Updated on 2026/05/27

写真a

 
YAMASHITA MAKOTO
 
Organization
School of Science Professor
Title
Professor
External link

Degree

  • Doctor of Science ( Hiroshima University )

  • 博士(理学) ( 広島大学 )

Research Interests

  • homogeneous catalyst

  • petrochemistry

  • main group chemistry

  • organometallic chemistry

Research Areas

  • Nanotechnology/Materials / Synthetic organic chemistry

  • Life Science / Bioorganic chemistry

  • Nanotechnology/Materials / Structural organic chemistry and physical organic chemistry

Education

  • Hiroshima University   Graduate School, Division of Natural Science   Chemistry

    - 2002.3

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    Country: Japan

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  • Hiroshima University   Faculty of Science

    - 1997.3

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    Country: Japan

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Research History

  • Institute of Science Tokyo   School of Science, Department of Chemistry   Professor

    2024.10

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  • Tokyo Institute of Technology   School of Science   Professor

    2024.4 - 2024.9

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  • Nagoya University   Graduate School of Engineering Molecular and Macromolecular Chemistry 1   Professor

    2017.4 - 2024.3

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  • Nagoya University   Graduate School of Engineering Department of Applied Chemistry, Chemical Engineering and Biotechnology Applied Organic Chemistry   Professor

    2016.10 - 2017.3

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  • Kyoto University   Visiting Professor

    2015.10 - 2016.3

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  • Chuo University   Faculty of Science and Engineering   Professor

    2015.4 - 2016.9

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  • Rikkyo University   Visiting Professor

    2013.4 - 2014.3

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  • Chuo University   Faculty of Science and Engineering   Associate Professor

    2011.4 - 2015.3

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  • The University of Tokyo   School of Engineering   Lecturer

    2008.7 - 2011.3

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  • The University of Tokyo   School of Engineering   Lecturer

    2008.7 - 2011.3

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  • Tokyo Institute of Technology   Visiting Professor

    2008.4 - 2009.3

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  • The University of Tokyo   School of Engineering   Assistant Professor

    2007.4 - 2008.7

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  • The University of Tokyo   School of Engineering   Research Associate

    2004.4 - 2007.3

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  • JSPS Research Fellow PD

    2003.4 - 2004.3

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  • 日本学術振興会特別研究員DC2,PD

    2001.4 - 2003.3

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Professional Memberships

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Papers

  • Substituent effect on the boron atoms in boron-bridged hexazenes

    Masahiro Yamamoto, Makoto Yamashita

    Dalton Transactions   2026

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/D5DT02896E

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  • Low-oxidation state dirhodium complex produced by four-electron reduction of dirhodium(ii) complex supported by a flexible macrocyclic ligand

    Liping Yan, Takumi Moriyama, Yutaro Akita, Satoshi Muratsugu, Mizuki Tada, Makoto Yamashita, Yuma Morimoto

    Chemical Science   2026

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/D5SC07037F

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  • An Acceleration Effect of a Carbene Catalyst Toward C–F Bond Cleavage at a Gallium Center

    Tao Ding, Farshad Shiri, Zhenyang Lin, Makoto Yamashita

    ChemistryEurope   2025.11

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/ceur.202500262

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  • Cleaving a C-F bond of C6F6 at a gallium(<sc>i</sc>) centre catalyzed by nitrogen-containing Lewis bases and its kinetic analysis

    Tao Ding, Makoto Yamashita

    DALTON TRANSACTIONS   54 ( 37 )   13859 - 13862   2025.9

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/d5dt01990g

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  • A Lewis Base-Free Trialumane: Enhanced Electrophilicity Based on Consecutive Vacant Orbitals Over Three Aluminum Atoms

    Ryotaro Yamanashi, Chaoqi Chen, Takumi Moriyama, Satoshi Muratsugu, Mizuki Tada, Taisuke Ozaki, Makoto Yamashita

    CHEMISTRY-A EUROPEAN JOURNAL   31 ( 28 )   2025.5

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/chem.202501315

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  • Toward a definition of valence as a quantity (IUPAC Technical Report)

    Pavel Karen, Lidia Armelao, Ian S. Butler, Vladislav Tomisic, Makoto Yamashita

    PURE AND APPLIED CHEMISTRY   97 ( 2 )   149 - 187   2025.2

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1515/pac-2023-0402

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  • Synthesis of an Unsymmetrical Dialumane and Kinetic Analysis of its Alkene Insertion

    Ryotaro Yamanashi, Kanata Mizutani, Makoto Yamashita

    Chemistry – A European Journal   31 ( 1 )   2025.1

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/chem.202403926

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  • Synthesis and Reactivity of an Alumanyl–Tin Species to Form an Al,N-Heteroallene Derivative

    Genfeng Feng, Makoto Yamashita

    Journal of the American Chemical Society   146 ( 42 )   28653 - 28657   2024.10

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    DOI: 10.1021/jacs.4c11586

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  • Base‐Stabilized Gallium Sulfides and Selenides Supported by a Bis(oxazolinyl)(phenyl)methanide Ligand

    Tao Ding, Ryo Nakano, Makoto Yamashita

    Chemistry – A European Journal   30 ( 42 )   2024.7

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/chem.202401665

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  • Photophysical properties of 1-Aza-2-boraacenaphthene synthesized by a reduction of base-stabilized aminodibromoborane

    Haruki Kumada, Ryo Nakano, Makoto Yamashita

    CHEMISTRY LETTERS   53 ( 4 )   2024.3

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    DOI: 10.1093/chemle/upae057

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  • Alumanyl-Samarium(II): Synthesis, Characterization, and Reactivity Studies

    Genfeng Feng, Ka Lok Chan, Zhenyang Lin, Makoto Yamashita

    Journal of the American Chemical Society   146 ( 11 )   7204 - 7209   2024.3

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/jacs.4c01193

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  • Oxidative Coupling of Methane under High-pressure Conditions Using a Na2WO4/SiO2 Catalyst

    Keiju Wachi, Tomohiro Yabe, Ryo Nakano, Makoto Yamashita, Kazuya Yamaguchi

    JOURNAL OF THE JAPAN PETROLEUM INSTITUTE   67 ( 2 )   71 - 79   2024

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1627/jpi.67.71

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  • 6.1.45 Diphosphino–Boryl (PBP) Pincer Complexes

    M. Yamashita

    2024

  • Mechanochemical Synthesis of Non‐Solvated Dialkylalumanyl Anion and XPS Characterization of Al(I) and Al(II) Species**

    Satoshi Kurumada, Ryotaro Yamanashi, Kengo Sugita, Koji Kubota, Hajime Ito, Satoru Ikemoto, Chaoqi Chen, Takumi Moriyama, Satoshi Muratsugu, Mizuki Tada, Takanori Koitaya, Taisuke Ozaki, Makoto Yamashita

    Chemistry – A European Journal   30 ( 7 )   2023.12

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/chem.202303073

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  • A Vanadium Alumanyl Complex: Synthesis, Characterization, Reactivity, and Application as a Catalyst for C–H Alumanylation of Alkenes

    Pavel Zatsepin, Takumi Moriyama, Chaoqi Chen, Satoshi Muratsugu, Mizuki Tada, Makoto Yamashita

    Journal of the American Chemical Society   146 ( 5 )   3492 - 3497   2023.11

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    DOI: 10.26434/chemrxiv-2023-d1q75

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  • Synthesis of Rhodium Complexes Having a Macrocyclic Ligand Based on Two m-Phenylene-Linked Bis(N-heterocyclic carbene) Moieties as a CCC-Pincer Ligand or Two Bis(carbene) Ligand

    Ayaka Komori, Makoto Yamashita, Jun-ichi Ito

    Organometallics   42 ( 21 )   3130 - 3137   2023.11

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.organomet.3c00370

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  • Reactions of Tetra(o‐tolyl)diborane(4) with Organic Azides: Formation of Fluorescent Boron‐Fused Hexazenes

    Masahiro Yamamoto, Wing Chun Chan, Zhenyang Lin, Makoto Yamashita

    Chemistry – A European Journal   29 ( 59 )   2023.9

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/chem.202302027

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  • Alkali Chloride Adducts of Acyclic Acylaluminum: Synthesis, Structure, and Reactivity Studies

    Genfeng Feng, Makoto Yamashita

    Angewandte Chemie   62 ( 30 )   2023.7

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/ange.202306366

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  • Low-Temperature Dehydrogenation of Cyclooctane by Using Pincer Iridium Complexes Bearing an N,N′-Diarylated PNCNP Ligand

    Naoto Uno, Ryo Nakano, Makoto Yamashita

    ACS Catalysis   13 ( 10 )   6956 - 6965   2023.5

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    DOI: 10.1021/acscatal.3c01739

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  • 5-Sulfurated Imidazo[1,5-a]Pyridin-3-ylidenes: Ligands for π-Acidic Catalysts

    Makoto Yamashita

    Israel Journal of Chemistry   2023

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/IJCH.202200038

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  • Base‐Stabilized Neutral Oxoborane and Thioxoborane Supported by a Bis(oxazolinyl)(phenyl)methanide Ligand

    Ryo Nakano, Ryotaro Yamanashi, Makoto Yamashita

    Chemistry – A European Journal   29 ( 9 )   2022.12

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    Publishing type:Research paper (scientific journal)   Publisher:Wiley  

    Abstract

    Base‐stabilized neutral oxoborane and thioxoborane supported by a bis(oxazolinyl)(phenyl)methanide ligand have been synthesized and structurally characterized. While previous synthetic attempts of oxoborane ligated by β‐diketiminate (NacNac) did not allow for its isolation in acid‐free form, oxoborane supported by a bis(oxazolinyl)(phenyl)methanide ligand is isolable, due to the absence of imine ɑ‐protons and steric protection of enamine carbon. Crystallographic analysis revealed the presence of a B−O double bond close to the shortest end of the reported lengths. Its reactivity has also been examined, and it was majorly governed by the nucleophilicity and basicity of the oxygen atom. The chemical inertness and synthetic convenience of the bis(oxazolinyl)(phenyl)methanide scaffold presented in this work suggest its utility as an innocent alternative to the NacNac scaffold.

    DOI: 10.1002/chem.202203280

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    Other Link: https://onlinelibrary.wiley.com/doi/full-xml/10.1002/chem.202203280

  • Lipophilic N ‐Hydroxyimide Derivatives: Design, Synthesis, and Application to Aerobic Alkane Oxidation Under Neat Conditions

    Takaya Kaneiwa, Kaito Yamada, Ryo Nakano, Makoto Yamashita

    ChemPlusChem   88 ( 4 )   2022.12

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    Publishing type:Research paper (scientific journal)   Publisher:Wiley  

    DOI: 10.1002/cplu.202200380

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    Other Link: https://onlinelibrary.wiley.com/doi/full-xml/10.1002/cplu.202200380

  • Rhodium-Catalyzed Acrylate Synthesis from Carbon Dioxide and Ethylene by using a Guanidine-Based Pincer Ligand: Perturbing Occupied d-Orbitals by p pi-d pi Repulsion Makes a Difference

    Makoto Yamashita

    Chemistry - A European Journal   2022.10

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/CHEM.202201870

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  • Al-Sc Bonded Complexes: Synthesis, Structure, and Reaction with Benzene in the Presence of Alkyl Halide

    Makoto Yamashita

    Journal of the American Chemical Society   2022.9

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/JACS.2C09746

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  • Theoretical Insight into Catalysis of the Aluminabenzene-Iridium Complex for C(sp(3))-H Borylation of NEt3: How to Control alpha- and beta-Regioselectivities?

    Makoto Yamashita

    ACS Catalysis   4880 - 4897   2022.5

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/ACSCATAL.1C05792

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  • A Tetraorganyl-Alumaborane with An Al-B σ-Bond and Two Adjacent Lewis-Acidic Centers

    Makoto Yamashita

    Journal of the American Chemical Society   144 ( 10 )   4327 - 4332   2022.3

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/JACS.2C01580

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  • Isomerization of a cis‐(2‐Borylalkenyl)Gold Complex via a Retro‐1,2‐Metalate Shift: Cleavage of a C−C/C−Si Bond trans to a C−Au Bond

    Akane Suzuki, Linlin Wu, Zhenyang Lin, Makoto Yamashita

    Angewandte Chemie   2021.9

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/ange.202108530

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  • Synthesis and Reduction of a Cyclic (Alkyl)(amino)bromoborane to Generate a Thermally Labile Cyclic (Alkyl)(amino)boryl Anion

    Haruki Kisu, Tomoyuki Kosai, Takeaki Iwamoto, Makoto Yamashita

    Chemistry Letters   50 ( 2 )   293 - 296   2021.2

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    Publishing type:Research paper (scientific journal)   Publisher:The Chemical Society of Japan  

    DOI: 10.1246/cl.200749

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  • Nucleophilic reactivity of the gold atom in a diarylborylgold(i) complex toward polar multiple bonds

    Makoto Yamashita

    Chemical Science   12 ( 3 )   917 - 928   2021

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/D0SC05478J

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  • Mechanistic study on the reaction of pinB-BMes(2) with alkynes based on experimental investigation and DFT calculations: gradual change of mechanism depending on the substituent

    Makoto Yamashita

    Chemical Science   2021

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/D1SC02863D

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  • Characteristic Reactions of Nucleophilic Aluminum Anion

    Makoto Yamashita

    Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry   2021

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  • Electrophilic Substitution of Anionic Aluminabenzene via Sequential Reactions with Electrophile and Base

    Makoto Yamashita

    Organometallics   39 ( 23 )   4139 - 4142   2020.12

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/ACS.ORGANOMET.9B00796

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  • A meta‐Selective C−H Alumination of Mono‐Substituted Benzene by Using An Alkyl‐Substituted Al Anion through Hydride‐Eliminating SNAr Reaction

    Satoshi Kurumada, Kengo Sugita, Ryo Nakano, Makoto Yamashita

    Angewandte Chemie   2020.11

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    DOI: 10.1002/ange.202009138

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  • CNC-pincer iron complexes containing a bis(N-heterocyclic carbene) Amido ligand: Synthesis and application to catalytic hydrogenation of alkenes

    Taniguchi Wakano, Ito Jun-ichi, Yamashita Makoto

    JOURNAL OF ORGANOMETALLIC CHEMISTRY   923   2020.9

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    DOI: 10.1016/j.jorganchem.2020.121436

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  • Corrigendum to: A Potassium Diboryllithate: Synthesis, Bonding Properties, and the Deprotonation of Benzene (Angewandte Chemie International Edition, (2016), 55, 38, (11426-11430), 10.1002/anie.201605005)

    Takuto Ohsato, Yuri Okuno, Shintaro Ishida, Takeaki Iwamoto, Ka Ho Lee, Zhenyang Lin, Makoto Yamashita, Kyoko Nozaki

    Angewandte Chemie - International Edition   59 ( 32 )   13149   2020.8

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/anie.202009063

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  • One-Electron Reduction of Ti(IV) Complex by Dialkylaluminum(I) Anion Giving the Ti(III) Species

    Makoto Yamashita

    Organometallics   39 ( 11 )   2125 - 2129   2020.6

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    DOI: 10.1021/ACS.ORGANOMET.0C00177

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  • Formation of a Dinuclear Rh(I)(-)/Rh(I)(+) Complex Exhibiting MMCT Absorption from Dianionic Diborane(4) through C-H Bond Cleavage

    Akiyama Seiji, Yamashita Makoto

    CHEMISTRY LETTERS   49 ( 6 )   721-723 - 723   2020.6

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:The Chemical Society of Japan  

    DOI: 10.1246/cl.200182

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  • An Alumanylyttrium Complex with an Absorption due to a Transition from the Al-Y Bond to an Unoccupied d-Orbital

    Makoto Yamashita

    Chemistry - A European Journal   26 ( 20 )   4520 - 4523   2020.4

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    DOI: 10.1002/CHEM.202000752

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  • Copper Complexes Bearing a Dianionic Diborane(4) Ligand: Synthesis and Evaluation of the Donor Property

    Akiyama Seiji, Ikemoto Satoru, Muratsugu Satoshi, Tada Mizuki, Yamashita Makoto

    ORGANOMETALLICS   39 ( 4 )   500-504 - 504   2020.2

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/acs.organomet.0c00027

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  • Cycloaddition of Dialkylalumanyl Anion toward Unsaturated Hydrocarbons in (1+2) and (1+4) Modes

    Makoto Yamashita

    Chemistry - A European Journal   26 ( 10 )   2174 - 2177   2020.2

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    DOI: 10.1002/CHEM.201905830

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  • Formation of BCBH/BCBCl Four-Membered Rings by Complexation of Boron- and Nitrogen-Substituted Acetylene with Hydro-/Chloroboranes

    Makoto Yamashita

    Organometallics   39 ( 3 )   383 - 387   2020.2

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    DOI: 10.1021/ACS.ORGANOMET.9B00876

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  • An alkyl-substituted aluminium anion with strong basicity and nucleophilicity

    Makoto Yamashita

    Nature Chemistry   12 ( 1 )   36-39   2020.1

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    DOI: 10.1038/S41557-019-0365-Z

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  • Synthesis of A Pincer‐IrV Complex with A Base‐Free Alumanyl Ligand and Its Application toward the Dehydrogenation of Alkanes

    Shogo Morisako, Seiya Watanabe, Satoru Ikemoto, Satoshi Muratsugu, Mizuki Tada, Makoto Yamashita

    Angewandte Chemie   58 ( 42 )   15031-15035   2019.10

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    DOI: 10.1002/ange.201909009

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  • Reactivity of a Tetra(o-tolyl)diborane(4) Dianion as a Diarylboryl Anion Equivalent

    Akiyama Seiji, Yamada Kaito, Yamashita Makoto

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   58 ( 34 )   11806 - 11810   2019.7

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Wiley  

    DOI: 10.1002/anie.201907400

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    Other Link: https://onlinelibrary.wiley.com/doi/full-xml/10.1002/anie.201907400

  • 9-Aza-10-boraanthracene Stabilized by Coordination of an N-Heterocyclic Carbene and Its Methylated Cation: Synthesis, Structure, and Electronic Properties

    Makoto Yamashita

    Organometallics   38 ( 13 )   2597 - 2601   2019.7

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    DOI: 10.1021/ACS.ORGANOMET.9B00310

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  • A Monomeric Stannabenzene: Synthesis, Structure, and Electronic Properties

    Canon Kaiya, Katsunori Suzuki, Makoto Yamashita

    Angewandte Chemie - International Edition   58 ( 23 )   7749 - 7752   2019.6

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    DOI: 10.1002/anie.201902639

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  • A Monomeric Stannabenzene: Synthesis, Structure, and Electronic Properties

    Canon Kaiya, Katsunori Suzuki, Makoto Yamashita

    Angewandte Chemie   131 ( 23 )   7831 - 7834   2019.6

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    DOI: 10.1002/ange.201902639

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  • Synthesis of a hydrogen-bridged tetraborane(6): a substituent effect of a diaminoboryl group toward the B–B multiple bond character

    Atsumi Yagi, Haruki Kisu, Makoto Yamashita

    Dalton Transactions   48 ( 17 )   5496-5499   2019.5

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry ({RSC})  

    DOI: 10.1039/C9DT01117J

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  • Chlorine-Substituted 9,10-Dihydro-9-aza-10-boraanthracene as a Precursor for Various Boron- and Nitrogen-Containing pi-Conjugated Compounds

    Makoto Yamashita

    Organic Letters   21 ( 6 )   1722 - 1725   2019.3

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/ACS.ORGLETT.9B00278

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  • Chlorine-Substituted Germabenzene: Generation and Application as a Precursor for Aryl-Substituted Germabenzenes

    Makoto Yamashita

    Organometallics   38 ( 3 )   610 - 613   2019.2

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    DOI: 10.1021/ACS.ORGANOMET.8B00938

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  • Reactivity of Highly Lewis-Acidic Diborane(4) toward C equivalent to N and N=N Bonds: Uncatalyzed Addition and N=N Bond-Cleavage Reactions

    Katsuma Yuhei, Wu Linlin, Lin Zhenyang, Akiyama Seiji, Yamashita Makoto

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   58 ( 1 )   317-321 - 321   2019.1

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Wiley  

    DOI: 10.1002/anie.201812692

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  • Characteristic Reactivity of Highly Lewis-Acidic Aryl-Substituted Diborane(4) toward Multiple Bonds

    Yamashita Makoto

    JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN   76 ( 11 )   1223-1231   2018.11

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  • Planar and Bent BN-Embedded p-Quinodimethanes Synthesized by Transmetalation of Bis(trimethylsilyl)-1,4-dihydropyrazines with Chloroborane

    Noguchi, Mao, Suzuki, Katsunori, Kobayashi, Jun, Yurino, Taiga, Tsurugi, Hayato, Mashima, Kazushi, Yamashita, Makoto

    ORGANOMETALLICS   37 ( 12 )   1833 - 1836   2018.6

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    DOI: 10.1021/acs.organomet.8b00294

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  • Reaction of B2(o-tol)4 with CO and Isocyanides: Cleavage of the C≡O Triple Bond and Direct C−H Borylations

    Yuhei Katsuma, Nana Tsukahara, Linlin Wu, Zhenyang Lin, Makoto Yamashita

    Angewandte Chemie - International Edition   57 ( 21 )   6109 - 6114   2018.5

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Wiley-VCH Verlag  

    DOI: 10.1002/anie.201800878

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  • Synthesis and application of pyrrole-based PNP-Ir complexes to catalytic transfer dehydrogenation of cyclooctane

    Shin Nakayama, Shogo Morisako, Makoto Yamashita

    Organometallics   37 ( 8 )   1304 - 1313   2018.4

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society  

    DOI: 10.1021/acs.organomet.8b00072

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  • Dimerization of boryl- and amino-substituted acetylenes by B2C2 four-membered ring formation

    Ryo Kitamura, Katsunori Suzuki, Makoto Yamashita

    Chemical Communications   54 ( 46 )   5819 - 5822   2018

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry  

    DOI: 10.1039/c8cc02122h

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  • A zwitterionic aluminabenzene-alkylzirconium complex having half-zirconocene structure: Synthesis and application for additive-free ethylene polymerization

    Taichi Nakamura, Katsunori Suzuki, Makoto Yamashita

    Chemical Communications   54 ( 33 )   4180 - 4183   2018

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    DOI: 10.1039/c8cc02186d

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  • Reactivity of highly Lewis acidic diborane(4) towards pyridine and isocyanide: Formation of boraalkene-pyridine complex and: Ortho -functionalized pyridine derivatives

    Yuhei Katsuma, Hiroki Asakawa, Makoto Yamashita

    Chemical Science   9 ( 5 )   1301 - 1310   2018

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    DOI: 10.1039/c7sc04759b

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  • Aluminabenzene-Rh and -Ir Complexes: Synthesis, Structure, and Application toward Catalytic C-H Borylation

    Taichi Nakamura, Katsunori Suzuki, Makoto Yamashita

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   139 ( 49 )   17763 - 17766   2017.12

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    DOI: 10.1021/jacs.7b11127

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  • Anionic indabenzene: synthesis and characterization

    Taichi Nakamura, Katsunori Suzuki, Makoto Yamashita

    CHEMICAL COMMUNICATIONS   53 ( 99 )   13260 - 13263   2017.12

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    DOI: 10.1039/c7cc08397a

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  • A Highly Active PBP-Iridium Catalyst for the Dehydrogenation of Dimethylamine-Borane: Catalytic Performance and Mechanism

    Enrique Huang Kwan, Hayato Ogawa, Makoto Yamashita

    CHEMCATCHEM   9 ( 13 )   2457 - 2462   2017.7

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    DOI: 10.1002/cctc.201700384

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  • Two-electron Reduction of Diboryldiphosphene: Formation of Intramolecular Charge-transfer Complex of Dianionic B-=P-P=B- Species Reviewed

    Shun-suke Asami, Katsunori Suzuki, Makoto Yamashita

    CHEMISTRY LETTERS   46 ( 5 )   686 - 689   2017.5

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    DOI: 10.1246/cl.170106

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  • Isolation and Characterization of Radical Anions Derived from a Boryl-Substituted Diphosphene Reviewed

    Shun-suke Asami, Shintaro Ishida, Takeaki Iwamoto, Katsunori Suzuki, Makoto Yamashita

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   56 ( 6 )   1658 - 1662   2017.2

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    DOI: 10.1002/anie.201611762

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  • Cleaving Dihydrogen with Tetra(o-tolyl)diborane(4) Reviewed

    Nana Tsukahara, Hiroki Asakawa, Ka-Ho Lee, Zhenyang Lin, Makoto Yamashita

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   139 ( 7 )   2593 - 2596   2017.2

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    DOI: 10.1021/jacs.7b00924

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  • A Boryl-Substituted Diphosphene: Synthesis, Structure, and Reaction with n-Butyllithium To Form a Stabilized Adduct by p-p Interaction Reviewed

    Shun-suke Asami, Masafumi Okamoto, Katsunori Suzuki, Makoto Yamashita

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   55 ( 41 )   12827 - 12831   2016.10

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    DOI: 10.1002/anie.201607995

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  • An Isolable Bismabenzene: Synthesis, Structure, and Reactivity Reviewed

    Takuya Ishii, Katsunori Suzuki, Taichi Nakamura, Makoto Yamashita

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   138 ( 39 )   12787 - 12790   2016.10

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    DOI: 10.1021/jacs.6b08714

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  • A Potassium Diboryllithate: Synthesis, Bonding Properties, and the Deprotonation of Benzene

    Takuto Ohsato, Yuri Okuno, Shintaro Ishida, Takeaki Iwamoto, Ka‐Ho Lee, Zhenyang Lin, Makoto Yamashita, Kyoko Nozaki

    Angewandte Chemie   128 ( 38 )   11598 - 11602   2016.9

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    DOI: 10.1002/ange.201605005

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  • A Potassium Diboryllithate: Synthesis, Bonding Properties, and the Deprotonation of Benzene Reviewed

    Takuto Ohsato, Yuri Okuno, Shintaro Ishida, Takeaki Iwamoto, Ka-Ho Lee, Zhenyang Lin, Makoto Yamashita, Kyoko Nozaki

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   55 ( 38 )   11426 - 11430   2016.9

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    DOI: 10.1002/anie.201605005

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  • Ring Contraction of a Pinacolatoboryl Group To Form a 1,2-Oxaboretane Ring: Reaction of Unsymmetrical Diborane(4) with 2,6-Dimethylphenyl Isocyanide Reviewed

    Yuhei Katsuma, Hiroki Asakawa, Ka-Ho Lee, Zhenyang Lin, Makoto Yamashita

    ORGANOMETALLICS   35 ( 15 )   2563 - 2566   2016.8

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    DOI: 10.1021/acs.organomet.6b00468

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  • Direct and Base-Catalyzed Diboration of Alkynes Using the Unsymmetrical Diborane(4), pinB-BMes(2) Reviewed

    Chiemi Kojima, Ka-Ho Lee, Zhenyang Lin, Makoto Yamashita

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   138 ( 20 )   6662 - 6669   2016.5

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    DOI: 10.1021/jacs.6b03686

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  • The Organometallic Chemistry of Boron-Containing Pincer Ligands based on Diazaboroles and Carboranes Reviewed

    Makoto Yamashita

    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN   89 ( 3 )   269 - 281   2016.3

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    DOI: 10.1246/bcsj.20150355

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  • A Qualitative Analysis of a "Bora-Brook Rearrangement": The Ambident Reactivity of Boryl-Substituted Alkoxide Including the Carbon-to-Oxygen Migration of a Boryl Group Reviewed

    Haruki Kisu, Hirotoshi Sakaino, Fumihiro Ito, Makoto Yamashita, Kyoko Nozaki

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   138 ( 10 )   3548 - 3552   2016.3

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    DOI: 10.1021/jacs.6b00283

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  • A long-tethered (P-B-P)-pincer ligand: synthesis, complexation, and application to catalytic dehydrogenation of alkanes Reviewed

    Enrique Huang Kwan, Yasushi Jack Kawai, Sei Kamakura, Makoto Yamashita

    DALTON TRANSACTIONS   45 ( 40 )   15931 - 15941   2016

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    DOI: 10.1039/c6dt02075e

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  • Feasibility of thoracoscopic thymectomy for treatment of early‐stage thymoma

    Makoto Odaka, Takamasa Shibasaki, Hisatoshi Asano, Hideki Marushima, Makoto Yamashita, Toshiaki Morikawa

    Asian Journal of Endoscopic Surgery   2015.11

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    DOI: 10.1111/ases.12202

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  • Synthesis of Pincer Iridium Complexes Bearing a Boron Atom and Pr-i-Substituted Phosphorus Atoms: Application to Catalytic Transfer Dehydrogenation of Alkanes Reviewed

    Keita Tanoue, Makoto Yamashita

    ORGANOMETALLICS   34 ( 16 )   4011 - 4017   2015.8

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    DOI: 10.1021/acs.organomet.5b00376

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  • An Isolable Anionic Gallabenzene: Synthesis and Characterization Reviewed

    Taichi Nakamura, Katsunori Suzuki, Makoto Yamashita

    ORGANOMETALLICS   34 ( 10 )   1806 - 1808   2015.5

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    DOI: 10.1021/acs.organomet.5b00310

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  • Dimesitylboryl- and Amino-substituted Acetylene Having Butatriene-type Resonance Contribution Reviewed

    Kaoru Onuma, Katsunori Suzuki, Makoto Yamashita

    CHEMISTRY LETTERS   44 ( 3 )   405 - 407   2015.3

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    DOI: 10.1246/cl.141063

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  • Rhombic Cyclobutadiene with a Boryl/Amino-Substitution Pattern: Boryl Group Migration Induced by Reaction with Water Reviewed

    Kaoru Onuma, Katsunori Suzuki, Makoto Yamashita

    ORGANIC LETTERS   17 ( 5 )   1212 - 1215   2015.3

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    DOI: 10.1021/acs.orglett.5b00163

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  • Lowering the Reduction Potential of a Boron Compound by Means of the Substituent Effect of the Boryl Group: One-Electron Reduction of an Unsymmetrical Diborane(4) Reviewed

    Hiroki Asakawa, Ka-Ho Lee, Ko Furukawa, Zhenyang Lin, Makoto Yamashita

    CHEMISTRY-A EUROPEAN JOURNAL   21 ( 11 )   4267 - 4271   2015.3

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    DOI: 10.1002/chem.201406609

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  • Aluminabenzene-Zirconium Complexes: Intramolecular Coordination of Chloride to Aluminum Reviewed

    Taichi Nakamura, Katsunori Suzuki, Makoto Yamashita

    ORGANOMETALLICS   34 ( 5 )   813 - 816   2015.3

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    DOI: 10.1021/acs.organomet.5b00073

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  • Boryl Anions Reviewed

    Makoto Yamashita, Kyoko Nozaki

    SYNTHESIS AND APPLICATION OF ORGANOBORON COMPOUNDS   49   1 - 37   2015

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    DOI: 10.1007/978-3-319-13054-5_1

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  • Synthesis, Structure, and Bonding Properties of Ruthenium Complexes Possessing a Boron-Based PBP Pincer Ligand and Their Application for Catalytic Hydrogenation Reviewed

    Takuma Miyada, Enrique Huang Kwan, Makoto Yamashita

    ORGANOMETALLICS   33 ( 23 )   6760 - 6770   2014.12

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    DOI: 10.1021/om500585j

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  • An Anionic Aluminabenzene Bearing Aromatic and Ambiphilic Contributions Reviewed

    Taichi Nakamura, Katsunori Suzuki, Makoto Yamashita

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   136 ( 26 )   9276 - 9279   2014.7

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    DOI: 10.1021/ja504771d

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  • Facile scission of isonitrile carbon-nitrogen triple bond using a diborane(4) reagent Reviewed

    Hiroki Asakawa, Ka-Ho Lee, Zhenyang Lin, Makoto Yamashita

    NATURE COMMUNICATIONS   5   2014.6

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    DOI: 10.1038/ncomms5245

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  • Assessing the Bronsted Basicity of Diaminoboryl Anions: Reactivity toward Methylated Benzenes and Dihydrogen Reviewed

    Nicole Dettenrieder, Yoshitaka Aramaki, Benjamin M. Wolf, Caecilia Maichle-Moessmer, Xiaoxi Zhao, Makoto Yamashita, Kyoko Nozaki, Reiner Anwander

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   53 ( 24 )   6259 - 6262   2014.6

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    DOI: 10.1002/anie.201402175

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  • Trial for anti-Markovnikov Hydration of 1-Decene Using Platinum Complexes Bearing a PBP Pincer Ligand, Inducing Alkene Isomerization and Decomposition of PBP Ligand Reviewed

    Hayato Ogawa, Makoto Yamashita

    CHEMISTRY LETTERS   43 ( 5 )   664 - 666   2014.5

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    DOI: 10.1246/cl.131208

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  • Study on Photocatalytic Organic Reactions Using Photocatalytic Microreactors Reviewed

    Kento Shimaoka, Shota Kuwahara, Makoto Yamashita, Kenji Katayama

    ANALYTICAL SCIENCES   30 ( 5 )   619 - 621   2014.5

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  • Oxygenation of a ruthenium complex bearing a PBP-Pincer ligand inducing the formation of a boronato ligand with a weak Ru-O bond Reviewed

    Takuma Miyada, Makoto Yamashita

    Organometallics   32 ( 19 )   5281 - 5284   2013.10

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    DOI: 10.1021/om400915x

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  • Oxidative addition of a strained C-C bond onto electron-rich rhodium(I) at room temperature Reviewed

    Yusuke Masuda, Maki Hasegawa, Makoto Yamashita, Kyoko Nozaki, Naoki Ishida, Masahiro Murakami

    Journal of the American Chemical Society   135 ( 19 )   7142 - 7145   2013.5

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    DOI: 10.1021/ja403461f

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  • Preparation of Organic Light-Emitting Diode Using Coal Tar Pitch, a Low-Cost Material, for Printable Devices Reviewed

    Miki Yamaoka, Shun-suke Asami, Nayuta Funaki, Sho Kimura, Liao Yingjie, Takeshi Fukuda, Makoto Yamashita

    PLOS ONE   8 ( 5 )   2013.5

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    DOI: 10.1371/journal.pone.0062903

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  • Platinum complexes bearing a boron-based PBP pincer ligand: synthesis, structure, and application as a catalyst for hydrosilylation of 1-decene Reviewed

    Hayato Ogawa, Makoto Yamashita

    DALTON TRANSACTIONS   42 ( 3 )   625 - 629   2013

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    DOI: 10.1039/c2dt31892j

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  • Synthesis and Characterization of B-Heterocyclic pi-Radical and Its Reactivity as a Boryl Radical Reviewed

    Yoshitaka Aramaki, Hideki Orniya, Makoto Yamashita, Koji Nakabayashi, Shin-ichi Ohkoshi, Kyoko Nozaki

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   134 ( 49 )   19989 - 19992   2012.12

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  • Tandem Hydroformylation/Hydrogenation of Alkenes to Normal Alcohols Using Rh/Ru Dual Catalyst or Ru Single Component Catalyst Reviewed

    Kohei Takahashi, Makoto Yamashita, Kyoko Nozaki

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   134 ( 45 )   18746 - 18757   2012.11

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    DOI: 10.1021/ja307998h

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  • Syntheses and Thermolysis of Arylpalladium Hydroxide Complexes: Implications for C(sp(2))-OH Bond-Forming Reductive Elimination To Generate Phenol Derivatives Reviewed

    Yumi Hayashi, Shinji Wada, Makoto Yamashita, Kyoko Nozald

    ORGANOMETALLICS   31 ( 3 )   1073 - 1081   2012.2

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    DOI: 10.1021/om201142s

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  • Isolation of a PBP-Pincer Rhodium Complex Stabilized by an Intermolecular C?H s Coordination as the Fourth Ligand Reviewed

    Maki Hasegawa, Yasutomo Segawa, Makoto Yamashita, Kyoko Nozaki

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   51 ( 28 )   6956 - 6960   2012

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    DOI: 10.1002/anie.201201916

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  • Ruthenium/C5Me5/Bisphosphine- or Bisphosphite-Based Catalysts for normal-Selective Hydroformylation Reviewed

    Kohei Takahashi, Makoto Yamashita, Yoshiyuki Tanaka, Kyoko Nozaki

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   51 ( 18 )   4383 - 4387   2012

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    DOI: 10.1002/anie.201108396

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  • Mechanistic Studies on the Reversible Hydrogenation of Carbon Dioxide Catalyzed by an Ir-PNP Complex Reviewed

    Ryo Tanaka, Makoto Yamashita, Lung Wa Chung, Keiji Morokuma, Kyoko Nozaki

    ORGANOMETALLICS   30 ( 24 )   6742 - 6750   2011.12

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    DOI: 10.1021/om2010172

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  • Creation of Nucleophilic Boryl Anions and Their Properties Reviewed

    Makoto Yamashita

    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN   84 ( 10 )   983 - 999   2011.10

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    DOI: 10.1246/bcsj.20110123

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  • One-Pot Carboboration of Alkynes Using Lithium Borylcyanocuprate and the Subsequent Suzuki-Miyaura Cross-Coupling of the Resulting Tetrasubstituted Alkenylborane Reviewed

    Yuri Okuno, Makoto Yamashita, Kyoko Nozaki

    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY   ( 20-21 )   3951 - 3958   2011.7

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    DOI: 10.1002/ejoc.201100373

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  • A catalytic synthesis of dialkylamines from alkylamines using neopentyl-substituted PNP pincer-iridium complex Reviewed

    Makoto Yamashita, Yoshiki Moroe, Toshiyuki Yano, Kyoko Nozaki

    INORGANICA CHIMICA ACTA   369 ( 1 )   15 - 18   2011.4

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    DOI: 10.1016/j.ica.2010.08.034

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  • Syntheses and properties of triborane(5)s possessing bulky diamino substituents on terminal boron atoms Reviewed

    Yumi Hayashi, Yasutomo Segawa, Makoto Yamashita, Kyoko Nozaki

    CHEMICAL COMMUNICATIONS   47 ( 20 )   5888 - 5890   2011

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    DOI: 10.1039/c1cc11334h

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  • Borylcyanocuprate in a One-Pot Carboboration by a Sequential Reaction with an Electron-Deficient Alkyne and an Organic Carbon Electrophile Reviewed

    Yuri Okuno, Makoto Yamashita, Kyoko Nozaki

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   50 ( 4 )   920 - 923   2011

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    DOI: 10.1002/anie.201005667

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  • Boryltrihydroborate: Synthesis, Structure, and Reactivity as a Reductant in Ionic, Organometallic, and Radical Reactions Reviewed

    Kyoko Nozaki, Yoshitaka Aramaki, Makoto Yamashita, Shau-Hua Ueng, Max Malacria, Emmanuel Lacote, Dennis P. Curran

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   132 ( 33 )   11449 - 11451   2010.8

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    DOI: 10.1021/ja105277u

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  • Boryl anion: Syntheses and properties of novel borylmetals Reviewed

    Makoto Yamashita, Kyoko Nozaki

    Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry   68 ( 4 )   359 - 369   2010.4

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    DOI: 10.5059/yukigoseikyokaishi.68.359

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  • Reduction of base-stabilized difluoroboranes to induce rearrangement reactions Reviewed

    Makoto Yamashita, Yoshitaka Aramaki, Kyoko Nozaki

    NEW JOURNAL OF CHEMISTRY   34 ( 8 )   1774 - 1782   2010

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    DOI: 10.1039/c0nj00363h

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  • High-Yielding Tandem Hydroformylation/Hydrogenation of a Terminal Olefin to Produce a Linear Alcohol Using a Rh/Ru Dual Catalyst System Reviewed

    Kohei Takahashi, Makoto Yamashita, Takeo Ichihara, Koji Nakano, Kyoko Nozaki

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   49 ( 26 )   4488 - 4490   2010

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    DOI: 10.1002/anie.201001327

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  • Diphenylphosphino- or Dicyclohexylphosphino-Tethered Boryl Pincer Ligands: Syntheses of PBP Iridium(III) Complexes and Their Conversion to Iridium-Ethylene Complexes Reviewed

    Segawa Yasutomo, Yamashita Makoto, Nozaki Kyoko

    ORGANOMETALLICS   28 ( 21 )   6234-6242   2009.11

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    DOI: 10.1021/om9006455

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  • Catalytic Hydrogenation of Carbon Dioxide Using Ir(III)-Pincer Complexes Reviewed

    Ryo Tanaka, Makoto Yamashita, Kyoko Nozaki

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   131 ( 40 )   14168 - +   2009.10

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    DOI: 10.1021/ja903574e

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  • Group-4 Transition-Metal Boryl Complexes: Syntheses, Structures, Boron-Metal Bonding Properties, and Application as a Polymerization Catalyst Reviewed

    Tomomi Terabayashi, Takashi Kajiwara, Makoto Yamashita, Kyoko Nozaki

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   131 ( 40 )   14162 - +   2009.10

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    DOI: 10.1021/ja905950g

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  • Chemistry of boryllithium: Synthesis, structure, and reactivity (Journal of the American Chemical Society (2008) 130, (16069-16079))

    Yasutomo Segawa, Yuta Suzuki, Makoto Yamashita, Kyoko Nozaki

    Journal of the American Chemical Society   131   9600   2009.7

  • Syntheses of PBP Pincer Iridium Complexes: A Supporting Boryl Ligand Reviewed

    Yasutomo Segawa, Makoto Yamashita, Kyoko Nozaki

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   131 ( 26 )   9201 - +   2009.7

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    DOI: 10.1021/ja9037092

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  • Neopentyl-substituted PNP-pincer Ligand: Complexation with Iridium to Form an Iridacycle via Alkyl C-H Activation Reviewed

    Toshiyuki Yano, Yoshiki Moroe, Makoto Yamashita, Kyoko Nozaki

    CHEMISTRY LETTERS   37 ( 12 )   1300 - 1301   2008.12

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    DOI: 10.1246/cl.2008.1300

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  • Recent Developments of Boryl Anions: Boron Analogues of Carbanion Reviewed

    Makoto Yamashita, Kyoko Nozaki

    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN   81 ( 11 )   1377 - 1392   2008.11

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    DOI: 10.1246/bcsj.81.1377

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  • Chemistry of Boryllithium: Synthesis, Structure, and Reactivity Reviewed

    Yasutomo Segawa, Yuta Suzuki, Makoto Yamashita, Kyoko Nozaki

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   130 ( 47 )   16069 - 16079   2008.11

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    DOI: 10.1021/ja8057919

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  • Syntheses of Ester-Substituted Norbornyl Palladium Complexes Ligated with (Bu3P)-Bu-t: Studies on the Insertion of exo- and endo-Monomers in the Ester-Substituted Norbornene Polymerization Reviewed

    Ikuko Takamiya, Makoto Yamashita, Kyoko Nozaki

    ORGANOMETALLICS   27 ( 20 )   5347 - 5352   2008.10

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    DOI: 10.1021/om800566j

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  • Polymerization of norbornene with a pendent sulfonyl fluoride group catalyzed by palladium complex bearing (BU3P)-B-t ligand Reviewed

    Ikuko Takamiya, Makoto Yamashita, Eisuke Murotan, Yoshitomi Morizawa, Kyoko Nozaki

    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY   46 ( 15 )   5133 - 5141   2008.8

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    DOI: 10.1002/pola.22841

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  • Crystal structure of boryllithium with two THF molecules and DFT analysis of its property as a boryl anion Reviewed

    Makoto Yamashita, Yuta Suzuki, Yasutomo Segawa, Kyoko Nozaki

    CHEMISTRY LETTERS   37 ( 7 )   802 - 803   2008.7

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    DOI: 10.1246/cl.2008.802

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  • Boryllithium: A novel boron nucleophile and its application in the synthesis of borylmetal complexes Reviewed

    Makoto Yamashita, Kyoko Nozaki

    PURE AND APPLIED CHEMISTRY   80 ( 5 )   1187 - 1194   2008.5

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    DOI: 10.1351/pac200880051187

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  • Carbonylative polymerization of oxetanes initiated by acetyl cobalt complexes Reviewed

    Yessi Permana, Koji Nakano, Makoto Yamashita, Daisuke Watanabe, Kyoko Nozaki

    CHEMISTRY-AN ASIAN JOURNAL   3 ( 4 )   710 - 718   2008

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    DOI: 10.1002/asia.200700339

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  • Syntheses, structures, and reactivities of borylcopper and -zinc compounds: 1,4-silaboration of an alpha,beta-unsaturated ketone to form a gamma-siloxyallylborane Reviewed

    Takashi Kajiwara, Tomomi Terabayashi, Makoto Yamashita, Kyoko Nozaki

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   47 ( 35 )   6606 - 6610   2008

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    DOI: 10.1002/anie.200801728

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  • Synthesis, structure of borylmagnesium, and its reaction with benzaldehyde to form benzoylborane Reviewed

    Makoto Yamashita, Yuta Suzuki, Yasutomo Segawa, Kyoko Nozaki

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   129 ( 31 )   9570 - +   2007.8

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    DOI: 10.1021/ja073037t

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  • Boryl anion attacks transition-metal chlorides to form boryl complexes: Syntheses, spectroscopic, and structural studies on group 11 borylmetal complexes Reviewed

    Segawa Yasutomo, Yamashita Makoto, Nozaki Kyoko

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   46 ( 35 )   6710-6713   2007

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    DOI: 10.1002/anie.200702369

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  • Boryllithium: Isolation, characterization, and reactivity as a boryl anion Reviewed

    Yasutomo Segawa, Makoto Yamashita, Kyoko Nozaki

    Science   314 ( 5796 )   113 - 115   2006.10

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    DOI: 10.1126/science.1131914

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  • Syntheses and structures of bulky monophosphine-ligated methylpalladium complexes: Application to homo- and copolymerization of norbornene and/or methoxycarbonylnorbornene Reviewed

    Makoto Yamashita, Ikuko Takamiya, Koichiro Jin, Kyoko Nozaki

    ORGANOMETALLICS   25 ( 19 )   4588 - 4595   2006.9

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    DOI: 10.1021/om060347w

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  • Organometallic chemistry of amidate complexes. Accelerating effect of bidentate ligands on the reductive elimination of N-aryl amidates from palladium(II) Reviewed

    Ken-ichi Fujita, Makoto Yamashita, Florian Puschmann, Miguel Martinez Alvarez-Falcon, Christopher D. Incarvito, John F. Hartwig

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   128 ( 28 )   9044 - 9045   2006.7

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    DOI: 10.1021/ja062333n

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  • Syntheses and characterizations of methylpalladium complexes bearing a biphenyl-based bulky phosphine ligand: Weak interactions suggested by NBO and QTAIM analyses Reviewed

    Makoto Yamashita, Ikuko Takamiya, Koichiro Jin, Kyoko Nozaki

    JOURNAL OF ORGANOMETALLIC CHEMISTRY   691 ( 14 )   3189 - 3195   2006.7

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    DOI: 10.1016/j.jorganchem.2006.02.001

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  • Immobilization of Catalysts for Hydroformylation

    YAMASHITA Makoto, NOZAKI Kyoko

    Kobunshi   55 ( 5 )   348 - 351   2006.5

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    Language:Japanese   Publisher:The Society of Polymer Science, Japan  

    DOI: 10.1295/kobunshi.55.348

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    Other Link: https://jlc.jst.go.jp/DN/JALC/00278207453?from=CiNii

  • Alternating copolymerization of fluoroalkenes with carbon monoxide Reviewed

    T Fujita, K Nakano, M Yamashita, K Nozaki

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   128 ( 6 )   1968 - 1975   2006.2

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    DOI: 10.1021/ja055862k

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  • Synthesis and structure of a germylene bearing a 1,8-dimethoxyanthracene ligand Reviewed

    M Yamashita, H Murakami, T Unrin-In, A Kawachi, K Akiba, Y Yamamoto

    CHEMISTRY LETTERS   34 ( 5 )   690 - 691   2005.5

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    DOI: 10.1246/cl.2005.690

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  • Extended hypervalent 5c-6e interactions: Linear alignment of five C-Z---O---Z-C (Z = S, Se) atoms in anthraquinone and anthracene systems Reviewed

    W Nakanishi, S Hayashi, T Furuta, N Itoh, Y Nishina, M Yamashita, Y Yamamoto

    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS   180 ( 5-6 )   1351 - 1355   2005.5

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    DOI: 10.1080/10426500590912321

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  • Fixation of both O-2 and CO2 from air by a crystalline palladium complex bearing N-heterocyclic carbene ligands Reviewed

    M Yamashita, K Goto, T Kawashima

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   127 ( 20 )   7294 - 7295   2005.5

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    DOI: 10.1021/ja051054h

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  • Syntheses and structures of hypervalent pentacoordinate carbon and boron compounds bearing an anthracene skeleton - Elucidation of hypervalent interaction based on X-ray analysis and DFT calculation Reviewed

    M Yamashita, Y Yamamoto, KY Akiba, D Hashizume, F Iwasaki, N Takagi, S Nagase

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   127 ( 12 )   4354 - 4371   2005.3

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  • An efficient Pd(II)-based catalyst system for carboxylation of aromatic C-H bond by addition of a phosphenium salt Reviewed

    K Sakakibara, M Yamashita, K Nozaki

    TETRAHEDRON LETTERS   46 ( 6 )   959 - 962   2005.2

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    DOI: 10.1016/j.tetlets.2004.12.027

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  • Synthesis, structure, and reductive elimination chemistry of three-coordinate arylpalladium amido complexes Reviewed

    M Yamashita, JF Hartwig

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   126 ( 17 )   5344 - 5345   2004.5

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    DOI: 10.1021/ja0315107

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  • Trans influence on the rate of reductive elimination. Reductive elimination of amines from isomeric arylpalladium amides with unsymmetrical coordination spheres Reviewed

    M Yamashita, JVC Vicario, JF Hartwig

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   125 ( 52 )   16347 - 16360   2003.12

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    DOI: 10.1021/ja037425g

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  • Synthesis of a new potential tridentate anthracene ligand bearing deprotectable methoxymethoxy (OMOM) group at 1,8-positions: Attempt to synthesize anionic hypervalent carbon compounds Reviewed

    M Yamashita, Y Mita, Y Yamamoto, KY Akiba

    CHEMISTRY-A EUROPEAN JOURNAL   9 ( 15 )   3655 - 3659   2003.8

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    DOI: 10.1002/chem.200204354

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  • Synthesis and application of new tridentate anthracene ligands bearing donative phosphorus(III) atoms at 1,8-positions Reviewed

    K Watanabe, M Yamashita, Y Yamamoto, K Akiba

    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS   177 ( 8-9 )   2047 - 2048   2002.8

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    DOI: 10.1080/10426500290094341

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  • Synthesis of a novel potential tridentate anthracene ligand, 1,8-bis(dimethylamino)-9-bromoanthracene, and its application as chelate ligand for synthesis of the corresponding boron and palladium compounds Reviewed

    M Yamashita, K Kamura, Y Yamamoto, K Akiba

    CHEMISTRY-A EUROPEAN JOURNAL   8 ( 13 )   2976 - 2979   2002.7

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  • Synthesis of a new tridentate anthracene ligand bearing (i-Pr)2P group at 1,8-positions: Facile bond switch on tetracoordinate boron atom Reviewed

    Makoto Yamashita, Kentaro Watanabe, Yohsuke Yamamoto, Kin-ya Akiba

    Chemistry Letters   ( 11 )   1104 - 1105   2001

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    DOI: 10.1246/cl.2001.1104

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  • Synthesis of a versatile tridentate anthracene ligand and its application for the synthesis of hypervalent pentacoordinate boron compounds (10-B-5) Reviewed

    M Yamashita, Y Yamamoto, K Akiba, S Nagase

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   39 ( 22 )   4055 - 4058   2000

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  • Synthesis and isolation of stable hypervalent carbon compound (10-C-5) bearing a 1,8-dimethoxyanthracene ligand Reviewed

    K Akiba, M Yamashita, Y Yamamoto, S Nagase

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   121 ( 45 )   10644 - 10645   1999.11

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▼display all

Books

  • Boryl Anions In Synthesis and Application of Organoboron Compounds

    Yamashita, M, Nozaki, K( Role: Contributor)

    Springer International Publishing  2015.1 

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  • Hydroformylation, Other Hydrocarbonylations, and Oxidative Alkoxycarbonylation In Comprehensive Organometallic Chemistry III

    Yamashita, M, Nozaki, K( Role: Contributor)

    Elsevier  2006.12  ( ISBN:008044590X

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    Responsible for pages:435-471   Language:Japanese   Book type:Dictionary, encyclopedia

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MISC

  • Planar and Bent BN-Embedded p-Quinodimethanes Synthesized by Transmetalation of Bis(trimethylsilyl)-1,4-dihydropyrazines with Chloroborane

    Noguchi, Mao, Suzuki, Katsunori, Kobayashi, Jun, Yurino, Taiga, Tsurugi, Hayato, Mashima, Kazushi, Yamashita, Makoto

    ORGANOMETALLICS   37 ( 12 )   1833 - 1836   2018.6

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    DOI: 10.1021/acs.organomet.8b00294

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  • Reaction of B2(o-tol)4 with CO and Isocyanides: Cleavage of the C≡O Triple Bond and Direct C−H Borylations

    Yuhei Katsuma, Nana Tsukahara, Linlin Wu, Zhenyang Lin, Makoto Yamashita

    Angewandte Chemie - International Edition   57 ( 21 )   6109 - 6114   2018.5

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    Language:English   Publishing type:Rapid communication, short report, research note, etc. (scientific journal)   Publisher:Wiley-VCH Verlag  

    DOI: 10.1002/anie.201800878

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  • Synthesis and application of pyrrole-based PNP-Ir complexes to catalytic transfer dehydrogenation of cyclooctane

    Shin Nakayama, Shogo Morisako, Makoto Yamashita

    Organometallics   37 ( 8 )   1304 - 1313   2018.4

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    DOI: 10.1021/acs.organomet.8b00072

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  • Dimerization of boryl- and amino-substituted acetylenes by B2C2 four-membered ring formation

    Ryo Kitamura, Katsunori Suzuki, Makoto Yamashita

    Chemical Communications   54 ( 46 )   5819 - 5822   2018

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    DOI: 10.1039/c8cc02122h

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  • A zwitterionic aluminabenzene-alkylzirconium complex having half-zirconocene structure: Synthesis and application for additive-free ethylene polymerization

    Taichi Nakamura, Katsunori Suzuki, Makoto Yamashita

    Chemical Communications   54 ( 33 )   4180 - 4183   2018

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    DOI: 10.1039/c8cc02186d

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  • Reactivity of highly Lewis acidic diborane(4) towards pyridine and isocyanide: Formation of boraalkene-pyridine complex and: Ortho -functionalized pyridine derivatives

    Yuhei Katsuma, Hiroki Asakawa, Makoto Yamashita

    Chemical Science   9 ( 5 )   1301 - 1310   2018

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    DOI: 10.1039/c7sc04759b

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  • Aluminabenzene-Rh and -Ir Complexes: Synthesis, Structure, and Application toward Catalytic C-H Borylation

    Taichi Nakamura, Katsunori Suzuki, Makoto Yamashita

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   139 ( 49 )   17763 - 17766   2017.12

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    DOI: 10.1021/jacs.7b11127

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  • A Highly Active PBP-Iridium Catalyst for the Dehydrogenation of Dimethylamine-Borane: Catalytic Performance and Mechanism

    Enrique Huang Kwan, Hayato Ogawa, Makoto Yamashita

    CHEMCATCHEM   9 ( 13 )   2457 - 2462   2017.7

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    DOI: 10.1002/cctc.201700384

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  • Two-electron Reduction of Diboryldiphosphene: Formation of Intramolecular Charge-transfer Complex of Dianionic B-=P-P=B- Species Reviewed

    Asami Shun-suke, Suzuki Katsunori, Yamashita Makoto

    CHEMISTRY LETTERS   46 ( 5 )   686-689   2017.5

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    DOI: 10.1246/cl.170106

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  • Isolation and Characterization of Radical Anions Derived from a Boryl‐Substituted Diphosphene Reviewed

    Shun‐suke Asami, Shintaro Ishida, Takeaki Iwamoto, Katsunori Suzuki, Makoto Yamashita

    Angewandte Chemie   56 ( 6 )   1658-1662   2017.2

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    DOI: 10.1002/ange.201611762

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  • Cleaving Dihydrogen with Tetra(o-tolyl)diborane(4) Reviewed

    Nana Tsukahara, Hiroki Asakawa, Ka-Ho Lee, Zhenyang Lin, Makoto Yamashita

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   139 ( 7 )   2593 - 2596   2017.2

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    DOI: 10.1021/jacs.7b00924

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  • Anionic indabenzene: Synthesis and characterization

    Taichi Nakamura, Katsunori Suzuki, Makoto Yamashita

    Chemical Communications   53 ( 99 )   13260 - 13263   2017

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    DOI: 10.1039/c7cc08397a

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  • A Boryl-Substituted Diphosphene: Synthesis, Structure, and Reaction with n-Butyllithium To Form a Stabilized Adduct by p-p Interaction Reviewed

    Shun-suke Asami, Masafumi Okamoto, Katsunori Suzuki, Makoto Yamashita

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   55 ( 41 )   12827 - 12831   2016.10

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    DOI: 10.1002/anie.201607995

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  • An Isolable Bismabenzene: Synthesis, Structure, and Reactivity Reviewed

    Takuya Ishii, Katsunori Suzuki, Taichi Nakamura, Makoto Yamashita

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   138 ( 39 )   12787 - 12790   2016.10

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    DOI: 10.1021/jacs.6b08714

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  • A Potassium Diboryllithate: Synthesis, Bonding Properties, and the Deprotonation of Benzene Reviewed

    Takuto Ohsato, Yuri Okuno, Shintaro Ishida, Takeaki Iwamoto, Ka-Ho Lee, Zhenyang Lin, Makoto Yamashita, Kyoko Nozaki

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   55 ( 38 )   11426 - 11430   2016.9

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    DOI: 10.1002/anie.201605005

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  • Ring Contraction of a Pinacolatoboryl Group To Form a 1,2-Oxaboretane Ring: Reaction of Unsymmetrical Diborane(4) with 2,6-Dimethylphenyl Isocyanide Reviewed

    Yuhei Katsuma, Hiroki Asakawa, Ka-Ho Lee, Zhenyang Lin, Makoto Yamashita

    ORGANOMETALLICS   35 ( 15 )   2563 - 2566   2016.8

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    DOI: 10.1021/acs.organomet.6b00468

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  • Direct and Base-Catalyzed Diboration of Alkynes Using the Unsymmetrical Diborane(4), pinB-BMes(2) Reviewed

    Chiemi Kojima, Ka-Ho Lee, Zhenyang Lin, Makoto Yamashita

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   138 ( 20 )   6662 - 6669   2016.5

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    DOI: 10.1021/jacs.6b03686

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  • The Organometallic Chemistry of Boron-Containing Pincer Ligands based on Diazaboroles and Carboranes Reviewed

    Yamashita Makoto

    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN   89 ( 3 )   269-281   2016.3

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    DOI: 10.1246/bcsj.20150355

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  • A Qualitative Analysis of a "Bora-Brook Rearrangement": The Ambident Reactivity of Boryl-Substituted Alkoxide Including the Carbon-to-Oxygen Migration of a Boryl Group Reviewed

    Haruki Kisu, Hirotoshi Sakaino, Fumihiro Ito, Makoto Yamashita, Kyoko Nozaki

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   138 ( 10 )   3548 - 3552   2016.3

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    DOI: 10.1021/jacs.6b00283

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  • A long-tethered (P-B-P)-pincer ligand: synthesis, complexation, and application to catalytic dehydrogenation of alkanes Reviewed

    Enrique Huang Kwan, Yasushi Jack Kawai, Sei Kamakura, Makoto Yamashita

    DALTON TRANSACTIONS   45 ( 40 )   15931 - 15941   2016

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    DOI: 10.1039/c6dt02075e

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  • Synthesis of Pincer Iridium Complexes Bearing a Boron Atom and Pr-i-Substituted Phosphorus Atoms: Application to Catalytic Transfer Dehydrogenation of Alkanes Reviewed

    Keita Tanoue, Makoto Yamashita

    ORGANOMETALLICS   34 ( 16 )   4011 - 4017   2015.8

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    DOI: 10.1021/acs.organomet.5b00376

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  • An isolable anionic gallabenzene: Synthesis and characterization Reviewed

    Taichi Nakamura, Katsunori Suzuki, Makoto Yamashita

    Organometallics   34 ( 10 )   1806 - 1808   2015.5

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    DOI: 10.1021/acs.organomet.5b00310

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  • Lowering the Reduction Potential of a Boron Compound by Means of the Substituent Effect of the Boryl Group: One-Electron Reduction of an Unsymmetrical Diborane(4) Reviewed

    Hiroki Asakawa, Ka-Ho Lee, Ko Furukawa, Zhenyang Lin, Makoto Yamashita

    CHEMISTRY-A EUROPEAN JOURNAL   21 ( 11 )   4267 - 4271   2015.3

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    DOI: 10.1002/chem.201406609

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  • Dimesitylboryl- and Amino-substituted Acetylene Having Butatriene-type Resonance Contribution Reviewed

    Kaoru Onuma, Katsunori Suzuki, Makoto Yamashita

    CHEMISTRY LETTERS   44 ( 3 )   405 - 407   2015.3

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    DOI: 10.1246/cl.141063

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  • Aluminabenzene-Zirconium Complexes: Intramolecular Coordination of Chloride to Aluminum Reviewed

    Taichi Nakamura, Katsunori Suzuki, Makoto Yamashita

    ORGANOMETALLICS   34 ( 5 )   813 - 816   2015.3

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    DOI: 10.1021/acs.organomet.5b00073

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  • Rhombic Cyclobutadiene with a Boryl/Amino-Substitution Pattern: Boryl Group Migration Induced by Reaction with Water Reviewed

    Kaoru Onuma, Katsunori Suzuki, Makoto Yamashita

    ORGANIC LETTERS   17 ( 5 )   1212 - 1215   2015.3

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    DOI: 10.1021/acs.orglett.5b00163

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  • Boryl Anions Reviewed

    Makoto Yamashita, Kyoko Nozaki

    SYNTHESIS AND APPLICATION OF ORGANOBORON COMPOUNDS   49   1 - 37   2015

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    DOI: 10.1007/978-3-319-13054-5_1

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  • Synthesis, Structure, and Bonding Properties of Ruthenium Complexes Possessing a Boron-Based PBP Pincer Ligand and Their Application for Catalytic Hydrogenation Reviewed

    Takuma Miyada, Enrique Huang Kwan, Makoto Yamashita

    ORGANOMETALLICS   33 ( 23 )   6760 - 6770   2014.12

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    DOI: 10.1021/om500585j

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  • An anionic aluminabenzene bearing aromatic and ambiphilic contributions Reviewed

    Taichi Nakamura, Katsunori Suzuki, Makoto Yamashita

    Journal of the American Chemical Society   136 ( 26 )   9276 - 9279   2014.7

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    DOI: 10.1021/ja504771d

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  • Assessing the Bronsted Basicity of Diaminoboryl Anions: Reactivity toward Methylated Benzenes and Dihydrogen Reviewed

    Nicole Dettenrieder, Yoshitaka Aramaki, Benjamin M. Wolf, Caecilia Maichle-Moessmer, Xiaoxi Zhao, Makoto Yamashita, Kyoko Nozaki, Reiner Anwander

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   53 ( 24 )   6259 - 6262   2014.6

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    DOI: 10.1002/anie.201402175

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  • Facile scission of isonitrile carbon-nitrogen triple bond using a diborane(4) reagent Reviewed

    Hiroki Asakawa, Ka-Ho Lee, Zhenyang Lin, Makoto Yamashita

    NATURE COMMUNICATIONS   5   2014.6

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    DOI: 10.1038/ncomms5245

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  • Study on Photocatalytic Organic Reactions Using Photocatalytic Microreactors Reviewed

    Kento Shimaoka, Shota Kuwahara, Makoto Yamashita, Kenji Katayama

    ANALYTICAL SCIENCES   30 ( 5 )   619 - 621   2014.5

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  • Trial for anti-Markovnikov Hydration of 1-Decene Using Platinum Complexes Bearing a PBP Pincer Ligand, Inducing Alkene Isomerization and Decomposition of PBP Ligand Reviewed

    Hayato Ogawa, Makoto Yamashita

    CHEMISTRY LETTERS   43 ( 5 )   664 - 666   2014.5

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    DOI: 10.1246/cl.131208

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  • Oxygenation of a ruthenium complex bearing a PBP-Pincer ligand inducing the formation of a boronato ligand with a weak Ru-O bond Reviewed

    Takuma Miyada, Makoto Yamashita

    Organometallics   32 ( 19 )   5281 - 5284   2013.10

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    DOI: 10.1021/om400915x

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  • Oxidative addition of a strained C-C bond onto electron-rich rhodium(I) at room temperature Reviewed

    Yusuke Masuda, Maki Hasegawa, Makoto Yamashita, Kyoko Nozaki, Naoki Ishida, Masahiro Murakami

    Journal of the American Chemical Society   135 ( 19 )   7142 - 7145   2013.5

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    DOI: 10.1021/ja403461f

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  • Preparation of Organic Light-Emitting Diode Using Coal Tar Pitch, a Low-Cost Material, for Printable Devices Reviewed

    Miki Yamaoka, Shun-suke Asami, Nayuta Funaki, Sho Kimura, Liao Yingjie, Takeshi Fukuda, Makoto Yamashita

    PLOS ONE   8 ( 5 )   2013.5

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    DOI: 10.1371/journal.pone.0062903

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  • Platinum complexes bearing a boron-based PBP pincer ligand: synthesis, structure, and application as a catalyst for hydrosilylation of 1-decene Reviewed

    Hayato Ogawa, Makoto Yamashita

    DALTON TRANSACTIONS   42 ( 3 )   625 - 629   2013

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    DOI: 10.1039/c2dt31892j

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  • Synthesis and Characterization of B-Heterocyclic pi-Radical and Its Reactivity as a Boryl Radical Reviewed

    Yoshitaka Aramaki, Hideki Orniya, Makoto Yamashita, Koji Nakabayashi, Shin-ichi Ohkoshi, Kyoko Nozaki

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   134 ( 49 )   19989 - 19992   2012.12

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    DOI: 10.1021/ja3094372

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  • Tandem hydroformylation/hydrogenation of alkenes to normal alcohols using Rh/Ru dual catalyst or Ru single component catalyst Reviewed

    Kohei Takahashi, Makoto Yamashita, Kyoko Nozaki

    Journal of the American Chemical Society   134 ( 45 )   18746 - 18757   2012.11

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    DOI: 10.1021/ja307998h

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  • Syntheses and Thermolysis of Arylpalladium Hydroxide Complexes: Implications for C(sp(2))-OH Bond-Forming Reductive Elimination To Generate Phenol Derivatives Reviewed

    Yumi Hayashi, Shinji Wada, Makoto Yamashita, Kyoko Nozald

    ORGANOMETALLICS   31 ( 3 )   1073 - 1081   2012.2

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    DOI: 10.1021/om201142s

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  • Ruthenium/C5Me5/Bisphosphine- or Bisphosphite-Based Catalysts for normal-Selective Hydroformylation Reviewed

    Kohei Takahashi, Makoto Yamashita, Yoshiyuki Tanaka, Kyoko Nozaki

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   51 ( 18 )   4383 - 4387   2012

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    DOI: 10.1002/anie.201108396

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  • Isolation of a PBP-Pincer Rhodium Complex Stabilized by an Intermolecular C?H s Coordination as the Fourth Ligand Reviewed

    Maki Hasegawa, Yasutomo Segawa, Makoto Yamashita, Kyoko Nozaki

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   51 ( 28 )   6956 - 6960   2012

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    DOI: 10.1002/anie.201201916

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  • Mechanistic Studies on the Reversible Hydrogenation of Carbon Dioxide Catalyzed by an Ir-PNP Complex Reviewed

    Ryo Tanaka, Makoto Yamashita, Lung Wa Chung, Keiji Morokuma, Kyoko Nozaki

    ORGANOMETALLICS   30 ( 24 )   6742 - 6750   2011.12

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    DOI: 10.1021/om2010172

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  • Creation of Nucleophilic Boryl Anions and Their Properties Reviewed

    Yamashita Makoto

    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN   84 ( 10 )   983-999 - 999   2011.10

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    DOI: 10.1246/bcsj.20110123

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  • One-Pot Carboboration of Alkynes Using Lithium Borylcyanocuprate and the Subsequent Suzuki-Miyaura Cross-Coupling of the Resulting Tetrasubstituted Alkenylborane Reviewed

    Yuri Okuno, Makoto Yamashita, Kyoko Nozaki

    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY   ( 20-21 )   3951 - 3958   2011.7

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    DOI: 10.1002/ejoc.201100373

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  • A catalytic synthesis of dialkylamines from alkylamines using neopentyl-substituted PNP pincer-iridium complex Reviewed

    Makoto Yamashita, Yoshiki Moroe, Toshiyuki Yano, Kyoko Nozaki

    INORGANICA CHIMICA ACTA   369 ( 1 )   15 - 18   2011.4

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    DOI: 10.1016/j.ica.2010.08.034

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  • Syntheses and properties of triborane(5)s possessing bulky diamino substituents on terminal boron atoms Reviewed

    Yumi Hayashi, Yasutomo Segawa, Makoto Yamashita, Kyoko Nozaki

    CHEMICAL COMMUNICATIONS   47 ( 20 )   5888 - 5890   2011

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    DOI: 10.1039/c1cc11334h

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  • Borylcyanocuprate in a One-Pot Carboboration by a Sequential Reaction with an Electron-Deficient Alkyne and an Organic Carbon Electrophile Reviewed

    Yuri Okuno, Makoto Yamashita, Kyoko Nozaki

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   50 ( 4 )   920 - 923   2011

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    DOI: 10.1002/anie.201005667

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  • Boryltrihydroborate: Synthesis, Structure, and Reactivity as a Reductant in Ionic, Organometallic, and Radical Reactions Reviewed

    Kyoko Nozaki, Yoshitaka Aramaki, Makoto Yamashita, Shau-Hua Ueng, Max Malacria, Emmanuel Lacote, Dennis P. Curran

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   132 ( 33 )   11449 - 11451   2010.8

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    DOI: 10.1021/ja105277u

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  • Boryl Anion: Syntheses and Properties of Novel Borylmetals Reviewed

    Makoto Yamashita, Kyoko Nozaki

    JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN   68 ( 4 )   359 - 369   2010.4

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  • High-Yielding Tandem Hydroformylation/Hydrogenation of a Terminal Olefin to Produce a Linear Alcohol Using a Rh/Ru Dual Catalyst System Reviewed

    Kohei Takahashi, Makoto Yamashita, Takeo Ichihara, Koji Nakano, Kyoko Nozaki

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   49 ( 26 )   4488 - 4490   2010

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    DOI: 10.1002/anie.201001327

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  • Reduction of base-stabilized difluoroboranes to induce rearrangement reactions Reviewed

    Makoto Yamashita, Yoshitaka Aramaki, Kyoko Nozaki

    NEW JOURNAL OF CHEMISTRY   34 ( 8 )   1774 - 1782   2010

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    DOI: 10.1039/c0nj00363h

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  • Diphenylphosphino- or Dicyclohexylphosphino-Tethered Boryl Pincer Ligands: Syntheses of PBP Iridium(III) Complexes and Their Conversion to Iridium-Ethylene Complexes Reviewed

    Yasutomo Segawa, Makoto Yamashita, Kyoko Nozaki

    ORGANOMETALLICS   28 ( 21 )   6234 - 6242   2009.11

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    DOI: 10.1021/om9006455

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  • Catalytic Hydrogenation of Carbon Dioxide Using Ir(III)-Pincer Complexes Reviewed

    Tanaka Ryo, Yamashita Makoto, Nozaki Kyoko

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   131 ( 40 )   14168-+   2009.10

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    DOI: 10.1021/ja903574e

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  • Group-4 Transition-Metal Boryl Complexes: Syntheses, Structures, Boron-Metal Bonding Properties, and Application as a Polymerization Catalyst Reviewed

    Tomomi Terabayashi, Takashi Kajiwara, Makoto Yamashita, Kyoko Nozaki

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   131 ( 40 )   14162 - +   2009.10

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    DOI: 10.1021/ja905950g

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  • Syntheses of PBP Pincer Iridium Complexes: A Supporting Boryl Ligand Reviewed

    Yasutomo Segawa, Makoto Yamashita, Kyoko Nozaki

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   131 ( 26 )   9201 - +   2009.7

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    DOI: 10.1021/ja9037092

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  • Neopentyl-substituted PNP-pincer Ligand: Complexation with Iridium to Form an Iridacycle via Alkyl C-H Activation Reviewed

    Toshiyuki Yano, Yoshiki Moroe, Makoto Yamashita, Kyoko Nozaki

    CHEMISTRY LETTERS   37 ( 12 )   1300 - 1301   2008.12

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    DOI: 10.1246/cl.2008.1300

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  • Recent Developments of Boryl Anions: Boron Analogues of Carbanion Reviewed

    Yamashita Makoto, Nozaki Kyoko

    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN   81 ( 11 )   1377-1392   2008.11

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    DOI: 10.1246/bcsj.81.1377

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  • Chemistry of Boryllithium: Synthesis, Structure, and Reactivity Reviewed

    Yasutomo Segawa, Yuta Suzuki, Makoto Yamashita, Kyoko Nozaki

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   130 ( 47 )   16069 - 16079   2008.11

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    DOI: 10.1021/ja8057919

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  • Syntheses of Ester-Substituted Norbornyl Palladium Complexes Ligated with (Bu3P)-Bu-t: Studies on the Insertion of exo- and endo-Monomers in the Ester-Substituted Norbornene Polymerization Reviewed

    Ikuko Takamiya, Makoto Yamashita, Kyoko Nozaki

    ORGANOMETALLICS   27 ( 20 )   5347 - 5352   2008.10

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    DOI: 10.1021/om800566j

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  • Polymerization of norbornene with a pendent sulfonyl fluoride group catalyzed by palladium complex bearing (BU3P)-B-t ligand Reviewed

    Ikuko Takamiya, Makoto Yamashita, Eisuke Murotan, Yoshitomi Morizawa, Kyoko Nozaki

    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY   46 ( 15 )   5133 - 5141   2008.8

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    DOI: 10.1002/pola.22841

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  • Crystal structure of boryllithium with two THF molecules and DFT analysis of its property as a boryl anion Reviewed

    Makoto Yamashita, Yuta Suzuki, Yasutomo Segawa, Kyoko Nozaki

    CHEMISTRY LETTERS   37 ( 7 )   802 - 803   2008.7

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    DOI: 10.1246/cl.2008.802

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  • Boryllithium: A novel boron nucleophile and its application in the synthesis of borylmetal complexes Reviewed

    Makoto Yamashita, Kyoko Nozaki

    Pure and Applied Chemistry   80 ( 5 )   1187 - 1194   2008.5

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    DOI: 10.1351/pac200880051187

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  • Carbonylative polymerization of oxetanes initiated by acetyl cobalt complexes Reviewed

    Yessi Permana, Koji Nakano, Makoto Yamashita, Daisuke Watanabe, Kyoko Nozaki

    CHEMISTRY-AN ASIAN JOURNAL   3 ( 4 )   710 - 718   2008

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    DOI: 10.1002/asia.200700339

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  • Syntheses, structures, and reactivities of borylcopper and -zinc compounds: 1,4-silaboration of an alpha,beta-unsaturated ketone to form a gamma-siloxyallylborane Reviewed

    Takashi Kajiwara, Tomomi Terabayashi, Makoto Yamashita, Kyoko Nozaki

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   47 ( 35 )   6606 - 6610   2008

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    DOI: 10.1002/anie.200801728

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  • Synthesis, structure of borylmagnesium, and its reaction with benzaldehyde to form benzoylborane Reviewed

    Makoto Yamashita, Yuta Suzuki, Yasutomo Segawa, Kyoko Nozaki

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   129 ( 31 )   9570 - +   2007.8

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    DOI: 10.1021/ja073037t

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  • Boryl anion attacks transition-metal chlorides to form boryl complexes: Syntheses, spectroscopic, and structural studies on group 11 borylmetal complexes Reviewed

    Yasutomo Segawa, Makoto Yamashita, Kyoko Nozaki

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   46 ( 35 )   6710 - 6713   2007

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    DOI: 10.1002/anie.200702369

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  • Boryllithium: Isolation, characterization, and reactivity as a boryl anion Reviewed

    Yasutomo Segawa, Makoto Yamashita, Kyoko Nozaki

    SCIENCE   314 ( 5796 )   113 - 115   2006.10

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    DOI: 10.1126/science.1131914

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  • Syntheses and structures of bulky monophosphine-ligated methylpalladium complexes: Application to homo- and copolymerization of norbornene and/or methoxycarbonylnorbornene Reviewed

    Makoto Yamashita, Ikuko Takamiya, Koichiro Jin, Kyoko Nozaki

    ORGANOMETALLICS   25 ( 19 )   4588 - 4595   2006.9

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    DOI: 10.1021/om060347w

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  • Organometallic chemistry of amidate complexes. Accelerating effect of bidentate ligands on the reductive elimination of N-aryl amidates from palladium(II) Reviewed

    Ken-ichi Fujita, Makoto Yamashita, Florian Puschmann, Miguel Martinez Alvarez-Falcon, Christopher D. Incarvito, John F. Hartwig

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   128 ( 28 )   9044 - 9045   2006.7

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    DOI: 10.1021/ja062333n

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  • Syntheses and characterizations of methylpalladium complexes bearing a biphenyl-based bulky phosphine ligand: Weak interactions suggested by NBO and QTAIM analyses Reviewed

    Makoto Yamashita, Ikuko Takamiya, Koichiro Jin, Kyoko Nozaki

    JOURNAL OF ORGANOMETALLIC CHEMISTRY   691 ( 14 )   3189 - 3195   2006.7

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    DOI: 10.1016/j.jorganchem.2006.02.001

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  • Alternating copolymerization of fluoroalkenes with carbon monoxide Reviewed

    T Fujita, K Nakano, M Yamashita, K Nozaki

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   128 ( 6 )   1968 - 1975   2006.2

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    DOI: 10.1021/ja055862k

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  • Extended hypervalent 5c-6e interactions: Linear alignment of five C-Z---O---Z-C (Z = S, Se) atoms in anthraquinone and anthracene systems Reviewed

    W Nakanishi, S Hayashi, T Furuta, N Itoh, Y Nishina, M Yamashita, Y Yamamoto

    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS   180 ( 5-6 )   1351 - 1355   2005.5

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    DOI: 10.1080/10426500590912321

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  • Fixation of both O-2 and CO2 from air by a crystalline palladium complex bearing N-heterocyclic carbene ligands Reviewed

    M Yamashita, K Goto, T Kawashima

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   127 ( 20 )   7294 - 7295   2005.5

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    DOI: 10.1021/ja051054h

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  • Synthesis and structure of a germylene bearing a 1,8-dimethoxyanthracene ligand Reviewed

    M Yamashita, H Murakami, T Unrin-In, A Kawachi, K Akiba, Y Yamamoto

    CHEMISTRY LETTERS   34 ( 5 )   690 - 691   2005.5

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    DOI: 10.1246/cl.2005.690

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  • Syntheses and structures of hypervalent pentacoordinate carbon and boron compounds bearing an anthracene skeleton - Elucidation of hypervalent interaction based on X-ray analysis and DFT calculation Reviewed

    M Yamashita, Y Yamamoto, KY Akiba, D Hashizume, F Iwasaki, N Takagi, S Nagase

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   127 ( 12 )   4354 - 4371   2005.3

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  • An efficient Pd(II)-based catalyst system for carboxylation of aromatic C-H bond by addition of a phosphenium salt Reviewed

    K Sakakibara, M Yamashita, K Nozaki

    TETRAHEDRON LETTERS   46 ( 6 )   959 - 962   2005.2

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    DOI: 10.1016/j.tetlets.2004.12.027

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  • Synthesis, structure, and reductive elimination chemistry of three-coordinate arylpalladium amido complexes Reviewed

    M Yamashita, JF Hartwig

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   126 ( 17 )   5344 - 5345   2004.5

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    DOI: 10.1021/ja0315107

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  • Trans influence on the rate of reductive elimination. Reductive elimination of amines from isomeric arylpalladium amides with unsymmetrical coordination spheres Reviewed

    M Yamashita, JVC Vicario, JF Hartwig

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   125 ( 52 )   16347 - 16360   2003.12

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    DOI: 10.1021/ja037425g

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  • Synthesis of a new potential tridentate anthracene ligand bearing deprotectable methoxymethoxy (OMOM) group at 1,8-positions: Attempt to synthesize anionic hypervalent carbon compounds Reviewed

    M Yamashita, Y Mita, Y Yamamoto, KY Akiba

    CHEMISTRY-A EUROPEAN JOURNAL   9 ( 15 )   3655 - 3659   2003.8

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    DOI: 10.1002/chem.200204354

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  • Synthesis and application of new tridentate anthracene ligands bearing donative phosphorus(III) atoms at 1,8-positions Reviewed

    K Watanabe, M Yamashita, Y Yamamoto, K Akiba

    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS   177 ( 8-9 )   2047 - 2048   2002.8

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    DOI: 10.1080/10426500290094341

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  • Synthesis of a novel potential tridentate anthracene ligand, 1,8-bis(dimethylamino)-9-bromoanthracene, and its application as chelate ligand for synthesis of the corresponding boron and palladium compounds Reviewed

    M Yamashita, K Kamura, Y Yamamoto, K Akiba

    CHEMISTRY-A EUROPEAN JOURNAL   8 ( 13 )   2976 - 2979   2002.7

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  • Synthesis of a new tridentate anthracene ligand bearing (i-Pr)(2)P group at 1,8-positions: Facile bond switch on tetracoordinate boron atom Reviewed

    M Yamashita, K Watanabe, Y Yamamoto, KY Akiba

    CHEMISTRY LETTERS   ( 11 )   1104 - 1105   2001.11

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  • Synthesis of a versatile tridentate anthracene ligand and its application for the synthesis of hypervalent pentacoordinate boron compounds (10-B-5) Reviewed

    M Yamashita, Y Yamamoto, K Akiba, S Nagase

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   39 ( 22 )   4055 - 4058   2000

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  • Synthesis and isolation of stable hypervalent carbon compound (10-C-5) bearing a 1,8-dimethoxyanthracene ligand Reviewed

    K Akiba, M Yamashita, Y Yamamoto, S Nagase

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   121 ( 45 )   10644 - 10645   1999.11

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Presentations

  • Ligation Behavior of a Pyridine-Tethered Cyclic Guanidine to Late Transition Metals

    7th Asian Conference of Coordination Chemistry (ACCC7)  2019.10 

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  • Synthesis of NHC-Based CNC-Pincer Fe Complex and Its Application to Catalytic Hydrogenation of Alkenes

    7th Asian Conference of Coordination Chemistry (ACCC7)  2019.10 

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  • 中性B-O二重結合種の合成と性質 International conference

    中野遼, 山下誠

    第30回基礎有機化学討論会  2019.10 

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  • Reaction of Alumanylpotassium toward Early Metal Complexes

    7th Asian Conference of Coordination Chemistry (ACCC7)  2019.10 

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  • 炭素置換6電子系Alアニオンと第3族および4族金属錯体との反応 International conference

    杉田健悟, 山下誠

    第69回錯体化学討論会  2019.9 

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  • ホウ素窒素置換アセチレンの反応:有機ホウ素化合物との錯形成および[2+2]二量化反応 International conference

    小林明弥, 鈴木克規, 北村亮, 山下誠

    第30回基礎有機化学討論会  2019.9 

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  • N-ヘテロ環状カルベンを有するCNCピンサー鉄錯体の合成とアルケンの触媒的水素化反応への応用 International conference

    谷口わか乃, 伊藤淳一, 山下誠

    第36回有機合成化学セミナー  2019.9 

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  • ジアリールボリル金属錯体の合成・構造・反応性 International conference

    鈴木あかね, 山下誠

    第69回錯体化学討論会  2019.9 

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  • N-ヘテロ環状カルベンを有するCNCピンサー鉄錯体の合成とアルケンの触媒的水素化反応への応用 International conference

    谷口わか乃, 伊藤淳一, 山下誠

    第66回有機金属化学討論会  2019.9 

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  • アルキル置換アルマニルアニオンと不飽和化合物との反応性の解明 International conference

    杉田健悟, 山下誠

    第36回有機合成化学セミナー  2019.9 

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  • 炭素置換6電子系Alニオンと不飽和化合物との反応性の解明 International conference

    杉田健悟, 山下誠

    第66回有機金属化学討論会  2019.9 

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  • Reactivity of Anionic Aluminabenzene: Substitution at 4-Position and Synthesis of Dianionic Bi(aluminabenzene)

    18th International Symposium on Novel Aromatic Compounds (ISNA-18)  2019.9 

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  • Synthesis and Characterization of Germanium-, Tin-, and Lead-Incorporated Benzenes

    International Conference on the Coordination and Organometallic Chemistry of Germanium, Tin, and Lead (ICCOC-GTL-16)  2019.9 

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  • Synthesis and Derivatization of Chlorine-substituted 9,10-Dihydro-9-aza-10-bora-anthracene

    18th International Symposium on Novel Aromatic Compounds (ISNA-18)  2019.7 

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  • Reaction of Bismabenzene with Electrophile and Nucleophile

    18th International Symposium on Novel Aromatic Compounds (ISNA-18)  2019.7 

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  • Reactions of Boryl- and Amino-substituted Acetylene toward Hydro-/Chloro-boranes

    ITbM-GTR Pre-ISNA Symposium"Toward Advanced Functions from New pi-skelton"  2019.7 

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  • Synthesis of Heavy Group 14 Element-Incorporated Benzenes

    ITbM-GTR Pre-ISNA Symposium"Toward Advanced Functions from New pi-skelton"  2019.7 

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  • Reactivity of Alumanylpotassium toward Early Metal Complexes

    ITbM-GTR Pre-ISNA Symposium"Toward Advanced Functions from New pi-skelton"  2019.7 

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  • Reactivity of Alkyl-substituted Aluminium Anion

    ITbM-GTR Pre-ISNA Symposium"Toward Advanced Functions from New pi-skelton"  2019.7 

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  • Synthesis of NHC-Based CNC-Pincer Fe Complex and Its Application to Catalytic Hydrogenation of Alkenes

    ITbM-GTR Pre-ISNA Symposium"Toward Advanced Functions from New pi-skelton"  2019.7 

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  • 側鎖の長いP-B-PピンサーIr錯体の合成 International conference

    河合泰志, 鎌倉聖, 山下誠

    日本化学会第94春季年会  2014.3 

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    Venue:名古屋大学 東山キャンパス  

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  • アニオン性アルミナベンゼンの反応性 International conference

    仲村太智, 鈴木克規, 山下誠

    日本化学会第94春季年会  2014.3 

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    Venue:名古屋大学 東山キャンパス  

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  • ハロゲン置換9-アザ-10-ボラアントラセンの合成、構造および 光物性 International conference

    根間慎也, 鈴木克規, 山下誠

    日本化学会第94春季年会  2014.3 

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    Venue:名古屋大学 東山キャンパス  

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  • Grignard反応剤を用いたアルキル化による不融化石炭ピッチの可溶化と固体および液体物性評価 International conference

    藤本翔, 福田武司, 山形憲一, 山下誠

    日本化学会第94春季年会  2014.3 

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    Venue:名古屋大学 東山キャンパス  

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  • アニオン性アルミナベンゼンの合成、構造およびその反応性 International conference

    仲村太智, 鈴木 克規, 山下 誠

    第40回有機典型元素化学討論会  2013.12 

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    Venue:近畿大学  

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  • ホウ素および窒素置換基を有するシクロブタジエンの合成 International conference

    小沼郁, 鈴木克規, 山下誠

    日本化学会第94春季年会  2014.3 

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    Venue:名古屋大学 東山キャンパス  

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  • ハロゲン置換9-アザ-10-ボラアントラセン誘導体の合成 International conference

    根間慎也, 鈴木克規, 山下 誠

    第40回有機典型元素化学討論会  2013.12 

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    Venue:近畿大学  

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  • 非対称ジボラン(4)と一酸化炭素およびイソニトリルの反応 International conference

    浅川 博祈, 山下 誠

    第40回有機典型元素化学討論会  2013.12 

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    Venue:近畿大学  

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  • Reactivity of Alkyl-substituted Al Anion toward Unsaturated Hydrocarbons and Early Metal Complexes International conference

    2020.3 

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  • 側鎖の長いPBPピンサーIr錯体の合成 International conference

    河合 泰志, 鎌倉 聖, 山下 誠

    錯体化学会第63回討論会  2013.11 

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    Venue:琉球大学  

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  • ホウ素、窒素置換アセチレンとチタノセン誘導体との反応 International conference

    小林明弥, 鈴木克規, 山下誠

    日本化学会第100回年会  2020.3 

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  • 窒素置換アセチレン:push-pull共役系の新規ビルディングブロック International conference

    小沼 郁, 鈴木 克規, 山下 誠

    第40回有機典型元素化学討論会  2013.12 

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    Venue:近畿大学  

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  • ジアリールボリル金錯体へのアルキンの挿入反応および続く異性化 International conference

    鈴木あかね, 山下誠

    日本化学会第100回年会  2020.3 

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  • Synthesis and Property of Alkyl-Substituted Al Anion International conference

    2020.3 

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  • 石炭ピッチおよびその誘導体の固体および溶液物性解明 International conference

    藤本翔, 福田武司, 山形憲一, 山下誠

    日本化学会秋季事業第3回CSJ化学フェスタ 2013  2013.10 

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    Venue:タワーホール船堀 東京  

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  • ビス(オキサゾリニル)メタニド配位子を有する後周期金属錯体の合成および反応 International conference

    山梨 遼太朗, 山下誠

    日本化学会第100回年会  2020.3 

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  • 1,4-アザボリン骨格を有するπ共役系化合物の合成 International conference

    根間慎也, 鈴木克規, 山下 誠

    日本化学会秋季事業第3回CSJ化学フェスタ 2013  2013.10 

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    Venue:タワーホール船堀 東京  

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  • 新規非対称ジボランの合成とCOおよびCN三重結合との反応性 International conference

    浅川 博祈, 山下 誠

    日本化学会秋季事業第3回CSJ化学フェスタ 2013  2013.10 

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    Venue:タワーホール船堀 東京  

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  • ヒドロキノン置換型N-ヘテロ環状カルベン配位子を有する新規Fe錯体の合成 International conference

    浅賀 一義, 大橋 謙一, 伊藤 淳一, 山下 誠

    日本化学会第100回年会  2020.3 

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  • ホウ素置換ホスフィドおよびジホスフェンの合成と性質 International conference

    浅見 俊介, 岡本 匡史, 鈴木 克規, 山下 誠

    日本化学会秋季事業第3回CSJ化学フェスタ 2013  2013.10 

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    Venue:タワーホール船堀 東京  

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  • N-ヘテロ環状カルベンを有するCNCピンサー鉄錯体の合成とアルケンの触媒的水素化反応への応用 International conference

    谷口わか乃, 伊藤淳一, 山下誠

    日本化学会第100回年会  2020.3 

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  • アニオン性アルミナベンゼンの合成 International conference

    仲村太智, 鈴木克規, 山下 誠

    日本化学会秋季事業第3回CSJ化学フェスタ 2013  2013.10 

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    Venue:タワーホール船堀 東京  

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  • ホウ素窒素置換アセチレンとチタノセン/ジルコノセン誘導体との反応 International conference

    小林明弥, 鈴木克規, 山下誠

    第46回有機典型元素化学討論会  2020.3 

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  • Synthesis and Property of a Mesityl-Substituted Unsymmetrical Diborane(4).

    H. Asakawa, M. Yamashita

    EUROBORON6  2013.9 

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    Venue:Radziejowice, Poland  

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  • ビス(ジアリール)ボリルメチルアニオンの構造と反応性 International conference

    秋山世治, 山下誠

    日本化学会第100回年会  2020.3 

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  • 窒素およびホウ素置換基をもったpush-pull型π系化合物の合成 International conference

    小沼 郁, 鈴木 克規, 山下 誠

    日本化学会秋季事業第3回CSJ化学フェスタ 2013  2013.10 

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    Venue:タワーホール船堀 東京  

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  • 炭素置換Alアニオンを用いた芳香族炭化水素の脱プロトン化 International conference

    車田怜史, 杉田健吾, 山下誠

    GTR/ITbM Chemistry Workshop 2019  2019.12 

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  • SYNTHESIS OF p-CONJUGATED FRAMEWORK BASED ON 1,4-AZABORINE SKELETON.

    Shin-ya Nema, katsunori Suzuki, Makoto Yamashita

    EUROBORON6  2013.9 

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    Venue:Radziejowice, Poland  

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  • 炭素置換Alアニオンを用いた芳香族炭化水素の脱プロトン化 International conference

    車田怜史, 杉田健吾, 山下誠

    第46回有機典型元素化学討論会  2019.12 

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  • SYNTHESES AND PROPERTIES OF BORYL-SUBSTITUTED PHOSPHORUS COMPOUNDS.

    Shunsuke ASAMI, Makoto Yamashita

    EUROBORON6  2013.9 

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    Venue:Radziejowice, Poland  

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  • 幾何拘束型アルミナベンゼンージルコニウム錯体の合成と構造 International conference

    久野真揮, 鈴木克規, 山下誠

    第50回中部化学関係学協会支部連合秋季大会  2019.11 

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  • ジアリールボリル金属錯体の合成・構造・反応性 International conference

    鈴木あかね, 山下誠

    第50回中部化学関係学協会支部連合秋季大会  2019.11 

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  • Synthesis of N,B-Substituted Push-Pull Type π Systems.

    Kaoru Onuma, Katsunori Suzuki, Makoto Yamashita

    EUROBORON6  2013.9 

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    Venue:Radziejowice, Poland  

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  • ヒドロキノン置換型N-ヘテロ環状カルベン配位子を有する新規鉄錯体の合成 International conference

    浅賀 一義, 伊藤 淳一, 山下 誠

    第50回中部化学関係学協会支部連合秋季大会  2019.11 

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  • ビスシリルピラジンとハロボランの反応によるホウ素、窒素含有共役系の合成、構造およびその物性 International conference

    野口真緒, 百合野大雅, 劒 隼人, 真島和志, 鈴木克規, 山下 誠

    第69回有機合成化学協会関東支部シンポジウム  2015.5 

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    Venue:横浜国立大学常盤台キャンパス(横浜市保土ヶ谷区)  

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  • Syntheses and Properties of diboryldiphosphene and diboryldiphosphene radical anion. International conference

    Shun-suke Asami, Masafumi Okamoto, Katsunori Suzuki, Makoto Yamashita

    2015.6 

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  • 1,5-ビスシリル1,4-ジインのヒドロアルミニウム化を経由した含15族高周期ベンゼンの合成 International conference

    石井拓弥, 仲村太智, 鈴木克規, 山下誠

    日本化学会 第95春季年会  2015.3 

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    Venue:日本大学 理工学部船橋キャンパス 千葉  

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  • 1,5-ビスシリル-1,4-ジインのヒドロアルミニウム化によるヘテラベンゼンの合成 International conference

    石井拓弥, 仲村太智, 鈴木克規, 山下 誠

    第69回有機合成化学協会関東支部シンポジウム  2015.5 

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    Venue:横浜国立大学常盤台キャンパス(横浜市保土ヶ谷区)  

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  • 非対称diborane(4)化合物pinB-BMes2の反応性とその高い電子受容性の起源 International conference

    浅川博祈, 山下誠, 古川貢・Lin Zhenyang・Lee, Ka Ho, 山下

    日本化学会 第95春季年会  2015.3 

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    Venue:日本大学 理工学部船橋キャンパス 千葉  

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  • アルキル化石炭ピッチの溶液および固体物性のアルキル鎖依存性 International conference

    藤本翔, 福田武司, 山形憲一, 山下誠

    日本化学会 第95春季年会  2015.3 

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    Venue:日本大学 理工学部船橋キャンパス 千葉  

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  • ホウ素、窒素置換シクロブタジエンの反応 International conference

    小沼郁, 鈴木克規, 山下誠

    日本化学会 第95春季年会  2015.3 

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    Venue:日本大学 理工学部船橋キャンパス 千葉  

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  • ビスシリルピラジンとハロボランの反応によるホウ素、窒素含有共役系の合成 International conference

    野口真緒, 百合野大雅, 劒隼人, 真島和志, 鈴木克規, 山下誠

    日本化学会 第95春季年会  2015.3 

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    Venue:日本大学 理工学部船橋キャンパス 千葉  

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  • Regioselective diboration using unsymmetrical diborane(4) in the absence of transition metal catalyst. International conference

    Chiemi Kojima, Makoto Yamashita

    2015.6 

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  • Bora-Brook rearrangement reaction and the effects of solvent polarity, the backbone of boryl group, and counter cation of base. International conference

    Haruki Kisu, Makoto Yamashita, Fumihiro Ito, Hirotoshi Sakaino, Kyoko Nozaki

    2015.6 

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  • Synthesis and properties of group 13 element-incorporated benzenes. International conference

    Taichi Nakamura, Katsunori Suzuki, Makoto Yamashita

    2015.6 

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  • Bora-Brook 転位における対カチオン効果 International conference

    木須遥規, 山下誠, 伊東史裕, 境野裕健, 野崎京子

    日本化学会 第95春季年会  2015.3 

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    Venue:日本大学 理工学部船橋キャンパス 千葉  

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  • i-Pr基置換PBP配位子を有するIr錯体による触媒的アルカン脱水素移動反応 International conference

    田上景太, 山下誠

    日本化学会 第95春季年会  2015.3 

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    Venue:日本大学 理工学部船橋キャンパス 千葉  

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  • ジボリルジホスフェンの合成・構造・反応性 International conference

    浅見 俊介, 岡本 匡史, 鈴木 克規, 山下 誠

    日本化学会 第95春季年会  2015.3 

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    Venue:日本大学 理工学部船橋キャンパス 千葉  

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  • アルミナベンゼン-ジルコニウム錯体の合成と構造 International conference

    仲村太智, 鈴木克規, 山下誠

    日本化学会 第95春季年会  2015.3 

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    Venue:日本大学 理工学部船橋キャンパス 千葉  

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  • 側鎖の長いP-B-P ピンサー配位子を有するIr錯体を用いたアルカンの脱水素化反応 International conference

    河合泰志, 鎌倉聖, 山下誠

    日本化学会 第95春季年会  2015.3 

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    Venue:日本大学 理工学部船橋キャンパス 千葉  

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  • ホウ素置換アルコキシドのbora-Brook転位と速度論解析 International conference

    木須遥規, 山下誠, 伊藤史裕, 境野裕健, 野崎京子

    第41回有機典型元素化学討論会  2014.11 

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    Venue:宇部市文化会館ホール 山口  

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  • Grignard反応剤を用いた不融化石炭ピッチのアルキル化による可溶化と溶液および固体物性解明 International conference

    藤本 翔, 福田 武司, 山形 憲一, 山下 誠

    第41回 炭素材料学会年会  2014.12 

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    Venue:大野城まどかぴあ 福岡  

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  • 1,5-ビスシリル1,4-ジインのヒドロアルミニウム化を経由したホスフィニンの合成 International conference

    石井拓弥, 仲村太智, 鈴木克規, 山下誠

    第41回有機典型元素化学討論会  2014.11 

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    Venue:宇部市文化会館ホール 山口  

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  • ホウ素置換ジホスフェンの合成・構造・反応性 International conference

    浅見 俊介, 岡本 匡史, 鈴木 克規, 山下 誠

    第41回有機典型元素化学討論会  2014.11 

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    Venue:宇部市文化会館ホール 山口  

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  • 遷移金属非存在下でのアルキンのジボリル化反応における位置選択性制御 International conference

    小島千絵美, 山下誠

    日本化学会 第95春季年会  2015.3 

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    Venue:日本大学 理工学部船橋キャンパス 千葉  

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  • 溶媒和の無いボリルアニオンの反応性 International conference

    大里拓人, 奥野友里, 石田真太郎, 岩本武明, 山下誠, 野崎京子

    日本化学会 第95春季年会  2015.3 

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    Venue:日本大学 理工学部船橋キャンパス 千葉  

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  • ホウ素置換ジホスフェンとn-BuLiの反応 International conference

    浅見 俊介, 山下 誠

    第42回有機典型元素化学討論会  2015.12 

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    Venue:名古屋大学野依記念学術交流館 愛知県名古屋市  

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  • アニオン性インダベンゼンの合成と性質 International conference

    仲村太智, 鈴木克規, 山下誠

    第42回有機典型元素化学討論会  2015.12 

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    Venue:名古屋大学野依記念学術交流館 愛知県名古屋市  

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  • Long-Tethered P-B-P Ligands: Synthesis, Complexation and Catalysis. International conference

    Enrique KWAN H, Yasushi KAWAI, Sei KAMAKURA, Makoto Yamashita

    The 8th International Forum on Chemistry of Functional Organic Chemicals  2015.11 

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    Venue:The University of Tokyo TOKYO  

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  • Synthesis and Structures of Anionic Aluminabenzene and Their Zirconium Complexes. International conference

    Taichi Nakamura, Katsunori Suzuki, Makoto Yamashita

    The 8th International Forum on Chemistry of Functional Organic Chemicals  2015.11 

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    Venue:The University of Tokyo TOKYO  

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  • 非対称ジボラン(4)を用いたピリジンのオルト位C-H 結合切断反応 International conference

    勝間雄平, 浅川博祈, 山下 誠

    第26回基礎有機化学討論会  2015.9 

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    Venue:愛媛大学 愛媛県松山市  

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  • Synthesis of Anionic Aluminabenzene and Their Zirconium Complexes. International conference

    Taichi Nakamura, Katsunori Suzuki, Makoto Yamashita

    Stimulating Meeting for Young Researchers in Chemistry on Stimuli-responsive Chemical Species  2015.11 

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  • アルミナベンゼンとガラベンゼンの合成と性質 International conference

    仲村太智, 鈴木克規, 山下誠

    第32回有機合成化学セミナー  2015.9 

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    Venue:ニューウェルシティ湯河原 静岡県熱海市  

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  • Synthesis and Structure of Aluminabenzene-Zirconium Complexes.

    Taichi NAKAMURA, Katsunori SUZUKI, Makoto YAMASHITA

    5th Asian Conference on Coordination Chemistry  2015.7 

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    Venue:The University of Hong Kong, Hong Kong  

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  • アルミナベンゼンとガラベンゼンおよびそのZr錯体の合成と性質 International conference

    仲村太智, 鈴木克規, 山下誠

    第62回有機金属化学討論会  2015.9 

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    Venue:関西大学千里山キャンパス 大阪府吹田市  

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  • SYNTHESIS AND PROPERTIES OF GROUP 13 ELEMENT-INCORPORATED BENZENES.

    Taichi NAKAMURA, Katsunori SUZUKI, Makoto YAMASHITA

    11th International Conference on Heteroatom Chemistry (ICHAC-11th)  2015.6 

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    Venue:University of Caen Basse-Normandie Caeny, Normandy, France  

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  • Syntheses and Properties of diboryldiphosphene and diboryldiphosphene radical anion

    Shun-suke Asami, Masafumi Okamoto, Katsunori Suzuki, Makoto Yamashita

    11th International Conference on Heteroatom Chemistry (ICHAC-11th)  2015.6 

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    Venue:University of Caen Basse-Normandie Caeny, Normandy, France  

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  • Synthesis and Properties of Reactive Diborane(4) Compounds. International conference

    Makoto Yamashita

    2015.6 

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  • SYNTHESIS AND PROPERTIES OF REACTIVE DIBORANE(4) COMPOUNDS.

    Makoto YAMASHITA

    11th International Conference on Heteroatom Chemistry (ICHAC-11th)  2015.6 

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    Venue:University of Caen Basse-Normandie Caeny, Normandy, France  

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  • ビスシリルピラジンとハロボランの反応によるホウ素、窒素含有共役系の合成およびその物性 International conference

    野口真緒, 百合野大雅, 劔 隼人, 真島和志, 鈴木克規, 山下 誠

    第26回基礎有機化学討論会  2015.9 

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    Venue:愛媛大学 愛媛県松山市  

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  • 溶媒和の無いボリルアニオンの発生とその塩基性 International conference

    大里拓人, 奥野友里, 石田真太郎, 岩本武明, 山下 誠, 野崎京子

    第26回基礎有機化学討論会  2015.9 

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    Venue:愛媛大学 愛媛県松山市  

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  • iPr基が置換したPBP配位子を有するIr及びRh錯体の合成、構造、反応 International conference

    田上景太, 山下誠

    錯体化学会第65回討論会  2015.9 

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    Venue:奈良女子大学 奈良県奈良市  

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  • 高周期15 族ヘテロベンゼンの合成と構造 International conference

    石井拓弥, 仲村太智, 鈴木克規, 山下 誠

    第26回基礎有機化学討論会  2015.9 

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    Venue:愛媛大学 愛媛県松山市  

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  • Synthesis of B,N Containing π Conjugated Compounds Containing Borabenzene.

    Mao NOGUCHI, Katsunori SUZUKI, Makoto YAMASHITA

    the International Meeting on Boron Chemistry (IMEBORON XV)  2014.8 

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    Venue:Czech Technical Univ.,Prague, Czech Republic  

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  • 求電子剤との反応を経由するアニオン性アルミナベンゼンの置換反応 International conference

    久野真揮, 鈴木克規, 仲村太智, 山下誠

    日本化学会 第98春季年会  2018.3 

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    Venue:日本大学 理工学部 船橋キャンパス  

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  • テトラアリールジボラン(4)ジアニオンおよびその銅錯体の合成と性質 International conference

    秋山世治, 山下誠

    日本化学会 第98春季年会  2018.3 

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    Venue:日本大学 理工学部 船橋キャンパス  

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  • ジアルキルアルマニルアニオンの合成と性質 International conference

    車田怜史, 高森修平, 山下誠

    日本化学会 第98春季年会  2018.3 

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    Venue:日本大学 理工学部 船橋キャンパス  

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  • ボリルリチウムを用いた直鎖ホウ素化合物の合成と性質 International conference

    八木篤実, 木須遥規, 山下誠

    日本化学会 第98春季年会  2018.3 

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    Venue:日本大学 理工学部 船橋キャンパス  

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  • 無置換9,10-ジヒドロ-9-アザ-10-ボラアントラセン の合成および構造 International conference

    石川祐太朗, 根間慎也, 林晃平, 鈴木克規, 山下誠

    日本化学会 第98春季年会  2018.3 

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    Venue:日本大学 理工学部 船橋キャンパス  

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  • テトラアルキルジアルマンの合成と性質 International conference

    車田怜史, 高森修平, 山下誠

    第44回有機典型元素化学討論会  2017.12 

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    Venue:東京工業大学 大岡山キャンパス  

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  • ジボランジアニオン(4)の反応性 International conference

    秋山世治, 山下誠

    第44回有機典型元素化学討論会  2017.12 

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    Venue:東京工業大学 大岡山キャンパス  

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  • 求電子剤と塩基によるアニオン性アルミナベンゼンの段階的置換反応 International conference

    久野真揮, 鈴木克規, 仲村太智, 山下誠

    第113回有機合成シンポジウム  2018.6 

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  • マクロサイクル骨格を有するポリN-ヘテロ環状カルベン配位子の合成および構造 International conference

    小森彩香, 伊藤淳一, 山下誠

    第113回有機合成シンポジウム  2018.6 

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  • クロロ置換ゲルマシクロヘキサジエンの反応を用いたゲルマベンゼン誘導体の合成と性質 International conference

    海谷河音, 鈴木克規, 山下誠

    第44回有機典型元素化学討論会  2017.12 

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    Venue:東京工業大学 大岡山キャンパス  

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  • ボリルリチウムを用いたジハロジボラン(4)の合成と性質 International conference

    八木篤実, 木須遥規, 山下誠

    第44回有機典型元素化学討論会  2017.12 

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    Venue:東京工業大学 大岡山キャンパス  

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  • B2(o-tol)4によるCO三重結合切断反応 International conference

    勝間雄平, 塚原菜那, 山下誠

    ITbM/IGER Chemistry Workshop 2017  2017.11 

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    Venue:名古屋大学ITbM  

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  • アルミナベンゼン-ジルコニウム錯体の合成、構造およびエチレン重合活性 International conference

    仲村太智, 鈴木克規, 山下誠

    第48回中部化学関係学協会支部連合秋季大会  2017.11 

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    Venue:岐阜大学  

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  • BN含有π共役系分子を前駆体としたBNドープグラファイトの合成と物性評価 International conference

    小林純, 鈴木克規, 菅原義之, 山下誠

    第28回基礎有機化学討論会  2017.9 

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    Venue:九州大学 伊都キャンパス  

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  • B2(o-tol)4によるCO三重結合切断反応 International conference

    勝間雄平, 塚原菜那, 山下誠

    第28回基礎有機化学討論会  2017.9 

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    Venue:九州大学 伊都キャンパス  

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  • 官能基変換可能なアミノ基とボリン酸部位を持つ9-アザ-10-ボラアントラセンの合成と誘導化 International conference

    石川祐太朗, 根間慎也, 林晃平, 鈴木克規, 山下誠

    第28回基礎有機化学討論会  2017.9 

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    Venue:九州大学伊都キャンパス  

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  • 中性アルミナベンゼン-ルイス塩基付加体の合成と構造 International conference

    仲村太智, 鈴木克規, 山下誠

    第28回基礎有機化学討論会  2017.9 

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    Venue:九州大学 伊都キャンパス  

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  • Synthesis and Property of BN-doped Carbon Materials Using BN Containing π-Conjugated Compounds as Precursors

    Jun Kobayashi, Katsunori Suzuki, Yoshiyuki Sugahara, Makoto Yamashita

    International ERATO Itami Molecular Nanocarbon Symposium 2017  2017.8 

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    Venue:Nagoya University  

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  • 嵩高いシリル基で安定化された塩素置換ゲルマベンゼンの合成とその変換反応 International conference

    海谷河音, 仲村太智, 鈴木克規, 山下誠

    第28回基礎有機化学討論会  2017.9 

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    Venue:九州大学 伊都キャンパス  

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  • 9-アザ-10-ボラアントラセンオリゴマーの合成、構造および光物性 International conference

    石川祐太朗, 根間慎也, 林晃平, 鈴木克規, 山下誠

    第44回有機典型元素化学討論会  2017.12 

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    Venue:東京工業大学 大岡山キャンパス  

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  • Long-Tethered P-B-P Ligands: Synthesis, Complexation and Catalysis International conference

    KWAN HUANG, Enrique, KAWAI, Jack Yasushi, KAMAKURA, Sei, OGAWA, Hayato, YAMASHITA, Makoto

    2016.3 

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  • 高周期13 族元素含有ベンゼンの合成と性質 International conference

    仲村太智, 鈴木克規, 山下誠

    日本化学会第96春季年会  2016.3 

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    Venue:同志社大学京田辺キャンパス 京都  

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  • ピロール骨格を有するPNP ピンサーIr 錯体のアルカン脱水素化触媒としての応用 International conference

    中山真, 山下誠

    日本化学会第96春季年会  2016.3 

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    Venue:同志社大学京田辺キャンパス 京都  

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  • 非対称ジボラン(4)とイソシアニドの反応による含窒素複素環化合物のオルト位官能基化反応 International conference

    勝間雄平, 浅川博祈, 山下誠

    日本化学会第96春季年会  2016.3 

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    Venue:同志社大学京田辺キャンパス 京都  

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  • ホウ素置換ホスフィノホスフィドの合成と性質 International conference

    浅見俊介, 岡本匡史, 鈴木克規, 山下誠

    日本化学会第96春季年会  2016.3 

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    Venue:同志社大学京田辺キャンパス 京都  

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  • ボリルリチウムを用いた新規非対称ジボランの合成と性質 International conference

    木須遥規, 山下誠

    日本化学会第96春季年会  2016.3 

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    Venue:同志社大学京田辺キャンパス 京都  

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  • ビスムタベンゼンの反応 International conference

    石井拓弥, 仲村太智, 鈴木克規, 山下誠

    日本化学会第96春季年会  2016.3 

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    Venue:同志社大学京田辺キャンパス 京都  

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  • テトラアリールジボラン(4)の簡便合成と還元反応 International conference

    塚原菜那, 浅川博祈, 山下誠

    日本化学会第96春季年会  2016.3 

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    Venue:同志社大学京田辺キャンパス 京都  

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  • ボリルアニオンによる炭化水素の脱プロトン化 International conference

    大里拓人, 奥野友里, 石田真太郎, 岩本武明, 山下誠, 野崎京子

    日本化学会第96春季年会  2016.3 

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    Venue:同志社大学京田辺キャンパス 京都  

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  • Long-tethered P-B-P ligand: Synthesis, complexation, and catalysis.

    E. Kwan Huang, Y. Kawai, S. Kamakura, M. Yamashita

    The International Chemical Congress of Pacific Basin Societies(The Pacifichem)2015  2015.12 

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    Venue:Hawaii Convention Center Honolulu, Hawaii  

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  • Base catalyzed bora-Brook rearrangement: the effects of solvent polarity, the backbone of boryl group, and counter cation of base toward reaction rate.

    Haruki Kisu, Makoto Yamashita, Fumihiro Ito, Hirotoshi Sakaino, Kyouko Nozaki

    The International Chemical Congress of Pacific Basin Societies(The Pacifichem)2015  2015.12 

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    Venue:Hawaii Convention Center Honolulu, Hawaii  

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  • Basicity of non-solvated boryl anion: Deprotonation of benzene.

    Takuto Osato, Yuri Okuno, Shintaro Ishida, Takeaki Iwamoto, Makoto Yamashita, Kyoko Nozaki

    The International Chemical Congress of Pacific Basin Societies(The Pacifichem)2015  2015.12 

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    Venue:Hawaii Convention Center Honolulu, Hawaii  

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  • Synthesis of boron- and nitrogen-containing conjugated systems by reaction of bis(silyl)pyrazines with haloboranes.

    Mao Noguchi, Taiga Yurino, Hayato Tsurugi, Kazushi Mashima, Katsunori Suzuki, Makoto, Yamashita

    The International Chemical Congress of Pacific Basin Societies(The Pacifichem)2015  2015.12 

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    Venue:Hawaii Convention Center Honolulu, Hawaii  

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  • Regioselective diboration using unsymmetrical diborane(4) in the absence of transition metal catalyst .

    Chiemi Kojima, Makoto Yamashita

    The International Chemical Congress of Pacific Basin Societies(The Pacifichem)2015  2015.12 

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    Venue:Hawaii Convention Center Honolulu, Hawaii  

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  • ynthesis, structure, photophysical property, and one-electron reduction of boryl-substituted diphosphene.

    Shunsuke ASAMI, Masafumi OKAMOTO, Katsunori SUZUKI, Makoto YAMASHITA

    The International Chemical Congress of Pacific Basin Societies(The Pacifichem)2015  2015.12 

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    Venue:Hawaii Convention Center Honolulu, Hawaii  

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  • Synthesis and properties of alumina- and galla-benzenes

    Taichi Nakamura, Katsunori Suzuki, Makoto Yamashita

    The International Chemical Congress of Pacific Basin Societies(The Pacifichem)2015  2015.12 

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    Venue:Hawaii Convention Center Honolulu, Hawaii  

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  • Synthesis, structure and property of Ir and Rh complexes bearing an iPr-substituted PBP ligand.

    Keita Tanoue, Makoto Yamashita

    The International Chemical Congress of Pacific Basin Societies(The Pacifichem)2015  2015.12 

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    Venue:Hawaii Convention Center Honolulu, Hawaii  

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  • Synthesis of phospha-, stiba-, and bismutha-benzenes via transmetallation of the 2,5-bis(silyl)-1-alumina-2,4-cyclohexadiene.

    Takuya Ishii, Taichi Nakamura, Katsunori Suzuki, Makoto Yamashita

    The International Chemical Congress of Pacific Basin Societies(The Pacifichem)2015  2015.12 

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    Venue:Hawaii Convention Center Honolulu, Hawaii  

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  • ボリルリチウムを用いた新規非対称ジボラン化合物の合成 International conference

    木須遥規, 山下誠

    第42回有機典型元素化学討論会  2015.12 

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    Venue:名古屋大学野依記念学術交流館 愛知県名古屋市  

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  • Synthesis of 9-aza-10-boraanthracene bearing transformable boron-chlorine bond synthesis of 9-aza-10-boraanthra- cene bearing transformable boron-chlo- rine bonds.

    K. Suzuki, K. Hayashi, S. Nema, M. Yamashita

    The International Chemical Congress of Pacific Basin Societies(The Pacifichem)2015  2015.12 

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    Venue:Hawaii Convention Center Honolulu, Hawaii  

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  • BN含有π共役系を前駆体としたBCN系炭素材料の合成 International conference

    小林 純, 鈴木 克規, 菅原 義之, 山下 誠

    日本化学会秋季事業第6回CSJ化学フェスタ2016  2016.11 

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    Venue:タワーホール船堀 東京  

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  • PNPピンサーIrおよびRh錯体の合成とアルカン脱水素化触媒としての応用 International conference

    中山 真, 山下 誠

    錯体化学会第66回討論会  2016.9 

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    Venue:福岡大学七隈キャンパス 福岡  

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  • アルミニウム含有P-Al-PピンサーIr錯体の合成と性質 International conference

    渡邉聖也, 山下誠

    錯体化学会第66回討論会  2016.9 

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    Venue:福岡大学七隈キャンパス 福岡  

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  • テトラピロリルジボラン(4)の合成と反応性 International conference

    浅沼秀治, 山下 誠

    第27回基礎有機化学討論会  2016.9 

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    Venue:広島国際会議場 広島  

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  • テトラアリールジボラン(o-tol)2B-B(o-tol)2 の反応性 International conference

    塚原菜那, 浅川博祈, 山下誠

    第27回基礎有機化学討論会  2016.9 

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  • Synthesis and Property of Aluminabenzene -Rh and -Ir Complexes.

    Taichi Nakamura, Katsunori Suzuki, Makoto Yamashita

    XXVII International Conference on Organometallic Chemistry  2016.7 

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    Venue:Melbourne Convention and Exhibition Centre, Melbourne, Australia  

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  • イソシアニド存在下での非対称ジボランと含窒素複素環化合物の反応 International conference

    勝間雄平, 浅川博祈, 山下 誠

    第27回基礎有機化学討論会  2016.9 

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    Venue:広島国際会議場 広島  

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  • Synthesis and Application of Pyrrole-Based P-N-P Pincer Ir Complexes as Catalyst for Dehydrogenation of Alkane.

    Shin Nakayama, Makoto Yamashita

    XXVII International Conference on Organometallic Chemistry  2016.7 

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    Venue:Melbourne Convention and Exhibition Centre, Melbourne, Australia  

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  • Dehydrogenation of Alkanes Catalyzed by Long-Tethered (P-B-P)-Pincer Iridium Complexes.

    Enrique H. KWAN, Yasushi Jack KAWAI, Sei KAMAKURA, Hayato OGAWA, Makoto YAMASHITA

    XXVII International Conference on Organometallic Chemistry  2016.7 

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    Venue:Melbourne Convention and Exhibition Centre, Melbourne, Australia  

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  • Ortho-functionalization of nitrogen-containing heterocycle by using unsymmetrical diborane(4) and isocyanide.

    Yuhei KATSUMA, Hiroki Asakawa, Makoto Yamashita

    XXVII International Conference on Organometallic Chemistry  2016.7 

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    Venue:Melbourne Convention and Exhibition Centre, Melbourne, Australia  

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  • Synthesis of PNP-Ir Complexes and Their Application as Catalyst for Dehydrogenation of Alkanes. International conference

    Shin Nakayama, Makoto Yamashita

    ISHC-XX  2016.7 

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    Venue:Kyoto Terrsa. KYOTO  

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  • Convenient Synthesis of New Tetraaryldiborane(4) and Its Reduction.

    Nana Tsukahara, Hiroki Asakawa, Makoto Yamashita

    XXVII International Conference on Organometallic Chemistry  2016.7 

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    Venue:Melbourne Convention and Exhibition Centre, Melbourne, Australia  

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  • iPrまたはtBuが置換したPNPピンサーIr錯体の合成とアルカン脱水素化触媒として の応用 International conference

    中山真, 山下 誠

    第11回有機元素化学セミナー  2016.6 

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    Venue:京都大学化学研究所  

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  • Dehydrogenation of Alkanes Catalyzed by New Long-Tethered PBP-Pincer Iridium Complexes: Ligand Design and Catalytic Performance. International conference

    Enrique Huang Kwan, Yasushi Jack Kawai, Sei Kamakura, Hayato Ogawa, Makoto Yamashita

    ISHC-XX  2016.7 

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    Venue:Kyoto Terrsa. KYOTO  

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  • 有機ケイ素還元剤を用いたBN含有含有π共役系分子の合成 International conference

    小林純, 鈴木克規, 山下誠

    第11回有機元素化学セミナー  2016.6 

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    Venue:京都大学化学研究所  

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  • 非対称ジボラン(4)の反応による含窒素複素環化合物のオルト位官能基化反応 International conference

    勝間雄平, 浅川博祈, 山下誠

    第11回有機元素化学セミナー  2016.6 

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    Venue:京都大学化学研究所  

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  • 非対称ジボラン(4)を用いた含窒素複素化合物のオルト位官能基化反応 International conference

    勝間雄平, 浅川博祈, 山下誠

    第71回有機合成化学協会関東支部シンポジウム  2016.5 

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    Venue:東京農工大学小金井キャンパス 東京  

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  • アルミナベンゼン-RhおよびIr錯体の合成と性質 International conference

    仲村太智, 鈴木克規, 山下誠

    第11回有機元素化学セミナー  2016.6 

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    Venue:京都大学化学研究所  

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  • 炭素繊維製造中間原料のアルキル化と続くマイクロ波による脱水および生成物の物性評価 International conference

    山﨑露菜, 藤本翔, 山形憲一, 福田武司, 山下誠

    日本化学会第96春季年会  2016.3 

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    Venue:同志社大学京田辺キャンパス 京都  

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  • テトラアリールジボラン(4)の簡便合成とその反応性 International conference

    塚原菜那, 浅川博祈, 山下誠

    第71回有機合成化学協会関東支部シンポジウム  2016.5 

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    Venue:東京農工大学小金井キャンパス 東京  

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  • アルカンの末端選択的酸化触媒としての応用へ向けた分子認識部位を 持つ金属オキソ錯体の合成と性質 International conference

    嶋田紘介, 山下誠

    第24回基礎有機化学討論会  2013.9 

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    Venue:学習院大学目白キャンパス 東京  

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  • 電子的に非対称なジボラン(4)によるイソニトリルのCN三重結合切断反応 International conference

    浅川 博祈, 山下 誠

    第24回基礎有機化学討論会  2013.9 

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    Venue:学習院大学目白キャンパス 東京  

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  • アニオン性アルミナベンゼン:合成と構造解析 International conference

    仲村太智, 鈴木 克規, 山下 誠

    第24回基礎有機化学討論会  2013.9 

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    Venue:学習院大学目白キャンパス 東京  

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  • Comparative Study on Photophysical Properties of Air-Blown Coal Tar Pitches vs. Graphene Derivatives.

    Sho Fujimoto, Takeshi Fukuda, Makoto Yamashita

    The 15th Asian Chemical Congress (15ACC)  2013.8 

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    Venue:Resorts World Sentosa, Sentosa Island, Singapore  

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  • SYNTHETIC APPROACH TO ALUMINABENZENE

    Taichi Nakamura, Katsunori Suzuki, Makoto Yamashita

    The 15th Asian Chemical Congress (15ACC)  2013.8 

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    Venue:Resorts World Sentosa, Sentosa Island, Singapore  

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  • ホウ素置換ホスフィンの合成と性質 International conference

    浅見 俊介, 岡本 匡史, 鈴木 克規, 山下 誠

    日本化学会第93春季年会  2013.3 

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    Venue:立命館大学びわこ・くさつキャンパス  

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  • Rh/Ru混合触媒系を用いた末端アルケンの直鎖選択的ヒドロホルミル化/水素化による直鎖アルコール合成と速度論解析による反応機構研究 International conference

    高橋 講平, 山下 誠, 野崎 京子

    日本化学会第93春季年会  2013.3 

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    Venue:立命館大学びわこ・くさつキャンパス  

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  • 含ホウ素複素環πラジカルの合成とボリルラジカルとしての反応性 International conference

    荒巻 吉孝, 大宮 秀貴, 山下 誠, 中林 耕二, 大越 慎一, 野崎 京子

    日本化学会第93春季年会  2013.3 

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    Venue:立命館大学びわこ・くさつキャンパス  

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  • 新規非対称diborane(4)化合物の合成と性質 International conference

    浅川 博祈, 山下 誠

    日本化学会第93春季年会  2013.3 

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    Venue:立命館大学びわこ・くさつキャンパス  

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  • PBPピンサー配位子を有するRu錯体の合成と反応性 International conference

    宮田 卓真, 山下 誠

    日本化学会第93春季年会  2013.3 

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    Venue:立命館大学びわこ・くさつキャンパス  

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  • PBPピンサー型配位子を有する白金錯体を用いたアルケンのヒドロシリル化反応 International conference

    小川 隼人, 山下 誠

    日本化学会第93春季年会  2013.3 

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    Venue:立命館大学びわこ・くさつキャンパス  

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  • Catalytic Hydrosilylation of Alkene Using Platinum Complexes Bearing a PBP Pincer Ligand.

    Hayato Ogawa, Makoto Yamashit

    OMCOS 17  2013.7 

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    Venue:the Lincoln center, Fort collins, CO, USA  

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  • Synthesis and Properties of Calix[4]arene Derivative Bearing Four n-Hexyl Groups for Recognition of n-Alkane toward Catalyst for Selective Oxidation of Alkane at Terminal Position.

    Kousuke Shimada, Makoto Yamashita

    OMCOS 17  2013.7 

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    Venue:the Lincoln center, Fort collins, CO, USA  

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  • アルカン認識部位を持つcalix[4]arene誘導体の合成と性質 International conference

    嶋田 紘介, 山下 誠

    日本化学会第93春季年会  2013.3 

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    Venue:立命館大学びわこ・くさつキャンパス  

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  • Syntheses and Properties of Late-Metal Complexes Bearing a Boron-Based Pincer Ligand, "Heterobimetallic Compounds and their Chemistry"

    Makoto YAMASHITA

    245th ACS National Meeting  2013.4 

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    Venue:245th ACS National Meeting, New Orleans, LA, USA  

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  • シクロペンタジエノン配位子を有する一元系Ru触媒を用いた末端アルケンの直鎖選択的ヒドロホルミル化/水素化による直鎖アルコール合成 International conference

    高橋 講平, 山下 誠, 野崎 京子

    日本化学会第93春季年会  2013.3 

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    Venue:立命館大学びわこ・くさつキャンパス  

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  • Nucleophilic Boron Reagent, Boryl Anions: Syntheses, Properties, and Applications

    Makoto YAMASHITA

    2011.12 

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  • Chirality Switch of NCN-Pincer Rh Complexes Containing Secondary Amino Ligands

    Jun-ichi Ito, Siti Rokiah, Hisao Nishiyama

    The 18th Japan-Korea Joint Symposium on Organometallic and Coordination Chemistry  2018.11 

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  • ネオペンチル置換PCPピンサー型配位子を有するイリジウム錯体の合成と炭化水素の脱水素化反応へ向けた応用 International conference

    谷口 諒, 山下 誠, 野崎 京子

    第61回錯体化学討論会  2011.9 

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    Venue:岡山理科大学 岡山  

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  • Nucleophilic Boron Reagent, Boryl Anions: Syntheses, Properties, and Applications

    Makoto YAMASHITA

    5th China-Japan Joint Symposium on Functional Supramolecular Architectures  2011.10 

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    Venue:Beijing  

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  • ジボラン(4)ジアニオンおよびその遷移金属錯体の合成と構造 International conference

    秋山世治, 山下誠

    第29回基礎有機化学討論会  2018.9 

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  • Syntheses and properties of transition metal complexes bearing a boron-based PBP-pincer ligand

    Makoto YAMASHITA

    IME Boron XIV  2011.9 

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    Venue:Naiagarafalls, Ontario, Canada  

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  • 14族元素上に様々な置換基を持つ高周期14族元素含有ベンゼンの合成 International conference

    海谷河音, 鈴木克規, 山下誠

    第22回ケイ素化学協会シンポジウム  2018.10 

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  • Synthesis and Properties of Lithium Boryltrihydroborate

    Yoshitaka Aramaki, Makoto Yamashita, Shau-Hua Ueng, Max Maracria, Emmanuel Lacote, Dennis P. Curran, Kyoko Nozaki

    IME Boron XIV  2011.9 

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    Venue:Naiagarafalls, Ontario, Canada  

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  • 無置換9,10-ジヒドロ-9-アザ-10-ボラアントラセンの合成、構造および反応性 International conference

    石川祐太朗, 根間慎也, 林晃平, 鈴木克規, 山下誠

    第29回基礎有機化学討論会  2018.9 

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  • Syntheses and properties of transition metal complexes bearing a boron-based PBP-pincer ligand

    Makoto YAMASHITA

    43rd IUPAC World Chemistry Congress  2011.7 

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    Venue:Puerto Rico Convention Center. San Juan  

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  • アニオン性アルミナベンゼンと求電子剤の反応 International conference

    久野真揮, 鈴木克規, 仲村太智, 山下誠

    第29回基礎有機化学討論会  2018.9 

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  • Rational Design of Ru-Catallysts for normal-Selective Hydroformylation and Tandem Hydroformylation/Hydrogenation (合理的にデザインしたRu触媒による直鎖選択的ヒドロホルミル化とタンデム型ヒドロホルミル化/水素化) International conference

    高橋 講平, 山下 誠, 田中 善幸, 野崎 京子

    第58回有機金属化学討論会  2011.9 

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    Venue:名古屋大学千種キャンパス 愛知  

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  • ボリルリチウムを用いた直鎖状ホウ素化合物の合成と性質 International conference

    八木篤実, 木須遥規, 山下誠

    第29回基礎有機化学討論会  2018.9 

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  • ビスマベンゼンと求電子剤との反応 International conference

    難波叶帆, 石井拓弥, 鈴木克規, 山下誠

    第29回基礎有機化学討論会  2018.9 

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  • 石炭ピッチを発光層に用いた有機EL International conference

    木村 翔, 山岡美貴, 福田武司, 本多善太郎, 鎌田憲彦, 浅見俊介, 山下 誠

    2012年春季 第59回 応用物理学関係連合講演会  2012.3 

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    Venue:早稲田大学, 東京  

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  • PBPピンサー型配位子を有する白金錯体の合成と性質 International conference

    小川 隼人, 山下 誠

    日本化学会第92春季年会  2012.3 

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    Venue:慶応大学日吉キャンパス 神奈川  

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  • Synthesis and Reactivity of Diborane(4) Dianion

    Seiji Akiyama, Makoto Yamashita

    International Symposium on Main Group Chemistry Directed towards Organic Synthesis (MACOS) Science  2018.8 

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  • Synthesis and Properties of Boryl-Substituted Multiple Boron-Boron Bond by Using Boryllithium

    Atsumi Yagi, Haruki Kisu, Makoto Yamashita

    International Symposium on Main Group Chemistry Directed towards Organic Synthesis (MACOS) Science  2018.8 

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  • Reactivity of Diborane(4) Dianion

    Seiji Akiyama, Makoto Yamashita

    16th Boron Chemistry Meeting in the Americas (BORAM XVI)  2018.6 

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  • Chirality Switch of NCN-Pincer Rh Complexes Containing Secondary Amino Ligands

    Jun-ichi Ito, Siti Rokiah, Hisao Nishiyama

    43rd International Conference on Coordination Chemistry  2018.8 

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  • Synthesis of Germabenzenes Having Various Aryl Groups by Reaction of in-situ Generated Chlorogermabenzene

    Canon Kaiya, Katsunori Suzuki, Makoto Yamashita

    The 15th International Symposium on Inorganic Ring Systems (IRIS-15)  2018.6 

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  • Synthesis and Structure of 9,10-Dihydro-9-aza-10-boraanthracene

    Yutaro Ishikawa, Shin-ya Nema, Kohei Hayashi, Katsunori Suzuki, Makoto Yamashita

    The 15th International Symposium on Inorganic Ring Systems (IRIS-16)  2018.6 

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  • ビスマベンゼンと求電子剤の反応 International conference

    難波叶帆, 石井拓弥, 鈴木克規, 山下誠

    第113回有機合成シンポジウム  2018.6 

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  • Reversible B2C2 Four-Membered Ring Formmation by Dimerization of Boryl- and Amino-Substituted Acetylenes

    Katsunori Suzuki, Ryo Kitamura, Makoto Yamashita

    The 15th International Symposium on Inorganic Ring Systems (IRIS-15)  2018.6 

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  • Reactions of Anionic Aluminabenzene with Electrophiles

    Masaki Kuno, Katsunori Suzuki, Taichi Nakamura, Makoto Yamashita

    International Symposium on Main Group Chemistry Directed towards Organic Synthesis (MACOS) Science  2018.8 

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  • Reactivity of Bismabenzene

    Yasuho Nanba, Takuya Ishii, Katsunori Suzuki, Makoto Yamashita

    International Symposium on Main Group Chemistry Directed towards Organic Synthesis (MACOS) Science  2018.8 

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  • Synthesis and Property of Nucleophilic Al anion

    Satoshi Kurumada, Shuhei Takamori, Makoto Yamashita

    International Symposium on Main Group Chemistry Directed towards Organic Synthesis (MACOS) Science  2018.8 

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  • Syntheses, Properties, and Catalytic Performance of Late-Transition Metal Complexes Bearing A Characteristic Multidentate Ligand International conference

    Yamashita, M

    8th RIKEN International Symposium Frontiers of Organometallic Chemistry  2012.11 

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    Venue:Suzuki Umetaro Hall, RIKEN  

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  • Syntheses and Properties of Late Transition Metal Complexes Bearing a PBP-Pincer Ligand International conference

    Makoto Yamashita

    2012.9 

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  • Organic Light-Emitting Diode Using Coal-Pitch as Emitting Layer

    T. Fukuda, M. Yamaoka, S. Asami, N. Funaki, S. Kimura, Z. Honda, N. Kamata, M. Yamashita

    International Union of Materials Research Societies - International Conference on Electronic Materials 2012  2012.9 

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    Venue:Pacifico Yokohama,Yokohama, JAPAN  

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  • PBPピンサー型配位子を有する白金錯体の合成と性質 International conference

    小川 隼人, 山下 誠

    錯体化学会第62回討論会  2012.9 

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    Venue:富山大学五福キャンパス 富山県  

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  • PBPピンサーRu錯体の合成と性質 International conference

    宮田 卓真, 山下 誠

    錯体化学会第62回討論会  2012.9 

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    Venue:錯体化学会第62回討論会 富山大学五福キャンパス 富山県  

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  • 三次元PLスペクトルを利用した石炭ピッチ溶液の分離状態評価 International conference

    木村 翔, 福田武司, 浅見俊介, 鎌田憲彦, 山下 誠

    第73回応用物理学会秋季学術講演会  2012.9 

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    Venue:愛媛大学, 松山  

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  • 新規含ホウ素複素環ラジカルの合成と性質 International conference

    荒巻 吉孝, 大宮 秀貴, 山下 誠, 中林 耕二, 大越 慎一, 野崎 京子

    第23回基礎有機化学討論会  2012.9 

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    Venue:京都テルサ 京都  

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  • 特徴的な多座配位子を有する後周期遷移金属錯体の合成と性質および触媒機能 International conference

    山下 誠

    高分子・ハイブリッド材料研究センター(PHyM)若手フォーラム  2012.12 

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    Venue:東北大学多元物質科学研究所  

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  • 含ホウ素多座配位子を有する金属錯体の構造と機能 International conference

    山下 誠

    分子研研究会「金属錯体機能の根源を探る~分子構造とその変化様式の探求最前 線」  2013.3 

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    Venue:分子科学研究所 愛知県  

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  • ホウ素置換ホスフィンの合成と性質 International conference

    浅見 俊介, 岡本 匡史, 鈴木 克規, 山下 誠

    第39回有機典型元素化学討論会  2012.12 

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    Venue:岩手大学 盛岡  

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  • Excitation-Emission Matrix Spectrum of Coal Tar Pitch Solution Separated by Soxhlet Extractor

    S. Kimura, T. Fukuda, N. Kamata, M. Yamashita

    10th International Conference in Nano-Molecular Electronics  2012.12 

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    Venue:Awaji Yumebutai International Conference Center, Awaji  

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  • Syntheses and Properties of Transition Metal Complexes Bearing a Boron-Based PBP Pincer Ligand :Effect of Boron Atom

    Makoto Yamashita

    XXV International Conference on Organometallic Chemistry (ICOMC25)  2012.9 

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    Venue:Lisbon, Portugal  

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  • Synthesis and Properties of Potassium Diaminodihydroborate with Two Tethers

    Takuma Miyada, Makoto Yamashita

    XXV International Conference on Organometallic Chemistry (ICOMC25)  2012.9 

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    Venue:Lisbon, Portugal  

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  • Bora-Brook Rearrangement: Migration of Boryl Group from Carbon to Anionic Oxygen Atom

    M. Yamashita

    The 10th International Conference on Heteroatom Chemistry  2012.5 

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    Venue:Uji, Kyoto  

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  • クロマトグラフィで分離した石炭ピッチを用いた有機EL International conference

    木村 翔, 山岡 美貴, 浅見 俊介, 福田 武司, 本多 善太郎, 鎌田 憲彦, 山下 誠

    有機エレクトロニクス研究会  2012.5 

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    Venue:NTT武蔵野研究開発センター, Tokyo, Japan  

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  • 石炭ピッチを用いた有機EL素子の作成と性能評価 International conference

    浅見 俊介, 山下 誠, 山岡 美貴, 木村 翔, 福田 武司

    日本化学会第92春季年会  2012.3 

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    Venue:慶応大学日吉キャンパス 神奈川  

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  • Reaction of Boryllithium with Boron Electrophile: Construction of Boron-Boron Bond by Nucleophilic Borylation Method International conference

    M. Yamashita

    The 3rd Tsukuba International Mini-symposium on Hybridization between Main Group Element Chemistry and π-Electron Chemistry - ICHAC-10 Pre-symposium in Tsukuba  2012.5 

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    Venue:University of Tsukuba, Ibaraki, Japan  

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  • Bora-Brook転位反応のアニオン性中間体と求電子剤との反応 International conference

    伊東 史裕, 境野 裕健, 山下 誠, 野崎 京子

    日本化学会第92春季年会  2012.3 

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    Venue:慶応大学日吉キャンパス 神奈川  

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  • Cp型配位子を有するRu錯体と二座リン配位子を用いた直鎖選択的ヒドロホルミル化触媒 International conference

    高橋 講平, 山下 誠, 田中 善幸, 野崎 京子

    日本化学会第92春季年会  2012.3 

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    Venue:慶応大学日吉キャンパス 神奈川  

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  • Tandem Hydroformylation/Hydrogenation of Terminal Alkenes to n-Alcohol Using a Rh/Ru Dual Catalyst System

    Kohei Takahashi, Makoto Yamashita, Kyoko Nozaki

    XXV International Conference on Organometallic Chemistry (ICOMC25)  2012.9 

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    Venue:Lisbon, Portugal  

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  • Separation Technique of Coal Pitch by Using Organic Solvent for Organic Light-Emitting Diode

    Takeshi Fukuda, Miki Yamaoka, Shun-suke Asami, Nayuta Funaki, Sho Kimura, Zentaro Honda, Norihiko Kamata, Makoto Yamashita

    The 2012 International Conference on Flexible and Printed Electronics  2012.9 

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    Venue:The University of Tokyo, Tokyo  

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  • Syntheses and Properties of Platinum Complexes Bearing a PBP-Pincer Ligand

    Hayato Ogawa, Makoto Yamashita

    XXV International Conference on Organometallic Chemistry (ICOMC25)  2012.9 

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    Venue:Lisbon, Portugal  

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  • Boryl-substituted diphosphene:Synthesis, structure, and physical properties.

    S. Asami, M. Okamoto, K. Suzuki, M. Yamashita

    248th ACS National Meeting  2014.8 

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    Venue:San Francisco, California  

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  • Synthesis and Reactivity of Unsymmetrical Diborane(4) Compound.

    Hiroki Asakawa, Ka Ho Lee, Zhenyang Lin, Ko Furukawa, Makoto Yamashita

    the International Meeting on Boron Chemistry (IMEBORON XV)  2014.8 

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    Venue:Czech Technical Univ.,Prague, Czech Republic  

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  • Synthesis, Characterization, and Reactions of Aluminabenzene.

    T. Nakamura, K. Suzuki, M. Yamashita

    248th ACS National Meeting  2014.8 

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    Venue:San Francisco, California  

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  • Development of synthetic method for heterabenzenes using anti-hydroalumination of 1. 4-diyne.

    T. Ishii, T. Nakamura, K. Suzuki, M. Yamashita

    248th ACS National Meeting  2014.8 

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    Venue:San Francisco, California  

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  • Synthesis and property of Ir complexes bearing an iPr-substituted PBP ligand.

    K. Tanoue, M. Yamashita

    248th ACS National Meeting  2014.8 

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    Venue:San Francisco, California  

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  • Solubilization of infusibilized coal-tar-pitch through alkylation by using Grignard reagent.

    S. Fujimoto, T. Fukuda, K. Yamagata, M. Yamashita

    248th ACS National Meeting  2014.8 

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    Venue:San Francisco, California  

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  • Generation of Boryl Anion in Saturated Hydrocarbon Using Ternary Reducing Agent.

    Takuto Osato, Yuri Okuno, Shintaro Ishida, Takeaki Iwamoto, Makoto Yamashita, Kyoko Nozaki

    the XXVI International Conference on Organometallic Chemistry  2014.7 

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    Venue:Royton Sapporo, Japan  

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  • Synthesis of π-conjugated compounds using the transformation of 9-bora-10-azaanthracene and borabenzene-Lewis base adducts.

    K. Suzuki, S. Nema, M. Noguchi, M. Yamashita

    248th ACS National Meeting  2014.8 

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    Venue:San Francisco, California  

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  • Reactivity of Unsymmetrical Diborane(4) Compound.

    Hiroki Asakawa, Ka Ho Lee, Zhenyang Lin, Ko Furukawa, Makoto Yamashita

    the XXVI International Conference on Organometallic Chemistry  2014.7 

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    Venue:Royton Sapporo, Japan  

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  • Synthesis of Anionic Aluminabenzene Bearing Aromatic and Ambiphilic Resonance Contribution .

    Taichi Nakamura, Katsunori Suzuki, Makoto Yamashita

    the XXVI International Conference on Organometallic Chemistry  2014.7 

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    Venue:Royton Sapporo, Japan  

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  • Synthesis, Structure, and Catalytic Activity of Ir Complexes Bearing an iPr-Substituted PBP Ligand for Transfer Dehydrogenation of Alkanes.

    Keita Tanoue, Makoto Yamashita

    the XXVI International Conference on Organometallic Chemistry  2014.7 

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    Venue:Royton Sapporo, Japan  

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  • Controllability of Emission Wavelength of Emissive Molecule Separated from Coal Tar Pitch.

    Takeshi Fukuda, Tomoaki Inoue, Ken-ichi Yamagata, Makoto Yamashita

    Carbon2014  2014.6 

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    Venue:International Convention Center, Jeju, KOREA  

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  • Solubilization of infusibilized coal-tar-pitch by alkylation with Grignard reagent. International conference

    Sho FUJIMOTO, Takeshi FUKUDA, Ken-ichi YAMAGATA, Makoto YAMASHITA

    NIMS Conference 2014  2014.7 

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    Venue:Tsukuba International Congress Center, Ibaraki  

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  • 反応剤を用いたアルキル化による不融化石炭ピッチの可溶化と固体および溶液物性解明 International conference

    藤本 翔, 福田 武司, 山形 憲一, 山下 誠

    第3回 JACI/GSC シンポジウム  2014.5 

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    Venue:東京国際フォーラム 東京  

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  • 側鎖の長いP-B-P ピンサーIr 錯体の合成 International conference

    河合 泰志, 鎌倉 聖, 山下 誠

    第3回 JACI/GSC シンポジウム  2014.5 

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    Venue:東京国際フォーラム 東京  

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  • 遷移金属非存在下での末端アルキンのジボリル化反応 International conference

    小島千絵美, 山下誠

    第67回有機合成化学協会関東支部シンポジウム  2014.5 

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    Venue:慶應義塾大学  

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  • ホウ素および窒素置換基を有するシクロブタジエンの合成と構造 International conference

    小沼郁, 鈴木克規, 山下誠

    第67回有機合成化学協会関東支部シンポジウム  2014.5 

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    Venue:慶應義塾大学  

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  • 遷移金属非存在下での末端アルキンのジボリル化反応 International conference

    小島千絵美, 山下誠

    日本化学会第94春季年会  2014.3 

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    Venue:名古屋大学 東山キャンパス  

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  • 新規非対称diborane(4)を用いた三重結合切断反応と機構解析 International conference

    浅川博祈, 山下誠

    日本化学会第94春季年会  2014.3 

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    Venue:名古屋大学 東山キャンパス  

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  • 三成分系還元剤を用いた飽和炭化水素溶液中でのボリルアニオン発生 International conference

    大里拓人, 奥野友里, 山下誠, 野崎京子

    日本化学会第94春季年会  2014.3 

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    Venue:名古屋大学 東山キャンパス  

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  • 非対称diborane(4)を用いたアルキンの直接ジボリル化反応における位置選択性制御 International conference

    小島千絵美, 山下 誠

    日本化学会秋季事業第4回CSJ化学フェスタ2014  2014.10 

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    Venue:タワーホール船堀 東京  

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  • Synthesis and Application of Ir Complexes Bearing an iPr-substituted PBP Ligand. International conference

    Keita Tanoue, Makoto Yamashita

    the Conference on C-C Bond Cleavage (CCCC)  2014.10 

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    Venue:Katsura Hall KYOTO Univ. KYOTO  

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  • ボラベンゼンの反応性を鍵としたホウ素ー窒素含有共役系化合物の合成研究 International conference

    野口真緒, 鈴木克規, 山下 誠

    日本化学会秋季事業第4回CSJ化学フェスタ2014  2014.10  タワーホール船堀 東京

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  • 1,4-ジインのヒドロアルミニウム化を用いたホスファベンゼンの効率的合成法の開発 International conference

    石井 拓弥, 鈴木 克規, 山下 誠

    日本化学会秋季事業第4回CSJ化学フェスタ2014  2014.10 

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    Venue:タワーホール船堀 東京  

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  • 溶媒和のないボリルアニオンによるベンゼンの脱プロトン化 International conference

    大里拓人, 奥野友里, 石田真太郎, 岩本武明, 山下 誠, 野崎京子

    日本化学会秋季事業第4回CSJ化学フェスタ2014  2014.10 

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    Venue:タワーホール船堀 東京  

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  • ホウ素置換アルコキシドのbora-Brook転位反応 International conference

    木須遥規, 山下 誠, 伊東史裕, 境野裕健, 野崎京子

    日本化学会秋季事業第4回CSJ化学フェスタ2014  2014.10 

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    Venue:タワーホール船堀 東京  

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  • 溶媒和の無いボリルアニオンの合成と性質 International conference

    大里拓人, 奥野友里, 石田真太郎, 岩本武明, 山下誠, 野崎京子

    第61回有機金属化学討論会  2014.9 

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    Venue:九州大学医学部 百年講堂(福岡県福岡市)  

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  • iPr基が置換したPBP配位子を有するIr錯体の合成・構造・アルカン脱水素化反応に対する触媒活性 International conference

    田上景太, 山下誠

    第61回有機金属化学討論会  2014.9 

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    Venue:九州大学医学部 百年講堂(福岡県福岡市)  

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  • Grignard反応剤を用いたアルキル化による不融化石炭ピッチの可溶化と固体および溶液物性解明 International conference

    藤本 翔, 福田 武司, 山形 憲一, 山下 誠

    第75回応用物理学会秋季学術講演会  2014.9 

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    Venue:北海道大学札幌キャンパス  

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  • アニオン性アルミナベンゼン配位子を持つZr錯体の合成 International conference

    仲村太智, 鈴木 克規, 山下 誠

    錯体化学会第64回討論会  2014.9 

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    Venue:中央大学後楽園キャンパス 東京  

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  • Synthesis of Long-Tethered P-B-P Ir complex Having a Boron-Containing Ligand and Its Application to Catalysic Dehydrogenation of Alkane. International conference

    Yasushi Kawai, Sei Kamakura, Makoto Yamashita

    the Conference on C-C Bond Cleavage (CCCC)  2014.10 

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    Venue:Katsura Hall KYOTO Univ. KYOTO  

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  • 窒素ホウ素置換シクロブタジエンの合成と構造 International conference

    小沼郁, 鈴木克規, 山下誠

    第25回基礎有機化学討論会  2014.9 

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    Venue:東北大学川内北キャンパス 宮城県仙台市  

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  • アニオン性アルミナベンゼンの合成、構造解析およびその反応性 International conference

    仲村太智, 鈴木 克規, 山下 誠

    第25回基礎有機化学討論会  2014.9 

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    Venue:東北大学川内北キャンパス 宮城県仙台市  

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  • 非対称ジボラン(4)の1電子還元によるアニオンラジカルの合成と性質 International conference

    浅川 博祈, 山下誠, Lee Ka Ho, Lin, Ahenyang,古川貢

    第25回基礎有機化学討論会  2014.9 

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    Venue:東北大学川内北キャンパス 宮城県仙台市  

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  • Diboration of Alkynes in the Absence of Transition Metals.

    Chiemi KOJIMA, M. Yamashita

    the International Meeting on Boron Chemistry (IMEBORON XV)  2014.8 

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    Venue:Czech Technical Univ.,Prague, Czech Republic  

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  • 非対称ジボランを用いたアルキンのジボリル化反応 International conference

    小島千絵美, 山下誠

    第25回基礎有機化学討論会  2014.9 

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    Venue:東北大学川内北キャンパス 宮城県仙台市  

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  • Generation of Boryl Anion in Saturated Hydrocarbon Using Ternary Reducing Agent.

    T. OSATO, Y. OKUNO, S. ISHIDA, T. IWAMOTO, M. Yamashita, K.NOZAKI

    the International Meeting on Boron Chemistry (IMEBORON XV)  2014.8 

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    Venue:Czech Technical Univ.,Prague, Czech Republic  

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  • SYNTHESIS AND STRUCTURE OF B,N-SUBSTITUTED CYCLOBUTADIENE.

    Kaoru Onuma, Katsunori Suzuki, M. Yamashita

    the International Meeting on Boron Chemistry (IMEBORON XV)  2014.8 

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    Venue:Czech Technical Univ.,Prague, Czech Republic  

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  • Bora-Brook Rearrangement in Ambident Boryl-substituted Alkoxide: Migration of A Boryl Group from Carbon Atom to Oxigen Atom.

    Haruki Kisu, Makoto Yamashita, Fumihiro Ito, Hirotoshi Sakaino, Kyoko Nozaki

    the International Meeting on Boron Chemistry (IMEBORON XV)  2014.8 

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    Venue:Czech Technical Univ.,Prague, Czech Republic  

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  • Synthesis, Structure, and Photophysical Properties of Chloro- Substituted 9-Aza-10-boraanthracene Derivative.

    Shin-ya NEMA, Katsunori SUZUKI, M. Yamashita

    the International Meeting on Boron Chemistry (IMEBORON XV)  2014.8 

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    Venue:Czech Technical Univ.,Prague, Czech Republic  

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  • 多環式芳香族炭化水素が置換したゲルマベンゼンの合成と性質 International conference

    海谷河音, 鈴木克規, 山下誠

    日本化学会 第98春季年会  2018.3 

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    Venue:日本大学 理工学部 船橋キャンパス  

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  • バナジル錯体による超臨界メタンの酸素酸化 International conference

    山田海人, 中野遼, 山下誠

    日本化学会 第99春季年会  2019.3 

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  • ホウ素窒素置換アセチレンと有機ホウ素化合物の反応 International conference

    小林 明弥, 北村 亮, 鈴木 克規, 山下誠

    日本化学会 第99春季年会  2019.3 

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  • テトラアリールジボラン(4)ジアニオンの反応性 International conference

    秋山世治, 山下誠

    日本化学会 第99春季年会  2019.3 

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  • ジアニオン性ビ(アルミナベンゼン)の合成と構造 International conference

    久野真揮, 鈴木克規, 仲村太智, 山下誠

    日本化学会 第99春季年会  2019.3 

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  • アルキルアミノハロボランの合成及び還元反応 International conference

    木須遥規, 小齋智之, 岩本武明, 山下誠

    日本化学会 第99春季年会  2019.3 

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  • ビ(ビスマベンゼン)の合成、構造および物性 International conference

    難波叶帆, 石井拓弥, 鈴木克規, 山下誠

    日本化学会 第99春季年会  2019.3 

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  • 単離可能なスタンナベンゼンの合成及び構造 International conference

    海谷河音, 鈴木克規, 山下誠

    日本化学会 第99春季年会  2019.3 

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  • N-ヘテロ環カルベンにより安定化されたアザボラアントラセンの合成、構造および反応 International conference

    石川祐太朗, 鈴木克規, 山下誠

    日本化学会 第99春季年会  2019.3 

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  • P-Al-Pピンサー型Ir錯体の合成と触媒反応への応用 International conference

    森迫 祥吾, 渡邉 聖也, 山下 誠

    日本化学会 第99春季年会  2019.3 

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  • テトラNHCマクロサイクル配位子を有する後周期金属錯体の合成および構造 International conference

    小森彩香, 伊藤淳一, 山下誠

    日本化学会 第99春季年会  2019.3 

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  • プルンバベンゼニルアニオンの合成 International conference

    海谷河音, 鈴木克規, 山下誠

    第45回有機典型元素化学討論会  2018.12 

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  • 塩素置換9-アザ-10-ボラアントラセンの合成とその誘導化 International conference

    石川祐太朗, 根間慎也, 林晃平, 鈴木克規, 山下誠

    第45回有機典型元素化学討論会  2019.3 

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  • 求核的2配位アルミニウムアニオンの反応性 International conference

    車田怜史, 高森修平, 山下誠

    第49回 中部化学関係学協会支部連合秋季大会  2018.11 

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  • 環状アルキルアミノボリルアニオンの合成研究 International conference

    木須遥規, 小齋智之, 岩本武明, 山下誠

    第45回有機典型元素化学討論会  2018.12 

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  • 多重結合性ホウ素化合物の合成と反応性 International conference

    森迫 祥吾, Shang Rong, 山本 陽介, 松井 啓史, 中野 雅由, 山下 誠

    第49回 中部化学関係学協会支部連合秋季大会  2018.11 

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  • ビスマベンゼンにおける求電子置換反応の解明 International conference

    難波叶帆, 石井拓弥, 鈴木克規, 山下誠

    第49回 中部化学関係学協会支部連合秋季大会  2018.11 

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  • ジボラン(4)ジアニオンの合成と反応 International conference

    秋山世治, 山下誠

    第49回 中部化学関係学協会支部連合秋季大会  2018.11 

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  • マクロサイクル骨格を有するポリN-ヘテロ環状カルベン錯体の合成および構造 International conference

    小森彩香, 伊藤淳一, 山下誠

    第49回 中部化学関係学協会支部連合秋季大会  2018.11 

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  • Group 9 Complexes Bearing A P-Al-P Pincer Ligand

    Shogo Morisako, Seiya Watanabe, Makoto Yamashita

    The 18th Japan-Korea Joint Symposium on Organometallic and Coordination Chemistry  2018.11 

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  • テトラアリールジボラン(4)と酸素置換11族金属錯体との反応 International conference

    鈴木あかね, 山下誠

    日本化学会 第99春季年会  2019.3 

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  • Synthesis of BCN Graphite Using BN-Containing π-Conjugated Systems as a Precursor

    Jun Kobayashi, Katsunori Suzuki, Yoshiyuki Sugahara, Makoto Yamashita

    16th International Meeting on Boron Chemistry (IMEBORON-16)  2017.7 

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    Venue:Chinese University of Hong Kong  

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  • BN含有π共役系化合物を前駆体としたBCNグラファイトの合成と物性評価 International conference

    小林純, 鈴木克規, 菅原義之, 山下誠

    第6回JACI/GSCシンポジウム  2017.7 

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    Venue:東京国際フォーラム  

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  • Reaction of Lewis Acidic Diborane(4) with Nitrogen-Containing Heterocycles inthe Presence of Isocyanide

    Yuhei Katsuma, Hiroki Asakawa, Makoto Yamashita

    16th International Meeting on Boron Chemistry (IMEBORON-16)  2017.7 

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    Venue:Chinese University of Hong Kong  

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  • PNPピンサーIrまたはRh錯体を触媒としたアルカンの脱水素化反応 International conference

    中山 真, 山下 誠

    第6回JACI/GSCシンポジウム  2017.7 

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    Venue:東京国際フォーラム  

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  • イソシアニド存在下でのルイス酸性ジボラン(4)と含窒素複素環の反応 International conference

    勝間雄平, 浅川博祈, 山下誠

    第6回JACI/GSCシンポジウム  2017.7 

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    Venue:東京国際フォーラム  

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  • Reaction of Lewis Acidic Diborane(4) with Nitrogen-Containing Heterocycles inthe Presence of Isocyanide

    Yuhei Katsuma, Hiroki Asakawa, Makoto Yamashita

    2017.6 

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    Venue:University of British Columbia (UBC)  

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  • Synthesis of BCN Graphite Using BN-Containing π-Conjugated Systems as Precursors

    Jun Kobayashi, Katsunori Suzuki, Yoshiyuki Sugahara, Makoto Yamashita

    12th International Conference on Herero Atom Chemistry (ICHAC-12)  2017.6 

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    Venue:University of British Columbia (UBC)  

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  • ホウ素、窒素置換アセチレンの合成と二量体形成反応 International conference

    北村亮, 鈴木克規, 山下誠

    日本化学会第97春季年会  2017.3 

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  • Synthesis and Catalytic Activity of Aluminabenzene-Rh and -Ir Complexes

    Taichi Nakamura, Katsunori Suzuki, Makoto Yamashita

    12th International Conference on Herero Atom Chemistry (ICHAC-12)  2017.6 

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  • ホウ素および窒素上が官能基変換可能な9-アザ-10-ボラアントラセンの合成および反応 International conference

    石川祐太朗, 根間慎也, 林晃平, 鈴木克規, 山下誠

    日本化学会第97春季年会  2017.3 

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  • ジボリルジホスフェンジアニオンの合成・構造・反応性 International conference

    浅見俊介, 鈴木克規, 山下誠

    日本化学会第97春季年会  2017.3 

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  • テトラアリールジボラン(4)と水素分子の反応機構解析 International conference

    塚原菜那, 浅川博祈, 山下誠・Lee Ka-Ho・Lin Zhenyang

    日本化学会第97春季年会  2017.3 

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  • BN含有π共役系を前駆体としたBNドープグラファイトの合成 International conference

    小林純, 鈴木克規, 菅原義之, 山下誠

    第43回有機典型元素化学討論会  2016.12 

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    Venue:仙台市民会館 宮城県仙台市  

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  • BN含有π共役系分子を前駆体としたBCNグラファイトの合成と物性評価 International conference

    小林純, 鈴木克規, 菅原義之, 山下誠

    日本化学会第97春季年会  2017.3 

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  • テトラアリールジボン(4)による水素分子直接切断反応 International conference

    塚原菜那, 浅川博祈, 山下誠・Lee Ka-Ho・Lin Zhenyang

    第43回有機典型元素化学討論会  2016.12 

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    Venue:仙台市民会館 宮城県仙台市  

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  • ホウ素、窒素置換シクロブタジエンと求電子剤の反応 International conference

    北村亮, 小沼郁, 鈴木克規, 山下誠

    第43回有機典型元素化学討論会  2016.12 

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    Venue:仙台市民会館 宮城県仙台市  

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  • テトラピロリルジボラン(4)の合成と反応性 International conference

    浅沼 秀治, 山下 誠

    日本化学会秋季事業第6回CSJ化学フェスタ2016  2016.11 

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    Venue:タワーホール船堀 東京  

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  • 豊かな社会を目指して元素を精密に操る合成化学 International conference

    山下 誠

    日本化学会秋季事業第6回CSJ化学フェスタ2016  2016.11 

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    Venue:タワーホール船堀 東京  

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  • PNPピンサーIrおよびRh錯体を用いたアルカンの触媒的脱水素化反応 International conference

    中山 真, 山下 誠

    日本化学会秋季事業第6回CSJ化学フェスタ2016  2016.11 

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    Venue:タワーホール船堀 東京  

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  • イソシアニド存在下での含窒素複素環化合物と非対称ジボラン(4)との反応 International conference

    勝間 雄平, 浅川 博祈, 山下 誠

    日本化学会秋季事業第6回CSJ化学フェスタ2016  2016.11 

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    Venue:タワーホール船堀 東京  

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  • 求核的アルミニウムアニオンR2Al-の合成と性質 International conference

    車田怜史, 高森修平, 山下誠

    第113回有機合成シンポジウム  2018.6 

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Industrial property rights

  • 有機電子デバイス及びその製造方法

    福田武司, 菱沼賢智, 山下誠, 山形憲一

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    Application no:2016-034062  Date applied:2016.2

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  • 可溶化炭素材の製造方法

    山下誠, 藤本翔, 福田武司, 山形憲一

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    Application no:2015-171990  Date applied:2014.2

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  • 有機EL素子およびその製造方法

    山下誠, 福田武司

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    Application no:2012-039202  Date applied:2012.2

    Announcement no:2013-175600 

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  • アルデヒドの製造方法及びアルコールの製造方法

    田中善幸, 山下誠, 野崎京子

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    Application no:2011-228100  Date applied:2011.10

    Announcement no:2012-188413  Date announced:2012.10

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  • ビニル系モノマー重合用触媒組成物および該組成物を用いたビニル系モノマーの重合へ の使用

    野崎京子, 山下誠, 井田大嗣, 魚住俊也

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    Application no:2011-113568  Date applied:2011.5

    Announcement no:2011-170912  Date announced:2011.9

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  • アルコールの製造方法

    田中善幸, 山下誠, 野崎京子

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    Application no:2009-150069  Date applied:2009.6

    Announcement no:2010-215604  Date announced:2010.9

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  • フルオロスルホニル基を有するノルボルネン重合体の製造方法、スルホン酸基を有する重 合体および該重合体を用いた燃料電池用電解質膜

    室谷英介, 山下誠, 野崎京子

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    Application no:2006-269306  Date applied:2006.6

    Announcement no:2008-88247  Date announced:2008.4

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  • ビニル系モノマー重合用触媒組成物および該組成物を用いたビニル系モノマーの重合への使用

    野崎京子, 山下誠, 井田大嗣, 魚住俊也

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    Application no:2005-059697  Date applied:2005.3

    Announcement no:2006-241325  Date announced:2006.9

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  • ビニル系モノマー重合用担持型触媒組成物および該組成物を用いたビニル系モノマーの 重合への使用

    野崎京子, 山下誠, 井田大嗣, 魚住俊也

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    Application no:2005-59697  Date applied:2005.3

    Announcement no:2006-241326  Date announced:2006.9

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Awards

  • Humboldt Research Award

    2024.6   Alexander Humboldt Foundation  

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  • 学術賞

    2024.4   日本化学会  

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  • JSPS Prize

    2020.2   Japan Society for the Promotion of Science   Creation of Highly Reactive Boron Compounds and Elucidation of Their Characteristic Reactivity

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    Country:Japan

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  • 特別研究員等審査会専門委員(書面担当)表彰

    2015.8   日本学術振興会  

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    Country:Japan

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  • Thieme Chemistry Journal Award 2015

    2015.1   Thieme  

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    Award type:Award from Japanese society, conference, symposium, etc.  Country:Japan

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  • 長瀬研究振興賞

    2012.6   長瀬科学技術振興財団   石炭抽出混合物を用いた有機合成化学不要の超格安有機デバイス作成法開発

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    Award type:Honored in official journal of a scientific society, scientific journal  Country:Japan

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  • 三井化学研究企画賞

    2010.12   有機合成化学協会   ホウ素を鍵元素とする配位子群を用いた炭化水素変換反応触媒の開発

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    Country:Japan

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  • Banyu Chemist Award 2010

    2010.11  

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    Award type:Honored in official journal of a scientific society, scientific journal  Country:Japan

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  • 東京大学グローバルCOE若手海外レクチャーシップ賞

    2010.10   東京大学GCOE「理工連携による化学イノベーション」   Chemsitry of Boryl Anion: Nucleophilic Boron Reagents

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    Country:Japan

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  • 文部科学大臣表彰若手科学者賞

    2009.4   文部科学省   新規ホウ素求核種ボリルアニオンの研究

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    Country:Japan

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  • 日本化学会進歩賞

    2009.3   日本化学会   求核的ボリルアニオン類の創製とその特性

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    Award type:Award from international society, conference, symposium, etc.  Country:Japan

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  • 日本化学会第87春季年会「第22回若い世代の特別講演会」講演賞

    2008.3   日本化学会   ボリルアニオンの合成、構造、反応性と応用

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    Award type:Award from international society, conference, symposium, etc.  Country:Japan

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  • 武田薬品工業研究企画賞

    2005.12   有機合成化学協会   新しいアニオン性ホウ素求核種リチウムボラニドを用いた含ホウ素化合物の系統的合成とその応用

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    Country:Japan

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  • 井上研究奨励賞

    2005.2   井上科学振興財団   超原子価5配位炭素およびホウ素化合物の合成と構造

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    Award type:Honored in official journal of a scientific society, scientific journal  Country:Japan

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  • 第15回基礎有機化学連合討論会ポスター賞

    2000.9   第15回基礎有機化学連合討論会実行委員会   剛直な構造を持つ新規3座配位子系における超原子価5配位炭素、ホウ素種(10-C-5, 10-B-5)の生成とその構造

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Research Projects

  • 結合性空軌道:空の原子軌道の組み合わせが創り出す新構造・新反応・新機能

    Grant number:24H00455  2024.4 - 2028.3

    日本学術振興会  科学研究費助成事業  基盤研究(A)

    山下 誠

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    Grant amount:\48490000 ( Direct Cost: \37300000 、 Indirect Cost:\11190000 )

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  • 普遍金属-Al錯体触媒を用いるC-Hアルミニウム化反応の開拓

    Grant number:24KF0040  2024.4 - 2026.3

    日本学術振興会  科学研究費助成事業  特別研究員奨励費

    山下 誠

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    Grant amount:\2100000 ( Direct Cost: \2100000 )

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  • Electronic perturbation of organic &#120587;-functional molecules using bonding vacant orbitals

    Grant number:23K17915  2023.6 - 2025.3

    Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research  Grant-in-Aid for Challenging Research (Exploratory)

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    Grant amount:\6500000 ( Direct Cost: \5000000 、 Indirect Cost:\1500000 )

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  • Construction of highly-condensed N6 conjugated systems and integration of &#120587;-conjugate molecules based on unique B2N6 skeleton

    Grant number:23H04022  2023.4 - 2025.3

    Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research  Grant-in-Aid for Transformative Research Areas (A)

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    Grant amount:\7800000 ( Direct Cost: \6000000 、 Indirect Cost:\1800000 )

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  • Development of general synthetic method for tetraarylammonium salts

    Grant number:21K18955  2021.7 - 2023.3

    Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research  Grant-in-Aid for Challenging Research (Exploratory)

    Yamashita Makoto

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    Grant amount:\6500000 ( Direct Cost: \5000000 、 Indirect Cost:\1500000 )

    In this study, in order to establish a method for synthesizing tetraarylammonium salts, we investigated three different synthetic pathways including characteristic intermediates. These approaches include (1) azasilatriptycene and azaphosphatriptycene, (2) o-bromophenylsilyl-substituted triarylamines, and (3) azaboranthracene. In the synthetic pathway (2), the reaction of the key intermediate, o-bromophenylsilyl-substituted triarylamine, with Pd(0) complex gave a product in which the resulting C-Pd bond and the pyramidalized nitrogen atom of the triarylamine are close to each other. However, the C-N bond reductive elimination reaction from this product could not be observed. We believe that it may be possible to obtain the desired product by induction of the C-N reductive elimination by using further transmetallation or oxidation.

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  • Simultaneous utilization of vacant and filled orbitals of group 13 element compounds in low oxidation state: novel reaction and photoelectronic property

    Grant number:21H01915  2021.4 - 2024.3

    Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research  Grant-in-Aid for Scientific Research (B)

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    Grant amount:\17420000 ( Direct Cost: \13400000 、 Indirect Cost:\4020000 )

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  • Synthesis of oxygen-substituted Al anion bearing reaction space and its application

    Grant number:20F20337  2020.11 - 2023.3

    Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research  Grant-in-Aid for JSPS Fellows

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    Grant amount:\2300000 ( Direct Cost: \2300000 )

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  • 二面性を持つアルミニウム化学種:アルマニルアニオンを用いた異種金属間化合物の合成

    2019.10 - 2020.9

    大幸財団  第29回自然科学系学術研究助成 

    山下 誠

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  • 超臨界メタンを基質兼媒質とした均一系・不均一系触媒プロセスの開発

    2017.10 - 2022.3

    文部科学省  戦略的創造研究推進事業 

    山下 誠, 山口 和也

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    本研究では、超臨界メタンを基質兼媒質として均一系・不均一系の触媒を反応させ、従来プロセスでは達成できなかった低温運転、高選択性のメタン転化反応プロセスの開拓を目指す。通常の均一系触媒反応における気液間での平衡が存在する条件や、不均一系触媒反応における気体フロー条件では反応速度が遅いが、超臨界メタンを利用することで基質濃度の上昇とこれに伴う反応速度の向上が期待できることが本研究の最も際立った特徴である。また本研究では超臨界メタン中での均一系触媒の振る舞いをNMRにより直接観測することで、触媒の構造活性相関を解明し、触媒構造改変による触媒活性及び選択性の向上を目指す。合わせて不均一系触媒表面の反応の解析を各種手法を駆使して行う。また、超臨界状態のON/OFFを加圧・減圧により制御して均一系触媒を分離する手法を確立できれば、固体触媒を凌駕するレベルで実プロセスを構築できる可能性がある。主に標的とする反応はメタンの酸化的脱水素カップリングによる高級アルカンへの転化、メタンの酸化反応によるメタノールの選択的合成、である。具体的に検討する研究項目は以下の6種を設定した。
    A. バッチ反応による均一系触媒と超臨界メタンの反応の生成物解析
    B. フロー反応による不均一系触媒と超臨界メタンの反応の生成物解析
    C. 新規触媒ライブラリの構築
    D. 高圧NMR測定を用いた超臨界メタンの素反応解析
    E. 超臨界メタンの反応後の固体触媒表面解析
    F. メタン超臨界状態の可逆制御と連続バッチプロセスの開発:圧力可変容器との組み合わせ

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  • Creation of highly reactive boron compounds by thorough utilization of vacant orbital

    Grant number:17H01191  2017.4 - 2020.3

    Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research  Grant-in-Aid for Scientific Research (A)

    YAMASHITA Makoto

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    Grant type:Competitive

    A cyclic aluminum compound was found to be a precursor of a nucleophilic Al-centered anion. After the isolation of the Al anion, its structure, reactivity, and spectroscopic properties were disclosed. As a part of the research about boryl anion, synthetic study on C,N-substituted boryl anion and synthesis of multiple-bonded main group element compounds having boryl substituents were investigated. On the other hand, (o-tol)2B-B(o-tol)2 was synthesized as a new diborane(4) compound. The remarkable reactivity of (o-tol)2B-B(o-tol)2 toward H2, CO, and N=N double bond was also revealed with a support of DFT calculations providing mechanistic insights. Throughout the research, we could demonstrate the characteristics of the vacant orbital of these compounds providing rare modes of reactions. Therefore, the initial purpose of this research project was well-achieved.

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  • 超臨界メタンを基質兼媒質とした均一系触媒プロセス開発

    2016.10 - 2017.3

    文部科学省  戦略的創造研究推進事業 

    山下 誠

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    Authorship:Principal investigator  Grant type:Competitive

    Grant amount:\3900000 ( Direct Cost: \3000000 、 Indirect Cost:\900000 )

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  • 多元素協働触媒による分子変換手法の創出

    2014.10 - 2020.3

    文部科学省  戦略的創造研究推進事業 

    中尾 佳亮, 中尾佳亮, 榊茂好

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    Grant type:Competitive

    Grant amount:\93210000 ( Direct Cost: \71700000 、 Indirect Cost:\21510000 )

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  • 石炭ピッチを用いた有機デバイス構築法開発

    2014.7 - 2016.3

    企業からの受託研究 

    山下 誠

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    Authorship:Principal investigator  Grant type:Competitive

    Grant amount:\4000000

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  • 高反応性diborane(4)化合物によるメタルフリー多重結合切断反応:ホウ素置換基の効果解明へ向けて

    2014.4 - 2017.3

    旭硝子財団  若手継続グラント 

    山下 誠

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    Authorship:Principal investigator  Grant type:Competitive

    Grant amount:\6000000 ( Direct Cost: \6000000 )

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  • Precise elucidation of effect of boryl substituents: novel reactivity caused by a vacant orbital

    Grant number:26288019  2014.4 - 2017.3

    Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research  Grant-in-Aid for Scientific Research (B)

    YAMASHITA Makoto

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    Grant amount:\17030000 ( Direct Cost: \13100000 、 Indirect Cost:\3930000 )

    Throughout this research, we obtained the following research results. (1) an ate complex of Li having two boryl anions can deprotonate H2 and benzene, boryl substituted alcohols induce Brook-type rearrangement under basic conditions, nBuLi adducts, radical anion, and dianion derived from a boryl-substituted diphosphene can be stabilized by the substituent effect of boryl groups, (2) an unsymmetrical diborane(4) cleaves the triple bond of CO and isocyanide, the unsymmetrical diborane(4) reacts with alkynes to give the corresponding diborylalkenes, unsymmetrical diborane(4) reacts with isocyanide to induce a ring contraction of Bpin, symmetrical diborane(4) directly reacts with H2.

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  • Solubilization and controlling physical properties of coal-tar-pitch as a source for carbon fiber: toward establishment of "bottom-up bulk chemistry"

    Grant number:26620185  2014.4 - 2016.3

    Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research  Grant-in-Aid for Challenging Exploratory Research

    YAMASHITA Makoto

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    Authorship:Principal investigator  Grant type:Competitive

    Grant amount:\3900000 ( Direct Cost: \3000000 、 Indirect Cost:\900000 )

    Fibers of coal-tar-pitch was heated under the air in an electric tube furnace to produce infusible pitch. Higher heating temperature led to higher oxygen contents in the resulting infusible pitch and the main source of the oxygen can be attributed to carbonyl functionality. The infusible pitch was further treated with alkyl Grignard reagent to form alkylated pitch, in which hydroxy groups were observed. Upon alkylation, solubility was improved and maxima of absorption and emission were shifted to the longer wavelength region. Alkylated pitch made at higher temperature exhibited higher molecular weight. Irradiation of the alkylated pitch to microwave induced dehydration reaction. The temperature for 10% weight loss of dehydrated pitch depended on the conditions to prepare the infusible pitch.

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  • 有機元素化学における含ホウ素新奇化合物群の創製と応用

    2013.4 - 2016.3

    日本私立学校振興・共済事業団  学術研究振興資金 

    山下 誠

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    Authorship:Principal investigator  Grant type:Competitive

    Grant amount:\17900000 ( Direct Cost: \17900000 )

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  • Synthesis and Properties of pi-Conjugated Compounds Based on Borabenzene-Lewis Base Adducts

    Grant number:25810029  2013.4 - 2015.3

    Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research  Grant-in-Aid for Young Scientists (B)

    SUZUKI Katsunori, YAMASHITA Makoto

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    Grant amount:\4420000 ( Direct Cost: \3400000 、 Indirect Cost:\1020000 )

    We have investigated the synthetic approach to the conjugated systems by using the Lewis acid-base interaction between borabenzene and pyridine derivatives. In this studies, we also found the novel cyclization reaction of 1,5-bis(silyl)-1,4-diyne with DIBAL-H and dibutyltin dichloride. Using this cyclization, an anionic aluminabenzene was synthesized for the first time. The unique aromatic character described by the resonance structure between aromatic and ambiphilic contributions have been revealed by experimental and theoretical studies. In addition, the first aluminabenzene zirconium complexes were also synthesized and characterized.

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  • ボリン酸類を中心とした含ホウ素有機化合物の製法検討及びそれらの新規用途探索

    2013.3 - 2015.3

    企業からの受託研究 

    山下 誠

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    Authorship:Principal investigator  Grant type:Competitive

    Grant amount:\1000000

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  • Stimuli-responsive Chemical Species for the Creation of Functional Molecules

    Grant number:24109001  2012.6 - 2017.3

    Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research  Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

    Yamamoto Yohsuke, MATSUO TSUKASA, IWAMOTO TAKEAKI, YAMAGO SHIGERU, SEKIGUCHI AKIRA, YAMAGUCHI SHIGEHIRO, ABE MANABU, IKEDA HIROSHI, OZAWA FUMIYUKI, HASHIMOTO HISAKO, YAMASHITA MAKOTO, TOKITOH NORIHIRO, YOSHIZAWA KAZUNARI, SUGIMOTO HIDEKI, OGO SEIJI, INOUE TSUYOSHI, NAKAI HIDETAKA

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    Grant amount:\36530000 ( Direct Cost: \28100000 、 Indirect Cost:\8430000 )

    In this area, we have promoted truly original and fusion-type fundamental chemical researches. A clear research concept called "Stimuli-responsive Chemical Species" and a variety of research perspectives brought by the collaboration of leading researchers are twin engines of our research. As a result, new material science was created, which is not reached without collaboration. And it has a great ripple effect not only in the specific field but also in related fields.
    For example, they are (1) creation of organic radical batteries based on the stabilization of the radical atom of the hypervalent group 16 element, (2) discovery of intermediate diradical state and development to nonlinear optical material based on its favorable electronic state, (3) Development of a novel nickel-iron catalyst that reduces oxygen molecules to water, (4) creation of a time-resolved X-ray structural analysis device to clarify the mechanism of enzymatic reactions, etc.

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  • Creation of stimuli-responsive metal complexes based on the ligand properties of low-coordinate boryl anion and their catalytic function

    Grant number:24109012  2012.4 - 2017.3

    Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research  Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

    YAMASHITA Makoto

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    Authorship:Principal investigator  Grant type:Competitive

    Grant amount:\39260000 ( Direct Cost: \30200000 、 Indirect Cost:\9060000 )

    Throughout this research, we obtained the following research results. (1) Five kinds of ligands were newly added to the library of boron-containing pincer ligand by using a novel synthetic methods. (2) We have succeeded in synthesis of the corresponding complexes by introduction of platinum, ruthenium, rhodium, and iridium into the PBP ligands in the library and have elucidated their properties. (3) Hydrosilylation of alkene progresses with PBP platinum catalyst, hydrogenation of aldehyde proceeds with PBP ruthenium catalyst, and dehydrogenation of alkane and dimethylamine-borane proceeds with PBP iridium catalyst.

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  • ホウ素-遷移金属錯体触媒の開発

    2012.4 - 2015.3

    東レ財団  東レ科学技術研究助成 

    山下 誠

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    Authorship:Principal investigator  Grant type:Competitive

    Grant amount:\10000000 ( Direct Cost: \10000000 )

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  • 石炭抽出混合物を用いた有機合成化学不要の超格安有機デバイス作成法開発

    2012.4 - 2013.3

    長瀬科学技術振興財団  研究助成 

    山下 誠

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    Authorship:Principal investigator  Grant type:Competitive

    Grant amount:\2500000 ( Direct Cost: \2500000 )

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  • 含ホウ素熱安定性多座配位子を有する金属錯体を用いた次世代型石油化学プロセスの開発

    2012.4 - 2013.3

    旭硝子財団  研究助成 

    山下 誠

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    Authorship:Principal investigator  Grant type:Competitive

    Grant amount:\2000000 ( Direct Cost: \2000000 )

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  • 熱安定性多座配位子を有する低配位型触媒活性種の発生と応用

    Grant number:23105510  2011.4 - 2013.3

    文部科学省  科学研究費助成事業  新学術領域研究

    山下 誠

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    Authorship:Principal investigator  Grant type:Competitive

    Grant amount:\7020000 ( Direct Cost: \5400000 、 Indirect Cost:\1620000 )

    平成24年度は以下の2種類の結果が得られた。
    1.PBPピンサー配位子を有するPt錯体を用いたアルケンのヒドロシリル化反応の開発および新規配位子前駆体としてのジヒドロボラートの合成
    昨年度の成果として得られたPBP-PtCl錯体をHSiEt_3および1-deceneと加熱することにより、ヒドロシリル化反応が進行して、トリメチルシリルデカンが得られることを発見した。反応機構を解析するため、ヒドリド錯体PBP-PtHを合成、単離して触媒反応に用いたところ、これを経由していないことがわかったため、典型的なChalk-Harrod型の機構で進行していることが明らかになった。一方で、このヒドリド錯体を二酸化炭素と反応させると、瞬時に反応して対応するPBP-Ptホルマト錯体に変換されることを見いだした。
    また、PBP配位子前駆体として用いているヒドロボランに対してTHF中で水素化カリウムを作用させることで、ホウ素上に水素が2つ結合したジヒドロボラート型の化合物を合成、単離することに成功した。この化合物は結晶中でカリウム原子がジヒドロボラート部位とベンゾ縮環部位を架橋して、無限構造をとっていることが明らかになった。
    2.Ru錯体触媒のみを用いたアルケンの直鎖選択的ヒドロホルミル化-水素化反応の開発
    独自に合成したシクロペンタジエノンRu錯体に対してXantphos配位子を加えて、プロペンまたは1-デセンを合成ガスと反応させたところ、直鎖選択的ヒドロホルミル化反応が進行して直鎖アルデヒドが生成すると共に、このアルデヒドが水素化された直鎖アルコールが最高73%の収率で得られた。また、昨年度の成果として既報のRh-Xantphos/二核Ruの二元系触媒を用いたアルケンの直鎖選択的ヒドロホルミル化-水素化反応における反応速度論解析を行い、ヒドロホルミル化段階の反応速度はアルケン濃度に対して一次、水素化段階の反応速度はアルデヒド濃度に対して0次であることを明らかにした。

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  • 精密設計多座配位子を有する熱安定性均一系錯体触媒の創製:次世代石油化学プロセスへ向けて

    2011.4 - 2013.3

    三菱財団  平成23年度研究助成 

    山下 誠

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    Grant amount:\7000000 ( Direct Cost: \7000000 )

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  • 含ホウ素配位子を鍵とする熱的に安定な錯体触媒の創製と脱石油化時代へ向けた次世代石油化学プロセスの確立を目指した反応開発

    2011.4 - 2013.3

    東電記念財団  平成23年度研究助成 

    山下 誠

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    Authorship:Principal investigator  Grant type:Competitive

    Grant amount:\10000000 ( Direct Cost: \10000000 )

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  • Searching a new preparative method for photovoltaic cells using a coal-pitch mixture

    Grant number:23656507  2011.4 - 2012.3

    Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research  Grant-in-Aid for Challenging Exploratory Research

    YAMASHITA Makoto

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    Authorship:Principal investigator  Grant type:Competitive

    Grant amount:\4160000 ( Direct Cost: \3200000 、 Indirect Cost:\960000 )

    It was found that coal-pitch, a mixture of coal tar, could be utilized as an emissive layer for organic light emitting diode. On the PEDOT/PSS-coated ITO electrode, a solution of coal-pitch was spin-coated, and LiF/Al electrode was deposited onto it. The obtained OLED properties depended on the used solvent and it could also be controlled by PTLC method, which is a conventional method for separation in organic chemistry.

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  • ホウ素を鍵元素とする配位子群を用いた炭化水素変換反応触媒の開発

    2010.11 - 2011.10

    有機合成化学協会  三井化学研究企画賞 

    山下 誠

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    Authorship:Principal investigator  Grant type:Competitive

    Grant amount:\500000 ( Direct Cost: \500000 )

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  • 求核的ホウ素化を利用したオリゴアジン類の合成とn型半導体への応用

    2010.4 - 2011.3

    松籟科学技術振興財団  研究助成 

    山下 誠

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    Authorship:Principal investigator  Grant type:Competitive

    Grant amount:\1000000 ( Direct Cost: \1000000 )

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  • 低原子価ホウ素化合物を基盤とした有機化学および触媒化学

    2009.4 - 2011.3

    日本学術振興会  科学研究費助成事業  若手研究(A)

    山下 誠

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    Authorship:Principal investigator  Grant type:Competitive

    Grant amount:\28340000 ( Direct Cost: \21800000 、 Indirect Cost:\6540000 )

    本研究では、(1)ボリルアニオンの化学の開拓、特に第2周期p-ブロック元素とホウ素との結合生成に関する検討およびこれらにより得られる生成物の有機合成化学への応用、(2)ホウ素中心ラジカルおよび低酸化数ホウ素化学種ボリレンの合成の試みと光活性化ボリルラジカル生成の確認、(3)含ホウ素多座配位子を有する遷移金属錯体の合成と性質の解明およびこれらの触媒化学への応用検討、の3項目に関して研究を行った。

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  • 低原子価ホウ素化合物「ボリレン」の合成と触媒化学への応用

    2008.11 - 2009.10

    住友財団  基礎科学研究助成 

    山下 誠

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    Authorship:Principal investigator  Grant type:Competitive

    Grant amount:\1500000 ( Direct Cost: \1500000 )

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  • ボリルアニオンを基軸としたホウ素-前周期金属結合の創成と新規重合触媒としての応用

    2008.4 - 2010.3

    文部科学省  科学研究費助成事業  特定領域研究

    山下 誠

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    Authorship:Principal investigator  Grant type:Competitive

    Grant amount:\3800000 ( Direct Cost: \3800000 )

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  • 低原子価ホウ素化学種「塩基安定化ボリレン」の合成と配位子としての応用

    2008.4 - 2009.3

    東京大学グローバルCOEプログラム  2008年度若手研究助成 

    山下 誠

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    Authorship:Principal investigator  Grant type:Competitive

    Grant amount:\900000 ( Direct Cost: \900000 )

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  • 新規含ホウ素配位子を用いた飽和炭化水素変換触媒の開発研究

    2008.4 - 2009.3

    ゼネラル石油研究奨励財団  研究奨励助成 

    山下 誠

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    Authorship:Principal investigator  Grant type:Competitive

    Grant amount:\800000 ( Direct Cost: \800000 )

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  • アニオン性ホウ素求核種ボリルリチウムの多様化と超電子供与性配位子としての応用

    2007.4 - 2008.3

    倉田記念日立科学財団  2007年度倉田奨励金 

    山下 誠

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    Authorship:Principal investigator  Grant type:Competitive

    Grant amount:\1300000 ( Direct Cost: \1300000 )

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  • 多座配位子系における炭素配位子の協奏効果を用いた炭化水素変換反応触媒の開発

    2007.4 - 2008.3

    文部科学省  科学研究費助成事業  特定領域研究

    山下 誠

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    Authorship:Principal investigator  Grant type:Competitive

    Grant amount:\2000000 ( Direct Cost: \2000000 )

    今年度の最も大きな成果として、ネオペンチル基置換PNP配位子を有するイリジウム錯体(0.1mol%)を塩基(0.4mol%)共存下、200℃でアルキルアミンと反応させることによって、ジアルキルアミンが非常に効率良く生成することを見いだした。特にアルキル基がオクチル基の場合においては、収率86%、触媒回転数860で反応が進行し、副生成物であるトリアルキルアミンはわずか0.6%が観測されたのみであった。この反応はこれまでに報告されているジアルキルアミンの合成に比べて最も触媒活性が高く、PNP配位子を有する金属錯体触媒の熱的安定性という特徴が大きく反映された結果となっている。また、アルキルアミンとしてシクロヘキシルアミンを用いた場合はジアルキルアミンの収率が69%と若干低下したものの、トリアルキルアミンの副生は全く観測されなかった。反応の触媒サイクルにおいては、アミンのN-H結合が低配位型のイリジウム錯体へと酸化的付加する段階が鍵であると考えており、かさ高いジアルキルアミンがイリジウムと反応するのが遅いために、先に述べた高い選択性が得られているものと言える。また、生成してくるジアルキルアミンは、柔軟剤等に使用されるカチオン系界面活性剤(時ステアリルアンモニウムクロリド)の合成などに対して応用が可能である。

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  • ボリルリチウムを基軸とした新しいホウ素-金属結合の創成と新規重合触媒としての応用

    2007.4 - 2008.3

    文部科学省  科学研究費助成事業  特定領域研究

    山下誠

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    Authorship:Principal investigator  Grant type:Competitive

    Grant amount:\2400000 ( Direct Cost: \2400000 )

    今年度はこれまでに、ボリルアニオン等価体であるボリルマグネシウム、ボリル銅、ボリル亜鉛をそれぞれ調整することに成功し、これら全てはX線結晶構造解析を行うことにも成功した。それぞれ最も特徴的な反応として、ボリルマグネシウムはベンズアルデヒドとの反応において、これまでに合成されたことのないベンゾイルボランを与えることを見いだした。また、ボリル銅及び亜鉛はα,β-不飽和エノンと反応して、対応する共役付加体を与えることがわかった。この反応における金属エノラート中間体をケイ素反応試剤で捕捉することによって、分子内にアリルボランとシリルエノールエーテルを有するγ-シロキシアリルボランを得ることにも成功した。また、今年度の最も大きな成果として、ボリルリチウムとチタンテトライソプロポキシドとの反応によって、ボリルチタントリイソプロポキシド錯体の合成に成功した。この錯体はボリルチタンの初めての合成例である。その結晶構造中でホウ素-チタン距離はそれぞれの原子の共有結合半径の和よりも長く、ホウ素-チタン結合のイオン性が高いことが明らかになった。また、チタン-酸素間距離はかなり短く、pπ-dπ相互作用の存在が示唆された。このように、今年度はホウ素原子と様々な金属間の結合を新しく作り出すことに成功した。

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  • 新規アニオン性ホウ素求核種ボラニドの創製と反応、配位子としての応用

    2006.4 - 2008.3

    日本学術振興会  科学研究費助成事業  若手研究(B)

    山下 誠

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    Authorship:Principal investigator  Grant type:Competitive

    Grant amount:\3700000 ( Direct Cost: \3700000 )

    昨年度はボリルリチウムの構造と反応性に関して新たな知見を得た。溶媒にTHFを使用して発生させたボリルリチウムの単結晶についてX線結晶構造解析を行ったところ、2分子のTHFがLi原子に配位した構造が得られてきた。単離したこの結晶をTHF-d_8に溶解させたところ、先のDME配位の結晶を溶解させたときと全く同じNMRスペクトルが得られてきた。この溶液の低温NMR測定を行ったところ、11B NMRにおいてシグナルの高磁場シフトを観測し、との変化が可逆であることもわかった。この現象を理解するために計算化学によってボリルリチウムにTHFが配位した構造の11B NMR化学シフト計算を行ったところ、THFの個数が少ないほど高磁場にシフトするという傾向が得られた。現在のところこの高磁場シフトは11B核の化学シフト異方性に由来するものだと考えており、今後は固体高分解能NMRの測定を通じてさらに詳細を明らかにする。一方で、ボリルリチウムと各種有機化合物の反応性に関して系統的に調べた。カルボニル化合物との反応においては、ボリルリチウムは対応する炭素求核種と同様の反応性を示し、ボリルカルボニル化合物等が得られてきた。これらの化合物中でボリル基は非常に電子供与性が高いことも明らかになった。さらにボリルリチウムを用いて、遷移金属塩化物錯体に対して求核的にボリル配位子を導入することで、新たなボリル錯体合成法を確立することにも成功した。

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  • Synthesis of Highly Stereoregular Polymers Utilizing Carbon Dioxide as a Comonomer

    Grant number:17065005  2005 - 2008

    Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research  Grant-in-Aid for Scientific Research on Priority Areas

    NOZAKI Kyoko, YAMASHITA Makoto, NAKANO Koji, ITO Shingo

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    Grant amount:\82700000 ( Direct Cost: \82700000 )

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  • 新しいアニオン性ホウ素求核種リチウムボラニドを用いた含ホウ素化合物の系統的合成とその応用

    2004.12 - 2005.11

    有機合成化学協会  有機合成化学協会研究企画賞 

    山下 誠

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    Authorship:Principal investigator  Grant type:Competitive

    Grant amount:\500000 ( Direct Cost: \500000 )

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  • 5配位窒素化合物の単離及び機能性カチオンの構築へ向けた新規アンモニウム塩の合成

    2003.4 - 2005.3

    日本学術振興会  科学研究費助成事業  特別研究員奨励費

    山下 誠

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    Authorship:Principal investigator  Grant type:Competitive

    Grant amount:\2200000 ( Direct Cost: \2200000 )

    電子的に非対称な摂動を与えたDPPF誘導体を2座のホスフィン配位子として有する不安定なパラジウムアリールアミド錯体を合成し、低温NMRによる還元的脱離反応速度の解析を通じて、還元的脱離反応に対する配位子の電子的摂動に対するトランス影響を明らかにすることができた。4配位パラジウムアリールアミド錯体において、配位子が電子不足な場合は反応が加速されるという事実は過去の事例と傾向が一致したが、アミド配位子のトランス位に電子求引性基が存在するとき反応は加速され、その程度はアリール配位子のトランス位にある電子求引基に比べて大幅に大きいものとなることを明らかとした。
    また、3配位パラジウムアリールハライド錯体を原料として用い、C-N結合生成反応における次段階の中間体に相当する3配位パラジウムアリールアミド錯体を合成、構造決定した。これらの錯体においてはホスフィン配位子がアミド配位子のトランス位に位置しており、トランス影響を反映した構造となっていた。また、いくつかの錯体はこれまで3配位パラジウム錯体において観測されていた分子内C-H agostic相互作用を有しておらず、純粋な3配位錯体として考えることができる。これらの錯体は加熱することにより還元的脱離反応を起こして対応するアリールアミンを与え、その収率は非常に高かった。速度測定の結果により還元的脱離反応が3配位錯体から直接進行すること、かさ高いホスフィン配位子が反応を加速すること、同じアリール基とアミド基をもつ対応する4配位錯体に比べて非常に早く反応が進行することを明らかとした。
    m-テルフェニル骨格を窒素上に有する新規なbowl型カルベン配位子を合成した。合成した配位子をPd[P(o-tol)_3]_2との配位子交換によりPd上に導入することで、直線2配位型Pd(0)錯体を得た。この錯体は室温、固体状態で空気中の酸素および二酸化炭素と連続的に反応し、これらの気体分子を1分子ずつ取り込むことでPd(II)-peroxocarbonate錯体へと変化した。

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  • アントラセン骨格を用いた新規平面性3座配位子の合成と不安定化学種単離への応用

    2001.4 - 2003.3

    日本学術振興会  科学研究費助成事業  特別研究員奨励費

    山下 誠

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    Authorship:Principal investigator  Grant type:Competitive

    Grant amount:\2000000 ( Direct Cost: \2000000 )

    新規3座配位子である1,8-dimethoxy-9-bromoanthraceneを合成し、9-位をリチオ化後、種々の置換基を有するホウ素原子を導入して、エックス線解析によって構造を検討した。種々の誘導体間での比較の結果、ホウ素原子上の置換基の電子求引性が増大すると、1,8-位の酸素原子と9-位のホウ素原子の距離が近くなることが分かり、酸素配位子と中心ホウ素の間に求引的な相互作用があることを確認した。また興味深いことに、ハロゲンを置換基とする場合(BF2, BC12)のX線構造はBF2体では5配位、BC12体では4配位と大きく変わることが明らかになった。この結果についてDFT計算を行ってその原因を解明した。またカテコール誘導体に対して、エックス線による精密電子密度解析を行い、そのAIM解析結果をDFT計算の結果と比較したところ、非常に良い相関を示し、酸素配位子と中心ホウ素の間に求引的な相互作用があることが確認できた。また、1,8-位に窒素原子を有する新規3座配位子である1,8-bis(dimethylamino)-9-bromoanthraceneの合成にも成功し、そのホウ素誘導体およびパラジウム誘導体のエックス線解析に成功した。さらに、1,8-位が酸素アニオンとなりうる新規3座配位子の合成にも成功し、中心に炭素を導入することができた。その炭素誘導体のエックス線解析も行ったが、アニオンと対カチオンとの相互作用のために中心炭素は4配位であることがわかった。

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Teaching Experience

  • 有機・高分子化学基礎論

    Institution:名古屋大学

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  • 有機化学セミナー2A

    Institution:名古屋大学

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  • 有機化学セミナー2B

    Institution:名古屋大学

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  • 有機化学特別実験及び演習Ⅰ

    Institution:名古屋大学

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  • 有機化学特別実験及び演習Ⅱ

    Institution:名古屋大学

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  • 有機化学セミナー1D

    Institution:名古屋大学

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  • 有機金属化学

    Institution:名古屋大学

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  • 有機化学セミナー1C

    Institution:名古屋大学

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  • 有機化学セミナー1A

    Institution:名古屋大学

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  • 有機化学セミナー1B

    Institution:名古屋大学

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  • 有機化学1および演習

    Institution:名古屋大学

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  • 有機化学セミナー2D

    Institution:名古屋大学

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  • 有機化学セミナー2E

    Institution:名古屋大学

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  • 有機化学セミナー2C

    Institution:名古屋大学

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