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Language：English   Publisher：IOP PUBLISHING LTD  

Ferroelectric barium titanate ceramics with grain sizes in the range (0.5, 20) mu m were used for a comparative study of grain-size influence on the ferro-para phase transition and its thermal hysteresis. The investigations were performed by recording the temperature dependence of the dielectric constant, heat capacity and pyrocharge. The experimental results have been analysed in the framework of Landau-Devonshire theory. The grain-size dependent Landau coefficients of the free energy have been derived from our experimental data and used to compute the grain-size dependence of the theoretical transition interval related to the thermal hysteresis. The good qualitative agreement between theory and experiment recommends the size dependent Landau coefficients as a way to improve the modelling of the size dependent ferro-para phase transition in ceramics.

DOI： 10.1088/0953-8984/11/6/024

Web of Science

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Language：English   Publisher：IOP PUBLISHING LTD  

A detailed analysis of polarization reversal in ferroelectrics has been performed, in the framework of the Landau model for phase transitions. Some important characteristics of homogeneous switching have been emphasized and later used in studying the more general case of inhomogeneous switching. The two extremes of switching current correspond to the inflexion points of the dielectric hysteresis loop. Hysteresis loops of poled ferroelectric samples are expected to include negative-susceptibility regions, for high-frequency applied electric fields. The switching current minimum is eliminated by the experimental method used for recording the switching responses. Equivalent Landau coefficients and electric fields have been defined, in order to integrate the size effects and inhomogeneity contribution to switching of the global order parameter. We correlated the size effects on the critical parameters of the switching (the coercive field) and the ferroelectric-to-paraelectric phase transition (the Curie temperature). Polarization reversal in small-size ferroelectrics can be regarded as a diffuse phase transition, whereas its character is closer to normal for large-size samples. The size dependencies of the reversal speed and maximum current result from the size dependencies of the equivalent Landau coefficients and electric field inducing reversal.

DOI： 10.1088/0953-8984/10/2/026

Web of Science

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DOI： 10.1143/JJAP.35.5210

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