chemistry   50 ( 20 )   10397 - 10401   2011.10

A germanate transparent conductive oxide Reviewed

Mizoguchi, H., Kamiya, T., Matsuishi, S., Hosono, H.

Nature Communications   2 ( 1 )   2011.9

Synthesis and crystal structure of two new cerium rhodium oxides: Ce _2/3-xRh³₂O₄ (x∼0.12) with Ce mixed valency and Ce⁴Rh³₂O₅ Reviewed

Mizoguchi, H., Zakharov, L.N., Bhuvanesh, N.S.P., Sleight, A.W., Subramanian, M.A.

Journal of Solid State Chemistry   184 ( 6 )   1381 - 1386   2011.6

Crystal and magnetic structures of the superconductor CeNi0.8Bi2 Reviewed

K. Kodama, S. Wakimoto, N. Igawa, S. Shamoto, H. Mizoguchi, H. Hosono

PHYSICAL REVIEW B   83 ( 21 )   2011.6

A Metal-Insulator transition in R₂O₂Bi with an unusual Bi^2- Square Net (R = Rare Earth or Y) Reviewed

Mizoguchi, H., Hosono, H.

Journal of the American Chemical Society   133 ( 8 )   2394 - 2397   2011.3

Coexistence of light and heavy carriers associated with superconductivity and antiferromagnetism in CeNi<inf>0.8</inf>Bi<inf>2</inf> with a Bi square net Reviewed

Hiroshi Mizoguchi, Satoru Matsuishi, Masahiro Hirano, Makoto Tachibana, Eiji Takayama-Muromachi, Hitoshi Kawaji, Hideo Hosono

Physical Review Letters   106 ( 5 )   2011.2

New oxides showing an intense blue color based on Mn³⁺ in trigonal-bipyramidal coordination Reviewed

Mizoguchi, H., Sleight, A.W., Subramanian, M.A.

Inorganic Chemistry   50 ( 1 )   10 - 12   2011.1

LaCo₂B₂: A co-based layered superconductor with a ThCr₂Si₂-type structure

Mizoguchi, H., Kuroda, T., Kamiya, T., Hosono, H.

Physical Review Letters   106 ( 23 )   2011

Verwey-type transition within the Pb₃Rh_7-xMn_xO₁₅ solid solution

Gatimu, A.J., Mizoguchi, H., Sleight, A.W., Subramanian, M.A.

Journal of Solid State Chemistry   183 ( 4 )   2010

Mn³⁺ in trigonal bipyramidal coordination: A new blue chromophore Reviewed

Smith, A.E., Mizoguchi, H., Delaney, K., Spaldin, N.A., Sleight, A.W., Subramanian, M.A.

Journal of the American Chemical Society   131 ( 47 )   17084 - 17086   2009.12

Possible verwey-type transition in Pb ₃Rh ₇O ₁₅ Reviewed

Mizoguchi, H., Ramirez, A.P., Siegrist, T., Zakharov, L.N., Sleight, A.W., Subramanian, M.A.

Chemistry of Materials   21 ( 11 )   2300 - 2305   2009.6

AA ₂Rh ₆O ₁₂: A new family of rhodium oxides exhibiting high thermopower coupled with high electrical conductivity Reviewed

Mizoguchi, H., Zakharov, L.N., Marshall, W.J., Sleight, A.W., Subramanian, M.A.

Chemistry of Materials   21 ( 6 )   994 - 999   2009.3

New a _2/3-xrh ₂O ₄ compounds with the CaFe ₂O ₄ structure where a is a rare earth or bi Reviewed

Mizoguchi, H., Zakharov, L.N., Ramirez, A.P., Marshall, W., Sleight, A.W., Subramanian, M.A.

Inorganic Chemistry   48 ( 1 )   204 - 208   2009.1

Bi_2/3Ce_1/3Rh₂O₅: A new mixed-valent Rh oxide with hitherto unknown structure Reviewed

Mizoguchi, H., Ramirez, A.P., Zakharov, L.N., Sleight, A.W., Subramanian, M.A.

Journal of Solid State Chemistry   181 ( 1 )   56 - 60   2008.1

Partial charge ordering in the mixed-valent compound (Bi₆ O₅) Rh₈^{3 +} Rh₄^{4 +} O₂₄ Reviewed

Mizoguchi, H., Marshall, W.J., Ramirez, A.P., Sleight, A.W., Subramanian, M.A.

Journal of Solid State Chemistry   180 ( 12 )   3463 - 3468   2007.12

Structures and bonding in K_0.91U_1.79S₆ and KU₂Se₆ Reviewed

Mizoguchi, H., Gray, D., Huang, F.Q., Ibers, J.A.

Inorganic Chemistry   45 ( 8 )   3307 - 3311   2006.4

Electrical properties and structure of p-type amorphous oxide semiconductor xZnO·Rh₂O₃

Kamiya, T., Narushima, S., Mizoguchi, H., Shimizu, K.-I., Ueda, K., Ohta, H., Hirano, M., Hosono, H.

Advanced Functional Materials   15 ( 6 )   2005

Electronic structure studies of main group oxides possessing edge-sharing octahedra: Implications for the design of transparent conducting oxides Reviewed

Mizoguchi, H., Woodward, P.M.

Chemistry of Materials   16 ( 25 )   5233 - 5248   2004.12

Strong Near-Infrared Luminescence in BaSnO3 Reviewed

Hiroshi Mizoguchi, Patrick M. Woodward, Cheol-Hee Park, Douglas A. Keszler

Journal of the American Chemical Society   126 ( 31 )   9796 - 9800   2004.8

Polymorphism in NaSbO₃: Structure and Bonding in Metal Oxides Reviewed

Mizoguchi, H., Woodward, P.M., Byeon, S.-H., Pariset, J.B.

Journal of the American Chemical Society   126 ( 10 )   3175 - 3184   2004.3

Probing the Electronic Structures of Ternary Perovskite and Pyrochlore Oxides Containing Sn4+or Sb5+ Reviewed

Hiroshi Mizoguchi, Hank W. Eng, Patrick M. Woodward

Inorganic Chemistry   43 ( 5 )   1667 - 1680   2004.3

Fabrication and characterization of heteroepitaxial p-n junction diode composed of wide-gap oxide semiconductors p-ZnRh2O4/n-ZnO

H Ohta, H Mizoguchi, M Hirano, S Narushima, T Kamiya, H Hosono

APPLIED PHYSICS LETTERS   82 ( 5 )   823 - 825   2003.2

Decomposition of water by a CaTiO₃ photocatalyst under UV light irradiation Reviewed

Hiroshi Mizoguchi, Kazushige Ueda, Masahiro Orita, Sang Chul Moon, Koichi Kajihara, Masahiro Hirano, Hideo Hosono

Materials Research Bulletin   37   2401 - 2406   2002.12

Electronic structure of SrNb8O14 and Mg3Nb6O11 studied by spectroscopic methods Reviewed

H Mizoguchi, K Ueda, K Fukumi, N Kitamura, Z Siroma, T Takeuchi, K Kadono, H Yanagi, H Hosono, H Kawazoe

CHEMISTRY OF MATERIALS   12 ( 9 )   2659 - 2663   2000.9

Valence states of bismuth in new mixed-valence oxides: Bi1-xYxO1.5+delta (x=0.4) by xanes Reviewed

H Mizoguchi, H Hosono, H Kawazoe, M Yasukawa, S Fujitsu, K Fukumi

MATERIALS RESEARCH BULLETIN   34 ( 3 )   373 - 379   1999.2

Observation of electronic structure in conduction band of CaTiO3 Reviewed

K Ueda, H Yanagi, R Noshiro, H Mizoguchi, T Omata, N Ueda, H Hosono, H Kawazoe

JOURNAL OF THE CERAMIC SOCIETY OF JAPAN   106 ( 10 )   964 - 967   1998.10

ELECTRONIC TRANSPORT-PROPERTIES OF HOLE-DOPED SR1+XLA1-XCRO4+DELTA Reviewed

T OMATA, T KAWANO, H IKAWA, T SASAMOTO, H HOSONO, H MIZOGUCHI, H KAWAZOE

JOURNAL OF THE CERAMIC SOCIETY OF JAPAN   103 ( 11 )   1112 - 1116   1995.11

NEW OXIDE PHASE WITH WIDE BAND-GAP AND HIGH ELECTROCONDUCTIVITY, MGIN2O4 Reviewed

N UEDA, T OMATA, N HIKUMA, K UEDA, H MIZOGUCHI, T HASHIMOTO, H KAWAZOE

APPLIED PHYSICS LETTERS   61 ( 16 )   1954 - 1955   1992.10

アンモニア分解用触媒の探索

2023.4 - 2025.3

フジクラ財団  2023年度研究助成 

溝口拓

金属間化合物触媒の探索

Grant number：2022-J-042  2022.10 - 2023.3

泉科学技術振興財団 

溝口拓

水素と親和性の高い金属間化合物電子化物の探索：軟らかさからの新アプロ-チ

Grant number：23K23440  2022.4 - 2027.3

日本学術振興会  科学研究費助成事業  基盤研究(B)

溝口 拓

金属間化合物の電子化物と水素吸蔵特性

2021.10 - 2022.9

三菱財団 

溝口拓

反応性蒸着による、空隙を有するアルカリ金属窒化物エレクトライドの合成

2019.4 - 2020.3

村田学術振興財団 

溝口拓

Electroactive materials possessing cavity sites

Grant number：18K05270  2018.4 - 2021.3

Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research  Grant-in-Aid for Scientific Research (C)

MIZOGUCHI Hiroshi

アルカリ金属窒化物エレクトライドの探索

2018.4 - 2019.3

大倉和親記念財団 

溝口拓