Updated on 2025/09/25

写真a

 
Satoh Kotaro
 
Organization
School of Materials and Chemical Technology Professor
Title
Professor
Contact information
メールアドレス
Homepage
http://chembio.nagoya-u.ac.jp/labhp/polymer2/en/members/satoh_e.html
External link

Degree

  • doctor of Engineering ( Kyoto University )

Research Interests

  • Polymer Synthesis

  • Living Polymerization/Living Radical Polymerization/Living Cationic Polymerization/Molecular Weight Control/Tacticity/Sequence/Sequence-regulated/Functional Polymer/High-performance Polymer/Renewable Resource/Bio-Based Polymer

Research Areas

  • Nanotechnology/Materials / Polymer chemistry

Education

  • Kyoto University   Graduate School, Division of Engineering   Polymer Chemistry

    - 2000

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    Country： Japan

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  • Kyoto University   Graduate School, Division of Engineering   Polymer Chemistry

    - 1997.3

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    Country： Japan

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  • Kyoto University   Faculty of Engineering

    1991.4 - 1995.3

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    Country： Japan

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Research History

  • Institute of Science Tokyo   Professor

    2024.10

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    Country：Japan

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  • Tokyo Institute of Technology   School of Materials and Chemical Technology   Professor

    2019.4 - 2024.9

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    Country：Japan

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  • Kansai University   Faculty of Chemistry , Materials and Bioengineering

    2018.4 - 2019.3

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  • Nagoya University   Graduate School of Engineering Molecular and Macromolecular Chemistry 2   Associate Professor

    2017.4 - 2019.3

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  • Nagoya Institute of Technology

    2017.4 - 2018.3

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  • Shizuoka University   Faculty of Science

    2016.10 - 2017.3

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  • JST PRESTO

    2014.10 - 2018.3

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  • Kyushu University   Institute for Materials Chemistry and Engineering

    2014.10 - 2015.3

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  • The University of Tokyo   Graduate School of Agricultural and Life Sciences

    2014.4 - 2015.3

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  • Associate Prof

    2010.8 - 2019.3

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  • Nagoya University   Graduate School of Engineering Department of Applied Chemistry, Chemical Engineering and Biotechnology   Associate Professor

    2010.8 - 2017.3

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  • University of California, Santa Barbara, Visiting Scientist

    2009.10 - 2010.3

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  • Associate Prof

    2007.4 - 2010.8

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  • Nagoya University   Graduate School of Engineering Department of Applied Chemistry, Chemical Engineering and Biotechnology   Lecturer

    2007.4 - 2010.7

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  • Nagoya University   Graduate School of Engineering Department of Applied Chemistry, Chemical Engineering and Biotechnology   Assistant

    2007.3

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  • Assistant Professor

    2004.4 - 2007.3

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  • Kuraray Co., Ltd., Tsukuba Resaerch Laboratories

    2000.4 - 2004.3

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  • Nagoya University Graduate School of Engineering Molecular and Macromolecular Chemistry 2   Associate Professor

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Professional Memberships

Papers

  • A DFT Study of Catechol Polymer Adhesion onto γ-Alumina (110) Surfaces

    Amit Shrestha, Ken Kojio, Yoshihito Shiota, Satoru Yamamoto, Keiji Tanaka, Kotaro Satoh, Kazunari Yoshizawa

    Langmuir   41 ( 35 )   23672 - 23687   2025.8

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    Authorship：Corresponding author   Publishing type：Research paper (scientific journal)   Publisher：American Chemical Society (ACS)  

    DOI： 10.1021/acs.langmuir.5c02791

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  • Iterative Synthesis and Marine-Biodegradation Assessment of Discrete Oligomers Based on Poly(Butylene Succinate), Poly(Ethylene Terephthalate), Polyamide 6, and Polyisoprene

    Tomohiro Kubo, Ravi Teja Ananthu, Takumi Noda, Yoshifumi Amamoto, Hironori Taguchi, Yingjun An, Ryoya Kamiki, Chihiro Homma, Hiroyasu Masunaga, Sono Sasaki, Mineto Uchiyama, Masami Kamigaito, Takako Kikuchi, Yasuhiro Kohsaka, Atsushi Takahara, Kotaro Satoh

    Macromolecules   58 ( 16 )   8649 - 8657   2025.8

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    Authorship：Last author,　Corresponding author   Publishing type：Research paper (scientific journal)   Publisher：American Chemical Society (ACS)  

    DOI： 10.1021/acs.macromol.5c01531

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  • RAFT Copolymerization of Glycerol-Derived Vinyl Ethers Possessing Acetal-Protected Diols for Biobased Hydrophilic and Thermoresponsive Polymers

    Riko Kashima, Tomohiro Kubo, Kotaro Satoh

    Macromolecules   58 ( 16 )   8753 - 8761   2025.7

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    Authorship：Last author,　Corresponding author   Publishing type：Research paper (scientific journal)   Publisher：American Chemical Society (ACS)  

    DOI： 10.1021/acs.macromol.5c01401

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  • Propargyl Amines as Simple Alkyne Initiators for Chain-Growth Controlled/"Living" Click Polymerization

    Satoshi Sakai, Yuta Yamazaki, Tomohiro Kubo, Kotaro Satoh

    Journal of Polymer Science   2025.7

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    Authorship：Last author,　Corresponding author  

    DOI： 10.1002/pol.20250087

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  • Controlled/″Living″ Click Polymerization with Possible Bidirectional Chain-Growth Propagation during Polyaddition Reviewed

    Satoshi Sakai, Takuya Nakamura, Seiichiro Uchida, Yuto Nakauchi, Mineto Uchiyama, Tomohiro Kubo, Masami Kamigaito, Kotaro Satoh

    Journal of the American Chemical Society   147 ( 25 )   21459 - 21467   2025.6

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    Authorship：Last author,　Corresponding author   Publishing type：Research paper (scientific journal)   Publisher：American Chemical Society (ACS)  

    DOI： 10.1021/jacs.5c01247

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  • Expectations for Papers on Electrochemical Processes and Materials in ACS Sustainable Chemistry & Engineering

    Elizabeth J. Biddinger, Nour Abdoulmoumine, Dean Brady, Danielle Julie Carrier, Jingwen Chen, Nicholas Gathergood, Hongxian Han, Sachin Handa, Ive Hermans, King Kuok Mimi Hii, Bing Joe Hwang, Kevin C. Leonard, Watson Loh, Andrew C. Marr, Michael A. R. Meier, Audrey Moores, Ryuhei Nakamura, Graham N. Newton, Victor Sans, Clara Santato, Kotaro Satoh, Yogendra Shastri, Wil V. Srubar, Bala Subramaniam, Lei Wang, Ning Yan, Carlos Toro, Peter Licence

    ACS Sustainable Chemistry & Engineering   13 ( 21 )   7683 - 7686   2025.6

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    Publishing type：Research paper (scientific journal)   Publisher：American Chemical Society (ACS)  

    DOI： 10.1021/acssuschemeng.5c04768

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  • Expectations for Manuscripts in the Field of Polymer Science in ACS Sustainable Chemistry & Engineering

    Michael A. R. Meier, Bala Subramaniam, Audrey Moores, Watson Loh, Elizabeth J. Biddinger, Bing Joe Hwang, Kotaro Satoh, Graham N. Newton, Sachin Handa, Ning Yan, King Kuok Mimi Hii, Andrew Craig Marr, Ive Hermans, Kevin C. Leonard, D. Julie Carrier, Jingwen Chen, Clara Santato, Dean Brady, Wil V. Srubar, Yogendra Shastri, Ryuhei Nakamura, Nicholas Gathergood, Hongxian Han, Julio F. Serrano, Peter Licence

    ACS Sustainable Chemistry & Engineering   13 ( 8 )   3022 - 3023   2025.3

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    Publishing type：Research paper (scientific journal)   Publisher：American Chemical Society (ACS)  

    DOI： 10.1021/acssuschemeng.5c01303

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  • Polyaddition of Discrete Oligo(butylene succinate)s with Divinyl Ethers for Periodic and Selectively Cleavable Main-Chain Acetal Linkages Reviewed

    Ravi Teja Ananthu, Yingjun An, Yusaku Tajima, Hironori Taguchi, Takako Kikuchi, Tomohiro Kubo, Hiroyasu Masunaga, Sono Sasaki, Atsushi Takahara, Kotaro Satoh

    Macromolecules   58 ( 5 )   2599 - 2608   2025.2

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    Authorship：Last author,　Corresponding author   Publishing type：Research paper (scientific journal)   Publisher：American Chemical Society (ACS)  

    DOI： 10.1021/acs.macromol.4c03178

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  • Photocontrolled RAFT Polymerization for the Preparation of Catechol‐Functionalized Surfaces Reviewed

    Rui Guo, Shiho Tanizaki, Yuta Nabae, Hiroyuki Aoki, Tomohiro Kubo, Kotaro Satoh

    Journal of Polymer Science   2024.12

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    Authorship：Last author,　Corresponding author   Language：English   Publishing type：Research paper (scientific journal)  

    <jats:title>ABSTRACT</jats:title><jats:p>In nature, there are numerous compounds bearing catechol groups that demonstrate various useful properties, such as adhesion and antioxidant capacity. This inspired us to apply catechol functional group‐containing polymers on a surface for adhesive properties. Herein, we report the preparation of catechol‐functionalized polymeric surfaces by photo‐induced electron transfer‐reversible addition‐fragmentation chain transfer (PET‐RAFT) polymerization using a “grafting‐from” approach using surface anchored RAFT agents. The polymerization of <jats:italic>tert</jats:italic>‐butoxycarbonyl (Boc)‐protected vinyl catechol, derived from naturally abundant caffeic acid, was investigated under visible light irradiation, which showed good control over molecular weights especially under green light irradiation. The catechol‐bearing polymeric surfaces were readily obtained after concise thermal deprotection, which was revealed by the changes in the surface properties evaluated by contact angles. This study proposes a straightforward route to catechol‐modified surface using functional and sustainable materials in coating applications.</jats:p>

    DOI： 10.1002/pol.20240867

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  • Development of a bio-based adhesive by polymerization of Boc-protected vinyl catechol derived from caffeic acid Reviewed

    Shiho Tanizaki, Tomohiro Kubo, Yosuke Bito, Shigeki Mori, Hiroyuki Aoki, Kotaro Satoh

    RSC Sustainability   3   1714 - 1720   2024.12

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    Authorship：Last author,　Corresponding author   Language：English   Publishing type：Research paper (scientific journal)  

    <jats:p>Catechol polymers enabled the preparation of a biomimetic adhesive using a bio-based raw material, in which the deprotection proceeded just upon heating with neither any solvent nor catalyst, releasing only gaseous byproducts without purification.</jats:p>

    DOI： 10.1039/d4su00629a

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  • Structures and properties of temperature-responsive gels with homogeneous networks prepared by photogelation of four-armed star-shaped poly(N-isopropylacrylamide) Reviewed

    Natsuki Itaya, Chisa Norioka, Kotaro Satoh, Masami Kamigaito, Akifumi Kawamura, Takashi Miyata

    Polymer Journal   57 ( 4 )   455 - 466   2024.12

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    Language：English   Publishing type：Research paper (scientific journal)   Publisher：Springer Science and Business Media LLC  

    DOI： 10.1038/s41428-024-01005-5

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    Other Link： https://www.nature.com/articles/s41428-024-01005-5

  • Reintroducing the INTRODUCTION: How to Write a Compelling Introduction for the ACS Sustainable Family of Journals

    Audrey Moores, Jingwen Chen, Bala Subramaniam, Michael KC Tam, Elizabeth J. Biddinger, Dean Brady, Danielle Julie Carrier, Ivet Ferrer, Nicholas Gathergood, Hongxian Han, Ive Hermans, King Kuok Hii, Bing Joe Hwang, Milad Kamkar, Watson Loh, Joachim Loo, Andrew C. Marr, Michael Meier, ryuhei nakamura, Graham Newton, T. Pradeep, Kotaro Satoh, Wil Srubar III, Ning Yan, Asha James, Mihir Jha, Atal Shivhare, Julio F. Serrano, Peter Licence

    ACS Sustainable Resource Management   2024.6

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    Language：English   Publishing type：Research paper (scientific journal)  

    DOI： 10.1021/acssusresmgt.4c00206

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  • Reintroducing the INTRODUCTION: How to Write a Compelling Introduction for the ACS Sustainable Family of Journals

    Audrey Moores, Jingwen Chen, Bala Subramaniam, Michael KC Tam, Elizabeth J. Biddinger, Dean Brady, Danielle Julie Carrier, Ivet Ferrer, Nicholas Gathergood, Hongxian Han, Ive Hermans, King Kuok Hii, Bing Joe Hwang, Milad Kamkar, Watson Loh, Joachim Loo, Andrew C. Marr, Michael Meier, ryuhei nakamura, Graham Newton, T. Pradeep, Kotaro Satoh, Wil Srubar III, Ning Yan, Asha James, Mihir Jha, Atal Shivhare, Julio F. Serrano, Peter Licence

    ACS Sustainable Chemistry and Engineering   2024.6

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    Language：English   Publishing type：Research paper (scientific journal)  

    DOI： 10.1021/acssuschemeng.4c04252

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  • Phantom-Chain Simulations for the Effect of Node Functionality on the Fracture of Star-Polymer Networks

    Yuichi Masubuchi, Yuya Doi, Takato Ishida, Naoyuki Sakumichi, Takamasa Sakai, Koichi Mayumi, Kotaro Satoh, Takashi Uneyama

    Macromolecules   2023.12

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    Language：English   Publishing type：Research paper (scientific journal)   Publisher：American Chemical Society (ACS)  

    DOI： 10.1021/acs.macromol.3c01291

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  • Effects of polycaprolactone degradation products on the water flea, <scp>Daphnia magna</scp>: Carbodiimide additives have acute and chronic toxicity

    Megumi Matsumoto, Haruka Ito, Ayaka Tateishi, Yasuaki Kobayashi, Kotaro Satoh, Keiji Numata, Hitoshi Miyakawa

    Journal of Applied Toxicology   2023.12

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    Language：English   Publishing type：Research paper (scientific journal)  

    <jats:title>Abstract</jats:title><jats:p>Plastics have benefited our lives in many ways, but their long persistence in the environment causes serious problems. Rapid decomposition and detoxification of plastics after use are significant challenges. As a possible solution, biodegradable plastics have attracted attention, and for environmental risk assessment research on polymer toxicity, use of indicator organisms, like water fleas and fish, has increased globally. However, such research often focuses on standardized substances without considering changes in toxicity due to plastic degradation products. Additionally, tests generally focus on acute toxicity, while long‐term effects on organismal reproduction and lifespan are largely unknown. Understanding the impact of degraded polymers on biological activities is crucial for accurate risk assessment. In this study, we investigated the biological toxicity of substances generated during degradation of polycaprolactone (PCL), a common biodegradable plastic, using the indicator organism, <jats:styled-content style="fixed-case"><jats:italic>Daphnia magna</jats:italic></jats:styled-content>. We examined PCL, oligocaprolactones (OCLs), and monomers resulting from polymer cleavage, as well as carbodiimides, added during polyester synthesis. As a result, PCL, which is insoluble in water, reduced individual survival and total number of offspring at an exposure concentration of 100 mg/L, while no toxicity was observed for water‐soluble degradation products, OCLs, and monomers. Furthermore, carbodiimides, which are expected to be released during PCL degradation, showed strong toxicity, significantly reducing individual survival and total number of offspring at 0.1–10 mg/L. These findings suggest that changes in physical properties due to polymer degradation and release of additives can significantly alter their toxicity.</jats:p>

    DOI： 10.1002/jat.4516

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  • Precision Synthesis of End-Functionalized Star Poly(vinyl alcohol)s by RAFT Polymerization and Post-polymerization Modification

    Gaishi Murakami, Tomohiro Kubo, Kotaro Satoh

    Precision Chemistry   2023.6

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    Authorship：Last author,　Corresponding author   Language：English   Publishing type：Research paper (scientific journal)  

    DOI： 10.1021/prechem.3c00051

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  • Effect of Oligomers Derived from Biodegradable Polyesters on Eco- and Neurotoxicity

    Naoto Yoshinaga, Ayaka Tateishi, Yasuaki Kobayashi, Tomohiro Kubo, Hitoshi Miyakawa, Kotaro Satoh, Keiji Numata

    Biomacromolecules   2023.6

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    Language：English   Publishing type：Research paper (scientific journal)   Publisher：American Chemical Society (ACS)  

    DOI： 10.1021/acs.biomac.3c00160

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  • Radical-promoted single-unit monomer insertion (SUMI) [aka. reversible-deactivation radical addition (RDRA)]

    Cyrille Boyer, Masami Kamigaito, Kotaro Satoh, Graeme Moad

    Progress in Polymer Science   2023.3

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    Language：English   Publishing type：Research paper (scientific journal)  

    DOI： 10.1016/j.progpolymsci.2023.101648

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  • Synthesis and Degradation of Vinyl Polymers with Evenly Distributed Thioacetal Bonds in Main Chains: Cationic DT Copolymerization of Vinyl Ethers and Cyclic Thioacetals

    Mineto Uchiyama, Yukihiro Murakami, Kotaro Satoh, Masami Kamigaito

    Angewandte Chemie International Edition   2023.1

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    Language：English   Publishing type：Research paper (scientific journal)  

    <jats:title>Abstract</jats:title><jats:p>We report a novel method to synthesize degradable poly(vinyl ether)s with cleavable thioacetal bonds periodically arranged in the main chains using controlled cationic copolymerization of vinyl ethers with a 7‐membered cyclic thioacetal (<jats:bold>7‐CTA</jats:bold>) via degenerative chain transfer (DT) to the internal thioacetal bonds. The thioacetal bonds, which are introduced into the main chain by cationic ring‐opening copolymerization of<jats:bold>7‐CTA</jats:bold>with vinyl ethers, serve as in‐chain dormant species to allow homogeneous propagation of vinyl ethers for all internal segments to afford copolymers with controlled overall and segmental molecular weights. The obtained polymers can be degraded into low‐ and controlled‐molecular‐weight polymers with narrow molecular weight distributions via hydrolysis. Various vinyl ethers with hydrophobic, hydrophilic, and functional pendants are available. Finally, one‐pot synthesis of multiblock copolymers and their degradation into diblock copolymers are also achieved.</jats:p>

    DOI： 10.1002/anie.202215021

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  • Addition–Fragmentation Ring‐Opening Polymerization of Bio‐Based Thiocarbonyl L‐Lactide for Dual Degradable Vinyl Copolymers

    Ryoya Kamiki, Tomohiro Kubo, Kotaro Satoh

    Macromolecular Rapid Communications   2023.1

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    Language：English   Publishing type：Research paper (scientific journal)  

    <jats:title>Abstract</jats:title><jats:p>This study is designed to synthesize novel degradable polymers by radical addition–fragmentation ring‐opening copolymerization of bio‐based thiocarbonyl compounds with various vinyl monomers. Thiocarbonyl <jats:sc>l</jats:sc>‐lactide is capable of radical copolymerization with acrylates and styrene via radical addition to the carbon–sulfur double bonds followed by ring‐opening as well as controlled copolymerization in conjunction with the reversible addition–fragmentation chain transfer (RAFT) process. The obtained polymers possess ring‐opened thioester and ring‐retained thioacetal functionalities in the backbone, both of which could be cleaved under appropriate conditions with different chemical stimuli.</jats:p>

    DOI： 10.1002/marc.202200537

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  • Sulfur‐Free Radical RAFT Polymerization of Methacrylates in Homogeneous Solution: Design of exo‐Olefin Chain‐Transfer Agents (R−CH2C(=CH2)Z)

    Maki Amano, Mineto Uchiyama, Kotaro Satoh, Masami Kamigaito

    Angewandte Chemie International Edition   2022.12

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    Language：English   Publishing type：Research paper (scientific journal)  

    <jats:title>Abstract</jats:title><jats:p>In this work, the development of <jats:italic>exo</jats:italic>‐olefin compounds (R−CH<jats:sub>2</jats:sub>C(=CH<jats:sub>2</jats:sub>)Z) as chain‐transfer agents for the sulfur‐free reversible addition‐fragmentation chain transfer (RAFT) radical polymerization of methacrylates in homogeneous solution is described. A series of <jats:italic>exo</jats:italic>‐olefin compounds with a methyl methacrylate (MMA) dimer structure as the R group and a substituted α‐methylstyrene unit as the −CH<jats:sub>2</jats:sub>C(=CH<jats:sub>2</jats:sub>)Z (Z: Ph−Y) group were synthesized and used for the radical polymerization of MMA in toluene and PhC(CF<jats:sub>3</jats:sub>)<jats:sub>2</jats:sub>OH. These compounds underwent transfer of the CH<jats:sub>2</jats:sub>C(=CH<jats:sub>2</jats:sub>)Z group via addition‐fragmentation of the propagating methacryloyl radical. More electron‐donating (Y) substituents, such as methoxy and dimethylamino groups, produced polymers with narrower molecular weight distributions. A continuous monomer addition method further improved molecular weight control and enabled the synthesis of colorless, sulfur‐free, multiblock copolymers of methacrylates in homogeneous solutions.</jats:p>

    DOI： 10.1002/anie.202212633

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  • Interlocking degradation of vinyl polymers via main‐chain CC bonds scission by introducing pendant‐responsive comonomers

    Sota Yamamoto, Tomohiro Kubo, Kotaro Satoh

    Journal of Polymer Science   2022.12

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    Language：English   Publishing type：Research paper (scientific journal)  

    <jats:title>Abstract</jats:title><jats:p>Degradation of vinyl polymers remains a challenge because of the robust main‐chain CC bonds. In this study, we designed novel pendant‐responsive comonomers with a carbon–halogen bond, which can be copolymerized with vinyl monomers to enable facile degradation of the CC backbone upon triggering stimulus. The comonomer unit was designed to induce interlocking degradation, that is, it first generates side‐chain radical upon trigger, subsequently provides a main‐chain radical via intramolecular 1,5‐shift, and then finally causes the main‐chain cleavage via <jats:italic>β</jats:italic>‐scission. A remarkable decrease in molecular weight was observed when the obtained copolymer was treated with a copper catalyst, and the effect of polymer structure was assessed on the interlocking degradation behavior.</jats:p>

    DOI： 10.1002/pol.20220250

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  • One-pot synthesis of structure-controlled temperature-responsive polymer gels

    Tomoki Sakai, Nagisa Ito, Mitsuo Hara, Takahiro Seki, Mineto Uchiyama, Masami Kamigaito, Kotaro Satoh, Taiki Hoshino, Yukikazu Takeoka

    POLYMER CHEMISTRY   13 ( 29 )   4230 - 4240   2022.7

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    Language：English   Publishing type：Research paper (scientific journal)  

    DOI： 10.1039/d2py00554a

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  • Asymmetric Cationic Polymerization of Benzofuran through a Reversible Chain-Transfer Mechanism: Optically Active Polybenzofuran with Controlled Molecular Weights

    Mineto Uchiyama, Daichi Watanabe, Yuhei Tanaka, Kotaro Satoh, Masami Kamigaito

    Journal of the American Chemical Society   2022.6

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    Language：English   Publishing type：Research paper (scientific journal)  

    DOI： 10.1021/jacs.2c02569

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  • Novel Bio‐Based Catechol‐Containing Copolymers by Precision Polymerization of Caffeic Acid‐Derived Styrenes Using Ester Protection

    Shiho Tanizaki, Tomohiro Kubo, Kotaro Satoh

    Macromolecular Chemistry and Physics   2022.6

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    Language：English   Publishing type：Research paper (scientific journal)  

    <jats:title>Abstract</jats:title><jats:p>In this study, ester‐protected vinyl catechols (VCs) derived from caffeic acid are synthesized to design novel functional copolymers. The protected VCs are polymerized or copolymerized with a series of common vinyl monomers via reversible addition‐fragmentation chain transfer (RAFT) polymerization using cumyl dithiobenzoate as the RAFT agent. The RAFT polymerizations of these protected VCs have been successfully proceeded to afford well‐defined polymers with relatively narrow molecular weight distributions. The deprotection of catechol ester proceeded quantitatively and selectively by primary amine with the formation of amide under a mild condition. In particular, the random/statistical and block copolymerization led to catechol‐containing copolymers with well‐defined structures.</jats:p>

    DOI： 10.1002/macp.202100378

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  • Periodically Functionalized Sequence‐Regulated Vinyl Polymers via Iterative Atom Transfer Radical Additions and Acyclic Diene Metathesis Polymerization

    Masato Miyajima, Kotaro Satoh, Masami Kamigaito

    Macromolecular Chemistry and Physics   2022.6

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    Language：English   Publishing type：Research paper (scientific journal)  

    <jats:title>Abstract</jats:title><jats:p>Sequence‐regulated vinyl polymers with functional groups, such as aliphatic, aromatic, hydroxy, amino, and carboxylic acid groups, as found in natural macromolecules such as proteins, are one of the ultimate targets in synthetic polymers. This study is directed toward the synthesis of periodically functionalized sequence‐regulated vinyl polymers using a series of reactions consisting of iterative atom transfer radical additions (ATRAs) of vinyl monomers, allylation, functionalization, protection, acyclic diene metathesis (ADMET) polymerization, hydrogenation, and deprotection. The functionalized sequence‐regulated telechelic diene oligomers, possessing protected hydroxy, carboxylic acid, and amino groups in the pendant of the acrylate unit between two styrene units, are prepared by iterative ATRAs of two styrene molecules to methyl dichloroacetate followed by allylation of both C–Cl termini and substitution of methyl ester with the protected functionalized groups. The protected functionalized sequence‐regulated telechelic diene oligomers are then polymerized by ADMET polymerization to afford polymers with main‐chain internal olefins and protected functionalized side chains in the acryl units between the two styrene units. The subsequent hydrogenation and deprotection reactions produce a series of sequence‐regulated vinyl polymers with periodic polar functional groups such as –OH, –CO<jats:sub>2</jats:sub>H, and –NH<jats:sub>3</jats:sub><jats:sup>+</jats:sup>Cl<jats:sup>–</jats:sup>. These functional groups affect the thermal properties and solubility of the polymers.</jats:p>

    DOI： 10.1002/macp.202100426

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  • Model and Terpenoid-Derived exo-Methylene Six-Membered Conjugated Dienes: Comprehensive Studies on Cationic and Radical Polymerizations of Substituted 3-Methylenecyclohexenes

    Takenori Nishida, Kotaro Satoh, Masazumi Tamura, Yingai Li, Keiichi Tomishige, Masami Kamigaito

    Macromolecules   2022.3

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    Language：English   Publishing type：Research paper (scientific journal)  

    DOI： 10.1021/acs.macromol.2c00099

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  • Cationic RAFT and DT polymerization

    Mineto Uchiyama, Kotaro Satoh, Masami Kamigaito

    Progress in Polymer Science   124   101485 - 101485   2022.1

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    Language：English   Publishing type：Research paper (scientific journal)   Publisher：Elsevier {BV}  

    DOI： 10.1016/j.progpolymsci.2021.101485

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  • Hydrophilic bio-based polymers by radical copolymerization of cyclic vinyl ethers derived from glycerol

    Riko Kashima, Akito Kajita, Tomohiro Kubo, Masami Kamigaito, Kotaro Satoh

    Chemical Communications   2022

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    Language：English   Publishing type：Research paper (scientific journal)  

    <jats:p>Novel hydrophilic bio-based polymers were prepared by controlled radical copolymerization of cyclic vinyl ethers derived from glycerol as a renewable raw material.</jats:p>

    DOI： 10.1039/d2cc02651a

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  • Adhesion Promoting Copolymer of Acetate-Protected Vinyl Catechol with Glycidyl Methacrylate: Unraveling Deprotection, Adsorption, and Adhesion Behaviors on Metal Substrates

    Chien Wei Chu, Yucheng Zhang, Tomohiro Kubo, Shiho Tanizaki, Ken Kojio, Kotaro Satoh, Atsushi Takahara

    ACS Applied Polymer Materials   2022

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    Publishing type：Research paper (scientific journal)  

    DOI： 10.1021/acsapm.2c00226

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  • Mechanical Properties of Homogeneous Polymer Networks Prepared by Star Polymer Synthesis Methods

    Yusuke Baba, Guohao Gao, Mitsuo Hara, Takahiro Seki, Kotaro Satoh, Masami Kamigaito, Taiki Hoshino, Kenji Urayama, Yukikazu Takeoka

    Macromolecules   54 ( 22 )   10468 - 10476   2021.11

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    Publishing type：Research paper (scientific journal)   Publisher：American Chemical Society (ACS)  

    DOI： 10.1021/acs.macromol.1c01680

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  • Hybridization of Step‐/Chain‐Growth and Radical/Cationic Polymerizations Using Thioacetals as Key Components for Triblock, Periodic and Random Multiblock Copolymers with Thermoresponsiveness

    Mineto Uchiyama, Masahiro Osumi, Kotaro Satoh, Masami Kamigaito

    Macromolecular Rapid Communications   2100192 - 2100192   2021.9

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    Publishing type：Research paper (scientific journal)   Publisher：Wiley  

    DOI： 10.1002/marc.202100192

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  • Nonturbid Fast Temperature-Responsive Hydrogels with Homogeneous Three-Dimensional Networks by Two Types of Star Polymer Synthesis Methods

    DoWoo Kwon, Yuto Jochi, Yuumi Okaya, Takahiro Seki, Kotaro Satoh, Masami Kamigaito, Taiki Hoshino, Kenji Urayama, Yukikazu Takeoka

    Macromolecules   2021.6

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    DOI： 10.1021/acs.macromol.1c00446

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  • Stereospecific cationic RAFT polymerization of bulky vinyl ethers and stereoblock poly(vinyl alcohol) via mechanistic transformation to radical RAFT polymerization of vinyl acetate

    Mineto Uchiyama, Kotaro Satoh, Masami Kamigaito

    Giant   5   100047 - 100047   2021.3

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    DOI： 10.1016/j.giant.2021.100047

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  • Sequence-regulated vinyl polymers: Via iterative atom transfer radical additions and acyclic diene metathesis polymerization

    Masato Miyajima, Kotaro Satoh, Masami Kamigaito

    Polymer Chemistry   12 ( 3 )   423 - 431   2021.1

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    DOI： 10.1039/d0py01564d

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  • Biobased Polymers via Radical Homopolymerization and Copolymerization of a Series of Terpenoid-Derived Conjugated Dienes with exo-Methylene and 6-Membered Ring

    Takenori Nishida, Kotaro Satoh, Masami Kamigaito

    Molecules (Basel, Switzerland)   25 ( 24 )   2020.12

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    DOI： 10.3390/molecules25245890

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  • Multifactor Control of Vinyl Monomer Sequence, Molecular Weight, and Tacticity via Iterative Radical Additions and Olefin Metathesis Reactions

    Masato Miyajima, Kotaro Satoh, Takahiro Horibe, Kazuaki Ishihara, Masami Kamigaito

    Journal of the American Chemical Society   142 ( 44 )   18955 - 18962   2020.11

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    DOI： 10.1021/jacs.0c09289

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  • Biobased Cycloolefin Polymers: Carvone-Derived Cyclic Conjugated Diene with Reactive exo-Methylene Group for Regioselective and Stereospecific Living Cationic Polymerization Reviewed

    Takenori Nishida, Kotaro Satoh, Shusaku Nagano, Takahiro Seki, Masazumi Tamura, Yingai Li, Keiichi Tomishige, Masami Kamigaito

    ACS Macro Letters   9 ( 8 )   1178 - 1183   2020.8

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    DOI： 10.1021/acsmacrolett.0c00479

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  • Thiol-Ene Cationic and Radical Reactions: Cyclization, Step-Growth, and Concurrent Polymerizations for Thioacetal and Thioether Units

    Uchiyama Mineto, Osumi Masahiro, Satoh Kotaro, Kamigaito Masami

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   59 ( 17 )   6832-6838 - 6905   2020.4

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    DOI： 10.1002/anie.201915132

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  • Interconvertible and switchable cationic/PET-RAFT copolymerization triggered by visible light

    Satoh Kotaro, Sun Zhihong, Uchiyama Mineto, Kamigaito Masami, Xu Jiangtao, Boyer Cyrille

    POLYMER JOURNAL   52 ( 1 )   65-73 - 73   2020.1

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    DOI： 10.1038/s41428-019-0257-5

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  • 1:3 ABAA Sequence-Regulated Substituted Polymethylenes via Alternating Radical Copolymerization of Methyl Cinnamate and Maleic Anhydride Followed by Post-Polymerization Reactions Invited Reviewed

    Y. Terao, S. Sugihara, K. Satoh, M. Kamigaito

    Eur. Polym. J.   120   109225   2019.11

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    DOI： 10.1016/j.eurpolymj.2019.109225

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  • Fully bio-based polymer blend of polyamide 11 and Poly(vinylcatechol) showing thermodynamic miscibility and excellent engineering properties

    Takayuki Hirai, Jumpei Kawada, Mamiko Narita, Taiji Ikawa, Hisaaki Takeshima, Kotaro Satoh, Masami Kamigaito

    Polymer   181   2019.10

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    DOI： 10.1016/j.polymer.2019.121667

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  • Cationic Polymerization via Activation of Alkoxyamines Using Photoredox Catalysts

    Konya Masato, Uchiyama Mineto, Satoh Kotaro, Kamigaito Masami

    CHEMPHOTOCHEM   2019.7

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    DOI： 10.1002/cptc.201900148

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  • Ferulic Acid-Based Reactive Core-Shell Latex by Seeded Emulsion Polymerization Reviewed

    W.-S. J. Li, V. Ladmiral, H. Takeshima, K. Satoh, M. Kamigaito, M. Semsarilar, C. Negrell, P. Lacoix-Desmazes, S. Caillol

    Polym. Chem.   10 ( 23 )   3116-3126   2019.6

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    DOI： 10.1039/C9PY00079H

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  • Halogenation of Propagating Terminal in Anionic Polymerization of Isoprene for the Synthesis of Block Copolymers Reviewed

    K. Satoh, Y.Mori, M. Kamigaito

    Kobunshi Ronbunshu   76 ( 3 )   234-240   2019.5

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    DOI： 10.1295/koron.2019-0004

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  • Construction of Sequence-Regulated Vinyl Copolymers via Iterative Single Vinyl Monomer Additions and Subsequent Metal-Catalyzed Step-Growth Radical Polymerization Reviewed

    K Satoh, K. Ishizuka, T. Hamada, M. Handa, T. Abe, S. Ozawa, M. Miyajima, M. Kamigaito

    Macromolecules   52 ( 9 )   3327-3341   2019.5

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    DOI： 10.1021/acs.macromol.9b00676

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  • Cooperative Reduction of Various RAFT Polymer Terminals using Hydrosilane and Thiol via Polarity Reversal Catalysis Invited Reviewed

    M. Uchiyama, K. Satoh, M. Kamigaito

    Chem. Commun.   55 ( 37 )   5327-5330   2019.5

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    DOI： 10.1039/C9CC00900K

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  • Professor Mitsuo Sawamoto-sensei and innovator in polymer synthesis Reviewed

    Makoto Ouchi, Takaya Terashima, Masami Kamigaito, Kotaro Satoh

    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY   57 ( 3 )   197 - 198   2019.2

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    DOI： 10.1002/pola.29306

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  • R-Cl/SnCl4/n-Bu4NCl-induced direct living cationic polymerization of naturally-derived unprotected 4-vinylphenol, 4-vinylguaiacol, and 4-vinylcatechol in CH3CN Invited Reviewed

    Hisaaki Takeshima, Kotaro Satoh, Masami Kamigaito

    Polymer Chemistry   in press   2019.2

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  • Valencene as a naturally occurring sesquiterpene monomer for radical copolymerization with maleimide to induce concurrent 1:1 and 1:2 propagation Invited Reviewed

    Hiroaki Hashimoto, Hisaaki Takeshima, Tomonari Nagai, Mineto Uchiyama, Kotaro Satoh, Masami Kamigaito

    Polymer Degradation and Stability   161   183-190   2019.2

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    DOI： 10.1016/j.polymdegradstab.2019.01.025

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  • A User-Friendly Living Cationic Polymerization: Degenerative Chain-Transfer Polymerization of Vinyl Ethers by Simply Using Mixtures of Weak and Superstrong Protonic Acids Invited Reviewed

    Mineto Uchiyama, Masataka Sakaguchi, Kotaro Satoh, Masami Kamigaito

    Chinese J. Polym. Sci.   in press   2019.2

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  • Degenerative Chain-Transfer Process: Controlling All Chain-Growth Polymerizations and Enabling Novel Monomer Sequences Invited Reviewed

    M. Kamigaito, K. Satoh, M. Uchiyama

    J. Polym. Sci., Part A: Polym. Chem.   57   243-254   2019.1

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    DOI： 10.1002/pola.29257

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  • Direct through Anionic, Cationic, and Radical Active Species: Terminal Carbon-Halogen Bond for "Controlled"/Living Polymerizations of Styrene Invited Reviewed

    K. Satoh, Y. Mori, M. Kamigaito

    J. Polym. Sci., Part A: Polym. Chem.   57   465-473   2019.1

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    DOI： 10.1002/pola.29261

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  • Controlled Radical Copolymerization of Cinnamic Derivatives as Renewable Vinyl Monomers with Both Acrylic and Styrenic Substituents: Reactivity, Regioselectivity, Properties, and Functions Invited Reviewed

    Yuya Terao, Kotaro Satoh, Masami Kamigaito

    Biomacromolecules   20   192-203   2019.1

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    DOI： 10.1021/acs.biomac.8b01298

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  • Helix-Sense-Selective Copolymerization of Triphenylmethyl Methacrylate with Chiral 2- Isopropenyl-4-phenyl-2-oxazoline Invited Reviewed

    J. Shen, N. Ikeda, W. Bi, K. Satoh, M. Kamigaito, Y. Okamoto

    J. Polym. Sci., Part A: Polym. Chem.   57   441-447   2019.1

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    DOI： 10.1002/pola.29238

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  • Bio-based vinylphenol family: Synthesis via decarboxylation of naturally occurring cinnamic acids and living radical polymerization for functionalized polystyrenes

    Hisaaki Takeshima, Kotaro Satoh, Masami Kamigaito

    Journal of Polymer Science, Part A: Polymer Chemistry   2019

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    DOI： 10.1002/pola.29453

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  • Naturally-Derived Amphiphilic Polystyrenes Prepared by Aqueous Controlled/Living Cationic Polymerization and Copolymerization of Vinylguaiacol with R-OH/BF3OEt2 Invited Reviewed

    Hisaaki Takeshima, Kotaro Satoh, Masami Kamigaito

    Polymers   10 ( 2 )   1404(11pages)   2018.12

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    DOI： 10.3390/polym10121404

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  • Scalable Synthesis of Bio-Based Functional Styrene: Protected Vinyl Catechol from Caffeic Acid and Controlled Radical and Anionic Polymerizations Thereof Invited Reviewed

    Hisaaki Takeshima, Kotaro Satoh, Masami Kamigaito

    ACS Sustainable Chem. Eng.   6   13681-13686   2018.10

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    DOI： 10.1021/acssuschemeng.8b04400

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  • Metal Free Living Cationic Polymerisations via Carbon Sulphur Bonds

    M. Uchiyama, K. Satoh, M. Kamigaito

    International Polymer Science and Technology   43 ( 8 )   7 - 12   2018.9

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    DOI： 10.1177/0307174x1604300802

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  • Discrete and Stereospecific Oligomers Prepared by Sequential and Alternating Single Unit Monomer Insertion Reviewed

    Zixuan Huang, Benjamin B. Noble, Nathaniel Corrigan, Yingying Chu, Kotaro Satoh, Donald S. Thomas, Craig J. Hawker, Graeme Moad, Masami Kamigaito, Michelle L. Coote, Cyrille Boyer, Jiangtao Xu

    J. Am. Chem. Soc.   140   13392-13406   2018.9

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    DOI： 10.1021/jacs.8b08386

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  • Vinyl Ether/Vinyl Ester Copolymerization by Cationic and Radical Interconvertible Simultaneous Polymerization Invited Reviewed

    Kotaro Satoh, Yuuma Fujiki, Mineto Uchiyama, Masami Kamigaito

    ACS Symp. Ser.   1284   323-334   2018.8

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    DOI： 10.1021/bk-2018-1284.ch015

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  • Synthesis and stereocomplexation of PMMA-based star polymers prepared by a combination of stereospecific anionic polymerization and crosslinking radical polymerization Reviewed

    Naoya Usuki, Hisakazu Okura, Kotaro Satoh, Masami Kamigaito

    Journal of Polymer Science, Part A: Polymer Chemistry   56 ( 11 )   1123 - 1127   2018.6

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    DOI： 10.1002/pola.28995

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  • Synthesis of PEve- b -P(CTFE- alt -Eve) block copolymers by sequential cationic and radical RAFT polymerization Reviewed

    Marc Guerre, Mineto Uchiyama, Gérald Lopez, Bruno Améduri, Kotaro Satoh, Masami Kamigaito, Vincent Ladmiral

    Polymer Chemistry   9 ( 3 )   352 - 361   2018.1

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    DOI： 10.1039/c7py01924f

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  • Degenerative Chain Transfer for Precision Polymer Synthesis Invited Reviewed

    Masami Kamigaito, Kotaro Satoh, Mineto Uchiyama

    KOBUNSHI   67 ( 1 )   30-33   2018.1

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  • Spontaneous Synthesis of a Homogeneous Thermoresponsive Polymer Network Composed of Narrow Molecular Weight Distribution Polymers Invited Reviewed

    Y. Jochi, T. Seki, T. Soejima, K. Satoh, M. Kamigaito, Y. Takeoka

    NPG Asia Materials   10   840–848 - 848   2018

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    DOI： 10.1038/s41427-018-0074-x

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  • Synthesis of isotactic-block-syndiotactic poly(methyl methacrylate) via stereospecific living anionic polymerizations in combination with metal-halogen exchange, halogenation, and click reactions Reviewed

    Naoya Usuki, Kotaro Satoh, Masami Kamigaito

    Polymers   9 ( 12 )   723   2017.12

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    DOI： 10.3390/polym9120723

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  • Diverse approaches to star polymers via cationic and radical RAFT cross-linking reactions using mechanistic transformation Invited Reviewed

    Mineto Uchiyama, Kotaro Satoh, Thomas G. McKenzie, Qiang Fu, Greg. G. Qiao, Masami Kamigaito

    POLYMER CHEMISTRY   8 ( 38 )   5972 - 5981   2017.10

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    DOI： 10.1039/c7py01401e

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  • One-shot controlled/living copolymerization for various comonomer sequence distributions via dual radical and cationic active species from RAFT terminals Invited Reviewed

    Kotaro Satoh, Hideyuki Hashimoto, Shinya Kumagai, Hiroshi Aoshima, Mineto Uchiyama, Ryoma Ishibashi, Yuuma Fujiki, Masami Kamigaito

    POLYMER CHEMISTRY   8 ( 34 )   5002 - 5011   2017.9

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    DOI： 10.1039/c7py00324b

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  • Synthesis of Syndiotactic Macrocyclic Poly(methyl methacrylate) via Transformation of the Growing Terminal in Stereospecific Anionic Polymerization Invited Reviewed

    Naoya Usuki, Kotaro Satoh, Masami Kamigaito

    MACROMOLECULAR CHEMISTRY AND PHYSICS   218 ( 12 )   1700041   2017.6

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    DOI： 10.1002/macp.201700041

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  • Bio-Based Functional Styrene Monomers Derived from Naturally Occurring Ferulic Acid for Poly(vinylcatechol) and Poly(vinylguaiacol) via Controlled Radical Polymerization Invited Reviewed

    Hisaaki Takeshima, Kotaro Satoh, Masami Karnigaito

    MACROMOLECULES   50 ( 11 )   4206 - 4216   2017.6

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    DOI： 10.1021/acs.macromol.7b00970

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  • Combination of Cationic and Radical RAFT Polymerizations: A Versatile Route to Well-Defined Poly(ethyl vinyl ether)-block-poly(vinylidene fluoride) Block Copolymers Invited Reviewed

    Marc Guerre, Mineto Uchiyama, Enrique Folgado, Mona Semsarilar, Bruno Ameduri, Kotaro Satoh, Masami Kamigaito, Vincent Ladmiral

    ACS MACRO LETTERS   6 ( 4 )   393 - 398   2017.4

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    DOI： 10.1021/acsmacrolett.7b00150

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  • BAB-random-C Monomer Sequence via Radical Terpolymerization of Limonene(A), Maleimide(B), and Methacrylate(C): Terpene Polymers with Randomly Distributed Periodic Sequences Reviewed

    Masataka Ojika, Kotaro Satoh, Masami Kamigaito

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   56 ( 7 )   1789 - 1793   2017.2

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    DOI： 10.1002/anie.201610768

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  • Light Leads to Ultra-Long Polymer Chains in Water Invited Reviewed

    Masami Kamigaito, Kotaro Satoh

    CHEM   2 ( 1 )   13 - 15   2017.1

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    DOI： 10.1016/j.chempr.2016.12.010

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  • Metal-Free Living Cationic Polymerization via Degenerative Chain-Transfer Mechanism Invited Reviewed

    Mineto Uchiyama, Kotaro Satoh, Masami Kamigaito

    Journal of the Adhesion Society of Japan : adhesion   53 ( 5 )   179-187 - 187   2017

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  • Control of stereochemistry in atom transfer radical addition and step-growth radical polymerization by chiral transition metal catalysts Reviewed

    Takamasa Soejima, Kotaro Satoh, Masami Kamigaito

    TETRAHEDRON   72 ( 48 )   7657 - 7664   2016.12

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    DOI： 10.1016/j.tet.2016.01.060

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  • Diversifying Cationic RAFT Polymerization with Various Counteranions: Generation of Cationic Species from Organic Halides and Various Metal Salts Reviewed

    Mineto Uchiyama, Kotaro Satoh, Masami Kamigaito

    ACS MACRO LETTERS   5 ( 10 )   1157 - 1161   2016.10

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    DOI： 10.1021/acsmacrolett.6b00541

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  • Beyond Traditional RAFT: Alternative Activation of Thiocarbonylthio Compounds for Controlled Polymerization Reviewed

    Thomas G. McKenzie, Qiang Fu, Mineto Uchiyama, Kotaro Satoh, Jiangtao Xu, Cyrille Boyer, Masami Kamigaito, Greg G. Qiao

    ADVANCED SCIENCE   3 ( 9 )   1500394   2016.9

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    DOI： 10.1002/advs.201500394

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  • Cross-linked nanocellular polymer films: water- and oil-repellent anti-reflection coating Reviewed

    Cedric Dutriez, Kotaro Satoh, Masami Kamigaito, Hideaki Yokoyama

    POLYMER JOURNAL   48 ( 4 )   497 - 501   2016.4

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    DOI： 10.1038/pj.2016.7

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  • Stereoregular High-Density Bottlebrush Polymer and Its Organic Nanocrystal Stereocomplex through Triple-Helix Formation Reviewed

    Jing M. Ren, Kenji Ishitake, Kotaro Satoh, Anton Blencowe, Qiang Fu, Edgar H. H. Wong, Masami Kamigaito, Greg G. Qiao

    MACROMOLECULES   49 ( 3 )   788 - 795   2016.2

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    DOI： 10.1021/acs.macromol.5b02295

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  • Selective Ring-Opening Controlled Radical Polymerization of Pinocarvone Derived from α-Pinene to Bio-Based Polyketone Reviewed

    Hisanari Miyaji, Kotaro Satoh, Masami Kamigaito

    Angew. Chem. Int. Ed.   55   1372-1376   2016.1

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    DOI： 10.1002/anie.201509379

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  • Bio-Based Polyketones by Selective Ring-Opening Radical Polymerization of alpha-Pinene-Derived Pinocarvone Reviewed

    Hisanari Miyaji, Kotaro Satoh, Masami Kamigaito

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   55 ( 4 )   1372 - 1376   2016.1

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  • Main-Chain and Side-Chain Sequence-Regulated Vinyl Copolymers by Iterative Atom Transfer Radical Additions and 1:1 or 2:1 Alternating Radical Copolymerization Reviewed

    Takamasa Soejima, Kotaro Satoh, Masami Kamigaito

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   138 ( 3 )   944 - 954   2016.1

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    DOI： 10.1021/jacs.5b11631

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  • Fullerene peapod nanoparticles as an organic semiconductor-electrode interface layer Reviewed

    Jing M. Ren, Jegadesan Subbiah, Bolong Zhang, Kenji Ishitake, Kotaro Satoh, Masami Kamigaito, Greg G. Qiao, Edgar H. H. Wong, Wallace W. H. Wong

    CHEMICAL COMMUNICATIONS   52 ( 16 )   3356 - 3359   2016

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    DOI： 10.1039/c5cc10444k

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  • Sequence-regulated vinyl copolymers with acid and base monomer units via atom transfer radical addition and alternating radical copolymerization Reviewed

    Takamasa Soejima, Kotaro Satoh, Masami Kamigaito

    POLYMER CHEMISTRY   7 ( 29 )   4833 - 4841   2016

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    DOI： 10.1039/c6py00965d

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  • A phosphonium intermediate for cationic RAFT polymerization Reviewed

    Mineto Uchiyama, Kotaro Satoh, Masami Kamigaito

    POLYMER CHEMISTRY   7 ( 7 )   1387 - 1396   2016

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    DOI： 10.1039/c5py01879j

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  • Metal free living cationic polymerisations via carbon sulphur bonds (2) DT mechanism using thioethers

    M. Uchiyama, K. Satoh, M. Kamigaito

    International Polymer Science and Technology   43 ( 8 )   461 - 465   2016

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  • Controlled/living polymerization of renewable vinyl monomers into bio-based polymers Invited Reviewed

    Kotaro Satoh

    POLYMER JOURNAL   47 ( 8 )   527 - 536   2015.8

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    DOI： 10.1038/pj.2015.31

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  • Thioether-Mediated Degenerative Chain-Transfer Cationic Polymerization: A Simple Metal-Free System for Living Cationic Polymerization Reviewed

    Mineto Uchiyama, Kotaro Satoh, Masami Kamigaito

    MACROMOLECULES   48 ( 16 )   5533 - 5542   2015.8

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    DOI： 10.1021/acs.macromol.5b01341

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  • Monomer Sequence Regulation in Main and Side Chains of Vinyl Copolymers: Synthesis of Vinyl Oligomonomers via Sequential Atom Transfer Radical Addition and Their Alternating Radical Copolymerization Reviewed

    Takamasa Soejima, Kotaro Satoh, Masami Kamigaito

    ACS MACRO LETTERS   4 ( 7 )   745 - 749   2015.7

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    DOI： 10.1021/acsmacrolett.5b00379

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  • Cationic RAFT Polymerization Using ppm Concentrations of Organic Acid Reviewed

    Mineto Uchiyama, Kotaro Satoh, Masami Kamigaito

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   54 ( 6 )   1924 - 1928   2015.2

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    DOI： 10.1002/anie.201410858

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  • 植物由来ビニルモノマーから新規高分子を合成 Invited

    上垣外正己, 佐藤浩太郎

    現代化学   2015 ( 7 )   24-29 - 29   2015

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  • Metal-Free Living Cationic Polymerization via Carbon-Sulfur Bonds (1) RAFT Mechanism Using Thioesters Invited Reviewed

    Mineto Uchiyama, Kotaro Satoh, Masami Kamigaito

    JOURNAL OF THE SOCIETY OF RUBBER SCIENCE AND TECHNOLOGY   88 ( 10 )   391-396   2015

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    DOI： 10.2324/gomu.88.391

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  • Periodic introduction of water-tolerant titanatrane complex to poly(NIPAM) prepared by simultaneous step-growth and living radical polymerization Invited Reviewed

    Kotaro Satoh, Daisuke Ito, Masami Kamigaito

    ACS Symposium Series   1188   1-14 (2015)   2015

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    DOI： 10.1021/bk-2015-1188.ch001

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  • Controlled radical polymerization of styrene with magnetic iron oxides prepared through hydrothermal, bioinspired, and bacterial processes Reviewed

    Arihiro Kanazawa, Kotaro Satoh, Shokyoku Kanaoka, Masato Kakihana, Makoto Kobayashi, Junki Sato, Hiroaki Imai, Yuya Oaki, Atsushi Arakaki, Kiyofumi Katagiri, Masami Kamigaito, Sadahito Aoshima

    RSC ADVANCES   5 ( 63 )   51122 - 51129   2015

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    DOI： 10.1039/c5ra09149g

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  • Molecular mapping of poly(methyl methacrylate) super-helix stereocomplexes Reviewed

    Andrew Joseph Christofferson, George Yiapanis, Jing Ming Ren, Greg Guanghua Qiao, Kotaro Satoh, Masami Kamigaito, Irene Yarovsky

    CHEMICAL SCIENCE   6 ( 2 )   1370 - 1378   2015

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    DOI： 10.1039/c4sc02971b

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  • 活性種の分類を超えた高分子合成戦略 Invited

    佐藤浩太郎

    DivisionTopics, 化学と工業   68   224   2015

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  • Controlled/Living Polymerization of Naturally Occurring Terpenes Invited Reviewed

    Kotaro Satoh, Masami Kamigaito

    KOBUNSHI RONBUNSHU   72 ( 7 )   421 - 432   2015

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    DOI： 10.1295/koron.2015-0011

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  • Metal-Free Living Cationic Polymerization 2: DT Mechanism Using Thioethers Invited Reviewed

    Mineto Uchiyama, Kotaro Satoh, Masami Kamigaito

    JOURNAL OF THE SOCIETY OF RUBBER SCIENCE AND TECHNOLOGY   88 ( 12 )   461-465 - 465   2015

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    This second review on novel metal-free cationic polymerizations is directed to living cationic polymerization that proceeds via reversible activation of carbon-sulfur bonds of thioethers via degenerative chain-transfer (DT) mechanism. In a similar way to cationic RAFT polymerization in the first review, a small amount of triflic acid generates the cationic propagating species, which interchanges with the thioether-dormant species via the sulfonium intermediate stabilized by the sulfur atom, to induce living cationic polymerization via the DT mechanism. This system can similarly control the molecular weight up to 1×105 with narrow molecular weight distributions (Mw/Mn < 1.2) and controlled chain-end groups in cationic polymerization of vinyl ethers and p-alkoxystyrene. The thioether-dormant species is highly stable and tolerant in comparison to the dormant species thus far reported in living cationic polymerization. This makes the obtained polymers applicable for subsequent post-polymerization reactions without any significant damages on the C-S bonds.

    DOI： 10.2324/gomu.88.461

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  • Interconvertible Living Radical and Cationic Polymerization through Reversible Activation of Dormant Species with Dual Activity Reviewed

    Hiroshi Aoshima, Mineto Uchiyama, Kotaro Satoh, Masami Kamigaito

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   53 ( 41 )   10932 - 10936   2014.10

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    DOI： 10.1002/anie.201406590

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  • Precision Control of Monomer Sequences in Vinyl Copolymers Invited

    Kotaro Satoh, Masami Kamigaito

    KOBUNSHI   63 ( 10 )   715-717   2014.10

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  • Synthesis of Titanium-Containing Block, Random, End-Functionalized, and Junction-Functionalized Polymers via Ruthenium-Catalyzed Living Radical Polymerization and Direct Observation of Titanium Domains by Electron Microscopy Reviewed

    Yasutaka Tsujimoto, Kotaro Satoh, Hidekazu Sugimori, Hiroshi Jinnai, Masami Kamigaito

    MACROMOLECULES   47 ( 3 )   944 - 953   2014.2

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    DOI： 10.1021/ma402332g

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  • きっちり包めばきれいにつくれる 立体規則性ラジカル包接重合 Invited

    佐藤浩太郎

    化学   69 ( 1 )   70-71   2014.1

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  • Precision Synthesis of Bio- Based Acrylic Thermoplastic Elastomer by RAFT Polymerization of Itaconic Acid Derivatives Reviewed

    Kotaro Satoh, Dong-Hyung Lee, Kanji Nagai, Masami Kamigaito

    MACROMOLECULAR RAPID COMMUNICATIONS   35 ( 2 )   161 - 167   2014.1

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    DOI： 10.1002/marc.201300638

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  • Stereospecific Cyclic Poly(methyl methacrylate) and Its Topology-Guided Hierarchically Controlled Supramolecular Assemblies Reviewed

    Jing Ming Ren, Kotaro Satoh, Tor Kit Goh, Anton Blencowe, Kanji Nagai, Kenji Ishitake, Andrew Joseph Christofferson, George Yiapanis, Irene Yarovsky, Masami Kamigaito, Greg Guanghua Qiao

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   53 ( 2 )   459 - 464   2014.1

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    DOI： 10.1002/anie.201308366

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  • Synthesis of side-chain-sequenced copolymers using vinyl oligomonomers via sequential single-monomer ATRA Invited Reviewed

    Takamasa Soejima, Kotaro Satoh, Masami Kamigaito

    ACS Symposium Series   1170   189 - 200   2014

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    DOI： 10.1021/bk-2014-1170.ch012

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  • Sustainable cycloolefin polymer from pine tree oil for optoelectronics material: living cationic polymerization of beta-pinene and catalytic hydrogenation of high-molecular-weight hydrogenated poly(beta-pinene) Reviewed

    Kotaro Satoh, Atsuhiro Nakahara, Kazunori Mukunoki, Hiroko Sugiyama, Hiromu Saito, Masami Kamigaito

    POLYMER CHEMISTRY   5 ( 9 )   3222 - 3230   2014

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    DOI： 10.1039/c3py01320k

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  • Construction of Vinyl Polymer and Polyester or Polyamide Units in a Single Polymer Chain via Metal-catalyzed Simultaneous Chain- and Step-growth Radical Polymerization of Various Monomers Invited Reviewed

    Masato Mizutani, Kotaro Satoh, Masami Kamigaito

    AUSTRALIAN JOURNAL OF CHEMISTRY   67 ( 4 )   544 - 554   2014

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    DOI： 10.1071/CH13476

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  • Renewable beta-methylstyrenes for bio-based heat-resistant styrenic copolymers: radical copolymerization enhanced by fluoroalcohol and controlled/living copolymerization by RAFT Reviewed

    Yoshiki Nonoyama, Kotaro Satoh, Masami Kamigaito

    POLYMER CHEMISTRY   5 ( 9 )   3182 - 3189   2014

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    DOI： 10.1039/c3py01066j

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  • Sequence-controlled vinyl polymers by transition metal-catalyzed step-growth and living radical polymerizations Reviewed

    Kotaro Satoh, Masami Kamigaito

    Materials Research Society Symposium Proceedings   1613   17 - 21   2014

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    DOI： 10.1557/opl.2014.153

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  • 植物由来のビニルモノマーを精密に重合して機能性バイオベースポリマーをつくる Invited Reviewed

    佐藤浩太郎, 上垣外正己

    バイオプラジャーナル   13 ( 51 )   12-17 - 17   2013.11

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  • さまざまな植物由来ビニルモノマーの制御重合 Invited Reviewed

    佐藤浩太郎, 上垣外正己

    接着の技術   33 ( 2 )   6-10   2013.9

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  • Periodically Functionalized and Grafted Copolymers via 1:2-Sequence-Regulated Radical Copolymerization of Naturally Occurring Functional Limonene and Maleimide Derivatives Reviewed

    Masaru Matsuda, Kotaro Satoh, Masami Kamigaito

    MACROMOLECULES   46 ( 14 )   5473 - 5482   2013.7

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    DOI： 10.1021/ma401021d

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  • Asymmetric anionic polymerization of tris(trimethylsilyl) silyl methacrylate: a highly isotactic helical chiral polymer Invited Reviewed

    Kenji Ishitake, Kotaro Satoh, Masami Kamigaito, Yoshio Okamoto

    POLYMER JOURNAL   45 ( 6 )   676 - 680   2013.6

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    DOI： 10.1038/pj.2012.178

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  • Direct Mechanistic Transformations from Isotactic or Syndiotactic Living Anionic Polymerizations of Methyl Methacrylate into Metal-Catalyzed Living Radical Polymerizations Reviewed

    Hiroshi Aoshima, Kotaro Satoh, Masami Kamigaito

    ACS MACRO LETTERS   2 ( 1 )   72 - 76   2013.1

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    DOI： 10.1021/mz300586m

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  • 1:2-Sequence-Regulated Radical Copolymerization of Naturally Occurring Terpenes with Maleimide Derivatives in Fluorinated Alcohol Reviewed

    Masaru Matsuda, Kotaro Satoh, Masami Kamigaito

    Journal of Polymer Science: Part A: Polymer Chemistry   51   1774-1785   2013.1

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  • In situ direct mechanistic transformation from FeCl3-catalyzed living cationic to radical polymerizations Invited Reviewed

    Hiroshi Aoshima, Kotaro Satoh, Masami Kamigaito

    Macromolecular Symposia   323 ( 1 )   64 - 74   2013.1

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    DOI： 10.1002/masy.201100115

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  • A Simple Combination of Higher-Oxidation-State FeX3 and Phosphine or Amine Ligand for Living Radical Polymerization of Styrene, Methacrylate, and Acrylate Reviewed

    Hiroshi Aoshima, Kotaro Satoh, Tomonari Umemura, Masami Kamigaito

    Polym. Chem.   4   3554-3562   2013

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  • 研究室紹介—北から南から Invited

    上垣外正己, 佐藤浩太郎, 永井寛嗣

    Organometallic News   ( 1 )   40-41   2013

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  • 植物由来ビニルモノマーの精密重合による新規バイオベースポリマーの構築 Invited Reviewed

    上垣外正己, 佐藤浩太郎

    材料の科学と工学   50 ( 1 )   20-25   2013

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  • 遷移金属触媒による逐次ラジカル重合を用いた精密構造制御ポリマー Invited Reviewed

    佐藤浩太郎, 上垣外正己

    触媒   55 ( 2 )   78-85   2013

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  • Controlled Radical Copolymerization of Naturally-Occurring Terpenes with Acrylic Monomers in Fluorinated Alcohol Invited Reviewed

    M. Matsuda, K. Satoh, M. Kamigaito

    KGK, Kautsch. Gummi Kunstst.   66   51-56   2013

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  • Cyclic Block Copolymers for Controlling Feature Sizes in Block Copolymer Lithography Reviewed

    Justin E. Poelma, Kosuke Ono, Daigo Miyajima, Takuzo Aida, Kotaro Satoh, Craig J. Hawker

    ACS NANO   6 ( 12 )   10845 - 10854   2012.12

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    DOI： 10.1021/nn304217y

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  • Kinetic Hydrate Inhibition of Poly(N-isopropylmethacrylamide)s with Different Tacticities Reviewed

    P. C. Chua, M. A. Kelland, K. Ishitake, K. Satoh, M. Kamigaito, Y. Okamoto

    Energy & Fuels   26   3577-3585   2012.5

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  • Intramolecular friedel-crafts cyclization and subsequent hydrogenation of styrene-isoprene random copolymers prepared by anionic polymerization for thermally-resistant and optical applications Reviewed

    Atsuhiro Nakahara, Kotaro Satoh, Hiromu Saito, Masami Kamigaito

    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY   50 ( 7 )   1298 - 1307   2012.4

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    DOI： 10.1002/pola.25894

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  • Design and Synthesis of Self-Degradable Antibacterial Polymers by Simultaneous Chain- and Step-Growth Radical Copolymerization Reviewed

    Mizutani, Masato, Palermo, Edmund, Thoma, Laura, Satoh, Kotaro, Kamigaito, Masami, Kuroda, Kenichi

    Biomacromolecules   13   1554–1563   2012.4

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  • 海外研究室レポート—UCSB での研究と留学生活 Invited

    佐藤浩太郎

    Organometallic News   ( 2 )   58-59   2012

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  • Metal-Catalyzed Step-Growth Radical Polymerization of AA and BB Monomers for Monomer Sequence Regulation Invited Reviewed

    Kotaro Satoh, Tomohiro Abe, Masami Kamigaito

    PROGRESS IN CONTROLLED RADICAL POLYMERIZATION: MECHANISMS AND TECHNIQUES   1100   133 - 144   2012

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    DOI： 10.1021/bk-2012-1100.ch009

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  • Random copolymer of styrene and diene derivatives via anionic living polymerization followed by intramolecular Friedel-Crafts cyclization for high-performance thermoplastics Reviewed

    Atsuhiro Nakahara, Kotaro Satoh, Masami Kamigaito

    POLYMER CHEMISTRY   3 ( 1 )   190 - 197   2012

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    DOI： 10.1039/c1py00433f

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  • A facile synthesis of clickable and acid-cleavable PEO for acid-degradable block copolymers Reviewed

    Kotaro Satoh, Justin E. Poelma, Luis M. Campos, Brian Stahl, Craig J. Hawker

    POLYMER CHEMISTRY   3 ( 7 )   1890 - 1898   2012

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    DOI： 10.1039/c1py00484k

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  • From-syndiotactic-to-isotactic stereogradient methacrylic polymers by RAFT copolymerization of methacrylic acid and its bulky esters Invited Reviewed

    Kenji Ishitake, Kotaro Satoh, Masami Kamigaito, Yoshio Okamoto

    POLYMER CHEMISTRY   3 ( 7 )   1750 - 1757   2012

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    DOI： 10.1039/c1py00401h

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  • Transition Metal Complexes for Metal-Catalyzed Atom Transfer Controlled/Living Radical Polymerization Reviewed

    K. Satoh, M. Kamigaito, M. Sawamoto

    Polymer Science: A Comprehensive Reference, 10 Volume Set   3   429 - 461   2012

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    DOI： 10.1016/B978-0-444-53349-4.00072-8

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  • Nanocellular foaming of fluorine containing block copolymers in carbon dioxide: the role of glass transition in carbon dioxide Reviewed

    Cedric Dutriez, Kotaro Satoh, Masami Kamigaito, Hideaki Yokoyama

    RSC ADVANCES   2 ( 7 )   2821 - 2827   2012

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    DOI： 10.1039/c2ra01268e

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  • Stereospecific Free Radical and RAFT Polymerization of Bulky Silyl Methacrylates for Tacticity and Molecular Weight Controlled Poly(methacrylic acid) Reviewed

    Kenji Ishitake, Kotaro Satoh, Masami Kamigaito, Yoshio Okamoto

    MACROMOLECULES   44 ( 23 )   9108 - 9117   2011.12

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    DOI： 10.1021/ma202155b

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  • Transition metal-catalyzed step-growth radical polymerization Invited Reviewed

    Kotaro Satoh, Masato Mizutani, Masami Kamioaito

    Kobunshi Ronbunshu   68 ( 7 )   436 - 456   2011.7

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    DOI： 10.1295/koron.68.436

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  • Degradable Poly(N-isopropylacrylamide) with Tunable Thermosensitivity by Simultaneous Chain- and Step-Growth Radical Polymerization Reviewed

    M. Mizutani, K. Satoh, M. Kamigaito

    Macromolecules   44 ( 7 )   2382-2386   2011.4

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  • Iron Oxides as Heterogeneous Catalysts for Controlled/Living Radical Polymerization of Styrene and Methyl Methacrylate Reviewed

    A. Kanazawa, K. Satoh, M. Kamigaito

    Macromolecules   44 ( 7 )   1927-1933   2011.4

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  • Highly Efficient Synthesis of Low Polydispersity Core Cross-Linked Star Polymers by Ru-Catalyzed Living Radical Polymerization Reviewed

    Tor Kit Goh, Satoshi Yamashita, Kotaro Satoh, Anton Blencowe, Masami Kamigaito, Greg G. Qiao

    MACROMOLECULAR RAPID COMMUNICATIONS   32 ( 5 )   456 - 461   2011.3

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    DOI： 10.1002/marc.201000641

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  • Nucleobase-Mediated Stereospecific Radical Polymerization and Combination with RAFT Polymerization for Simultaneous Control of Molecular Weight and Tacticity Reviewed

    Youhua Tao, Kotaro Satoh, Masami Kamigaito

    MACROMOLECULAR RAPID COMMUNICATIONS   32 ( 2 )   226 - 232   2011.1

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    DOI： 10.1002/marc.201000614

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  • In-Situ Direct Mechanistic Transformation from RAFT to Living Cationic Polymerization for (Meth)acrylate-Vinyl Ether Block Copolymers Reviewed

    Shinya Kumagai, Kanji Nagai, Kotaro Satoh, Masami Kamigaito

    MACROMOLECULES   43 ( 18 )   7523 - 7531   2010.9

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    DOI： 10.1021/ma101420u

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  • AAB-Sequence Living Radical Chain Copolymerization of Naturally Occurring Limonene with Maleimide: An End-to-End Sequence-Regulated Copolymer Reviewed

    Kotaro Satoh, Masaru Matsuda, Kanji Nagai, Masami Kamigaito

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   132 ( 29 )   10003 - 10005   2010.7

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    DOI： 10.1021/ja1042353

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  • Metal-Catalyzed Simultaneous Chain- and Step-Growth Radical Polymerization: Marriage of Vinyl Polymers and Polyesters Reviewed

    Masato Mizutani, Kotaro Satoh, Masami Kamigaito

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   132 ( 21 )   7498 - 7507   2010.6

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    DOI： 10.1021/ja1023892

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  • Sequence-regulated vinyl copolymers by metal-catalysed step-growth radical polymerization Reviewed

    Kotaro Satoh, Satoshi Ozawa, Masato Mizutani, Kanji Nagai, Masami Kamigaito

    NATURE COMMUNICATIONS   1   1:6   2010.4

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    DOI： 10.1038/ncomms1004

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  • Precision Polymerization of Naturally-Occurring Vinyl Monomers for Novel High-Performance Polymers Invited Reviewed

    SATOH Kotaro, KAMIGAITO Masami

    Journal of the Adhesion Society of Japan   46 ( 1 )   29-36 - 36   2010

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  • 精密に構造制御しながら高分子を合成する―ラジカル重合での挑戦― Invited

    上垣外正己, 佐藤浩太郎, 永井寛嗣

    現代化学   471 ( 471 )   32-37 - 37   2010

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  • ラジカル重合における配列制御 Invited

    上垣外正己, 佐藤浩太郎

    高分子   59 ( 10 )   781-784   2010

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  • Mn-2(CO)(10)-Induced Controlled/Living Radical Copolymerization of Methyl Acrylate and 1-Hexene in Fluoroalcohol: High alpha-Olefin Content Copolymers with Controlled Molecular Weights Reviewed

    Kazuhiko Koumura, Kotaro Satoh, Masami Kamigaito

    MACROMOLECULES   42 ( 7 )   2497 - 2504   2009.4

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    DOI： 10.1021/ma9001275

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  • Stereogradient Polymers Formed by Controlled/Living Radical Polymerization of Bulky Methacrylate Monomers Reviewed

    Kenji Ishitake, Kotaro Satoh, Masami Kamigaito, Yoshio Okamoto

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   48 ( 11 )   1991 - 1994   2009

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    DOI： 10.1002/anie.200805168

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  • Thiourea-Mediated Stereospecific Radical Polymerization of Acrylamides and Combination with RAFT for Simultaneous Control of Molecular Weight and Tacticity Invited Reviewed

    Harumi Murayama, Kotaro Satoh, Masami Kamigaito

    CONTROLLED/LIVING RADICAL POLYMERIZATION: PROGRESS IN RAFT, DT, NMP & OMRP   1024   49 - 63   2009

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  • Mn-2(CO)(10)-Induced RAFT Polymerization of Vinyl Acetate, Methyl Acrylate, and Styrene Reviewed

    Kazuhiko Koumura, Kotaro Satoh, Masami Kamigaito

    POLYMER JOURNAL   41 ( 8 )   595 - 603   2009

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    DOI： 10.1295/polymj.PJ2009070

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  • Cycloolefin Copolymer Analogues from Styrene and Isoprene: Cationic Cyclization of the Random Copolymers Prepared by Living Anionic Polymerization Invited Reviewed

    A. Nakahara, K. Satoh, M. Kamigaito

    Macromolecules   42 ( 3 )   620–625   2009

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  • Metal-Catalyzed Living Radical Polymerization and Radical Polyaddition for Precision Polymer Synthesis Invited Reviewed

    M. Mizutani, K. Satoh, M. Kamigaito

    J. Phys: Conf. Ser.   184   012025   2009

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  • Mn2(CO)10-Induced Controlled/Living Radical Copolymerization of Vinyl Acetate and Methyl Acrylate: Spontaneous Formation of Block Copolymers Consisting of Gradient and Homopolymer Segments Reviewed

    K. Koumura, K. Satoh, M. Kamigaito

    Journal of Polymer Science: Part A: Polymer Chemistry   47 ( 5 )   1343-1353   2009

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  • Metal-Catalyzed Radical Polyaddition for Aliphatic Polyesters via Evolution of Atom Transfer Radical Addition into Step-Growth Polymerization Invited Reviewed

    M. Mizutani, K. Satoh, M. Kamigaito

    Macromolecules   42 ( 2 )   472-480   2009

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  • Nano-to-Macroscale Poly(methyl methacrylate) Stereocomplex Assemblies Reviewed

    Tor Kit Goh, Jing Fung Tan, Stefanie Nina Guntari, Kotaro Satoh, Anton Blencowe, Masami Kamigaito, Greg Guanghua Qiao

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   48 ( 46 )   8707 - 8711   2009

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    DOI： 10.1002/anie.200903932

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  • *Stereospecific Living Radical Polymerization: Dual Control of Chain Length and Tacticity for Precision Polymer Synthesis Invited Reviewed

    K. Satoh, M. Kamigaito

    Chem. Rev.   109   5120-5156   2009

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  • ラジカル重合 Invited Reviewed

    上垣外正己, 佐藤浩太郎

    ネットワークポリマー   30 ( 5 )   234-249   2009

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  • Stereogradient Polymers via Spontaneously Increasing Isospecificity during Controlled/Living Radical Polymerization of Bulky Methacrylate Invited Reviewed

    K. Ishitake, K. Satoh, M. Kamigaito, Y. Okamoto

    Angew. Chem. Int. Ed.   48 ( 11 )   1991-1994   2009

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  • 低環境負荷型重合系の開発―極性モノマーの重合反応制御から実用化まで Invited

    佐藤浩太郎, 上垣外正己

    化学   63 ( 11 )   70-71   2008.11

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  • Manganese-Based Controlled/Living Radical Polymerization of Vinyl Acetate, Methyl Acrylate, and Styrene: Highly Active, Versatile, and Photoresponsive Systems Invited Reviewed

    Kazuhiko Koumura, Kotaro Satoh, Masami Kamigaito

    MACROMOLECULES   41 ( 20 )   7359 - 7367   2008.10

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    DOI： 10.1021/ma801151s

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  • 遷移金属錯体を用いたリビングラジカル重合による多重制御グラフト共重合体 Invited Reviewed

    佐藤浩太郎, 上垣外正己

    日本ゴム協会誌   81 ( 10 )   424-430   2008.10

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  • Iron(III) Chloride/R-Cl/Tributylphosphine for Metal-Catalyzed Living Radical Polymerization: A Unique System with a Higher Oxidation State Iron Complex Reviewed

    KOTARO SATOH, HIROSHI AOSHIMA, MASAMI KAMIGAITO

    Journal of Polymer Science: Part A: Polymer Chemistry   46   6358-6363   2008.8

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  • ラジカル重合における精密制御 ― 分子量、立体構造、モノマー配列の制御 Invited

    上垣外正己, 佐藤浩太郎

    有機合成化学協会誌   66 ( 6 )   578-589   2008.6

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  • Precision control in radical polymerization - Control of molecular weight, stereochemistry, and monomer sequence Reviewed

    Masami Kamigaito, Kotaro Satoh

    JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN   66 ( 6 )   578 - 589   2008.6

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  • Regiospecific radical polymerization of vinyl methacrylate in the presence of lewis acids into soluble polymers with pendent vinyl ester substituents Invited Reviewed

    Fumitaka Sugiyama, Kotaro Satoh, Masami Kamigaito

    MACROMOLECULES   41 ( 9 )   3042 - 3048   2008.5

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    DOI： 10.1021/ma702855s

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  • Development of functional polymers by precision polymerization: novel alicyclic hydrocarbon polymer by living cationic polymerization Invited Reviewed

    59 ( 1 )   1-9 - 9   2008.1

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  • Stereoregulation in living radical polymerization Invited Reviewed

    Masami Kamigaito, Kotaro Satoh

    MACROMOLECULES   41 ( 2 )   269 - 276   2008.1

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  • リビングラジカル重合の基礎と展開 Invited

    上垣外正己, 佐藤浩太郎

    色材協会誌   81 ( 11 )   459-470   2008

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  • Nanometer voids prevent crack growth in polymeric materials Reviewed

    Cedric Dutriez, Kotaro Satoh, Masami Kamigaito, Hideaki Yokoyama

    MACROMOLECULES   40 ( 21 )   7433 - 7436   2007.10

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    DOI： 10.1021/ma071262p

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  • A linear lignin analogue: Phenolic alternating copolymers from naturally occurring beta-methylstyrene via aqueous-controlled cationic copolymerization Reviewed

    Kotaro Satoh, Shoichi Saitoh, Masami Kamigaito

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   129 ( 31 )   9586 - +   2007.8

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    DOI： 10.1021/ja0732227

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  • A(x)BA(x)-type block-graft polymers with middle soft segments and outer hard graft chains by ruthenium-catalyzed living radical polymerization: Synthesis and characterization Reviewed

    Yu Miura, Kotaro Satoh, Masami Kamigaito, Yoshio Okamoto, Takeshi Kaneko, Hiroshi Jinnai, Syuji Kobukata

    MACROMOLECULES   40 ( 3 )   465 - 473   2007.2

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    DOI： 10.1021/ma062098t

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  • Chiral (-)-DIOP ruthenium complexes for asymmetric radical addition and living radical polymerization reactions Reviewed

    Yusuke Iizuka, Zhaoming Li, Kotaro Satoh, Masarni Karnigaito, Yoshio Okamoto, Jun-ichi Ito, Hisao Nishiyama

    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY   2007 ( 5 )   782 - 791   2007.2

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    DOI： 10.1002/ejoc.200600862

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  • A Neutron Reflectivity Study on a Terraced Lamellar Morphology in a Block Copolymer Thin Film Reviewed

    Ken-ichi Niihara, Ukyo Matsuwaki, Naoya Torikai, Kotaro Satoh, Masami Kamigaito, Hiroshi Jinnai

    POLYMER JOURNAL   39 ( 11 )   1105 - 1111   2007

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    DOI： 10.1295/polymj.PJ2007100

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  • Metal-catalyzed radical polyaddition as a novel polymer synthetic route Reviewed

    Kotaro Satoh, Masato Mizutani, Masami Kamigaito

    CHEMICAL COMMUNICATIONS   2007 ( 12 )   1260 - 1262   2007

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    DOI： 10.1039/b616598b

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  • A(x)BA(x)-type block-graft polymers with soft methacrylate middle segments and hard styrene outer grafts: Synthesis, morphology, and mechanical properties Reviewed

    Yu Miura, Takeshi Kaneko, Kotaro Satoh, Masami Kamigaito, Hiroshi Jinnai, Yoshio Okamoto

    CHEMISTRY-AN ASIAN JOURNAL   2 ( 5 )   662 - 672   2007

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    DOI： 10.1002/asia.200600403

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  • Stereogradient polymers by ruthenium-catalyzed stereospecific living radical copolymerization of two monomers with different stereospecificities and reactivities Reviewed

    Yu Miura, Takuya Shibata, Kotaro Satoh, Masami Kamigaito, Yoshio Okamoto

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   128 ( 50 )   16026 - 16027   2006.12

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    DOI： 10.1021/ja067587n

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  • A bicyclic conjugated diene monomer, tetrahydroindene, for cationic polymerization and a novel alicyclic hydrocarbon polymer with heat resistance Reviewed

    Naomi Mizuno, Kotaro Satoh, Masami Kamigaito, Yoshio Okamoto

    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY   44 ( 21 )   6214 - 6225   2006.11

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    DOI： 10.1002/pola.21714

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  • Triple hydrogen bonding for stereospecific radical polymerization of a DAD monomer and simultaneous control of tacticity and molecular weight Reviewed

    Decheng Wan, Kotaro Satoh, Masami Kamigaito

    MACROMOLECULES   39 ( 20 )   6882 - 6886   2006.10

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    DOI： 10.1021/ma0615654

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  • Cationic polymerization of a novel bicyclic conjugated diene monomer, tetrahydroindene, and its block copolymers with vinyl ether Reviewed

    Naomi Mizuno, Kotaro Satoh, Masami Kamigaito, Yoshio Okamoto

    MACROMOLECULES   39 ( 16 )   5280 - 5285   2006.8

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    DOI： 10.1021/ma060911e

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  • Simultaneous control of the stereospecificity and molecular weight in the ruthenium-catalyzed living radical polymerization of methyl and 2-hydroxyethyl methacrylates and sequential synthesis of stereoblock polymers Reviewed

    Takuya Shibata, Kotaro Satoh, Masami Kamigaito, Yoshio Okamot

    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY   44 ( 11 )   3609 - 3615   2006.6

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    DOI： 10.1002/pola.21469

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  • Iodine transfer radical polymerization of vinyl acetate in fluoroalcohols for simultaneous control of molecular weight, stereospecificity, and regiospecificity Reviewed

    Kazuhiko Koumura, Kotaro Satoh, Masami Kamigaito, Yoshio Okamoto

    MACROMOLECULES   39 ( 12 )   4054 - 4061   2006.6

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    DOI： 10.1021/ma0602775

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  • Iron-catalyzed radical polymerization of acrylamides in the presence of Lewis acid for simultaneous control of molecular weight and tacticity Reviewed

    Y Sugiyama, K Satoh, M Kamigaito, Y Okamoto

    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY   44 ( 6 )   2086 - 2098   2006.3

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    DOI： 10.1002/pola.21310

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  • Stereospecific Living Radical Polymerization for Simultaneous Control of Molecular Weight and Tacticity Invited Reviewed

    M. Kamigaito, K. Satoh

    J. Polym. Sci.: Part A: Polym. Chem.   44   6147-6158   2006

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  • 立体特異性リビングラジカル重合 Invited

    上垣外正己, 佐藤浩太郎

    高分子   55   250-253   2006

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  • A "ladder" morphology in an ABC triblock copolymer Reviewed

    Takeshi Kaneko, Kazuya Suda, Kotaro Satoh, Masami Kamigaito, Toshinori Kato, Tomohiro Ono, Eiji Nakamura, Toshio Nishi, Hiroshi Jinnai

    MACROMOLECULAR SYMPOSIA   242   80 - 86   2006

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    DOI： 10.1002/masy.200651013

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  • Biomass-Derived Heat-Resistant Alicyclic Hydrocarbon Polymers: Poly(terpenes) and Their Hydrogenated Derivatives Reviewed

    K. Satoh, H. Sugiyama, M. Kamigaito

    Green Chemistry   8   878-882   2006

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  • Radical polymerization of unsymmetrical divinyl compounds with lewis acid

    Fumitaka Sugiyama, Kotaro Satoh, Masami Kamigaito

    Polymer Preprints, Japan   55 ( 1 )   167   2006

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  • Living cationic polymerization of plant-originated terpenes

    Hiroko Sugiyama, Kotaro Satoh, Masami Kamigaito

    Polymer Preprints, Japan   55 ( 2 )   2515 - 2516   2006

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  • Well-defined graft copolymers of methacrylate, acrylate, and styrene via ruthenium-catalyzed living radical polymerization Reviewed

    Yu Miura, Kotaro Satoh, Masami Kamigaito, Yoshio Okamoto

    POLYMER JOURNAL   38 ( 9 )   930 - 939   2006

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    DOI： 10.1295/polymj.PJ2006031

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  • Stereospecific living radical polymerization of 2-hydroxyethyl methacrylate

    Takuya Smbata, Kotaro Satoh, Masami Kamigaito, Yoshio Okamoto

    Polymer Preprints, Japan   55 ( 1 )   448   2006

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  • Stereospecific Living Radical Polymerization Invited Reviewed

    M. Kamigaito, K. Satoh, D. Wan, K. Koumura, T, Shibata, Y. Okamoto

    ACS Symposium Series   994   26-39   2006

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  • Xanthate-mediated radical polymerization of N-vinylpyrrolidone in fluoroalcohols for simultaneous control of molecular weight and tacticity Reviewed

    DC Wan, K Satoh, M Kamigaito, Y Okamoto

    MACROMOLECULES   38 ( 25 )   10397 - 10405   2005.12

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    DOI： 10.1021/ma0515230

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  • Stereospecific living radical polymerization of hydroxy-functionalized monomer with transition metal complex

    Takuva Shibata, Yuya Sugiyama, Kotaro Satoh, Masami Kamigaito, Yoshio Okamoto

    Polymer Preprints, Japan   54 ( 1 )   184   2005

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  • Living cationic polymerization of tetrahydroindene: Synthesis and characterization of nobel poly(cycloolefin)

    Naomi Mizuno, Kotaro Satoh, Masami Kamigaito, Yoshio Okamoto

    Polymer Preprints, Japan   54 ( 2 )   2456   2005

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  • Radical addition and polymerization with chiral ruthenium complexes

    Zhaoming Li, Kotaro Satoh, Masami Kamigaito, Yoshio Okamoto

    Polymer Preprints, Japan   54 ( 1 )   188   2005

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  • Controlled radical polymerization of vinyl acetate: Control by catalysts and additives

    Kazuhiko Koumura, Kotaro Satoh, Masami Kamigaito, Yoshio Okamoto

    Polymer Preprints, Japan   54 ( 2 )   2482   2005

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  • Cationic Polymerization in Aqueous Media with Water-Tolerant Lewis Acids Reviewed

    Kotaro Satoh

    KOBUNSHI RONBUNSHU   62 ( 8 )   335-351   2005

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  • Controlled Cationic Polymerization of p-(Chloromethyl)styrene: BF3-Catalyzed Selective Activation of a C-O Terminal from Alcohol Reviewed

    M. Kamigaito, J. Nakashima, K. Satoh, M. Sawamoto

    Macromolecules   36   3540-3544   2003

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  • Novel BF3OEt2/R-OH initiating system for controlled cationic polymerization of styrene in the presence of water Reviewed

    K Satoh, J Nakashima, Kamigaito, I, M Sawamoto

    MACROMOLECULES   34 ( 3 )   396 - 401   2001.1

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    DOI： 10.1021/ma0006070

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  • Direct synthesis of amphiphilic random and block copolymers of p-hydroxystyrene and p-methoxystyrene via living cationic polymerization with BF3OEt2/ROH systems Reviewed

    K Satoh, M Kamigaito, M Sawamoto

    MACROMOLECULES   33 ( 16 )   5830 - 5835   2000.8

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  • Direct living cationic polymerization of p-hydroxystyrene with boron trifluoride etherate in the presence of water Reviewed

    K Satoh, M Kamigaito, M Sawamoto

    MACROMOLECULES   33 ( 15 )   5405 - 5410   2000.7

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  • Lanthanide triflates-mediated emulsion cationic polymerization of p-alkoxystyrenes in aqueous media Reviewed

    K Satoh, M Kamigaito, M Sawamoto

    MACROMOLECULES   33 ( 13 )   4660 - 4666   2000.6

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  • Aromatic acetals as new initiators for cationic polymerization of isobutyl vinyl ether Reviewed

    K Satoh, M Kamigaito, M Sawamoto

    MACROMOLECULES   33 ( 3 )   748 - 753   2000.2

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  • Metal Triflates and Tetrafluoroborates as Water-Tolerant Lewis Acids for Cationic Polymerization in Aqueous Media Reviewed

    K. Satoh, M. Kamigaito, M. Sawamoto

    Macromolecules   33   5836-5840   2000

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  • Sulfonic Acids as Water-Soluble Initiators for Cationic Polymerization in Aqueous Media with Yb(OTf)3 Reviewed

    K. Satoh, M. Kamigaito, M. Sawamoto

    J. Polym. Sci.: Part A: Polym. Chem.   38   2728-2733   2000

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  • Controlled cationic polymerization of p-alkoxystyrene and p-hydroxystyrene in aqueous media

    Kotaro Satoh, Masami Kamigaito, Mitsuo Sawamoto

    American Chemical Society, Polymer Preprints, Division of Polymer Chemistry   40 ( 2 )   895 - 896   1999.8

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  • Controlled cationic polymerization of p-methoxystyrene in aqueous media with Yb(OTf)(3) Reviewed

    K Satoh, M Kamigaito, M Sawamoto

    MACROMOLECULES   32 ( 12 )   3827 - 3832   1999.6

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  • 3-Arm Star Block Polymers by Living Cationic Polymerization Reviewed

    R. Takahashi, M. Ouchi, K. Satoh, M. Kamigaito, M. Sawamoto

    Polymer Journal   31   995-1000   1999

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  • Living cationic polymerization with Yb(OSO2CF3)(3) as a water-resistant, recoverable Lewis acid Reviewed

    K Satoh, H Katayama, M Kamigaito, M Sawamoto

    CATIONIC POLYMERIZATION   665   106 - 112   1997

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▼display all

Books

  • 「活性種の直接変換による新しい精密重合」リビングラジカル重合―機能性高分子の合成と応用展開―, 松本章一 監修 , シーエムシー出版, 2018

    佐藤浩太郎（ Role： Joint author）

    シーエムシー出版  2018.9 

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    Responsible for pages：印刷中   Language：Japanese  

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  • "Molecular Technology for Synthesis of Versatile Copolymers via Multiple Polymerization Mechanisms " in "Molecular Technology", H. Yamamoto, T. Kato eds.

    Kotaro Satoh（ Role： Sole author）

    Wiley-VCH  2018 

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    Responsible for pages：in press   Language：English   Book type：Scholarly book

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  • "Sustainable Vinyl Polymers via Controlled Polymerization of Terpenes" in "Sustainable Polymers from Biomass"

    M. Kamigaito, K. Satoh（ Role： Joint author）

    Wiley-VCH  2017.2  （ ISBN:9783527340163 ）

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    Responsible for pages：55-90   Language：English   Book type：Scholarly book

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  • 「立体制御重合：ビニルポリマーの立体構造の制御」CSJカレントレビュー20 精密重合が拓く高分子合成—高度な制御と進む実用化,日本化学会編, 化学同人, 2016, pp. 113-120.

    佐藤浩太郎, 上垣外正己（ Role： Joint author）

    化学同人  2016.3 

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    Responsible for pages：113-120   Language：Japanese  

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  • 「イオン重合」CSJカレントレビュー20 精密重合が拓く高分子合成—高度な制御と進む実用化,日本化学会編, 化学同人, 2016, pp. 26-33.

    佐藤浩太郎（ Role： Joint author）

    化学同人  2016.3 

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    Responsible for pages：26-33   Language：Japanese  

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  • 「テルペン類の重合反応」テルペン利用の新展開, 大平辰朗, 宮澤三雄, 監修 , シーエムシー出版, pp35-46 (2016)

    上垣外正己, 佐藤浩太郎（ Role： Joint author）

    シーエムシー出版  2016 

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    Responsible for pages：35-46   Language：Japanese  

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  • "Bio-Based Hydrocarbon Polymers" in Encyclopedia of Polymeric Nanomaterials , S. Kobayashi and K. Mullen, eds. (New York: Springer), vol 1, 108-118 (2015)..

    Masami Kamigaito, Kotaro Satoh（ Role： Sole author）

    Springer  2015.8 

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    Responsible for pages：108-118   Language：English  

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  • "Poly(vinyl alcohol)" in Encyclopedia of Polymeric Nanomaterials , S. Kobayashi and K. Mullen, eds. (New York: Springer), vol 3, 1734-1739..

    Kotaro Satoh（ Role： Sole author）

    Springer  2015.8 

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    Responsible for pages：1734-1739   Language：English  

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  • "Control of Polymer Sequences", McGraw-Hill Yearbook of Science and Technology 2015

    Masami Kamigaito, Kotaro Satoh（ Role： Joint author）

    McGraw-Hill  2015.5 

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    Responsible for pages：http://dx.doi.org/10.1036/1097-8542.YB150543   Language：English  

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  • 進化する医療用バイオベースマテリアル「第10章 植物由来モノマーからのポリマー合成」,大矢裕一,相羽誠一監修，シーエムシー出版，2015，pp. 100-108.

    佐藤浩太郎, 上垣外正己（ Role： Joint author）

    シーエムシー出版  2015.1 

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    Responsible for pages：100-108   Language：Japanese  

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  • 「リビングラジカル重合」高分子ナノテクノロジーハンドブック〜最新ポリマーABC技術を中心に〜, 西敏夫 他編, エヌ・ティー・エス

    上垣外正己, 佐藤浩太郎（ Role： Joint author）

    エヌ・ティー・エス  2014.3 

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    Responsible for pages：265-271   Language：Japanese  

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  • 化学便覧 第７版, 応用化学編 II, 日本化学会編・「熱可塑性樹脂」

    佐藤浩太郎, 上垣外正己（ Role： Joint author）

    丸善  2014.1 

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    Responsible for pages：1133-1143   Language：Japanese  

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  • 「植物由来のポリマー材料」太陽エネルギー社会を築く材料テクノロジー, 河本邦仁, 金武直幸 編

    上垣外正己, 佐藤浩太郎（ Role： Joint author）

    コロナ社  2013.12 

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    Responsible for pages：150-170   Language：Japanese  

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  • 高分子基礎科学One Point 1 精密重合I：ラジカル重合

    上垣外正己, 佐藤浩太郎（ Role： Joint author）

    共立出版  2013.4 

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  • Bio-Based Polymers"New Polymerization Methods for Bio-Based Polymers from Renewable Vinyl Monomers"

    K. Satoh, M. Kamigaito（ Role： Joint author）

    CMC  2013.4 

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    Responsible for pages：95-111   Language：English  

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  • Polymer Science: A Comprehensive Reference" K. Matyjaszewski and M. Möller, eds.,

    K. Satoh, M. Kamigaito, M. Sawamoto（ Role： Joint author）

    Elsevier BV, Amsterdam, Netherlands  2012 

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  • 使える！有機合成反応241実践ガイド「官能基選択型ラジカル重合反応」

    上垣外正己, 佐藤浩太郎（ Role： Joint author）

    化学同人  2010 

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    Responsible for pages：208-209   Language：Japanese  

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  • 使える！有機合成反応241実践ガイド「アルケンの光誘起リビングラジカル重合」2010, pp. 204-205

    上垣外正己, 佐藤浩太郎（ Role： Joint author）

    化学同人  2010 

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  • 高分子の合成「ラジカル重合」pp1－146

    上垣外正己, 佐藤浩太郎, 監修)澤本光男（ Role： Joint author）

    講談社  2010  （ ISBN:9784061543614 ）

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  • 新訂版 ラジカル重合ハンドブック「遷移金属錯体によるリビングラジカル重合」

    佐藤浩太郎, 上垣外正己, 澤本光男（ Role： Joint author）

    エヌ・ティー・エス  2010 

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    Responsible for pages：185-196   Language：Japanese  

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  • 新訂版 ラジカル重合ハンドブック「ラジカル重付加反応」，エヌ・ティー・エス，2010，475-493

    佐藤浩太郎, 上垣外正己（ Role： Joint author）

    エヌ・ティー・エス  2010 

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  • 触媒年鑑 触媒技術の動向と展望2008「リビングラジカル重合における遷移金属触媒の最近の展開」, pp. 51-64.

    佐藤浩太郎, 上垣外正己（ Role： Joint author）

    触媒学会編  2008 

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  • 触媒便覧「環状オレフィンのビニル重合」, 2008, 745-748

    佐藤浩太郎, 上垣外正己（ Role： Joint author）

    触媒学会編, 講談社サイエンティフィク  2008 

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  • 植物由来プラスチックの高機能化とリサイクル技術「植物由来テルペンの精密重合によるバイオベースシクロオレフィンポリマー」, pp.292-301

    佐藤浩太郎, 上垣外正己（ Role： Joint author）

    サイエンス＆テクノロジー  2007 

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  • 自然に学ぶ材料プロセッシング「4.1.6 自然に学ぶ機能高分子の合成」, pp.228-232.

    佐藤浩太郎（ Role： Joint author）

    三共出版  2007 

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MISC

  • 植物由来化合物の精密重合—特集 人と地球をつなぐ高分子

    佐藤 浩太郎, 久保 智弘

    高分子 = High polymers, Japan : polymers   72 ( 10 )   502 - 504   2023.10

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    Language：Japanese   Publisher：東京 : 高分子学会  

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  • 植物由来ビニル化合物の特徴を活かしたバイオベースポリマー開発—特集 高分子科学の明日を拓(ひら)く : 環境への配慮と機能性を満たす新技術

    佐藤 浩太郎, 上垣外 正己

    Milsil : 自然と科学の情報誌   15 ( 6 )   15 - 17   2022.11

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    Language：Japanese   Publisher：東京 : 国立科学博物館  

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  • 24.高分子合成・反応における最近の進歩(1)制御/リビングラジカル重合の基礎から最新の研究動向まで—24. Recent Advances in Polymer Synthesis and Reactions(1)From Fundamental Chemistry to Recent Development on Controlled/"Living" Radical Polymerization

    佐藤 浩太郎

    日本接着学会誌 = Journal of the Adhesion Society of Japan : adhesion   58 ( 4 )   159 - 168   2022

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  • Precise Synthesis of a Homogeneous Thermoresponsive Polymer Network Composed of Four-Branched Star Polymers with a Narrow Molecular Weight Distribution

    Yuumi Okaya, Yuto Jochi, Takahiro Seki, Kotaro Satoh, Masami Kamigaito, Taiki Hoshino, Tomotaka Nakatani, So Fujinami, Masaki Takata, Yukikazu Takeoka

    Macromolecules   53 ( 1 )   374 - 386   2020.1

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  • 交換連鎖移動機構による精密高分子合成—Precision Polymer Synthesis via Degenerative Chain-Transfer Mechanism—特集 精密高分子合成に関する最近の研究動向

    上垣外 正己, 佐藤 浩太郎, 内山 峰人

    触媒 = Catalysts & catalysis   61 ( 3 )   118 - 123   2019.6

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  • Halogenation of Propagating Terminal in Anionic Polymerization of Isoprene for the Synthesis of Block Copolymers

    SATOH Kotaro, MORI Yuya, KAMIGAITO Masami

    KOBUNSHI RONBUNSHU   76 ( 3 )   234 - 240   2019.5

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    Language：Japanese   Publisher：The Society of Polymer Science, Japan  

    In this work, we investigated the direct halogenation of growing species in living anionic polymerization of hydrocarbon monomers for subsequent mechanistic transformation and post-polymerization reactions. The direct halogenation of propagating living anionic species of isoprene (Ip) was examined with CCl4 in THF/methylcyclohexane at −78°C to form a carbon-halogen terminal. The mechanistic transformation from living anionic into radical polymerization was then investigated using the anionically-prepared poly(Ip) (PIp) bearing a chloride terminal as the macroinitiator for the living radical polymerization with the RuCp*Cl(PPh3)/Et3N initiating system in toluene at 80°C, which resulted in the formation of block copolymers of PIp with various radically-polymerized segments. Furthermore, the terminal halogen of the anionically-prepared PIp was also converted into an azide group by SN2 reaction, which could be employed for the click reaction with alkyne-terminated poly(ethylene oxide) by a Cu catalyst to form an amphiphilic block copolymer.

    DOI： 10.1295/koron.2019-0004

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  • 可逆的連鎖移動機構に基づくリビングカチオン重合による精密高分子合成—Precision Polymer Synthesis via Living Cationic Polymerization Based on Reversible Chain-Transfer Mechanism—特集 分子を揃える

    内山 峰人, 佐藤 浩太郎, 上垣外 正己

    材料の科学と工学 : 日本材料科学会誌   56 ( 4 )   138 - 141   2019

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    Language：Japanese   Publisher：東京 : 日本材料科学会 ; 2002-  

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  • Scalable Synthesis of Bio-Based Functional Styrene: Protected Vinyl Catechol from Caffeic Acid and Controlled Radical and Anionic Polymerizations Thereof Invited Reviewed

    Hisaaki Takeshima, Kotaro Satoh, Masami Kamigaito

    ACS Sustainable Chem. Eng.   6   13681-13686   2018.10

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    DOI： 10.1021/acssuschemeng.8b04400

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  • Controlled Radical Copolymerization of Cinnamic Derivatives as Renewable Vinyl Monomers with Both Acrylic and Styrenic Substituents: Reactivity, Regioselectivity, Properties, and Functions Invited Reviewed

    Yuya Terao, Kotaro Satoh, Masami Kamigaito

    Biomacromolecules   in press   2018.10

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    DOI： 10.1021/acs.biomac.8b01298

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  • Degenerative Chain-Transfer Process: Controlling All Chain-Growth Polymerizations and Enabling Novel Monomer Sequences Invited Reviewed

    M. Kamigaito, K. Satoh, M. Uchiyama

    J. Polym. Sci., Part A: Polym. Chem.   56   in press   2018.9

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    DOI： 10.1002/pola.29257

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  • Direct through Anionic, Cationic, and Radical Active Species: Terminal Carbon-Halogen Bond for "Controlled"/Living Polymerizations of Styrene Invited Reviewed

    K. Satoh, Y. Mori, M. Kamigaito

    J. Polym. Sci., Part A: Polym. Chem.   56   in press   2018.9

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    DOI： 10.1002/pola.29261

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  • Discrete and Stereospecific Oligomers Prepared by Sequential and Alternating Single Unit Monomer Insertion Reviewed

    Zixuan Huang, Benjamin B. Noble, Nathaniel Corrigan, Yingying Chu, Kotaro Satoh, Donald S. Thomas, Craig J. Hawker, Graeme Moad, Masami Kamigaito, Michelle L. Coote, Cyrille Boyer, Jiangtao Xu

    J. Am. Chem. Soc.   140   13392-13406   2018.9

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    DOI： 10.1021/jacs.8b08386

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  • Vinyl Ether/Vinyl Ester Copolymerization by Cationic and Radical Interconvertible Simultaneous Polymerization Invited Reviewed

    Kotaro Satoh, Yuuma Fujiki, Mineto Uchiyama, Masami Kamigaito

    ACS Symp. Ser.   1284   323-334   2018.8

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    DOI： 10.1021/bk-2018-1284.ch015

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  • Helix-Sense-Selective Copolymerization of Triphenylmethyl Methacrylate with Chiral 2- Isopropenyl-4-phenyl-2-oxazoline Invited Reviewed

    J. Shen, N. Ikeda, W. Bi, K. Satoh, M. Kamigaito, Y. Okamoto

    J. Polym. Sci., Part A: Polym. Chem.   56   in press   2018.8

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    DOI： 10.1002/pola.29238

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  • Synthesis and stereocomplexation of PMMA-based star polymers prepared by a combination of stereospecific anionic polymerization and crosslinking radical polymerization Reviewed

    Naoya Usuki, Hisakazu Okura, Kotaro Satoh, Masami Kamigaito

    Journal of Polymer Science, Part A: Polymer Chemistry   56 ( 11 )   1123 - 1127   2018.6

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    DOI： 10.1002/pola.28995

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  • Synthesis of PEve- b -P(CTFE- alt -Eve) block copolymers by sequential cationic and radical RAFT polymerization Reviewed

    Marc Guerre, Mineto Uchiyama, Gérald Lopez, Bruno Améduri, Kotaro Satoh, Masami Kamigaito, Vincent Ladmiral

    Polymer Chemistry   9 ( 3 )   352 - 361   2018.1

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    DOI： 10.1039/c7py01924f

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  • 高分子科学最近の進歩 交換連鎖移動機構に基づく精密重合—Front-Line Polymer Science : Degenerative Chain Transfer for Precision Polymer Synthesis

    上垣外 正己, 佐藤 浩太郎, 内山 峰人

    高分子 = High polymers, Japan : polymers   67 ( 1 )   30 - 33   2018.1

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  • Degenerative Chain Transfer for Precision Polymer Synthesis Invited Reviewed

    Masami Kamigaito, Kotaro Satoh, Mineto Uchiyama

    KOBUNSHI   67 ( 1 )   30-33   2018.1

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  • Spontaneous Synthesis of a Homogeneous Thermoresponsive Polymer Network Composed of Narrow Molecular Weight Distribution Polymers Invited Reviewed

    Y. Jochi, T. Seki, T. Soejima, K. Satoh, M. Kamigaito, Y. Takeoka

    NPG Asia Materials   10   840–848 - 848   2018

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    DOI： 10.1038/s41427-018-0074-x

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  • Synthesis of isotactic-block-syndiotactic poly(methyl methacrylate) via stereospecific living anionic polymerizations in combination with metal-halogen exchange, halogenation, and click reactions Reviewed

    Naoya Usuki, Kotaro Satoh, Masami Kamigaito

    Polymers   9 ( 12 )   723   2017.12

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    DOI： 10.3390/polym9120723

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  • Diverse approaches to star polymers via cationic and radical RAFT cross-linking reactions using mechanistic transformation Invited Reviewed

    Mineto Uchiyama, Kotaro Satoh, Thomas G. McKenzie, Qiang Fu, Greg. G. Qiao, Masami Kamigaito

    POLYMER CHEMISTRY   8 ( 38 )   5972 - 5981   2017.10

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    DOI： 10.1039/c7py01401e

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  • One-shot controlled/living copolymerization for various comonomer sequence distributions via dual radical and cationic active species from RAFT terminals Invited Reviewed

    Kotaro Satoh, Hideyuki Hashimoto, Shinya Kumagai, Hiroshi Aoshima, Mineto Uchiyama, Ryoma Ishibashi, Yuuma Fujiki, Masami Kamigaito

    POLYMER CHEMISTRY   8 ( 34 )   5002 - 5011   2017.9

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    DOI： 10.1039/c7py00324b

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  • Bio-Based Functional Styrene Monomers Derived from Naturally Occurring Ferulic Acid for Poly(vinylcatechol) and Poly(vinylguaiacol) via Controlled Radical Polymerization Invited Reviewed

    Hisaaki Takeshima, Kotaro Satoh, Masami Karnigaito

    MACROMOLECULES   50 ( 11 )   4206 - 4216   2017.6

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    DOI： 10.1021/acs.macromol.7b00970

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  • Synthesis of Syndiotactic Macrocyclic Poly(methyl methacrylate) via Transformation of the Growing Terminal in Stereospecific Anionic Polymerization Invited Reviewed

    Naoya Usuki, Kotaro Satoh, Masami Kamigaito

    MACROMOLECULAR CHEMISTRY AND PHYSICS   218 ( 12 )   1700041   2017.6

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    DOI： 10.1002/macp.201700041

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  • Combination of Cationic and Radical RAFT Polymerizations: A Versatile Route to Well-Defined Poly(ethyl vinyl ether)-block-poly(vinylidene fluoride) Block Copolymers Invited Reviewed

    Marc Guerre, Mineto Uchiyama, Enrique Folgado, Mona Semsarilar, Bruno Ameduri, Kotaro Satoh, Masami Kamigaito, Vincent Ladmiral

    ACS MACRO LETTERS   6 ( 4 )   393 - 398   2017.4

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    DOI： 10.1021/acsmacrolett.7b00150

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  • 座談会 変わりゆく研究環境とこれからの高分子学会—A Talk : The Coming SPSJ Under the Changing Environment of R&D—特集 高分子科学のはじまりと未来

    樫田 啓, 児島 千恵, 酒井 崇匡, 寺島 崇矢, 沼田 圭司, 星野 友, 藪 浩, 佐藤 浩太郎

    高分子 = High polymers, Japan : polymers   66 ( 4 )   167 - 174   2017.4

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  • BAB-random-C Monomer Sequence via Radical Terpolymerization of Limonene(A), Maleimide(B), and Methacrylate(C): Terpene Polymers with Randomly Distributed Periodic Sequences Reviewed

    Masataka Ojika, Kotaro Satoh, Masami Kamigaito

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   56 ( 7 )   1789 - 1793   2017.2

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    DOI： 10.1002/anie.201610768

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  • Light Leads to Ultra-Long Polymer Chains in Water Invited Reviewed

    Masami Kamigaito, Kotaro Satoh

    CHEM   2 ( 1 )   13 - 15   2017.1

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    DOI： 10.1016/j.chempr.2016.12.010

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  • Metal-Free Living Cationic Polymerization via Degenerative Chain-Transfer Mechanism Invited Reviewed

    Mineto Uchiyama, Kotaro Satoh, Masami Kamigaito

    Journal of the Adhesion Society of Japan : adhesion   53 ( 5 )   179-187 - 187   2017

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  • Control of stereochemistry in atom transfer radical addition and step-growth radical polymerization by chiral transition metal catalysts Reviewed

    Takamasa Soejima, Kotaro Satoh, Masami Kamigaito

    TETRAHEDRON   72 ( 48 )   7657 - 7664   2016.12

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    DOI： 10.1016/j.tet.2016.01.060

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  • Diversifying Cationic RAFT Polymerization with Various Counteranions: Generation of Cationic Species from Organic Halides and Various Metal Salts Reviewed

    Mineto Uchiyama, Kotaro Satoh, Masami Kamigaito

    ACS MACRO LETTERS   5 ( 10 )   1157 - 1161   2016.10

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    DOI： 10.1021/acsmacrolett.6b00541

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  • Beyond Traditional RAFT: Alternative Activation of Thiocarbonylthio Compounds for Controlled Polymerization Reviewed

    Thomas G. McKenzie, Qiang Fu, Mineto Uchiyama, Kotaro Satoh, Jiangtao Xu, Cyrille Boyer, Masami Kamigaito, Greg G. Qiao

    ADVANCED SCIENCE   3 ( 9 )   1500394   2016.9

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    DOI： 10.1002/advs.201500394

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  • Cross-linked nanocellular polymer films: water- and oil-repellent anti-reflection coating Reviewed

    Cedric Dutriez, Kotaro Satoh, Masami Kamigaito, Hideaki Yokoyama

    POLYMER JOURNAL   48 ( 4 )   497 - 501   2016.4

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    DOI： 10.1038/pj.2016.7

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  • A phosphonium intermediate for cationic RAFT polymerization Reviewed

    Mineto Uchiyama, Kotaro Satoh, Masami Kamigaito

    Polymer Chemistry   7 ( 7 )   1387 - 1396   2016.2

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    DOI： 10.1039/c5py01879j

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  • Stereoregular High-Density Bottlebrush Polymer and Its Organic Nanocrystal Stereocomplex through Triple-Helix Formation Reviewed

    Jing M. Ren, Kenji Ishitake, Kotaro Satoh, Anton Blencowe, Qiang Fu, Edgar H. H. Wong, Masami Kamigaito, Greg G. Qiao

    MACROMOLECULES   49 ( 3 )   788 - 795   2016.2

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    DOI： 10.1021/acs.macromol.5b02295

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  • Selective Ring-Opening Controlled Radical Polymerization of Pinocarvone Derived from α-Pinene to Bio-Based Polyketone Reviewed

    Hisanari Miyaji, Kotaro Satoh, Masami Kamigaito

    Angew. Chem. Int. Ed.   55   1372-1376   2016.1

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    DOI： 10.1002/anie.201509379

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  • Main-Chain and Side-Chain Sequence-Regulated Vinyl Copolymers by Iterative Atom Transfer Radical Additions and 1:1 or 2:1 Alternating Radical Copolymerization Reviewed

    Takamasa Soejima, Kotaro Satoh, Masami Kamigaito

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   138 ( 3 )   944 - 954   2016.1

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    DOI： 10.1021/jacs.5b11631

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  • Fullerene peapod nanoparticles as an organic semiconductor-electrode interface layer Reviewed

    Jing M. Ren, Jegadesan Subbiah, Bolong Zhang, Kenji Ishitake, Kotaro Satoh, Masami Kamigaito, Greg G. Qiao, Edgar H. H. Wong, Wallace W. H. Wong

    CHEMICAL COMMUNICATIONS   52 ( 16 )   3356 - 3359   2016

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    DOI： 10.1039/c5cc10444k

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  • Sequence-regulated vinyl copolymers with acid and base monomer units via atom transfer radical addition and alternating radical copolymerization Reviewed

    Takamasa Soejima, Kotaro Satoh, Masami Kamigaito

    POLYMER CHEMISTRY   7 ( 29 )   4833 - 4841   2016

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    DOI： 10.1039/c6py00965d

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  • Thioether-Mediated Degenerative Chain-Transfer Cationic Polymerization: A Simple Metal-Free System for Living Cationic Polymerization Reviewed

    Mineto Uchiyama, Kotaro Satoh, Masami Kamigaito

    Macromolecules   48 ( 16 )   5533 - 5542   2015.8

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    DOI： 10.1021/acs.macromol.5b01341

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  • Monomer Sequence Regulation in Main and Side Chains of Vinyl Copolymers: Synthesis of Vinyl Oligomonomers via Sequential Atom Transfer Radical Addition and Their Alternating Radical Copolymerization Reviewed

    Takamasa Soejima, Kotaro Satoh, Masami Kamigaito

    ACS MACRO LETTERS   4 ( 7 )   745 - 749   2015.7

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    DOI： 10.1021/acsmacrolett.5b00379

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  • 植物由来ビニルモノマーから新規高分子を合成

    上垣外 正己, 佐藤 浩太郎

    現代化学 = Chemistry today   ( 532 )   24 - 29   2015.7

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  • Controlled/Living Polymerization of Renewable Vinyl Monomers into Bio-Based Polymers Invited Reviewed

    Kotaro Satoh

    Polymer Journal   47   527-536   2015.5

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    DOI： 10.1038/pj.2015.31

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  • Cationic RAFT polymerization using ppm concentrations of organic acid Reviewed

    Mineto Uchiyama, Kotaro Satoh, Masami Kamigaito

    Angewandte Chemie - International Edition   54 ( 6 )   1924 - 1928   2015.2

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    DOI： 10.1002/anie.201410858

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  • Controlled/Living Polymerization of Naturally Occurring Terpenes

    SATOH Kotaro, KAMIGAITO Masami

    KOBUNSHI RONBUNSHU   72 ( 7 )   421 - 432   2015

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    While in recent years a large number of living/controlled polymerization systems for petrochemical-derived vinyl monomers have been described, bio-based polymer materials from renewable resources become attractive from a viewpoint of environmentally benign and sustainable chemistry. In this study, we examined controlled/living (co)polymerization of a series of naturally-occurring alicyclic terpenes, such as β-pinene and d-limonene, as alternatives for those from traditional petrochemical products. For example, the living cationic polymerization of β-pinene was achieved using the HCl/EtAlCl2/Lewis base system to produce relatively high molecular weight polymers with Mw > 105, which was subsequently hydrogenated into a bio-based cycloolefin polymer. Also, the radical copolymerization of β-pinene and d-limonene with maleimide derivatives proceeded in unprecedented 1:2 alternating fashion when polymerized in fluorinated alcohol solvents, of which the combination with RAFT polymerization resulted in end-to-end sequence-regular copolymers.

    DOI： 10.1295/koron.2015-0011

    DOI： 10.1016/j.polymdegradstab.2019.01.025_references_DOI_IIE6KquN52Aoeieb6VH96ITYN5G

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  • Periodic Introduction of Water-Tolerant Titanatrane Complex to Poly(NIPAM) Prepared by Simultaneous Step-Growth and Living Radical Polymerization Invited Reviewed

    Kotaro Satoh, Daisuke Ito, Masami Kamigaito

    CONTROLLED RADICAL POLYMERIZATION, VOL 2: MATERIALS   1188   1 - 14   2015

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    DOI： 10.1021/bk-2015-1188.ch001

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  • Controlled radical polymerization of styrene with magnetic iron oxides prepared through hydrothermal, bioinspired, and bacterial processes Reviewed

    Arihiro Kanazawa, Kotaro Satoh, Shokyoku Kanaoka, Masato Kakihana, Makoto Kobayashi, Junki Sato, Hiroaki Imai, Yuya Oaki, Atsushi Arakaki, Kiyofumi Katagiri, Masami Kamigaito, Sadahito Aoshima

    RSC ADVANCES   5 ( 63 )   51122 - 51129   2015

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    DOI： 10.1039/c5ra09149g

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  • Molecular mapping of poly(methyl methacrylate) super-helix stereocomplexes Reviewed

    Andrew Joseph Christofferson, George Yiapanis, Jing Ming Ren, Greg Guanghua Qiao, Kotaro Satoh, Masami Kamigaito, Irene Yarovsky

    CHEMICAL SCIENCE   6 ( 2 )   1370 - 1378   2015

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    DOI： 10.1039/c4sc02971b

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  • 活性種の分類を超えた高分子合成戦略 Invited

    佐藤浩太郎

    DivisionTopics, 化学と工業   68   224   2015

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  • Controlled/Living Polymerization of Naturally Occurring Terpenes Invited Reviewed

    Kotaro Satoh, Masami Kamigaito

    KOBUNSHI RONBUNSHU   72 ( 7 )   421 - 432   2015

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    DOI： 10.1295/koron.2015-0011

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  • 植物由来ビニルモノマーから新規高分子を合成 Invited

    上垣外正己, 佐藤浩太郎

    現代化学   2015 ( 7 )   24-29   2015

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  • Metal-Free Living Cationic Polymerization via Carbon-Sulfur Bonds (1) RAFT Mechanism Using Thioesters Invited Reviewed

    Mineto Uchiyama, Kotaro Satoh, Masami Kamigaito

    JOURNAL OF THE SOCIETY OF RUBBER SCIENCE AND TECHNOLOGY   88 ( 10 )   391-396   2015

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    DOI： 10.2324/gomu.88.391

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  • Metal-Free Living Cationic Polymerization 2: DT Mechanism Using Thioethers Invited Reviewed

    Mineto Uchiyama, Kotaro Satoh, Masami Kamigaito

    JOURNAL OF THE SOCIETY OF RUBBER SCIENCE AND TECHNOLOGY   88 ( 12 )   461-465 - 465   2015

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    This second review on novel metal-free cationic polymerizations is directed to living cationic polymerization that proceeds via reversible activation of carbon-sulfur bonds of thioethers via degenerative chain-transfer (DT) mechanism. In a similar way to cationic RAFT polymerization in the first review, a small amount of triflic acid generates the cationic propagating species, which interchanges with the thioether-dormant species via the sulfonium intermediate stabilized by the sulfur atom, to induce living cationic polymerization via the DT mechanism. This system can similarly control the molecular weight up to 1×105 with narrow molecular weight distributions (Mw/Mn < 1.2) and controlled chain-end groups in cationic polymerization of vinyl ethers and p-alkoxystyrene. The thioether-dormant species is highly stable and tolerant in comparison to the dormant species thus far reported in living cationic polymerization. This makes the obtained polymers applicable for subsequent post-polymerization reactions without any significant damages on the C-S bonds.

    DOI： 10.2324/gomu.88.461

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  • Precision Control of Monomer Sequences in Vinyl Copolymers Invited

    Kotaro Satoh, Masami Kamigaito

    KOBUNSHI   63 ( 10 )   715-717   2014.10

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  • Interconvertible Living Radical and Cationic Polymerization through Reversible Activation of Dormant Species with Dual Activity Reviewed

    Hiroshi Aoshima, Mineto Uchiyama, Kotaro Satoh, Masami Kamigaito

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   53 ( 41 )   10932 - 10936   2014.10

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    DOI： 10.1002/anie.201406590

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  • Living cationic RAFT polymerization: Development of new chain-transfer agent and synthesis of novel block copolymer via transformation from cationic into radical RAFT polymerization

    Mineto Uchiyama, Kotaro Satoh, Masami Kamigaito

    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY   248   2014.8

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  • Alternating copolymer of styrene and maleimides with side-chain sequence-regulated acrylate/styrene oligomer

    Takamasa Soejima, Kotaro Satoh, Masami Kamigaito

    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY   248   2014.8

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  • Periodically functionalized poly(NIPAM) by metal-catalyzed step- and chain-growth radical polymerizations

    Kotaro Satoh, Masami Kamigaito

    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY   248   2014.8

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  • Synthesis of Titanium-Containing Block, Random, End-Functionalized, and Junction-Functionalized Polymers via Ruthenium-Catalyzed Living Radical Polymerization and Direct Observation of Titanium Domains by Electron Microscopy Reviewed

    Yasutaka Tsujimoto, Kotaro Satoh, Hidekazu Sugimori, Hiroshi Jinnai, Masami Kamigaito

    MACROMOLECULES   47 ( 3 )   944 - 953   2014.2

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    DOI： 10.1021/ma402332g

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  • きっちり包めばきれいにつくれる 立体規則性ラジカル包接重合 Invited

    佐藤浩太郎

    化学   69 ( 1 )   70-71   2014.1

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  • Precision Synthesis of Bio- Based Acrylic Thermoplastic Elastomer by RAFT Polymerization of Itaconic Acid Derivatives Reviewed

    Kotaro Satoh, Dong-Hyung Lee, Kanji Nagai, Masami Kamigaito

    MACROMOLECULAR RAPID COMMUNICATIONS   35 ( 2 )   161 - 167   2014.1

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    DOI： 10.1002/marc.201300638

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  • Stereospecific Cyclic Poly(methyl methacrylate) and Its Topology-Guided Hierarchically Controlled Supramolecular Assemblies Reviewed

    Jing Ming Ren, Kotaro Satoh, Tor Kit Goh, Anton Blencowe, Kanji Nagai, Kenji Ishitake, Andrew Joseph Christofferson, George Yiapanis, Irene Yarovsky, Masami Kamigaito, Greg Guanghua Qiao

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   53 ( 2 )   459 - 464   2014.1

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    DOI： 10.1002/anie.201308366

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  • Synthesis of Side-Chain-Sequenced Copolymers Using Vinyl Oligomonomers via Sequential Single-Monomer ATRA Invited Reviewed

    Takamasa Soejima, Kotaro Satoh, Masami Kamigaito

    SEQUENCE-CONTROLLED POLYMERS: SYNTHESIS, SELF-ASSEMBLY, AND PROPERTIES   1170   189 - 200   2014

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    DOI： 10.1021/bk-2014-1170.ch012

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  • Construction of Vinyl Polymer and Polyester or Polyamide Units in a Single Polymer Chain via Metal-catalyzed Simultaneous Chain- and Step-growth Radical Polymerization of Various Monomers Invited Reviewed

    Masato Mizutani, Kotaro Satoh, Masami Kamigaito

    AUSTRALIAN JOURNAL OF CHEMISTRY   67 ( 4 )   544 - 554   2014

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    DOI： 10.1071/CH13476

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  • Renewable beta-methylstyrenes for bio-based heat-resistant styrenic copolymers: radical copolymerization enhanced by fluoroalcohol and controlled/living copolymerization by RAFT Reviewed

    Yoshiki Nonoyama, Kotaro Satoh, Masami Kamigaito

    POLYMER CHEMISTRY   5 ( 9 )   3182 - 3189   2014

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    DOI： 10.1039/c3py01066j

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  • Sustainable cycloolefin polymer from pine tree oil for optoelectronics material: living cationic polymerization of beta-pinene and catalytic hydrogenation of high-molecular-weight hydrogenated poly(beta-pinene) Reviewed

    Kotaro Satoh, Atsuhiro Nakahara, Kazunori Mukunoki, Hiroko Sugiyama, Hiromu Saito, Masami Kamigaito

    POLYMER CHEMISTRY   5 ( 9 )   3222 - 3230   2014

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    DOI： 10.1039/c3py01320k

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  • 植物由来のビニルモノマーを精密に重合して機能性バイオベースポリマーをつくる Invited Reviewed

    佐藤浩太郎, 上垣外正己

    バイオプラジャーナル   ( 51 )   12-17   2013.11

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  • さまざまな植物由来ビニルモノマーの制御重合 Invited Reviewed

    佐藤浩太郎, 上垣外正己

    接着の技術   33 ( 2 )   6-10   2013.9

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  • Transition metal-catalyzed step-growth radical polymerization for various sequence-regulated vinyl polymers

    Kotaro Satoh, Masami Kamigaito

    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY   246   2013.9

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  • Periodically Functionalized and Grafted Copolymers via 1:2-Sequence-Regulated Radical Copolymerization of Naturally Occurring Functional Limonene and Maleimide Derivatives Reviewed

    Masaru Matsuda, Kotaro Satoh, Masami Kamigaito

    MACROMOLECULES   46 ( 14 )   5473 - 5482   2013.7

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    DOI： 10.1021/ma401021d

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  • A simple combination of higher-oxidation-state FeX3 and phosphine or amine ligand for living radical polymerization of styrene, methacrylate, and acrylate Reviewed

    Hiroshi Aoshima, Kotaro Satoh, Tomonari Umemura, Masami Kamigaito

    Polymer Chemistry   4 ( 12 )   3554 - 3562   2013.6

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    DOI： 10.1039/c3py00352c

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  • Asymmetric anionic polymerization of tris(trimethylsilyl) silyl methacrylate: a highly isotactic helical chiral polymer Invited Reviewed

    Kenji Ishitake, Kotaro Satoh, Masami Kamigaito, Yoshio Okamoto

    POLYMER JOURNAL   45 ( 6 )   676 - 680   2013.6

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    DOI： 10.1038/pj.2012.178

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  • Controlled Radical Copolymerization of Naturally-Occurring Terpenes with Acrylic Monomers in Fluorinated Alcohol Invited Reviewed

    Masaru Matsuda, Kotaro Satoh, Masami Kamigaito

    KGK-KAUTSCHUK GUMMI KUNSTSTOFFE   66 ( 5 )   51 - 56   2013.5

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  • In situ direct mechanistic transformation from FeCl3-catalyzed living cationic to radical polymerizations Invited Reviewed

    Hiroshi Aoshima, Kotaro Satoh, Masami Kamigaito

    Macromolecular Symposia   323 ( 1 )   64 - 74   2013.1

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    DOI： 10.1002/masy.201100115

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  • Direct Mechanistic Transformations from Isotactic or Syndiotactic Living Anionic Polymerizations of Methyl Methacrylate into Metal-Catalyzed Living Radical Polymerizations Reviewed

    Hiroshi Aoshima, Kotaro Satoh, Masami Kamigaito

    ACS MACRO LETTERS   2 ( 1 )   72 - 76   2013.1

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    DOI： 10.1021/mz300586m

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  • 1:2-Sequence-Regulated Radical Copolymerization of Naturally Occurring Terpenes with Maleimide Derivatives in Fluorinated Alcohol Reviewed

    Masaru Matsuda, Kotaro Satoh, Masami Kamigaito

    Journal of Polymer Science: Part A: Polymer Chemistry   51   1774-1785   2013.1

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  • 遷移金属触媒による逐次ラジカル重合を用いた精密構造制御ポリマー Invited Reviewed

    佐藤浩太郎, 上垣外正己

    触媒   55 ( 2 )   78-85   2013

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  • 研究室紹介—北から南から Invited

    上垣外正己, 佐藤浩太郎, 永井寛嗣

    Organometallic News   ( 1 )   40-41   2013

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  • 植物由来ビニルモノマーの精密重合による新規バイオベースポリマーの構築 Invited Reviewed

    上垣外正己, 佐藤浩太郎

    材料の科学と工学   50 ( 1 )   20-25   2013

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  • Cyclic Block Copolymers for Controlling Feature Sizes in Block Copolymer Lithography Reviewed

    Justin E. Poelma, Kosuke Ono, Daigo Miyajima, Takuzo Aida, Kotaro Satoh, Craig J. Hawker

    ACS NANO   6 ( 12 )   10845 - 10854   2012.12

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    DOI： 10.1021/nn304217y

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  • Kinetic Hydrate Inhibition of Poly(N-isopropylmethacrylamide)s with Different Tacticities Reviewed

    P. C. Chua, M. A. Kelland, K. Ishitake, K. Satoh, M. Kamigaito, Y. Okamoto

    Energy & Fuels   26   3577-3585   2012.5

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  • Intramolecular friedel-crafts cyclization and subsequent hydrogenation of styrene-isoprene random copolymers prepared by anionic polymerization for thermally-resistant and optical applications Reviewed

    Atsuhiro Nakahara, Kotaro Satoh, Hiromu Saito, Masami Kamigaito

    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY   50 ( 7 )   1298 - 1307   2012.4

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    DOI： 10.1002/pola.25894

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  • Design and Synthesis of Self-Degradable Antibacterial Polymers by Simultaneous Chain- and Step-Growth Radical Copolymerization Reviewed

    Mizutani, Masato, Palermo, Edmund, Thoma, Laura, Satoh, Kotaro, Kamigaito, Masami, Kuroda, Kenichi

    Biomacromolecules   13   1554–1563   2012.4

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  • From-syndiotactic-to-isotactic stereogradient methacrylic polymers by RAFT copolymerization of methacrylic acid and its bulky esters Invited Reviewed

    Kenji Ishitake, Kotaro Satoh, Masami Kamigaito, Yoshio Okamoto

    POLYMER CHEMISTRY   3 ( 7 )   1750 - 1757   2012

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    DOI： 10.1039/c1py00401h

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  • Nanocellular foaming of fluorine containing block copolymers in carbon dioxide: the role of glass transition in carbon dioxide Reviewed

    Cedric Dutriez, Kotaro Satoh, Masami Kamigaito, Hideaki Yokoyama

    RSC ADVANCES   2 ( 7 )   2821 - 2827   2012

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    DOI： 10.1039/c2ra01268e

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  • 海外研究室レポート—UCSB での研究と留学生活 Invited

    佐藤浩太郎

    Organometallic News   ( 2 )   58-59   2012

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  • A facile synthesis of clickable and acid-cleavable PEO for acid-degradable block copolymers Reviewed

    Kotaro Satoh, Justin E. Poelma, Luis M. Campos, Brian Stahl, Craig J. Hawker

    POLYMER CHEMISTRY   3 ( 7 )   1890 - 1898   2012

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    DOI： 10.1039/c1py00484k

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  • Metal-Catalyzed Step-Growth Radical Polymerization of AA and BB Monomers for Monomer Sequence Regulation Invited Reviewed

    Kotaro Satoh, Tomohiro Abe, Masami Kamigaito

    PROGRESS IN CONTROLLED RADICAL POLYMERIZATION: MECHANISMS AND TECHNIQUES   1100   133 - 144   2012

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    DOI： 10.1021/bk-2012-1100.ch009

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  • Random copolymer of styrene and diene derivatives via anionic living polymerization followed by intramolecular Friedel-Crafts cyclization for high-performance thermoplastics Reviewed

    Atsuhiro Nakahara, Kotaro Satoh, Masami Kamigaito

    POLYMER CHEMISTRY   3 ( 1 )   190 - 197   2012

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    DOI： 10.1039/c1py00433f

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  • Stereospecific Free Radical and RAFT Polymerization of Bulky Silyl Methacrylates for Tacticity and Molecular Weight Controlled Poly(methacrylic acid) Reviewed

    Kenji Ishitake, Kotaro Satoh, Masami Kamigaito, Yoshio Okamoto

    MACROMOLECULES   44 ( 23 )   9108 - 9117   2011.12

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    DOI： 10.1021/ma202155b

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  • Mechanistic transformation during FeCl3-catalyzed living cationic and radical polymerization

    Hiroshi Aoshima, Kotaro Satoh, Kanji Nagai, Masami Kamigaito

    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY   242   2011.8

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  • Heterogeneous catalytic systems using iron oxides for controlled/living radical polymerization

    Arihiro Kanazawa, Kotaro Satoh, Masami Kamigaito

    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY   242   2011.8

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  • Mechanistic transformation between RAFT and living cationic polymerization

    Kotaro Satoh, Masami Kamigaito

    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY   242   2011.8

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  • AAB-sequence-regulated radical copolymerization of naturally-occurring limonene with maleimide: An end-to-end sequence-regulated copolymer

    Masaru Matsuda, Kanji Nagai, Kotaro Satoh, Masami Kamigaito

    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY   242   2011.8

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  • RAFT copolymerization of bulky silyl vinyl ethers

    Mitsumasa Nakawaki, Kotaro Satoh, Kanji Nagai, Masami Kamigaito

    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY   242   2011.8

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  • Metal-catalyzed living radical polymerization and step-growth radical polymerization for monomer sequence control

    Masami Kamigaito, Kotaro Satoh, Masato Mizutani

    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY   242   2011.8

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  • Degradable Poly(N-isopropylacrylamide) with Tunable Thermosensitivity by Simultaneous Chain- and Step-Growth Radical Polymerization Reviewed

    Masato Mizuntani, Kotaro Satoh, Masami Kamigaito

    MACROMOLECULES   44 ( 7 )   2382 - 2386   2011.4

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    DOI： 10.1021/ma2000465

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  • Iron Oxides as Heterogeneous Catalysts for Controlled/Living Radical Polymerization of Styrene and Methyl Methacrylate Reviewed

    Arihiro Kanazawa, Kotaro Satoh, Masami Kamigaito

    MACROMOLECULES   44 ( 7 )   1927 - 1933   2011.4

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    DOI： 10.1021/ma102812n

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  • Highly Efficient Synthesis of Low Polydispersity Core Cross-Linked Star Polymers by Ru-Catalyzed Living Radical Polymerization Reviewed

    Tor Kit Goh, Satoshi Yamashita, Kotaro Satoh, Anton Blencowe, Masami Kamigaito, Greg G. Qiao

    MACROMOLECULAR RAPID COMMUNICATIONS   32 ( 5 )   456 - 461   2011.3

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    DOI： 10.1002/marc.201000641

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  • Highly ordered nanoporous thin films derived from polystyrene-block-poly(ethylene oxide) with a cleavable acetal linkage

    Justin E. Poelma, Kotaro Satoh, Luis M. Campos, Craig J. Hawker

    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY   241   2011.3

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  • Nucleobase-Mediated Stereospecific Radical Polymerization and Combination with RAFT Polymerization for Simultaneous Control of Molecular Weight and Tacticity Reviewed

    Youhua Tao, Kotaro Satoh, Masami Kamigaito

    MACROMOLECULAR RAPID COMMUNICATIONS   32 ( 2 )   226 - 232   2011.1

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    DOI： 10.1002/marc.201000614

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  • 遷移金属触媒による逐次ラジカル重合—Transition metal-catalyzed step-growth radical polymerization—特集 高分子と触媒(2)

    佐藤 浩太郎, 水谷 将人, 上垣外 正己

    高分子論文集 = Japanese journal of polymer science and technology   68 ( 7 )   436 - 456   2011

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  • Transition Metal-Catalyzed Step-Growth Radical Polymerization

    SATOH Kotaro, MIZUTANI Masato, KAMIGAITO Masami

    KOBUNSHI RONBUNSHU   68 ( 7 )   436 - 456   2011

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    Metal-catalyzed atom transfer radical addition (Kharasch reaction) is a highly efficient carbon-carbon bond forming radical reaction. Nowadays, the chemistry is widely applied to chain-growth radical polymerization reactions referred as metal-catalyzed living radical polymerization or atom transfer radical polymerization (ATRP). In this study, we report a new class of transition metal-catalyzed radical polyaddition proceeding via step-growth polymerization mechanism of a designed monomer, which has a reactive carbon-halogen bond and an unconjugated carbon-carbon double bond in the same molecule. The reaction proceeded by simultaneous chain- and step-growth polymerization, both of which were based on the formation of the growing radical species from a stable carbon-halogen covalent bond. Unprecedented sequence-regulated copolymers with perfect vinyl monomer sequences were also obtained by the step-growth radical polymerization of designed monomers prepared from common vinyl monomers. This strategy will open a new era in the study for designing novel functional synthetic polymers.<br>

    DOI： 10.1295/koron.68.436

    DOI： 10.1038/s41428-022-00680-6_references_DOI_AqrGSxbs1xerhe1XTQN91BEvnmX

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  • Transition Metal-Catalyzed Step-Growth Radical Polymerization Invited Reviewed

    Kotaro Satoh, Masato Mizutani, Masami Kamigaito

    KOBUNSHI RONBUNSHU   68 ( 7 )   436 - 456   2011

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  • ラジカル重合における配列制御—Sequence control in radical polymerization—特集 精密重合の最前線 Reviewed

    上垣外 正己, 佐藤 浩太郎

    高分子 = High polymers, Japan : polymers   59 ( 10 )   781 - 784   2010.10

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  • AAB-Sequence Living Radical Chain Copolymerization of Naturally Occurring Limonene with Maleimide: An End-to-End Sequence-Regulated Copolymer Reviewed

    Kotaro Satoh, Masaru Matsuda, Kanji Nagai, Masami Kamigaito

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   132 ( 29 )   10003 - 10005   2010.7

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    DOI： 10.1021/ja1042353

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  • Metal-Catalyzed Simultaneous Chain- and Step-Growth Radical Polymerization: Marriage of Vinyl Polymers and Polyesters Reviewed

    Masato Mizutani, Kotaro Satoh, Masami Kamigaito

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   132 ( 21 )   7498 - 7507   2010.6

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    DOI： 10.1021/ja1023892

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  • 精密に構造制御しながら高分子を合成する--ラジカル重合での挑戦

    上垣外 正己, 佐藤 浩太郎, 永井 寛嗣

    現代化学 = Chemistry today   ( 471 )   32 - 37   2010.6

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  • Sequence-regulated vinyl copolymers by metal-catalysed step-growth radical polymerization Reviewed

    Kotaro Satoh, Satoshi Ozawa, Masato Mizutani, Kanji Nagai, Masami Kamigaito

    NATURE COMMUNICATIONS   1   1:6   2010.4

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    DOI： 10.1038/ncomms1004

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  • High performance polymers from naturally-occurring vinyl monomers via controlled/living cationic polymerization

    Kotaro Satoh, Masami Kamigaito

    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY   239   2010.3

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  • ラジカル重合における配列制御 Invited

    上垣外正己, 佐藤浩太郎

    高分子   59 ( 10 )   781-784   2010

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  • 植物由来モノマーの精密重合に基づく機能性高分子の合成 Invited Reviewed

    佐藤浩太郎, 上垣外正己

    日本接着学会誌   46 ( 1 )   29-36   2010

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  • In-Situ Direct Mechanistic Transformation from RAFT to Living Cationic Polymerization for (Meth)acrylate-Vinyl Ether Block Copolymers Reviewed

    S. Kumagai, K. Nagai, K. Satoh, M. Kamigaito

    Macromolecules   43 ( 18 )   7523-7531   2010

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  • 12.環境にやさしい高分子材料の設計(9)植物由来モノマーの精密重合に基づく機能性高分子の合成—12. Design of environmentally friendly polymeric materials (9) Precision polymerization of naturally-occurring vinyl monomers for novel high-performance polymers

    佐藤 浩太郎, 上垣外 正己

    日本接着学会誌 = Journal of the Adhesion Society of Japan : adhesion   46 ( 1 )   29 - 36   2010

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  • 精密に構造制御しながら高分子を合成する―ラジカル重合での挑戦― Invited

    上垣外正己, 佐藤浩太郎, 永井寛嗣

    現代化学   471 ( 471 )   32-37 - 37   2010

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  • Stereospecific Living Radical Polymerization: Dual Control of Chain Length and Tacticity for Precision Polymer Synthesis Invited Reviewed

    Kotaro Satoh, Masami Kamigaito

    CHEMICAL REVIEWS   109 ( 11 )   5120 - 5156   2009.11

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    DOI： 10.1021/cr900115u

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  • Thiourea-mediated stereospecific radical polymerization of acrylamides and combination with RAFT for simultaneous control of molecular weight and tacticity Invited Reviewed

    Harumi Murayama, Kotaro Satoh, Masami Kamigaito

    ACS Symposium Series   1024   49 - 63   2009.8

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    DOI： 10.1021/bk-2009-1024.ch004

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  • Does Intuition Whisper a Well-Polished Idea?

    SATOH Kotaro

    58 ( 4 )   176   2009.4

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  • Mn-2(CO)(10)-Induced Controlled/Living Radical Copolymerization of Methyl Acrylate and 1-Hexene in Fluoroalcohol: High alpha-Olefin Content Copolymers with Controlled Molecular Weights Reviewed

    Kazuhiko Koumura, Kotaro Satoh, Masami Kamigaito

    MACROMOLECULES   42 ( 7 )   2497 - 2504   2009.4

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    DOI： 10.1021/ma9001275

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  • Mn-2(CO)(10)-Induced Controlled/Living Radical Copolymerization of Vinyl Acetate and Methyl Acrylate: Spontaneous Formation of Block Copolymers Consisting of Gradient and Homopolymer Segments Reviewed

    Kazuhiko Koumura, Kotaro Satoh, Masami Kamigaito

    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY   47 ( 5 )   1343 - 1353   2009.3

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    DOI： 10.1002/pola.23243

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  • Cycloolefin Copolymer Analogues from Styrene and Isoprene: Cationic Cyclization of the Random Copolymers Prepared by Living Anionic Polymerization Invited Reviewed

    Atsuhiro Nakahara, Kotaro Satoh, Masami Kamigaito

    MACROMOLECULES   42 ( 3 )   620 - 625   2009.2

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    DOI： 10.1021/ma802024t

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  • Metal-Catalyzed Radical Polyaddition for Aliphatic Polyesters via Evolution of Atom Transfer Radical Addition into Step-Growth Polymerization Invited Reviewed

    Masato Mizutani, Kotaro Satoh, Masami Kamigaito

    MACROMOLECULES   42 ( 2 )   472 - 480   2009.1

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    DOI： 10.1021/ma802067c

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  • Metal-catalyzed living radical polymerization and radical polyaddition for precision polymer synthesis Invited Reviewed

    M. Mizutani, K. Satoh, M. Kamigaito

    Journal of Physics: Conference Series   184   012025   2009

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    DOI： 10.1088/1742-6596/184/1/012025

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  • ラジカル重合 Invited Reviewed

    上垣外正己, 佐藤浩太郎

    ネットワークポリマー   30 ( 5 )   234-249   2009

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  • Nano-to-Macroscale Poly(methyl methacrylate) Stereocomplex Assemblies Reviewed

    Tor Kit Goh, Jing Fung Tan, Stefanie Nina Guntari, Kotaro Satoh, Anton Blencowe, Masami Kamigaito, Greg Guanghua Qiao

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   48 ( 46 )   8707 - 8711   2009

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    DOI： 10.1002/anie.200903932

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  • Mn-2(CO)(10)-Induced RAFT Polymerization of Vinyl Acetate, Methyl Acrylate, and Styrene Reviewed

    Kazuhiko Koumura, Kotaro Satoh, Masami Kamigaito

    POLYMER JOURNAL   41 ( 8 )   595 - 603   2009

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    DOI： 10.1295/polymj.PJ2009070

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  • Stereogradient Polymers via Spontaneously Increasing Isospecificity during Controlled/Living Radical Polymerization of Bulky Methacrylate Invited Reviewed

    K. Ishitake, K. Satoh, M. Kamigaito, Y. Okamoto

    Angew. Chem. Int. Ed.   48 ( 11 )   1991-1994   2009

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  • Radical Polymerization

    Kamigaito Masami, Satoh Kotaro

    Journal of Network Polymer,Japan   30 ( 5 )   234 - 249   2009

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    Radical polymerization proceeds via highly reactive neutral radical growing species and has been investigated from various aspects for many years. It is also one of the most common and widely employed polymerizations in industy due to the high reactivity and applicability as well as the tolerance to polar compounds like water. In addition, recent years witnessed great developments in living radical polymerization, which has now been emplyed for the precision polymer synthesis. This review covers fundamental aspects in conventional radical polymerizations including polymerizable monomers, mechanisms like initiation, propagation, termination and chain transfers, and copolymerizations in addition to the recent advances in living radical polymerizations and stereospecific radical polymerizations.

    DOI： 10.11364/networkpolymer.30.234

    DOI： 10.4011/shikizai.92.49_references_DOI_NI1FDpvDVActdQ7mSgnfrNZCccl

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  • 低環境負荷型重合系の開発―極性モノマーの重合反応制御から実用化まで Invited

    佐藤浩太郎, 上垣外正己

    化学   63 ( 11 )   70-71   2008.11

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  • Manganese-Based Controlled/Living Radical Polymerization of Vinyl Acetate, Methyl Acrylate, and Styrene: Highly Active, Versatile, and Photoresponsive Systems Invited Reviewed

    Kazuhiko Koumura, Kotaro Satoh, Masami Kamigaito

    MACROMOLECULES   41 ( 20 )   7359 - 7367   2008.10

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    DOI： 10.1021/ma801151s

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  • 遷移金属錯体を用いたリビングラジカル重合による多重制御グラフト共重合体 Invited Reviewed

    佐藤浩太郎, 上垣外正己

    日本ゴム協会誌   81 ( 10 )   424-430   2008.10

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  • POLY 383-Metal-catalyzed radical polyaddition as a novel polymer synthetic route: Design and analysis

    Masato Mizutani, Kotaro Satoh, Masami Kamigaito

    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY   236   2008.8

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  • POLY 573-Sequence-regulated vinyl polymers by metal-catalyzed radical polyaddition of designed monomers

    Kotaro Satoh, Masami Kamigaito, Tomohiro Abe, Satoshi Ozawa

    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY   236   2008.8

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  • POLY 382-Stereospecific controlled/living radical polymerization of methacrylates with bulky substituents for stereogradient polymers

    Kenji Ishitake, Kotaro Satoh, Masami Kamigaito, Yoshio Okamoto

    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY   236   2008.8

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  • Iron(III) Chloride/R-Cl/Tributylphosphine for Metal-Catalyzed Living Radical Polymerization: A Unique System with a Higher Oxidation State Iron Complex Reviewed

    KOTARO SATOH, HIROSHI AOSHIMA, MASAMI KAMIGAITO

    Journal of Polymer Science: Part A: Polymer Chemistry   46   6358-6363   2008.8

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  • POLY 319-Photoinduced living radical polymerization with highly active manganese complex

    Kazuhiko Koumura, Kotaro Satoh, Masami Kamigaito

    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY   236   2008.8

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  • ラジカル重合における精密制御 ― 分子量、立体構造、モノマー配列の制御 Invited

    上垣外正己, 佐藤浩太郎

    有機合成化学協会誌   66 ( 6 )   578-589   2008.6

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  • Regiospecific radical polymerization of vinyl methacrylate in the presence of lewis acids into soluble polymers with pendent vinyl ester substituents Invited Reviewed

    Fumitaka Sugiyama, Kotaro Satoh, Masami Kamigaito

    MACROMOLECULES   41 ( 9 )   3042 - 3048   2008.5

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    DOI： 10.1021/ma702855s

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  • Stereoregulation in living radical polymerization Invited Reviewed

    Masami Kamigaito, Kotaro Satoh

    Macromolecules   41 ( 2 )   269 - 276   2008.1

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    DOI： 10.1021/ma071499l

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  • Development of functional polymers by precision polymerization: novel alicyclic hydrocarbon polymer by living cationic polymerization Invited Reviewed

    59 ( 1 )   1-9 - 9   2008.1

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  • 精密重合に基づく機能性高分子材料の開発--リビングカチオン重合による新規脂環式ポリオレフィンの合成—Development of functional polymers by precision polymerization: novel alicyclic hydrocarbon polymer by living cationic polymerization—特集 未来社会を支える化学技術

    上垣外 正己, 佐藤 浩太郎

    化學工業   59 ( 1 )   1 - 9   2008.1

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  • リビングラジカル重合の基礎と展開 Invited

    上垣外正己, 佐藤浩太郎

    色材協会誌   81 ( 11 )   459-470   2008

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  • Basic and Development of Living Radical Polymerization

    KAMIGAITO Masami, SATOH Kotaro

    Journal of the Japan Society of Colour Material   81 ( 11 )   459 - 470   2008

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  • Nanometer voids prevent crack growth in polymeric materials Reviewed

    Cedric Dutriez, Kotaro Satoh, Masami Kamigaito, Hideaki Yokoyama

    MACROMOLECULES   40 ( 21 )   7433 - 7436   2007.10

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    DOI： 10.1021/ma071262p

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  • A linear lignin analogue: Phenolic alternating copolymers from naturally occurring beta-methylstyrene via aqueous-controlled cationic copolymerization Reviewed

    Kotaro Satoh, Shoichi Saitoh, Masami Kamigaito

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   129 ( 31 )   9586 - +   2007.8

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    DOI： 10.1021/ja0732227

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  • A(x)BA(x)-type block-graft polymers with middle soft segments and outer hard graft chains by ruthenium-catalyzed living radical polymerization: Synthesis and characterization Reviewed

    Yu Miura, Kotaro Satoh, Masami Kamigaito, Yoshio Okamoto, Takeshi Kaneko, Hiroshi Jinnai, Syuji Kobukata

    MACROMOLECULES   40 ( 3 )   465 - 473   2007.2

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    DOI： 10.1021/ma062098t

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  • Chiral (-)-DIOP ruthenium complexes for asymmetric radical addition and living radical polymerization reactions Reviewed

    Yusuke Iizuka, Zhaoming Li, Kotaro Satoh, Masarni Karnigaito, Yoshio Okamoto, Jun-ichi Ito, Hisao Nishiyama

    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY   2007 ( 5 )   782 - 791   2007.2

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    DOI： 10.1002/ejoc.200600862

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  • A(x)BA(x)-type block-graft polymers with soft methacrylate middle segments and hard styrene outer grafts: Synthesis, morphology, and mechanical properties Reviewed

    Yu Miura, Takeshi Kaneko, Kotaro Satoh, Masami Kamigaito, Hiroshi Jinnai, Yoshio Okamoto

    CHEMISTRY-AN ASIAN JOURNAL   2 ( 5 )   662 - 672   2007

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    DOI： 10.1002/asia.200600403

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  • A Neutron Reflectivity Study on a Terraced Lamellar Morphology in a Block Copolymer Thin Film Reviewed

    Ken-ichi Niihara, Ukyo Matsuwaki, Naoya Torikai, Kotaro Satoh, Masami Kamigaito, Hiroshi Jinnai

    POLYMER JOURNAL   39 ( 11 )   1105 - 1111   2007

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    DOI： 10.1295/polymj.PJ2007100

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  • Metal-catalyzed radical polyaddition as a novel polymer synthetic route Reviewed

    Kotaro Satoh, Masato Mizutani, Masami Kamigaito

    CHEMICAL COMMUNICATIONS   2007 ( 12 )   1260 - 1262   2007

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    DOI： 10.1039/b616598b

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  • Stereogradient polymers by ruthenium-catalyzed stereospecific living radical copolymerization of two monomers with different stereospecificities and reactivities Reviewed

    Yu Miura, Takuya Shibata, Kotaro Satoh, Masami Kamigaito, Yoshio Okamoto

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   128 ( 50 )   16026 - 16027   2006.12

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    DOI： 10.1021/ja067587n

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  • A bicyclic conjugated diene monomer, tetrahydroindene, for cationic polymerization and a novel alicyclic hydrocarbon polymer with heat resistance Reviewed

    Naomi Mizuno, Kotaro Satoh, Masami Kamigaito, Yoshio Okamoto

    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY   44 ( 21 )   6214 - 6225   2006.11

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    DOI： 10.1002/pola.21714

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  • Stereospecific living radical polymerization for simultaneous control of molecular weight and tacticity Invited Reviewed

    Masami Kamigaito, Kotaro Satoh

    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY   44 ( 21 )   6147 - 6158   2006.11

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    DOI： 10.1002/pola.21688

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  • Triple hydrogen bonding for stereospecific radical polymerization of a DAD monomer and simultaneous control of tacticity and molecular weight Reviewed

    Decheng Wan, Kotaro Satoh, Masami Kamigaito

    MACROMOLECULES   39 ( 20 )   6882 - 6886   2006.10

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    DOI： 10.1021/ma0615654

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  • Cationic polymerization of a novel bicyclic conjugated diene monomer, tetrahydroindene, and its block copolymers with vinyl ether Reviewed

    Naomi Mizuno, Kotaro Satoh, Masami Kamigaito, Yoshio Okamoto

    MACROMOLECULES   39 ( 16 )   5280 - 5285   2006.8

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    DOI： 10.1021/ma060911e

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  • Simultaneous control of the stereospecificity and molecular weight in the ruthenium-catalyzed living radical polymerization of methyl and 2-hydroxyethyl methacrylates and sequential synthesis of stereoblock polymers Reviewed

    Takuya Shibata, Kotaro Satoh, Masami Kamigaito, Yoshio Okamot

    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY   44 ( 11 )   3609 - 3615   2006.6

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    DOI： 10.1002/pola.21469

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  • Iodine transfer radical polymerization of vinyl acetate in fluoroalcohols for simultaneous control of molecular weight, stereospecificity, and regiospecificity Reviewed

    Kazuhiko Koumura, Kotaro Satoh, Masami Kamigaito, Yoshio Okamoto

    MACROMOLECULES   39 ( 12 )   4054 - 4061   2006.6

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    DOI： 10.1021/ma0602775

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  • Iron-catalyzed radical polymerization of acrylamides in the presence of Lewis acid for simultaneous control of molecular weight and tacticity Reviewed

    Y Sugiyama, K Satoh, M Kamigaito, Y Okamoto

    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY   44 ( 6 )   2086 - 2098   2006.3

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    DOI： 10.1002/pola.21310

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  • A "ladder" morphology in an ABC triblock copolymer Reviewed

    Takeshi Kaneko, Kazuya Suda, Kotaro Satoh, Masami Kamigaito, Toshinori Kato, Tomohiro Ono, Eiji Nakamura, Toshio Nishi, Hiroshi Jinnai

    MACROMOLECULAR SYMPOSIA   242   80 - 86   2006

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    DOI： 10.1002/masy.200651013

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  • Well-defined graft copolymers of methacrylate, acrylate, and styrene via ruthenium-catalyzed living radical polymerization Reviewed

    Yu Miura, Kotaro Satoh, Masami Kamigaito, Yoshio Okamoto

    POLYMER JOURNAL   38 ( 9 )   930 - 939   2006

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    DOI： 10.1295/polymj.PJ2006031

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  • Stereospecific Living Radical Polymerization

    KAMIGAITO Masami, SATOH Kotaro

    Kobunshi   55 ( 4 )   250 - 253   2006

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  • Biomass-derived heat-resistant alicyclic hydrocarbon polymers: poly(terpenes) and their hydrogenated derivatives Reviewed

    Kotaro Satoh, Hiroko Sugiyama, Masami Kamigaito

    GREEN CHEMISTRY   8 ( 10 )   878 - 882   2006

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    DOI： 10.1039/b607789g

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  • Stereospecific Living Radical Polymerization Invited Reviewed

    M. Kamigaito, K. Satoh, D. Wan, K. Koumura, T, Shibata, Y. Okamoto

    ACS Symposium Series   994   26-39 - 39   2006

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  • 立体特異性リビングラジカル重合 Invited

    上垣外正己, 佐藤浩太郎

    高分子   55   250-253   2006

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  • Xanthate-mediated radical polymerization of N-vinylpyrrolidone in fluoroalcohols for simultaneous control of molecular weight and tacticity Reviewed

    DC Wan, K Satoh, M Kamigaito, Y Okamoto

    MACROMOLECULES   38 ( 25 )   10397 - 10405   2005.12

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    DOI： 10.1021/ma0515230

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  • 多糖誘導体担持型ルテニウム触媒を用いた精密制御ラジカル重合

    新井厚仁, 佐藤浩太郎, 山本智代, 上垣外正己, 岡本佳男

    高分子学会予稿集(CD-ROM)   54 ( 2 Disk1 )   1PF014   2005.9

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  • Living cationic polymerization of tetrahydroindene and its block copolymer: A novel high Tg poly(cycloolefin)

    Kotaro Satoh, Naomi Mizuno, Masami Kamigaito, Yoshio Okamoto

    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY   230   U4081 - U4081   2005.8

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  • Metal-catalyzed stereospecific living radical polymerization

    M Kamigaito, K Satoh, Y Okamoto

    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY   230   U4019 - U4019   2005.8

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  • Star polymers with chiral-functionalized core by living radical polymerization: Synthesis and characterization

    Kotaro Satoh, Masaya Isonaga, Masami Kamigaito, Yoshio Okamoto

    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY   230   U4203 - U4204   2005.8

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  • セルロース担持型ルテニウム触媒を用いた精密制御ラジカル重合

    新井厚仁, 佐藤浩太郎, 山本智代, 上垣外正己, 岡本佳男

    高分子学会予稿集(CD-ROM)   54 ( 1 Disk1 )   1PD012   2005.5

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  • Cationic polymerization in aqueous media with water-tolerant lewis acids Reviewed

    K Satoh

    KOBUNSHI RONBUNSHU   62 ( 8 )   335 - 351   2005

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  • Cationic Polymerization in Aqueous Media with Water-Tolerant Lewis Acids

    SATOH Kotaro

    KOBUNSHI RONBUNSHU   62 ( 8 )   335 - 351   2005

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    Contrary to the long-time belief, the present study has demonstrated cationic polymerizations in aqueous media via two different methods. The first one is based on the finding that water-tolerant Lewis acids of lanthanide and related metal triflates, in conjunction with the HCl adduct of a monomer, induce controlled cationic polymerization of styrene derivatives in heterogeneous aqueous systems, where the growing carbocationic species is formed in the organic phase via entrance of a water-soluble Lewis acid from the aqueous phase. The second method is based on BF3OEt2 as another water-tolerant Lewis acid. When coupled with the monomer-water adduct, the boron compound mediates living cationic polymerizations of styrenes even in a homogeneous aqueous solvent, where the C-OH bond is selectively activated by the oxophilic Lewis acid to generate carbocationic species in the aqueous monophase. Furthermore, the C-OH/BF3OEt2 system also induces direct living cationic polymerizations of functional monomers such as unprotected pHS. The author hopes that these novel systems for carbocationic polymerizations will contribute to the progress of ion chemistry as well as to environmentally benign industrial processes.

    DOI： 10.1295/koron.62.335

    DOI： 10.3390/polym10121404_references_DOI_DrtGULNCdfkDAVaqzCYMSGrHEOF

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    Other Link： https://ndlsearch.ndl.go.jp/books/R000000004-I7461058

  • Controlled cationic polymerization of p-(chloromethyl)styrene: BF3-catalyzed selective activation of a C-O terminal from alcohol Reviewed

    M Kamigaito, J Nakashima, K Satoh, M Sawamoto

    MACROMOLECULES   36 ( 10 )   3540 - 3544   2003.5

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    DOI： 10.1021/ma0216876

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  • Novel BF3OEt2/R-OH initiating system for controlled cationic polymerization of styrene in the presence of water Reviewed

    K Satoh, J Nakashima, Kamigaito, I, M Sawamoto

    MACROMOLECULES   34 ( 3 )   396 - 401   2001.1

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    DOI： 10.1021/ma0006070

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  • Sulfonic acids as water-soluble initiators for cationic polymerization in aqueous media with Yb(OTf)(3) Reviewed

    K Satoh, M Kamigaito, M Sawamoto

    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY   38 ( 15 )   2728 - 2733   2000.8

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  • Metal triflates and tetrafluoroborates as water-tolerant Lewis acids for cationic polymerization in aqueous media Reviewed

    K Satoh, M Kamigaito, M Sawamoto

    MACROMOLECULES   33 ( 16 )   5836 - 5840   2000.8

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    DOI： 10.1021/ma000069r

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  • Direct living cationic polymerization of p-hydroxystyrene with boron trifluoride etherate in the presence of water Reviewed

    K Satoh, M Kamigaito, M Sawamoto

    MACROMOLECULES   33 ( 15 )   5405 - 5410   2000.7

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  • Lanthanide triflates-mediated emulsion cationic polymerization of p-alkoxystyrenes in aqueous media Reviewed

    K Satoh, M Kamigaito, M Sawamoto

    MACROMOLECULES   33 ( 13 )   4660 - 4666   2000.6

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  • Aromatic acetals as new initiators for cationic polymerization of isobutyl vinyl ether Reviewed

    K Satoh, M Kamigaito, M Sawamoto

    MACROMOLECULES   33 ( 3 )   748 - 753   2000.2

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  • Direct Synthesis of Amphiphilic Block or Random Copolymers of p-Hydroxystyrene and p-Methoxystyrene via Living Cationic Polymerization with BF3OEt2/ROH Systems Reviewed

    K. Satoh, M. Kamigaito, M. Sawamoto

    Macromolecules   33   5830-5835   2000

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  • Controlled cationic polymerization of P-alkoxystyrene and P-hydroxystryrene in aqueous media.

    K Satoh, M Kamigaito, M Sawamoto

    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY   218   U466 - U466   1999.8

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  • Controlled cationic polymerization of p-methoxystyrene in aqueous media with Yb(OTf)(3) Reviewed

    K Satoh, M Kamigaito, M Sawamoto

    MACROMOLECULES   32 ( 12 )   3827 - 3832   1999.6

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  • Amphiphilic 3-arm star block polymers by living cationic polymerization Reviewed

    R Takahashi, M Ouchi, K Satoh, M Kamigaito, M Sawamoto

    POLYMER JOURNAL   31 ( 11 )   995 - 1000   1999

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  • Living cationic polymerization with Yb(OSO2CF3)(3) as a water-resistant, recoverable Lewis acid Reviewed

    K Satoh, H Katayama, M Kamigaito, M Sawamoto

    CATIONIC POLYMERIZATION   665   106 - 112   1997

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Presentations

  • Interconvertible Living Radical and Cationic Polymerization

    Kotaro Satoh, Masami KAMIGAITO

    The 4th Federation Of Asian Polymer Societies International Polymer Congress (4FAPS-IPC 2015) , 5-8 Oct 2015, Kuala Lumpur  2015.10 

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  • Controlling the Growing Nature in Controlled/Living Polymerizations and Renewable Vinyl Monomers for Novel Bio-Based Polymer

    Kotaro Satoh

    Department Seminar of Polymer Science and Engineering, 22 Oct 2015, Soochow Univ, Suzhou, China  2015.10 

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  • Unprecedented Copolymer Synthesis by Transformation of Growing Nature in Vinyl Polymerizations

    Kotaro Satoh

    35th Australiasian Polymer Symposium, 12-15 July 2015, Gold Coast  2015.7 

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  • Precision Polymerization of Vinyl Monomers by Controlling Different Reaction Mechanisms International conference

    64th SPSJ Symposium on Macromolecules, SPSJ Wiley Award 2015 Lecture  2015.9 

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  • ビニルモノマーの重合における配列制御への挑戦 International conference

    佐藤浩太郎

    15－1超分子研究会「精密集積・配列が拓く超分子材料」、2015年5月15日、早稲田大学  2015.5  高分子学会超分子研究会

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    Venue：早稲田大学 西早稲田キャンパス  

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  • Controlled/Living Polymerization of Renewable Vinyl Monomers into Novel Bio-Based Polymers

    Kotaro Satoh

    The 5th International Conference on Bio-based Polymers (ICBP2015), Jun24-27,2015,Singapore  2015.6 

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  • Reversible Umpolung Interconversion of Growing Nature during Vinyl Polymerizations

    Kotaro Satoh

    International Symposium on Polymer Science and Technology MACRO2015, Jan23-26,2015,Kolkata,India  2015.1 

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  • リビング重合の最先端研究 International conference

    佐藤浩太郎

    高分子の基礎と応用：レビュー講演会、高分子学会関西支部、2015年11月4日、大阪  2015.11  高分子学会関西支部

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    Venue：日本ペイント株式会社 本社ホール  

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  • Controlled/living polymerization of naturally occurring terpenes

    Kotaro Satoh

    The International Chemical Congress of Pacific Basin Societies 2015 (Pacifichem 2015), Session #37, December 15-20, 2015 Honolulu, Hawaii  2015.12 

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  • Mechanistic Transformation of Growing Nature in Vinyl Polymerizations

    Kotaro Satoh

    The International Chemical Congress of Pacific Basin Societies 2015 (Pacifichem 2015), Session #112, December 15-20, 2015 Honolulu, Hawaii  2015.12 

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  • リビング重合の新展開：異種反応機構を介する精密重合 Invited International conference

    佐藤浩太郎

    1６-１精密ネットワークポリマー研究会-精密重合をネットワークポリマーに生かす-、2016年4月22日、東京  2016.4  高分子学会精密ネットワークポリマー研究会

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    Venue：東工大蔵前会館 ロイアルブルーホール  

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  • Unprecedented Copolymer Synthesis by Concurrent and Interconvertible Living Polymerizations Invited

    Kotaro Satoh

    International Symposium on Advanced Polymeric Materials (ISAPM2016) under the auspices of IMTCE2016, May16-19, 2016, Kuala Lumpur, Malaysia  2016.5 

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  • Reversible Mechanistic Transformation of Growing Species during Vinyl Polymerization for Novel Copolymers Invited

    Kotaro Satoh

    Materials Architecturing Research Center Seminar, Korea Institute of Science and Technology (KIST), Apr 6, 2016, Seoul, Korea  2016.4 

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  • Concurrent and Interconvertible Living Polymerizations for Unprecedented Copolymer Synthesis Invited

    Kotaro Satoh

    2016 Spring Meeting, The Polymer Society of Korea, Apr 7-8, 2016, Daejeon, Korea  2016.4 

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  • 異種反応機構を介したビニルモノマーの新しい精密重合系の開発 International conference

    佐藤浩太郎

    触媒学会重合触媒設計研究会セミナー -高分子合成に関する最近の話題-、2016年2月1日、東京  2016.2  触媒学会（重合触媒設計研究会）

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    Venue：キャンパス・イノベーションセンター東京  

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  • Polymer Synthesis ~Polymers in Our Daily Life and Polymerization of Vinyl Monomers Invited

    Kotaro Satoh

    Educational Workshop and Symposium on Polymer Science and Technology, UniKL, Mar 29-30, 2016, Kuala lumpur  2016.3 

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  • Controlled/living polymerization of styrenes derived from natural resources

    Kotaro Satoh

    The International Chemical Congress of Pacific Basin Societies 2015 (Pacifichem 2015), Session #396, December 15-20, 2015 Honolulu, Hawaii  2015.12 

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  • Reversible Mechanistic Transformation of Growing Species during Vinyl Polymerization for Novel Copolymers

    Kotaro Satoh

    Polymer Material Research Center Seminar, Harbin Engineering University, Jan 12, 2016, Harbin, China  2016.1 

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  • Reversible Mechanistic Transformation between Radical and Cationic Species during Vinyl Copolymerization Invited

    Kotaro Satoh, Masami Kamigaito

    23rd IUPAC International Conference on Physical Organic Chemistry (ICPOC23), Jul3-8, 2016, Sydney, Australia  2016.7 

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  • Interconvertible Concurrent Controlled/Living Polymerizations for Unprecedented Copolymer Synthesis Invited

    Kotaro Satoh

    Centre for Advanced Macromolecular Design (CAMD) Seminar,University of New South Wales(UNSW), Jul7, 2016, Sydney, Australia  2016.7 

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  • 高分子精密合成の揺籃期から全盛期に学ぶ高分子化学の将来展望 Invited International conference

    佐藤浩太郎

    高分子の歴史に学び、未来を展望する ―科学技術史第2巻出版記念―、2016年5月25日、神戸  2016.5  高分子学会

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    Venue：神戸国際会議場  

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  • 異なる反応機構を操った新しい高分子共重合体合成技術の開発 International conference

    佐藤浩太郎

    理化学研究所 創発物性科学研究センター (CEMS)セミナー、2013年11月1日、和光市  2013.11  理化学研究所創発物性科学研究センター (CEMS)

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    Venue：埼玉県和光市  

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  • 新しいバイオベースポリマーの創出にむけたさまざまな植物由来モノマーの精密重合 International conference

    佐藤浩太郎

    東京大学大学院農学生命科学研究科 生物材料科学専攻 専攻セミナー、2013年11月14日、東京大学  2013.11  東京大学大学院農学生命科学研究科 生物材料科学専攻

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    Venue：東京大学  

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  • Transition metal-catalyzed step-growth radical polymerization for various sequence-regulated vinyl polymers

    Kotaro Satoh, Masami Kamigaito

    Sequence-Controlled Polymers, 246th ACS National Meeting and Exposition September 8-12, 2013, Indianapolis, Indiana, USA  2013.9 

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  • Living Cationic and Radical Polymerizations by Reversible Activation of C-S Bond

    Kotaro Satoh, Masami Kamigaito

    IUPAC International Symposium on Ionic Polymerization 2013, September 23-28, Awaji, JAPAN  2013.9 

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  • 機能性バイオベース高分子材料開発に向けた植物由来ビニルモノマーの精密重合 International conference

    佐藤浩太郎

    平成25年度日本接着学会中部支部 講演会、2013年7月22日、名古屋  2013.7  日本接着学会中部支部

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    Venue：愛知工業大学  

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  • Sequence-Controlled Vinyl Polymers by Transition Metal-Catalyzed Step-Growth and Living Radical Polymerizations

    Kotaro Satoh, Masami Kamigaito

    XXII International Materials Research Congress 2013 [4D: New Trends in Polymer Chemistry and Characterization], 11-15 Aug, Cancún, Mexico  2013.8 

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  • 異なる反応機構を組み合わせた新しい精密重合系の開発 International conference

    佐藤浩太郎

    高分子学会関東支部 第48回茨城地区活動講演会「高分子の精密制御と機能性材料への展開」、2013年7月19日、つくば  2013.7  高分子学会 関東支部

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    Venue：クラレつくばセンター  

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  • 植物由来ビニルモノマーの精密重合による新規機能性バイオベース高分子材料の開発 International conference

    佐藤浩太郎

    粘着研究会第137回例会 講演会、2014年3月7日、東京  2014.3  日本接着学会 粘着研究会

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    Venue：東京大学  

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  • Synthesis of Periodically Functionalized Polymers by Simultaneous Chain- and Step-Growth Radical Polymerization

    Kotaro Satoh, Masami Kamigaito

    The 13th Pacific Polymer Conference (PPC13), Nov.17-22, Kaohsiung, Taiwan  2013.11 

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  • 新しい精密重合系の開発と植物由来モノマーへの展開 International conference

    佐藤浩太郎

    九州大学先導物質化学研究所 先端高分⼦化学講演会、2014年2月10日、九州大学  2014.2  九州大学先導物質化学研究所

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    Venue：九州大学  

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  • Precision polymer synthesis and polymers from renewable resources

    Kotaro Satoh

    Department Seminar, Department of Polymer Science & Engineering, Peking University, October 27, 2014, Beijing, China  2014.10 

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  • Reversible Umpolung of Growing Nature during Vinyl Polymerizations

    Kotaro Satoh, Masami Kamigaito

    18th Malaysian International Chemical Congress (18MICC), November 3-5, 2014, Kuala Lumpur, Malaysia  2014.11 

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  • 異種反応機構の組み合わせによる新しい精密重合系の開発 International conference

    佐藤浩太郎

    第82回高分子若手研究会[関西]、2014年7月27-28日、神戸市  2014.7  高分子学会関西支部

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    Venue：六甲山YMCA  

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  • Periodically Functionalized Poly(NIPAM) by Metal-Catalyzed Step- and Chain-Growth Radical Polymerizations

    Kotaro Satoh, Masami Kamigaito

    Controlled Radical Polymerization, 248th ACS National Meeting and Exposition, August 10-14, 2014, San Francisco, CA, USA  2014.8 

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  • Transformation of Growing Nature in Vinyl Polymerizations

    Kotaro Satoh

    2014 International Symposium on Polymer Materials, July 1-3, 2014, Harbin, China  2014.7 

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  • Simultaneous Chain and Step Growth Radical Polymerization for Tailored Periodically Functionalized Thermoresponsive Polymers

    Kotaro Satoh

    The IUPAC World Polymer Congress MACRO2014, July 6-11, 2014, Chiang Mai, Thailand  2014.7 

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  • Reversible mechanistic transformation of active species during controlled/living polymerization

    Kotaro Satoh, Masami Kamigaito

    3rd International Symposium on CONTROLLED/LIVING POLYMERIZATION (CLP14), May 1-4, Antalya, Turkey  2014.5 

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  • Transition Metal-Catalyzed Step-Growth and Living Radical Polymerizations for Sequence-Control in Vinyl Polymers

    Kotaro Satoh, Masami Kamigaito

    International Symposium on Polymer Chemistry (PC2014), June 4-7, 2014, Shanghai, China  2014.6 

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  • Terpene as Renewable Vinyl Monomer for Novel Bio-Based Polymers

    Kotaro Satoh, Masami Kamigaito

    Vietnam Malaysia International Chemical Congress (VMICC), November 7-10, 2014, Hanoi, Vietnam  2014.11 

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  • 植物由来ビニルモノマーの精密重合による高分子材料設計 International conference

    佐藤浩太郎

    第36回日本バイオマテリアル学会大会「シンポジウム1 バイオマテリアル創製の新時代」、2014年11月17-18日、東京  2014.11  日本バイオマテリアル学会

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    Venue：タワーホール船堀  

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  • Controlled Polymerization of Terpene as Renewable Vinyl Monomer for Novel Bio-Based Polymers

    Kotaro Satoh, Masami Kamigaito

    The 8th International Conference on Materials Science and Technology (MSAT8), Thailand-Japan Initiative, December 15, 2014, Bangkok, Thailand  2014.12 

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  • Controlled/Living Polymerization of Naturally Occurring Terpenes and Related Monomers International conference

    Kotaro Satoh, Masami Kamigaito

    The 11th SPSJ International Polymer Conference (IPC 2016), December 13-16, 2016, Fukuoka, Japan  2016.12 

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  • リビング重合の最先端研究~基礎とラジカル重合を中心に~ Invited International conference

    佐藤浩太郎

    第２回レビュー講演会、高分子学会関西支部、2016年10月28日、大阪  2016.10  高分子学会関西支部

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    Venue：大阪市立大学文化交流センターホール  

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  • 高分子合成の新展開:異種重合反応の組み合わせと自在な高分子設計技術 Invited International conference

    佐藤浩太郎

    第６５回高分子学会北陸支部研究発表会 特別講演、高分子学会北陸支部、2016年11月12日-13日、福井  2016.11  高分子学会北陸支部

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    Venue：福井大学  

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  • 異なる反応機構を操った新しい高分子合成 International conference

    佐藤浩太郎

    静岡大学理学部化学科講演会、2016年9月23日、静岡大学  2016.9  静岡大学理学部化学科

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    Venue：静岡大学  

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  • 'Multiply-Controlled'   Macrocyclic   Polymers   Prepared   via   Living   and   Stereospecific Polymerizations Invited

    Kotaro Satoh

    Symposium of Cyclic Polymer (Suzhou-2016), Soochow University, Oct 15, 2016, Suzhou,China  2016.10  Soochow University

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    Venue：Suzhou  

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  • Interconvertible Controlled/Living Radical and Cationic Polymerization via RAFT Terminal Invited

    Kotaro Satoh

    Symposium for Biomacromolecules/Macromolecules Young Investigator Award, 252nd ACS National Meeting, August 22, 2016, Philadelphia,USA  2016.8 

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  • Sequence-Controlled Vinyl Polymers by Transition Metal-Catalyzed Radical Addition Invited

    Kotaro Satoh

    Symposium on Sequence-controlled Polymers, 252nd ACS National Meeting, August 22-25, 2016, Philadelphia,USA  2016.8 

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  • 植物由来ビニルモノマーの精密重合による新しい高分子材料設計 Invited International conference

    佐藤浩太郎

    第３２回繊維学会西部支部 講演会・見学会、繊維学会、2017年10月6日、種子島、鹿児島  2017.10  繊維学会西部支部

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    Venue：種子島あらきホテル  

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  • Controlled/Living Polymerization of Novel Functional Renewable Vinyl Monomers Invited

    Kotaro Satoh

    25th POLYCHAR (2017 World Forum on Advanced Materials), Putra World Trade Centre, Oct 9-13, 2017, Kuala Lumpur, Malaysia  2017.10  POLYCHAR, Malaysia

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    Venue：Putra World Trade Centre  

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  • 植物由来物質を原料とした精密高分子合成 Invited International conference

    佐藤浩太郎

    名古屋大学協力会工学系セミナー「高分子化学における最近の発展」, 名古屋大学協力会, 2017年11月17日、名古屋.  2017.11  名古屋大学協力会

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    Venue：名古屋大学 ES 総合館  

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  • 異種重合反応の組み合わせによる新しいポリマー材料設計技術 Invited International conference

    佐藤浩太郎

    東京工業大学有機材料フォーラム・ポリマー材料科学若⼿研究会合同セミナー, 東工大ポリマー材料科学若手研究会/優材会, 2017年12月6日、東京  2017.12  東工大ポリマー材料科学若手研究会

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    Venue：東京工業大学 大岡山キャンパス  

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  • オレフィンの化学と汎用樹脂の合成・製造：ビニルポリマー(基礎) Invited International conference

    佐藤浩太郎

    第２回ポリマーカレッジ, 高分子学会, 2017年11月15日、大阪.  2017.11  高分子学会

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    Venue：大阪国際交流センター  

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  • 様々な精密重合と最近の研究動向：ビニルポリマー(アドバンスト) Invited International conference

    佐藤浩太郎

    第２回ポリマーカレッジ, 高分子学会, 2017年11月15日、大阪.  2017.11  高分子学会

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    Venue：大阪国際交流センター  

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  • さまざまな重合反応における最新の精密重合 Invited International conference

    佐藤浩太郎

    JACI先端科学・材料技術部会講演会, 新化学技術推進協会（JACI）, 2017年10月20日、東京.  2017.10  JACI

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    Venue：JACI  

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  • Polymerization of Renewable Vinyl Monomers for Novel Green Functional Materials Invited

    Kotaro Satoh

    International Symposium on Green Technology for Value Chains (GreenVC 2017), October 23-24, 2017, Jakarta, Indonesia  2017.10  LIPI

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    Venue：Balai Kartini Convention Center  

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  • Novel Bio-Based Polymers by Controlled/Living Polymerization of Functional Renewable Vinyl Compounds Invited

    Kotaro Satoh

    13th IUPAC Int. Conf. on Novel Materials and their Synthesis (NMS-XIII), Oct15-20, Nanjing, China  2017.10  IUPAC NMS-XIII

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    Venue：Nanjing Tech University  

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  • 異種反応を介した高分子共重合体の自在設計技術の構築 Invited International conference

    佐藤浩太郎

    第7回CSJ化学フェスタ, JST特別企画：分子技術が創り出す新しい世界と材料～さきがけ若手研究者たちの挑戦～, 2017年10月18日, 東京  2017.10  JST

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    Venue：タワーホール船堀  

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  • `Multiply-Controlled' Cyclic Polymers Prepared by Controlled/Living and Stereospecific Polymerizations Invited

    Kotaro Satoh, Masami Kamigaito

    Symposium on Cyclic & Topologically Complex Polymers, 255th ACS National Meeting, Mar 18-22, 2018, New Orleans, LA, USA  2018.3  Cyclic & Topologically Complex Polymers

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  • 異種活性種を使い自在に作る新しい高分子合成技術 Invited International conference

    佐藤浩太郎

    分子設計と分子技術：新機能によるイノベーション, 日本化学会第98春季年会 中長期企画講演, 2018年3月20日、日本大学理工学部、船橋  2018.3  日本化学会

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    Venue：日本大学理工学部 船橋キャンパス  

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  • Precision Polymerization of Renewable Vinyl Monomers for Novel Functional Bio-Based Polymers Invited

    Kotaro Satoh

    The 15th Pacific Polymer Conference (PPC-15), December 10-14, 2017, Xiamen, China  2017.12  Pacific Polymer Federation Council

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    Venue：Xiamen International Conference & Exhibition Center  

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  • Renewable Vinyl Monomers for Novel Bio-Based Polymer Using Precision Polymerizations Invited

    Kotaro Satoh

    The 10th International Conference of Modification,Degradation and Stabilization of Polymers (MoDeSt2018), September 2-6, Tokyo.  2018.9 

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  • Renewable Vinyl Monomers and Their Precision Polymerization for Novel Functional Materials Invited

    Kotaro Satoh

    JSPS Core-to-Core Program; Bioplastic Global Joint Satellite Symposium, Universiti Sains Malaysia, July 9, Penang, Malyasia.  2018.7  JSPS Core-to-Core Program

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    Venue：Universiti Sains Malaysia  

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  • 異種活性種を変換して自在に作る新しい高分子合成 Invited International conference

    佐藤浩太郎

    関西大学 化学生命工学部 大学院特別講義 講演会, 2018年8月2日、関西大学、大阪  2018.8  関西大学

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    Venue：関西大学化学生命工学部  

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  • Various Renewable Vinyl Monomers for Novel Bio-Based Polymer Using Precision Polymerization Invited

    Kotaro Satoh

    Applied Chemistry Lecture Series, Changchun Institute of Applied Chemistry (CIAC), Chinese Academy of Sciences (CAS), June 9, Changchun, China.  2018.6  Changchun Institute of Applied Chemistry (CIAC)

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    Venue：Key State Laboratory, Changchun Institute of Applied Chemistry (CIAC)  

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  • Switching Active Species During RAFT Radical and Cationic Polymerizations for the Synthesis of Unprecedented Copolymers Invited

    Kotaro Satoh

    The IUPAC World Polymer Congress (MACRO2018), July 1-5, 2018, Cairns, Australia  2018.7  The IUPAC World Polymer Congress

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    Venue：Cairns Convention Centre  

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  • Switching Active Species  During Controlled/"Living" Polymerization of Vinyl Monomers Invited

    Kotaro Satoh

    Department of Polymer Science and Engineering Seminar, University of Science and Technology of China, June 5, 2018, Hefei, China.  2018.6  Department of Polymer Science and Engineering, University of Science and Technology of China

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    Venue：University of Science and Technology of China  

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  • Cationic/Radical Interconvertible and Simultaneous Polymerization Invited

    Kotaro Satoh

    8th International Symposium on Polymer Chemistry (PC2018), June 6-9, Changchun, China.  2018.6  8th International Symposium on Polymer Chemistry (PC2018)

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    Venue：South Lake Hotel, Changchun  

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  • Controlled/Living Polymerization via Switchable Dual Active Species Using Dormant Covalent Bond International conference

    Kotaro Satoh, Masami Kamigaito

    The 11th SPSJ International Polymer Conference (IPC 2016), December 13-16, 2016, Fukuoka, Japan  2016.12 

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  • Photoswitchable dual radical and cationic controlled/living polymerization for various comonomer sequence distributions Invited

    Kotaro Satoh

    8th Symposium on Controlled Radical Polymerization, 254th ACS National Meeting, August 20-24, 2017, Washington, DC, USA.  2017.8  8th Symposium on Controlled Radical Polymerization

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  • Switching Active Species During Controlled/Living Polymerization of Vinyl Monomers Invited

    Kotaro Satoh

    POLY/MAT Seminar, Department of Chemistry, University of North Carolina, Chapel Hill, August 25, 2017, North Carolina, USA  2017.8  Department of Chemistry, University of North Carolina, Chapel Hill

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    Venue：University of North Carolina, Chapel Hill  

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  • Renewable Vinyl Monomers and Their Precision Polymerization for Novel Functional Materials Invited

    Kotaro Satoh

    JSPS-Core-to-Core Program, Japan-South-East Asia Collaboration Hub of Bioplastics Study, Kick-off Symposium, Jul 31-Aug 1, 2017, Osaka, Japan  2017.7  JSPS-Core-to-Core Program

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    Venue：Osaka University  

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  • Various Renewable Vinyl Monomers for Novel Bio-Based Polymer Using Precision Polymerization Invited

    Kotaro Satoh

    Departmental Seminar, Department of Chemistry, University of Florida, August 17, 2017, Florida, USA  2017.8  Department of Chemistry, University of Florida

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    Venue：Department of Chemistry, University of Florida  

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  • Fundamental Aspect of Vinyl Polymerizations and Renewable Vinyl Monomers for Novel Bio-Based Polymer Invited

    Kotaro Satoh

    Biomaterials Seminar, Vietnam National University Ho Chi Minh City, University of Science, Jun 7, 2017, Vietnam  2017.6  Vietnam National University Ho Chi Minh City, University of Science

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    Venue：University of Science Ho Chi Minh  

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  • Switching Active Species during Polymerization for Unprecedented Copolymer Synthesis Invited

    Kotaro Satoh

    International Symposium on Pure & Applied Chemistry (ISPAC) 2017, Jun 8-10, 2017, Ho Chi Minh, Vietnam  2017.6  Chemical Society of Vietnam (CSV) and Institut Kimia Malaysia (IKM)

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    Venue：Hotel Continental Saigon  

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  • Transformation of Active Species during Vinyl Copolymerization Invited International conference

    Kotaro Satoh

    The 1st International Meeting of M&M SYNTECH Unit, Dec 17, 2016, Nagoya University, Nagoya  2016.12  M&M SYNTECH Unit

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    Venue：Nagoya University  

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  • NOVEL FUNCTIONAL RENEWABLE VINYL MONOMERS AND THEIR PRECISION POLYMERIZATION Invited International conference

    Kotaro Satoh

    The 6th International Conference on Bio-based Polymers (ICBP2017), May 14-17, 2017, Yuan Ze University, Taiwan  2017.5 

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  • 水に対して安定なルイス酸による水系でのカチオン重合〜不可能を可能にする重合化学の挑戦〜 Invited International conference

    佐藤浩太郎

    「高分子論文集」75周年記念シンポジウム ―ニューウェーブのその後の展開―、高分子討論会併設行事、高分子学会、2017年9月21日、愛媛  2017.9  高分子学会

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    Venue：愛媛大学  

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  • Design of Novel Polymerization System via Radical and Cationic Intermediates Using RAFT Agents

    Kotaro Satoh, Masami Kamigaito

    The 12th Pacific Polymer Conference (PPC12), Jeju, Korea, Nov.13-17  2011.11 

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  • 既成概念を超えた新規精密重合系の開発〜特異的な配列制御重合および活性種相互変換重合 International conference

    佐藤浩太郎

    平成23年度九州地区高分子若手研究会・冬の講演会、2011年12月8日、大分  2011.12 

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    Venue：別府  

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  • リビングラジカル重合による金属含有特殊構造ポリマーの開発 International conference

    佐藤浩太郎, 辻本康貴, 上垣外正己

    第60回高分子学会討論会、2011年9月28-30日、岡山  2011.9 

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    Venue：岡山大学  

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  • Precision Polymerization of Renewable Vinyl Monomers for Novel Bio-based Polymers

    The 3rd International Conference on Biobased Polymers (ICBP2011),Oct.18-21,Beijing  2011.10 

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  • 遷移金属触媒連鎖／逐次ラジカル同時重合による精密制御ブランチポリマーの合成 International conference

    佐藤浩太郎, 伊藤大祐, 水谷将人, 上垣外正己

    第60回高分子学会討論会、2011年9月28-30日、岡山  2011.9 

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    Venue：岡山大学  

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  • Reversible Formation of Core Crosslinked Star Polymers by RAFT Polymerization of Functional Acrylamide

    Kotaro Satoh, Shingo Sakamoto, Masami Kamigaito

    9th International gel symposium -Gelsympo2012-  2012.10 

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  • 逐次およびリビングラジカル重合による有機／無機融合材料に向けた配列周期的官能基導入ポリマー International conference

    佐藤浩太郎, 伊藤大介, 上垣外正己

    第61回高分子学会討論会、2012年9月19-21日、名古屋  2012.9 

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    Venue：名古屋工業大学  

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  • 新規バイオベースポリマーに向けた植物由来ビニルモノマーの制御重合系の開発 International conference

    佐藤浩太郎

    第61回高分子学会討論会、高分子学会旭化成賞受賞講演、2012年9月19-21日、名古屋  2012.9 

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    Venue：名古屋工業大学  

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  • Mechanistic Transformation of Active Species during Vinyl Polymerizations Using Dormant C-S Covalent Bond

    Kotaro Satoh, Masami Kamigaito

    IUPAC World Polymer Congress (Macro2012), Virginia Tech, Blacksburg, USA, June 24-29  2012.6 

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  • 融合マテリアル創出に向けたリビングラジカル重合による周期配列ポリマーの合成 International conference

    佐藤浩太郎

    新学術領域「配位プログラム」×「融合 マテリアル」合同若手シンポジウム、2012年12月20-21日、東京  2012.12  文部科学省 科学研究費補助金 新学術領域研究「配位プログラミング」「融合 マテリアル」

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    Venue：東京大学  

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  • 精密制御重合系の開発と植物由来モノマーへの展開 International conference

    佐藤浩太郎

    2012年度東海高分子学生研究会、2013年3月9日、名古屋  2013.3  高分子学会東海支部

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    Venue：名古屋大学  

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  • Concurrent Radical/Cationic Mixed Polymerization by Interconvertible Intermediates via Covalent C-­S Bond

    Kotaro Satoh, Hiroshi Aoshima, Mineto Uchiyama, Masami Kamigaito

    The 9th SPSJ International Polymer Conference (IPC 2012)  2012.12 

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  • さまざまな植物由来ビニルモノマーの制御重合系の開発 International conference

    佐藤浩太郎

    高分子学会東海支部 高分子講演会、2012年12月17日、長野  2012.12  高分子学会東海支部

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    Language：Japanese   Presentation type：Oral presentation (invited, special)  

    Venue：信州大学  

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  • 種々の植物由来ビニルモノマーの精密重合 International conference

    佐藤浩太郎

    第43回 中部化学関係学協会支部連合秋季大会、2012年11月10-11日、名古屋  2012.11 

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    Venue：名古屋工業大学  

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  • 異なる反応機構を操った新規精密重合系の開発 International conference

    佐藤浩太郎

    KIPS高分子若手シンポジウム、2012年12月7日、京都  2012.12  京都高分子科学研究所

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    Language：Japanese   Presentation type：Oral presentation (invited, special)  

    Venue：京都大学  

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  • 植物由来ビニルモノマーの制御重合による新規バイオベースポ リマーの開発 International conference

    佐藤浩太郎

    高分子学会中国四国支部 高分子研究会、2013年6月19日、鳥取  2013.6  高分子学会中国四国支部

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    Venue：鳥取大学  

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  • さまざまな再生可能ビニルモノマーの制御重合 International conference

    佐藤浩太郎

    13-1エコマテリアル研究会「環境にやさしいプラスチックの研究最前線」、2013年7月5日、東京  2013.7  高分子学会 エコマテリアル研究会

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    Language：Japanese   Presentation type：Oral presentation (invited, special)  

    Venue：東京大学  

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  • Sequence-Regulated Vinyl Polymers by Transition Metal- Catalyzed Step-Growth Radical Polymerization International conference

    Kotaro Satoh

    Asian International Symposium at 93rd Spring Annual Meeting of the Chemical Society of Japan, Shiga, Japan  2013.3 

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  • Transition Metal-Catalyzed Step-Growth and Living Radical Polymerizations for Tailored Polymeric Structures

    Kotaro Satoh, Masami Kamigaito

    3rd Federation of the Asian Polymer Scieties (FAPS) and MACRO 2013, Bangalore, India  2013.5 

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  • Controlled/Living Polymerization of Renewable Vinyl Monomers for Novel Functional Bio-Based Polymers Invited International conference

    Kotaro Satoh

    12th SPSJ International Polymer Conference (IPC2018), December 4-7, 2018, Hiroshima  2018.12 

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  • Precision Polymerization of Plant-Derived Vinyl Monomers for Novel Functional Bio-Based Polymers Invited

    Kotaro Satoh

    International Conference on Advanced and Applied Petroleum, Petrochemicals, and Polymers in 2018 (ICAPPP 2018), December 18-20, 2018, Bangkok  2018.12 

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  • 種々の桂皮酸化合物及びその誘導体の制御重合: バイオベース官能化ポリスチレンの合成 International conference

    佐藤浩太郎, 竹嶋久晶, 杉原 静, 上垣外正己

    第67回高分子討論会, 1Y13, 北海道大学、2018年9月12-14日,北海道  2018.9 

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    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：関西大学化学生命工学部  

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  • Plant-Derived Renewable Functional Vinyl Monomers for Novel Bio-Based Polymer Invited International conference

    Kotaro Satoh

    Polymer minisympo in Tsukuba, Tsukuba University, September 14, Tsukuba.  2018.9 

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  • 植物由来の脂環式炭化水素系ポリマーの合成 International conference

    佐藤浩太郎, 杉山紘子, 上垣外正己

    第55回高分子学会討論会、2006年9月20-22日、富山大学  2006.9 

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  • 水系でのカチオン重合とその制御 International conference

    佐藤浩太郎

    第16回 高分子学会茨城地区「若手の会」、2001年11月1-2日、茨城  2001.11  高分子学会茨城地区

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    Venue：いこいの村涸沼  

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  • 水に対して安定なルイス酸による水系でのカチオン重合 International conference

    佐藤浩太郎

    第109回東海高分子研究会、2004年9月3-4日、三重  2004.9  東海高分子研究会

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    Venue：プラージュ鈴鹿  

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  • Multiply-Controlled Topological Polymers by Combination of Controlled/Living Polymerizations Invited International conference

    Kotaro Satoh

    International Symposium Polymers meet Topology, January 30-February 1, 2019, Tokyo  2019.1 

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    Venue：Tokyo Institute of Technology  

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  • Well-defined 1:1 and 2:1 sequence-regulated copolymers bycontrolled radical copolymerization

    The 2010 International Chemical Congress of Pacific Basin Societies (Pacifichem), Honolulu, Hawaii, USA, December 15-20, 2010  2010.12 

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  • ラジカル精密重合による特異的な配列制御高分子の合成 International conference

    佐藤浩太郎

    高分子学会九州支部有機材料研究会  2011.3  高分子学会九州支部

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  • 植物由来テルペンのリビング重合によるキラル機能性高分子の合成 International conference

    佐藤浩太郎

    第1４回 VBLシンポジウム「キラルナノ化学・ソフトナノ化学、プロセスの新展開」  2010.11  名古屋大学ベンチャー・ビジネス・ラボラトリー

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  • Controlled radical (co)polymerization of renewable vinylmonomers for novel biobased polymers

    The 2010 International Chemical Congress of Pacific Basin Societies (Pacifichem), Honolulu, Hawaii, USA, December 15-20, 2010  2010.12 

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  • MECHANISTIC TRANSFORMATION BETWEEN RAFT AND LIVING CATIONIC POLYMERIZATION

    242nd American Chemical Society (ACS) National Meeting, Denver, CO, Aug.28-Sep.1  2011.8 

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  • Mechanistic Transformation of Active Species during Vinyl Polymerization

    14th Asian Chemical Congress, Sep.5-8, Bangkok  2011.9 

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  • 新規バイオベースポリマー創出に向けた植物由来モノマーの精密重合系の開発 International conference

    佐藤浩太郎

    バイオマス研究会 第18回研究会  2011.7  NPO法人近畿バイオインダストリー振興会議

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    Venue：大阪科学技術センター  

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  • CONTROLLED/LIVING POLYMERIZATIONS OF NATURALLY-OCCURRING TERPENES

    Establishment of Carbon-Cycle-System with Natural Rubber (ESCANBER) KICK-OFF SYMPOSIUM, Hanoi, Aug.2-4  2011.8 

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  • Transition Metal-Catalyzed Step-Growth Radical Polymerization for Sequence-Regulated Vinyl Polymers International conference

    Asian International Symposium at 91st Annual Meeting of the Chemical Society of Japan  2011.3 

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  • Design of Novel Synthetic Polymers via Metal-Catalyzed Step-Growth Radical Polymerization

    Annual Spring Meeting of Polymer Society of Korea, Daejon, Korea, Apr.7-8  2011.4 

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Awards

  • SPSJ Wiley Award 2015

    2015.9   The Society of Polymer Science, Japan  

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    Country：Japan

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  • SPSJ Asahi Kasei Award 2012

    2012.9   The Society of Polymer Science, Japan  

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    Country：Japan

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  • The Commendation for Science and Technology by the Minister of Education, Culture, Sports, Science and Technology: The Young Scientists' Prize

    2012.4   Ministry of Education, Culture, Sports, Science and Technology, Japan  

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    Country：Japan

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  • Tokai Chemical Industries Association Prize 2010

    2010.5   Tokai Chemical Industries Association  

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    Country：Japan

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  • Award for Encouragement of Research in Polymer Science

    2008.5   The Society of Polymer Science, Japan  

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    Country：Japan

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  • Award for Encouragement of Research of Materials Science(18th Symposium of Material Research Society of Japan)

    2008.1   MRS-J  

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    Country：Japan

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Research Projects

  • 先端電子顕微鏡と高分子化学の融合による高分子一本鎖の直接観察と解析

    Grant number：22H00329  2022.4 - 2025.3

    日本学術振興会  科学研究費助成事業  基盤研究(A)

    陣内 浩司, 早川 晃鏡, 佐藤 浩太郎, 千賀 亮典

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    Grant amount：\43160000 （ Direct Cost: \33200000 、 Indirect Cost：\9960000 ）

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  • 精密高分子分解を志向した高分子解析基盤

    Grant number：20H05732  2020.10 - 2023.3

    日本学術振興会  科学研究費助成事業  学術変革領域研究(B)

    沼田 圭司, 畝山 多加志, 佐藤 浩太郎, 酒井 崇匡

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    Grant amount：\5980000 （ Direct Cost: \4600000 、 Indirect Cost：\1380000 ）

    解析基盤として、相互利用および対外的に共有可能なプラットフォームを2年度目までに形成することを目標として掲げた。結果的には、初年度でほぼ共用利用可能な解析基盤を構築できた。「時空間効果の学理」に取り組むために必須である、SPring-8などの外部施設については、コロナの影響もあり、セットアップが初年度に間に合わなかったため、２年度目で整備を完了した。「均一・不均一構造の学理」では、非晶性や網目状高分子の分解挙動と、オレフィンなどの結晶性高分子の分解挙動を比較研究することを目指しており、各モデル高分子を決定し、領域内で共有することが重要であった。初年度において、結晶性および非晶性のモデル高分子を決定し、サンプルを各計画研究班に配布することに成功した。2年度目では、結晶性と非晶性のサンプルのデータが出てきており、順調に進展している。
    非公開のキックオフシンポジウムを開催するとともに、公開キックオフシンポジウムをアドバイザーの先生方とともに開催し、高分子精密分解についての現状と課題、そして将来的に必要とされる方向性を明らかにした。また、高分子精密分解について議論する場として、外部の著名な研究者を招いて隔月で学術変革セミナーを開催する体制を整えた。また、国際会議や国内学会において、シンポジウムを共催、開催することで周知と多様な意見を得ることができている。

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  • Precision design and time-scale analysis of polymer depolymerization and degradation under verious environment

    Grant number：20H05734  2020.10 - 2023.3

    Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research  Grant-in-Aid for Transformative Research Areas (B)

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    Grant amount：\41600000 （ Direct Cost: \32000000 、 Indirect Cost：\9600000 ）

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  • マルチ反応変換と組合せによる高分子の新規構造制御法の開発

    Grant number：19H00910  2019.4 - 2023.3

    日本学術振興会  科学研究費助成事業 基盤研究(A)  基盤研究(A)

    佐藤 浩太郎

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    Grant amount：\44720000 （ Direct Cost: \34400000 、 Indirect Cost：\10320000 ）

    本研究では、従来重合反応における副反応の抑制に用いられてきた生長末端の安定なドーマント種を、複数の刺激を用いて解離し複数のマルチアクティブ種へ可逆変換するとともに、クリック反応など他の反応系と組み合わせることで、異種反応を経由して高分子を形成する新規な高分子構造制御法を開発・確立することを目的とした。具体的には、生長末端に従来のリビング重合のドーマント種を異なる複数の刺激で可逆的に活性化もしくはアジド基などへ化学変換することで、同一のドーマント種から炭素カチオンやアニオン、ラジカル、金属配位といった異種の重合もしくはクリック反応へと系内で可逆的に変換させる全く新しい重合概念の確立を目指している。とくに、マルチアクティブ種や異種反応での可逆的成長を制御することで、自在に高分子を設計できる革新的高分子精密合成を可能とするとともに、得られる従来未開拓の高分子材料についてその性質を明らかにするために検討を行った。
    今年度は、リビングクリック重合の一般原理の確立及び適用範囲の拡大に注力して研究を行った。とくに、リビングクリック重合において、開始剤の効果を明らかにするとともに、種々のエステル型モノマー、特に長鎖スペーサーをもつモノマーへの適用可能性が示された。これにより従来のリビング重合とは異なり、繰り返し構造単位の分子鎖が長いモノマーの重合制御が可能であることが明らかになった。さらに、本重合系を糖鎖モノマーへの適用可能性も示され、さまざまな構造をもつ未開拓のポリマーの精密重合が期待された。以上のように、研究活動が大幅に制限されている中で、本研究は順調に進捗した。これらの一部の研究成果に対して海外での招待講演を含めて外部発表を行った。

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  • Innovative precision polymerization via photo-induced multi active species

    Grant number：18KK0158  2018.10 - 2022.3

    Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research Fund for the Promotion of Joint International Research (Fostering Joint International Research (B))  Fund for the Promotion of Joint International Research (Fostering Joint International Research (B))

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    Grant amount：\17940000 （ Direct Cost: \13800000 、 Indirect Cost：\4140000 ）

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  • Novel Bio-Based Polymers by Chemical Conversion of Carbohydrates

    Grant number：20K20402  2018.6 - 2021.3

    Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research  Grant-in-Aid for Challenging Research (Pioneering)

    Satoh Kotaro

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    Grant type：Competitive

    Grant amount：\25740000 （ Direct Cost: \19800000 、 Indirect Cost：\5940000 ）

    Focusing on chemical compounds derived from saccharides or related carbohydrates, which is one of the most abundant and cheapest biomass, we designed their chemical conversion reactions into vinyl monomers for novel high-performance bio-based polymers. Glycerol was converted to the corresponding vinyl carbonate and vinyl ether derivatives through a dehydration reaction, of which cationic or radical polymerization was carried out. In addition, tetrahydrofurfuryl alcohol produced by the hydrogenation reaction of furfural was employed to be converted into a monomer having a vinyl ether skeleton by a dehydration reaction.

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  • Sequence-Regulated Vinyl Polymers via Precision Radical Polymerization

    Grant number：15H02181  2015.4 - 2018.3

    Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research Grant-in-Aid for Scientific Research (A)  Grant-in-Aid for Scientific Research (A)

    Kamigaito Masami, SATOH Kotaro

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    Grant amount：\43290000 （ Direct Cost: \33300000 、 Indirect Cost：\9990000 ）

    This research was directed to monomer sequence control in synthetic polymers, which is one of the biggest challenges in polymer chemistry, by developing novel synthetic approaches for the synthesis of sequence-regulated vinyl polymers via radical chain-growth and step-growth polymerizations. In particular, we focused on developing sequence-selective radical chain-growth polymerizations as well as controlled polymerizations of sequence-regulated monomers embedded with vinyl monomer sequences and investigating the effects of monomer sequence in main- and side-chains on the properties of polymers.

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  • Novel Macromolecular Technology of Versatile Copolymerization System via Multiple Reactions

    2014.10 - 2018.3

    JST 

    Kotaro Satoh

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    Authorship：Principal investigator  Grant type：Competitive

    Grant amount：\39130000 （ Direct Cost: \30100000 、 Indirect Cost：\9030000 ）

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  • 連鎖および逐次ラジカル重合による金属含有特殊構造ポリマーの開発

    Grant number：25107714  2013.4 - 2015.3

    日本学術振興会  科学研究費助成事業 新学術領域研究(研究領域提案型)  新学術領域研究(研究領域提案型)

    佐藤 浩太郎

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    Grant type：Competitive

    Grant amount：\5980000 （ Direct Cost: \4600000 、 Indirect Cost：\1380000 ）

    AA-BB型の逐次重合を連鎖(リビング)ラジカル重合と組み合わせた同時重合系を開発し、配列周期的にさまざまな官能基や金属錯体が導入された特殊構造ポリマーの合成を検討した。とくに、温度応答性ポリマーを与えるNIPAMをモノマーとして用い、周期的に導入された官能基が温度応答性に与える影響について考察した。温度応答性は、一般に周期的に導入された疎水性基・親水性基によって変化するが、周期的にそれらを導入した場合、その個数よりもむしろ周期間隔が温度応答性に影響することなどを明らかとした。ここで、水酸基を配位子とすることで周期的に水に対して安定な有機チタン錯体を導入することにも成功した。
    さらに、より親水性の高いカルボン酸ナトリウム塩を周期的に導入した場合、50~70ユニットに一つしか金属塩が導入されていないにもかかわらず、相転移温度以上では凝集沈殿は生じず、直径が数十nm程度のミセル凝集体を形成することも明らかとした。このような現象は周期的官能化ポリマーのときにのみ特異的に観測され、ランダムポリマーや末端官能性ポリマーでは系全体で凝集し沈殿を生じた。このとき、凝集体の大きさは周期間隔にはほとんど影響しなかったが、導入するカルボン酸の主鎖からの距離により20nmから30nmまで変化した。
    また、カルボン酸塩とは別にアルコキシシリル基を周期的に導入することにも成功した。このようにして得られたポリマーに対して、シランカップリング反応を行なうことで、生成したミセル凝集体の構造を無機成分で固定化することで、温度に応答して膨潤・収縮を繰り返し行なうことのできる機能性微粒子も合成できることも明らかにした。

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  • Development of Novel Polymerization System

    Grant number：23685023  2011.4 - 2014.3

    Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research Grant-in-Aid for Young Scientists (A)  Grant-in-Aid for Young Scientists (A)

    SATOH Kotaro

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    Grant type：Competitive

    Grant amount：\29380000 （ Direct Cost: \22600000 、 Indirect Cost：\6780000 ）

    In the present study, we investigated concurrent mixed polymerizations by interconvertible intermediates via various covalent bond, such as C–S and C-X (X: halogen) bonds. By using C-S bond as the dormant species, we found that concurrent cationic and radical copolymerization prodeeded well in a living fashion to form multiblock-type copolymer consinsting of cationically-and radically-polymerized segments. Furthermore, we achieved that mechanistic transformation from anionic polymerization to radical one with C–X bond as the dormant species.

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  • リビングラジカル重合による金属含有特殊構造ポリマーの開発

    Grant number：23107515  2011.4 - 2013.3

    日本学術振興会  科学研究費助成事業 新学術領域研究(研究領域提案型)  新学術領域研究(研究領域提案型)

    佐藤 浩太郎

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    Grant type：Competitive

    Grant amount：\5980000 （ Direct Cost: \4600000 、 Indirect Cost：\1380000 ）

    本研究では、特殊構造ポリマーのセグメント中、周期的に安定な金属錯体や金属イオンなどを導入した融合マテリアルを創出すること目的として、リビングラジカル重合や配列制御重合などの精密重合を用いて、高分子鎖中に配列周期的に金属の導入された高分子の合成やこれまでにない周期配列構造を有する高分子の合成を検討した。
    １．金属触媒リビングラジカル重合による金属含有特殊構造ポリマーの開発 配位子を設計することで、前周期金属であるチタン原子を用いても、Titanatraneと呼ばれる対称性の高いチタン錯体がポリマー中に定量的に導入でき、水や大気中でも安定性の高い新規金属錯体含有ポリマーが得られることを明らかにした。リビングラジカル重合によるブロック共重合体などの構造が明確に制御された特殊構造ポリマーの合成と有機配位子への高効率変換反応を組み合わせることで、高分子鎖中のセグメント特異的、もしくは末端など位置特異的に金属原子が導入された材料設計が可能となった。
    その他、以下の点を明らかとした。 ２．連鎖／逐次ラジカル同時重合による周期配列特殊構造ポリマーの開発 ３．逐次ラジカル重合によるモノマー配列特殊構造ポリマーの開発
    ４．融合マテリアル創成に向けた配列特殊構造ポリマー合成法の開発（共同研究）

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  • Development of Novel Precision Polymerization Systems for Naturally Occurring Phenylpropanoids in Aqueous Media

    Grant number：19750091  2007 - 2008

    Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research Grant-in-Aid for Young Scientists (B)  Grant-in-Aid for Young Scientists (B)

    SATOH Kotaro

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    Grant amount：\3670000 （ Direct Cost: \3400000 、 Indirect Cost：\270000 ）

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  • 金属触媒による新しいラジカル重付加反応の開発と配列制御高分子の合成

    Grant number：18350061  2006 - 2007

    日本学術振興会  科学研究費助成事業 基盤研究(B)  基盤研究(B)

    上垣外 正己, 佐藤 浩太郎

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    Grant amount：\16930000 （ Direct Cost: \15700000 、 Indirect Cost：\1230000 ）

    本研究では、金属触媒による新しい重付加反応の開発とこれによる配列制御高分子の構築を目的としている。具体的には、遷移金属錯体によるリビングラジカル付加重合の概念を重付加反応へと展開することで、金属触媒による新しい重付加反応を開発・確立し、さらにモノマー設計を行うことにより、これまでにない交互共重合体、多元交互共重合体を合成し、新しい配列制御高分子の構築を行う。本年度は主に以下の成果を得た。
    1.遷移金属触媒による炭素-ハロゲン結合の活性化に基づくラジカル重付加反応の確立
    カルボニル基に隣接した炭素-塩素結合と非共役二重結合がエステル結合でつながれたモノマーの重付加反応が、鉄錯体[FeC1_2(PBu_3)_2]により効率よく進行し、比較的高分子量(M>3,000)のポリマーが生成した。とくにNMRにより反応系を解析することで、理想的な逐次反応機構により重付加反応が進行していることを明らかとした。
    2.ビニルモノマーからのモノマー設計に基づく定序配列高分子の合成
    スチレンを原料とし、ラジカル重付加反応により塩化ビニル-スチレン-アクリル酸エステルの三元交互共重合体と等価な骨格を与える一連のモノマーを設計、合成した。鉄や銅錯体により、これらモノマーの重付加反応が可能であったが、高分子量体のポリマーを得るにはさらにモノマー及び反応系の設計が必要であることがわかった。
    3.ジビニル化合物とジハロゲン化合物のラジカル重付加による多元配列制御高分子の合成
    それぞれ分子内に2つの二重結合をもつ化合物と2つの炭素-ハロゲン結合をもつ化合物間での重付加反応を行うことで、abac型やabbacc型の多元配列制御高分子の合成を検討した。ラジカル重付加反応は進行しほぼ目的の骨格を有するオリゴマーの合成が可能となった。

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  • Precision Controlled Radical Polymerization of Alkenes

    Grant number：17065008  2005 - 2008

    Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research Grant-in-Aid for Scientific Research on Priority Areas  Grant-in-Aid for Scientific Research on Priority Areas

    KAMIGAITO Masami, SATOH Kotaro, NISHIYAMA Hisao, ITO Jun-ichi, OKAMOTO Yoshio

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    Grant amount：\26900000 （ Direct Cost: \26900000 ）

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Teaching Experience

  • 化学生命工学部大学院特別講義

    Institution：関西大学

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  • 生命・応用化学特別講義Ⅳ

    Institution：名古屋工業大学

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  • 有機化学 IV

    Institution：名古屋大学

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  • 基礎セミナーＡ

    Institution：名古屋大学

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  • 有機高分子化学基礎論

    Institution：名古屋大学

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  • 基礎セミナーB

    Institution：名古屋大学

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  • 有機化学 III

    Institution：名古屋大学

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  • 有機化学演習第２

    Institution：名古屋大学

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  • 機能高分子化学特論

    Institution：名古屋大学

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  • 有機化学演習第１

    Institution：名古屋大学

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  • 応用有機化学基礎論

    Institution：名古屋大学

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  • 有機化学演習第一

    Institution：名古屋大学

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  • 工場見学

    Institution：名古屋大学

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  • 特別講義

    Institution：九州大学

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  • 化学特別講義「身の回りの高分子と有機化学」

    Institution：静岡大学

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  • バイオマス化学特別講義ＩＩ

    Institution：東京大学

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