Japan Society for the Promotion of Science

2013.4

Japan Society for the Promotion of Science

2011.4 - 2013.3

Mechanistic studies on catalytic alkane oxidation by Murahashi's O₂/copper(<scp>ii</scp>)/aldehyde system

Kohei Yamaguchi, Yuya Uemura, Hideki Sugimoto, Rin Ito, Yuma Morimoto, Shinobu Itoh

Catalysis Science &amp; Technology   2023

Alkane hydroxylation by m-chloroperbenzoic acid catalyzed by nickel(II) complexes of linear N4-tetradentate ligands

Takuma Wada, Hideki Sugimoto, Yuma Morimoto, Shinobu Itoh

Polyhedron   227   116150 - 116150   2022.11

Hydroxylation of Aliphatic and Aromatic C-H Bonds Catalyzed by Biomimetic Transition-metal Complexes

Yuma Morimoto, Shinobu Itoh

Journal of Synthetic Organic Chemistry, Japan   80 ( 5 )   506 - 516   2022.5

Revisiting Alkane Hydroxylation with m‐CPBA (mChloroperbenzoic Acid) Catalyzed by Nickel(II) Complexes Reviewed

Shinobu Itoh, Tomoya Shinke, Mayu Itoh, Takuma Wada, Yuma Morimoto, Sachiko Yanagisawa, Hideki Sugimoto, Minoru Kubo

Chemistry – A European Journal   27 ( 59 )   14730 - 14737   2021.8

Controlling the Reactivity of Copper(II) Acylperoxide Complexes Reviewed

Yuma Morimoto, Makito Kawai, Aya Nakanishi, Hideki Sugimoto, Shinobu Itoh

Inorganic Chemistry   60 ( 12 )   8554 - 8565   2021.6

Hydroxylation of Unactivated C(sp3)–H Bonds with m-Chloroperbenzoic Acid Catalyzed by an Iron(III) Complex Supported by a Trianionic Planar Tetradentate Ligand

Yuma Morimoto, Shinichi Hanada, Ryusuke Kamada, Arisa Fukatsu, Hideki Sugimoto, Shinobu Itoh

Inorganic Chemistry   2021.1

Controlling coordination number of rhodium(III) complex by ligand-based redox for catalytic CH amination Reviewed

Fujita, D., Kaga, A., Sugimoto, H., Morimoto, Y., Itoh, S.

Bulletin of the Chemical Society of Japan   93 ( 2 )   279 - 286   2020

Modelling a ‘histidine brace’ motif in mononuclear copper monooxygenases Reviewed

Fukatsu, A., Morimoto, Y., Sugimoto, H., Itoh, S.

Chemical Communications   56 ( 38 )   5123 - 5126   2020

Characterization and Reactivity of a Tetrahedral Copper(II) Alkylperoxido Complex Reviewed

Shimizu, I., Morimoto, Y., Velmurugan, G., Gupta, T., Paria, S., Ohta, T., Sugimoto, H., Ogura, T., Comba, P., Itoh, S.

Chemistry - A European Journal   25 ( 47 )   11157 - 11165   2019

Direct Observation of Primary C−H Bond Oxidation by an Oxido-Iron(IV) Porphyrin π-Radical Cation Complex in a Fluorinated Carbon Solvent Reviewed

Morimoto, Y., Shimaoka, Y., Ishimizu, Y., Fujii, H., Itoh, S.

Angewandte Chemie - International Edition   58 ( 32 )   10863 - 10866   2019

Cupric-superoxide complex that induces a catalytic aldol reaction-type C–C bond formation Reviewed

Abe, T., Hori, Y., Shiota, Y., Ohta, T., Morimoto, Y., Sugimoto, H., Ogura, T., Yoshizawa, K., Itoh, S.

Communications Chemistry   2 ( 1 )   12 - 7   2019

A Bis(μ-oxido)dinickel(III) Complex with a Triplet Ground State

Yuma Morimoto, Yusaku Takagi, Toru Saito, Takehiro Ohta, Takashi Ogura, Norimitsu Tohnai, Motohiro Nakano, Shinobu Itoh

Angewandte Chemie   130 ( 26 )   7766 - 7769   2018.6

Copper(I)-Dioxygen Reactivity in the Isolated Cavity of a Nanoscale Molecular Architecture (Eur. J. Inorg. Chem. 19/2018) Reviewed

Sayantan Paria, Yuma Morimoto, Takehiro Ohta, Shinsuke Okabe, Hideki Sugimoto, Takashi Ogura, Shinobu Itoh

European Journal of Inorganic Chemistry   2018 ( 19 )   1955 - 1955   2018.5

Tyrosinases in Organic Chemistry: A Versatile Tool for the α-Arylation of β-Dicarbonyl Compounds Reviewed

Roxanne Krug, Dennis Schröder, Jan Gebauer, Sanel Suljić, Yuma Morimoto, Nobutaka Fujieda, Shinobu Itoh, Jörg Pietruszka

European Journal of Organic Chemistry   2018 ( 15 )   1789 - 1796   2018.4

Copper(I)–Dioxygen Reactivity in the Isolated Cavity of a Nanoscale Molecular Architecture Reviewed

Paria, S., Morimoto, Y., Ohta, T., Okabe, S., Sugimoto, H., Ogura, T., Itoh, S.

European Journal of Inorganic Chemistry   2018 ( 19 )   1976 - 1983   2018

Noninnocent Ligand in Rhodium(III)-Complex-Catalyzed C-H Bond Amination with Tosyl Azide Reviewed

Fujita, D., Sugimoto, H., Morimoto, Y., Itoh, S.

Inorganic Chemistry   57 ( 16 )   9738 - 9747   2018

A Bis(μ-oxido)dinickel(III) Complex with a Triplet Ground State Reviewed

Morimoto, Y., Takagi, Y., Saito, T., Ohta, T., Ogura, T., Tohnai, N., Nakano, M., Itoh, S.

Angewandte Chemie - International Edition   57 ( 26 )   7640 - 7643   2018

2-(2-Pyridyl)ethylamine (Pye) ligands in copper(I)-dioxygen chemistry Reviewed

Itoh, S., Abe, T., Morimoto, Y., Sugimoto, H.

Inorganica Chimica Acta   481   38 - 46   2018

Structure and Reactivity of Copper Complexes Supported by a Bulky Tripodal N<inf>4</inf> Ligand: Copper(I)/Dioxygen Reactivity and Formation of a Hydroperoxide Copper(II) Complex Reviewed

Paria, S., Ohta, T., Morimoto, Y., Sugimoto, H., Ogura, T., Itoh, S.

Zeitschrift fur Anorganische und Allgemeine Chemie   644 ( 14 )   780 - 789   2018

Crystal structure and oxygen reduction reaction (ORR) activity of copper(II) complexes of pyridylmethylamine ligands containing a carboxy group Reviewed

Asahi, M., Yamazaki, S.-I., Morimoto, Y., Itoh, S., Ioroi, T.

Inorganica Chimica Acta   471   91 - 98   2018

Geometric effects on O–O bond scission of copper(II)-alkylperoxide complexes Reviewed

Tsukasa Abe, Yuma Morimoto, Kaoru Mieda, Hideki Sugimoto, Nobutaka Fujieda, Takashi Ogura, Shinobu Itoh

Journal of Inorganic Biochemistry   177   375 - 383   2017.12

Tetrahedral Copper(II) Complexes with a Labile Coordination Site Supported by a Tris-tetramethylguanidinato Ligand Reviewed

Ikuma Shimizu, Yuma Morimoto, Dieter Faitermeier, Marion Kerscher, Sayantan Paria, Tsukasa Abe, Hideki Sugimoto, Nobutaka Fujieda, Kaori Asano, Takeyuki Suzuki, Peter Comba, Shinobu Itoh

INORGANIC CHEMISTRY   56 ( 16 )   9634 - 9645   2017.8

Generation and characterisation of a stable nickel(II)-aminoxyl radical complex Reviewed

Arnaud Parrot, Yuma Morimoto, Sayantan Paria, Hideki Sugimoto, Nobutaka Fujieda, Shinobu Itoh

DALTON TRANSACTIONS   46 ( 25 )   8013 - 8016   2017.7

Catalytic C-H amination driven by intramolecular ligand-to-nitrene one-electron transfer through a rhodium((III)) centre Reviewed

Daiki Fujita, Hideki Sugimoto, Yoshihito Shiota, Yuma Morimoto, Kazunari Yoshizawa, Shinobu Itoh

CHEMICAL COMMUNICATIONS   53 ( 35 )   4849 - 4852   2017.5

Catalytic C-H amination driven by intramolecular ligand-to-nitrene one-electron transfer through a rhodium(III) centre (vol 53, pg 4849, 2017) Reviewed

Daiki Fujita, Hideki Sugimoto, Yoshihito Shiota, Yuma Morimoto, Kazunari Yoshizawa, Shinobu Itoh

CHEMICAL COMMUNICATIONS   53 ( 41 )   5669 - 5669   2017.5

A Well-Defined Osmium-Cupin Complex: Hyperstable Artificial Osmium Peroxygenase Reviewed

Nobutaka Fujieda, Takumi Nakano, Yuki Taniguchi, Haruna Ichihashi, Hideki Sugimoto, Yuma Morimoto, Yosuke Nishikawa, Genji Kurisu, Shinobu Itoh

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   139 ( 14 )   5149 - 5155   2017.4

Cerium-Complex-Catalyzed Oxidation of Arylmethanols under Atmospheric Pressure of Dioxygen and Its Mechanism through a Side-On -Peroxo Dicerium(IV) Complex Reviewed

Mitali Paul, Satoru Shirase, Yuma Morimoto, Laurent Mathey, Balasubramanian Murugesapandian, Shinji Tanaka, Shinobu Itoh, Hayato Tsurugi, Kazushi Mashima

CHEMISTRY-A EUROPEAN JOURNAL   22 ( 12 )   4008 - 4014   2016.3

Generation, Characterization, and Reactivity of a Cu-II-Alkylperoxide/Anilino Radical Complex: Insight into the O-O Bond Cleavage Mechanism Reviewed

Sayantan Paria, Takehiro Ohta, Yuma Morimoto, Takashi Ogura, Hideki Sugimoto, Nobutaka Fujieda, Kei Goto, Kaori Asano, Takeyuki Suzuki, Shinobu Itoh

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   137 ( 34 )   10870 - 10873   2015.9

Chemistry of Iron-superoxide Complexes Invited Reviewed

Yuma Morimoto, Shinobu Itoh

Chemistry   70 ( 9 )   64 - 65   2015.9

Direct Hydroxylation of Benzene to Phenol Using Hydrogen Peroxide Catalyzed by Nickel Complexes Supported by Pyridylalkylamine Ligands Reviewed

Yuma Morimoto, Shuji Bunno, Nobutaka Fujieda, Hideki Sugimoto, Shinobu Itoh

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   137 ( 18 )   5867 - 5870   2015.5

β-Diketiminates as Redox Non-innocent Supporting Ligands in Coordination Chemistry Invited Reviewed

Shinobu Itoh, Yuma Morimoto

Chemical Science of Electron Systems   715 - 730   2015.1

Redox behavior of novel nickel and palladium complexes supported by trianionic non-innocent ligand containing beta-diketiminate and phenol groups Reviewed

Yuma Morimoto, June Takaichi, Shinichi Hanada, Kei Ohkubo, Hideki Sugimoto, Nobutaka Fujieda, Shunichi Fukuzumi, Shinobu Itoh

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES   19 ( 1-3 )   377 - 387   2015.1

A Tetradentate beta-Diiminato Ligand Containing Phenolate Substituents: Flexivalent Coordination to Mn-III, Co-III, Ni-II, and Cu-II Reviewed

Fadhil Lafta Faraj, Hamid Khaledi, Yuma Morimoto, Shinobu Itoh, Marilyn M. Olmstead, Hapipah Mohd Ali

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY   ( 33 )   5752 - 5759   2014.11

Geometric Control of Nuclearity in Copper(I)/Dioxygen Chemistry Reviewed

Tsukasa Abe, Yuma Morimoto, Tetsuro Tano, Kaoru Mieda, Hideki Sugimoto, Nobutaka Fujieda, Takashi Ogura, Shinobu Itoh

INORGANIC CHEMISTRY   53 ( 16 )   8786 - 8794   2014.8

Redox Chemistry of Nickel(II) Complexes Supported by a Series of Noninnocent beta-Diketiminate Ligands Reviewed

June Takaichi, Yuma Morimoto, Kei Ohkubo, Chizu Shimokawa, Takayuki Hojo, Seiji Mori, Haruyasu Asahara, Hideki Sugimoto, Nobutaka Fujieda, Nagatoshi Nishiwaki, Shunichi Fukuzumi, Shinobu Itoh

INORGANIC CHEMISTRY   53 ( 12 )   6159 - 6169   2014.6

Unified View of Oxidative C-H Bond Cleavage and Sulfoxidation by a Nonheme Iron(IV)-Oxo Complex via Lewis Acid-Promoted Electron Transfer Reviewed

Jiyun Park, Yuma Morimoto, Yong-Min Lee, Wonwoo Nam, Shunichi Fukuzumi

INORGANIC CHEMISTRY   53 ( 7 )   3618 - 3628   2014.4

Effects of Proton Acceptors on Formation of a Non-Heme Iron(IV)-Oxo Complex via Proton-Coupled Electron Transfer Reviewed

Yusuke Nishida, Yuma Morimoto, Yong-Min Lee, Wonwoo Nam, Shunichi Fukuzumi

INORGANIC CHEMISTRY   52 ( 6 )   3094 - 3101   2013.3

An autocatalytic radical chain pathway in formation of an iron(IV)-oxo complex by oxidation of an iron(II) complex with dioxygen and isopropanol Reviewed

Yuma Morimoto, Yong-Min Lee, Wonwoo Nam, Shunichi Fukuzumi

CHEMICAL COMMUNICATIONS   49 ( 25 )   2500 - 2502   2013

Mechanistic Borderline of One-Step Hydrogen Atom Transfer versus Stepwise Sc3+-Coupled Electron Transfer from Benzyl Alcohol Derivatives to a Non-Heme Iron(IV)-Oxo Complex Reviewed

Yuma Morimoto, Jiyun Park, Tomoyoshi Suenobu, Yong-Min Lee, Wonwoo Nam, Shunichi Fukuzumi

INORGANIC CHEMISTRY   51 ( 18 )   10025 - 10036   2012.9

Proton-Promoted Oxygen Atom Transfer vs Proton-Coupled Electron Transfer of a Non-Heme Iron(IV)-Oxo Complex Reviewed

Jiyun Park, Yuma Morimoto, Yong-Min Lee, Wonwoo Nam, Shunichi Fukuzumi

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   134 ( 8 )   3903 - 3911   2012.2

Mechanisms of metal ion-coupled electron transfer Reviewed

Shunichi Fukuzumi, Kei Ohkubo, Yuma Morimoto

PHYSICAL CHEMISTRY CHEMICAL PHYSICS   14 ( 24 )   8472 - 8484   2012

Electron-transfer properties of a nonheme manganese(IV)-oxo complex acting as a stronger one-electron oxidant than the iron(IV)-oxo analogue Reviewed

Heejung Yoon, Yuma Morimoto, Yong-Min Lee, Wonwoo Nam, Shunichi Fukuzumi

CHEMICAL COMMUNICATIONS   48 ( 91 )   11187 - 11189   2012

Scandium Ion-Enhanced Oxidative Dimerization and N-Demethylation of N,N-Dimethylanilines by a Non-Heme Iron(IV)-Oxo Complex Reviewed

Jiyun Park, Yuma Morimoto, Yong-Min Lee, Youngmin You, Wonwoo Nam, Shunichi Fukuzumi

INORGANIC CHEMISTRY   50 ( 22 )   11612 - 11622   2011.11

Metal Ion Effect on the Switch of Mechanism from Direct Oxygen Transfer to Metal Ion-Coupled Electron Transfer in the Sulfoxidation of Thioanisoles by a Non-Heme Iron(IV)-Oxo Complex Reviewed

Jiyun Park, Yuma Morimoto, Yong-Min Lee, Wonwoo Nam, Shunichi Fukuzumi

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   133 ( 14 )   5236 - 5239   2011.4

Metal Ion-Coupled Electron, Transfer of a Nonheme Oxoiron(IV) Complex: Remarkable Enhancement of Electron-Transfer Rates by Sc3+ Reviewed

Yuma Morimoto, Hiroaki Kotani, Jiyun Park, Yong-Min Lee, Wonwoo Nam, Shunichi Fukuzumri

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   133 ( 3 )   403 - 405   2011.1

Crystal structure of a metal ion-bound oxoiron(IV) complex and implications for biological electron transfer Reviewed

Shunichi Fukuzumi, Yuma Morimoto, Hiroaki Kotani, Pance Naumov, Yong-Min Lee, Wonwoo Nam

NATURE CHEMISTRY   2 ( 9 )   756 - 759   2010.9

Dioxygen Activation by a Non-Heme Iron(II) Complex: Formation of an Iron(IV)-Oxo Complex via C-H Activation by a Putative Iron(III)-Superoxo Species Reviewed

Yong-Min Lee, Seungwoo Hong, Yuma Morimoto, Woonsup Shin, Shunichi Fukuzumi, Wonwoo Nam

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   132 ( 31 )   10668 - 10670   2010.8

Effects of Axial Ligand on Alkane Hydroxylation by Oxido-Iron(IV) Porphyrin π-Radical Cation Complex

Toshiya Higashi, Yuma Morimoto, Hiroshi Fujii, Shinobu Itoh

10th Asian Biological Inorganic Chemistry (AsBIC10)  2022.11 

Activation of A Di(µ-oxido)dinickel(III) Complex Induced by Coordination of Carboxylate

Ryouichiro Ogumo, Yuma Morimoto, Shinobu Itoh

10th Asian Biological Inorganic Chemistry (AsBIC10)  2022.11 

Characterization and Reactivity of Rare Cu(II)-halide Complexes Having a Distorted Tetrahedral Geometry

Lan Yang, Yuma Morimoto, Hideki Sugimoto, Shinobu Itoh

10th Asian Biological Inorganic Chemistry (AsBIC10)  2022.11 

Axial Ligand Effect on Cyclohexane Hydroxylation by Compound I Model Complex

Yuma Morimoto, Toshiya Higashi, Hiroshi Fujii, Shinobu Itoh

2022.9 

ヘム酵素活性サイトモデル錯体によるシクロヘキサン水酸化における軸配位子効果

東俊哉, 森本祐麻, 藤井浩, 伊東忍

第16回バイオ関連化学シンポジウム  2022.9 

カルボキシラートの配位によるジ(µ-オキシド)二核ニッケル(III)錯体の活性化

小雲諒一郎, 森本祐麻, 伊東忍

第31回金属の関与する生体関連シンポジウム  2022.6 

Introduction of Bond Hardness into the Analysis of Hydrogen Atom Abstraction from Alkanes to Compound I Model Complex Invited

Yuma Morimoto

The 51st Kast International Symposium  2022.6 

ヘム酵素の反応中間体 Compound I モデル錯体の反応性の重回帰分析による機構検討 Invited

森本祐麻

第1回生命金属科学シンポジウム  2022.5 

Substituent Effects on Formation Reaction of Nickel(II)-percarboxylate Complex by Ozone Oxidation of Nickel(II)-carboxylate Complexes

Yuma Morimoto, Ryotaro Hariki, Shinobu Itoh

2022.3 

鉄(IV)オキソポルフィリン-π-カチオンラジカル錯体によるアルカンの水酸化反応における軸配位子の効果

東俊哉, 森本祐麻, 藤井浩, 伊東忍

日本化学会第102回春季年会  2022.3 

ジ(µ-オキシド)二核ニッケル(III)錯体の酸化活性に及ぼすカルボキシラートの配位効果

小雲諒一郎, 森本祐麻, 伊東忍

日本化学会第102回春季年会  2022.3 

Efect of π-Donar Ability of Axical Ligand on Aliphatic Hydroxylation by Compound I Model Complex Invited

森本祐麻

11th Asian Biological Inorganic Chemistry Conference  2024.12 

長さの異なるアルキレン架橋基を有する二核Ni錯体とH2O2の等電子体との反応

廣瀬拓也, 森本祐麻, 山下誠

第57回 酸化反応討論会  2024.11 

構造歪の導入による二核ニッケル錯体の酸化還元過程の速度論的活性化

廣瀬拓也, 森本祐麻, 山下誠

日本化学会第105春季年会  2025.3 

Mechanistic Investigations on sp3-C–H Activation by Compound I Model Complex Invited

Yuma Morimoto

2025.1 

Dirhodium Complexes with a Redox Flexibility Supported by a Macrocyclic PDI2 Ligand

Liping YAN, Yuma MORIMOTO, Makoto YAMASHITA

日本化学会第105春季年会  2025.3 

長さの異なるアルキレン鎖によって架橋された二核ニッケル(Ⅲ)錯体の構造と反応性

廣瀬拓也, 森本祐麻, 山下誠

錯体化学会第74回討論会  2024.9 

Electrochemical Reduction of CO2 Catalyzed by Dirhodium(Ⅱ) Complex Supoorted by A Macrocycllc Ligand

YAN Liping, MORIMOTO Yuma, YAMASHITA Makoto

錯体化学会第74回討論会  2024.9 

Studies on Inert-Alkane Oxidation Systems with Reactive-Oxygen Transition-Metal Complexes Invited

2024.9 

Effect of Axial-ligand π-Donor Ability on Reactivity of Compound I Model Complex Invited

Yuma Morimoto, Toshiya Higashi, Hiroshi Fujii, Shinobu Itoh

The 9th Asian Conference on Coordination Chemistry  2023.2 

反応座標を可視化する：反応速度論と多変量解析の交差点

森本祐麻

有機金属若手研究者の会  2023.9 

オゾンガスを利用した不活性アルカンの酸化反応

森本祐麻

第一回MA-T学会  2023.11 

自然界に学ぶ酸化還元活性配位子を利用したHAT触媒デザイン

森本祐麻

電気化学会第91回大会  2024.3 

錯体化学会第61回討論会学生講演賞

2011.10   錯体化学会  

森本祐麻

Development of Mononucelar Copper-oxyl Radical Species

Grant number：16K13963  2016.4 - 2019.3

Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research  Grant-in-Aid for Challenging Exploratory Research

Itoh Shinobu, MORIMOTO Yuma, Sugimoto Hideki

過酸化水素を酸化剤とした環境負荷の小さいベンゼン水酸化反応の開発

2016.4 - 2017.3

宇部興産学術振興財団  学術奨励賞 

森本祐麻

金属イオンの配位による高原子価金属オキソ種の活性化

Grant number：11J00730  2011.4 - 2014.3

日本学術振興会  学振特別研究員奨励金  特別研究員奨励費

森本祐麻

Creation of Transition-metal-Oxido Complexes for Direct C-H Bond Hydroxylation

Grant number：22105007  2010.4 - 2016.3

Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research  Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

Itoh Shinobu, SUGIMOTO Hideki, FUJIEDA Nobutaka, MORIMOTO Yuma