Updated on 2025/09/30

写真a

 
tsukamoto takamasa
 
Organization
Institute of Integrated Research Laboratory for Chemistry and Life Science Visiting Associate Professor (Lecturer)
Title
Visiting Associate Professor (Lecturer)
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News & Topics

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Research Interests

  • 超周期表

  • Inorganic Nanosheets

  • Artificial Photosynthesis

  • Functional Dyes

  • Organic-Inorganic Hybrid Materials

  • Atom-Hybridization Method

  • Super-Periodic Table

  • Super-Degeneracy

Research Areas

  • Nanotechnology/Materials / Organic functional materials  / Supramolecular Chemistry

  • Natural Science / Semiconductors, optical properties of condensed matter and atomic physics  / Photochemistry

  • Nanotechnology/Materials / Inorganic compounds and inorganic materials chemistry  / Catalytic Chemistry

  • Nanotechnology/Materials / Inorganic/coordination chemistry  / Coordination Chemistry

  • Nanotechnology/Materials / Inorganic compounds and inorganic materials chemistry  / Cluster Chemistry

Education

  • Tokyo Metropolitan University   Department of Applied Chemistry, D. Sc. (accelerated graduation)

    2013.4 - 2015.3

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    Country: Japan

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  • Tokyo Metropolitan University   Department of Applied Chemistry, M. Sc.

    2011.4 - 2013.3

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    Country: Japan

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  • Tokyo Metropolitan University   Department of Applied Chemistry

    2007.4 - 2011.3

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    Country: Japan

    Notes: B. Sc.

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Research History

  • The University of Tokyo

    2024.11

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    Country:Japan

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  • Institute of Science Tokyo   Visiting Associate Professor (Lecturer)

    2024.10

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  • 国立研究開発法人 新エネルギー・産業技術総合開発機構   先導研究プログラム (未踏チャレンジ)   研究開発責任者

    2024.5

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    Country:Japan

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  • The University of Tokyo   The Graduate School of Engineering Department of Applied Chemistry

    2023.4

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    Country:Japan

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  • The University of Tokyo   Institute of Industrial Science (Department of Materials and Environmental Science)   Lecturer

    2023.4

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  • Tokyo Institute of Technology   Visiting Associate Professor (Lecturer)

    2023.4 - 2024.9

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  • Japan Science and Technology Agency   PRESTO Researcher

    2020.12

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  • Tokyo Institute of Technology   Institute of Innovative Research, Laboratory for Chemistry and Life Science   Assistant Professor

    2019.4 - 2023.3

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  • Tokyo Institute of Technology   Institute of Innovative Research, Hybrid Materials Unit   Project Assistant Professor

    2018.2 - 2019.3

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    Country:Japan

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  • Tokyo Institute of Technology   Institute of Innovative Research, Hybrid Materials Unit   Postdoctoral Researcher

    2016.4 - 2018.1

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    Country:Japan

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  • The University of Tokyo   Graduate School of Science Department of Chemistry   Doctoral Research Fellow

    2015.4 - 2016.3

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    Country:Japan

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  • Japan Society for the Promotion of Science   Research Fellow PD

    2015.4 - 2016.3

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    Country:Japan

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  • Japan Society for the Promotion of Science   Research Fellow DC2

    2014.4 - 2015.3

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    Country:Japan

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  • University of Miami   Department of Chemistry   Visiting Scholar

    2014.4 - 2014.7

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    Country:United States

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Professional Memberships

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Papers

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MISC

  • ナノ物質周期表と超縮退ナノ物質――金属クラスターが創る新たな科学領域 Invited

    塚本孝政

    化学と工業   74 ( 10 )   782 - 783   2021.10

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    Authorship:Lead author   Language:Japanese   Publishing type:Article, review, commentary, editorial, etc. (trade magazine, newspaper, online media)  

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  • 樹状高分子鋳型を利用した原子クラスターの精密合成と機能開拓 Invited

    塚本 孝政, 山元 公寿

    THE CHEMICAL TIMES   262 ( 4 )   2 - 7   2021.10

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    Authorship:Lead author   Language:Japanese   Publishing type:Article, review, commentary, editorial, etc. (trade magazine, newspaper, online media)  

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  • Precise Synthesis and Design Methods of Multimetallic Clusters Invited

    塚本 孝政, 山元 公寿

    Bulletin of Japan Society of Coordination Chemistry   76   53 - 56   2020.11

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    Authorship:Lead author   Language:Japanese   Publishing type:Article, review, commentary, editorial, etc. (trade magazine, newspaper, online media)  

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  • 新しい元素化学を拓くアトムハイブリッド Invited

    Takamasa Tsukamoto

    化学と工業   37   390 - 392   2020.5

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    Authorship:Lead author   Language:Japanese   Publishing type:Article, review, commentary, editorial, etc. (other)  

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  • 対称性に着目したモデルに基づいてナノ物質の周期律を発見 Invited

    Takamasa Tsukamoto

    Chem-Station   2019.12

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    Authorship:Lead author, Last author, Corresponding author   Language:Japanese   Publishing type:Article, review, commentary, editorial, etc. (trade magazine, newspaper, online media)  

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  • 「ナノ物質の周期表」の誕生 – 幾何学的対称性から生まれた新たな理論モデル Invited

    Takamasa Tsukamoto

    academist Journal   2019.10

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    Authorship:Lead author   Language:Japanese   Publishing type:Article, review, commentary, editorial, etc. (trade magazine, newspaper, online media)  

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  • 原子の対称性を超えるナノ物質を発見!? Invited

    Takamasa Tsukamoto

    academist Journal   2018

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    Language:Japanese   Publishing type:Article, review, commentary, editorial, etc. (trade magazine, newspaper, online media)  

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  • Atom hybridization of metallic elements: Emergence of subnano metallurgy for the post-nanotechnology

    Takane Imaoka, Akiyoshi Kuzume, Makoto Tanabe, Takamasa Tsukamoto, Tetsuya Kambe, Kimihisa Yamamoto

    COORDINATION CHEMISTRY REVIEWS   474   2023.1

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    Language:English   Publishing type:Book review, literature introduction, etc.  

    DOI: 10.1016/j.ccr.2022.214826

    Web of Science

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  • 金属元素を自由自在に混ぜる Invited

    Takamasa Tsukamoto

    現代化学   576   52 - 57   2019.3

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    Authorship:Lead author   Language:Japanese   Publishing type:Article, review, commentary, editorial, etc. (trade magazine, newspaper, online media)  

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  • ADSORPTION AND PHOTOCHEMICAL BEHAVIOR OF NOVEL CATIONIC Ga(III) PHTHALOCYANINE ON THE CLAY SURFACE

    HONNA RYOU, TSUKAMOTO TAKAMASA, SHIMADA TETSUYA, SHIRAGAMI TSUTOMU, TAKAGI SHINSUKE

    Clay science   19 ( 2 )   53 - 58   2015.6

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    Language:English   Publisher:The Clay Science Society of Japan  

    Novel cationic Ga(III)phthalocyanine (hydroxo[tetrakis(N,N,N-trimethylanilinium) phthalocyaninato] gallium(III), [Ga^<III>(TMAPc)(OH)]^<4+>) was synthesized and its adsorption and photochemical behavior on clay were investigated. Ga^<III>(TMAPc)(OH) adsorbed on the clay surface without an aggregation at high density conditions. The fluorescence quantum yield and excited lifetime of Ga^<III>(TMAPc)(OH)^<4+> on clay was 0.33 and 2.1 ns at 0.05% vs. CEC, respectively. Photo-oxygenation reaction sensitized by Ga^<III>(TMAPc)(OH)^<4+> on clay was examined. Cyclohexen-2-ol and 1,2-dichlorocyclohexane were obtained as major products. Because the Size-matching rule suppresses a molecular aggregation, Ga^<III>(TMAPc)(OH)^<4+> had photochemical activity on the clay surface.

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  • 金属錯体のナノシート化、光電変換効率向上とその期待される応用

    Takamasa Tsukamoto

    MATERIAL STAGE   15 ( 5 )   41 - 45   2015

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    Language:Japanese  

    CiNii Books

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  • Functional "Bottom-up" Metal Complex Nanosheets

    57 ( 6 )   362 - 367   2015

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    Language:Japanese  

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  • 粘土ナノシート/有機色素複合体の光化学特性とその応用 Invited

    Takamasa Tsukamoto

    無機マテリアル学会誌   2014

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    Authorship:Lead author   Language:Japanese   Publishing type:Article, review, commentary, editorial, etc. (other)  

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  • Photochemical Properties of Mono-, Tri-, and Penta-Cationic Antimony(V) Metalloporphyrin Derivatives on a Clay Layer Surface (vol 117, pg 7823, 2013)

    Takamasa Tsukamoto, Tetsuya Shimada, Shinsuke Takagi

    JOURNAL OF PHYSICAL CHEMISTRY A   117 ( 48 )   13037 - 13037   2013.12

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  • THE ADSORPTION BEHAVIOR OF PROTONATED CATIONIC PORPHYRIN ON THE CLAY SURFACE

    EGUCHI MIHARU, TSUKAMOTO TAKAMASA, OHTANI YUTA, SHIMADA TETSUYA, TAKAGI SHINSUKE

    Clay science   17 ( 2 )   31 - 33   2013.6

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    Language:English   Publisher:The Clay Science Society of Japan  

    The adsorption behavior of protonated species of 5,10-diphenyl-15,20-di(4-pyridyl)porphyrin (DPyP) on saponite clay surface was examined under PH=1 in aqueous solution. Beer's plot at Soret band and Q-band indicated that H_4DPyP^<4+> adsorbs on the clay surface without aggregation up to 15% and 100% versus CEC, respectively. The λ_<max> of Soret band slightly shifted to longer wavelength, as porphyrin loading level increased. These indicate that neutral molecule with pyridyl and pyrrole groups can adsorb on the clay surface under acidic conditions, although weak aggregation behavior was observed. The incomplete matching of inter-charge distances in porphyrin molecule and on the clay surface would be a reason for such aggregation behavior.

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  • 色素の光化学挙動におけるナノシートの効果 Invited

    Takamasa Tsukamoto

    日本化学会研究会「低次元系光機能材料研究会」ニュースレター   2013

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    Authorship:Lead author   Language:Japanese  

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Awards

  • 第13回 新化学技術研究奨励賞

    2024.6   新化学技術推進協会   メタンドライリフォーミング反応の低温駆動に向けた金属・合金クラスター触媒に関する研究

    塚本 孝政

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  • 令和6年度 文部科学大臣表彰 若手科学者賞

    2024.4   文部科学省   クラスター物質の新規合成技術および新規設計理論の研究

    塚本 孝政

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  • 第72回進歩賞

    2023.3   日本化学会   量子サイズ物質の新規合成技術の開発および新規設計理論の提唱

    塚本 孝政

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  • ATI研究奨励賞

    2022.5   新世代研究所   異種元素配合サブナノ粒子の物性・機能に関わる組成効果の解明

    塚本 孝政

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  • IIRウィーク優秀発表賞

    2021.8   東京工業大学   「ナノ物質の周期表」による次世代量子サイズ材料の設計

    塚本 孝政

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  • Nanoscale Horizons Award

    2021.5  

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  • 手島精一記念研究賞 若手研究賞

    2021.4   東京工業大学   対称適合軌道モデルの開発と「ナノ物質周期表」の提唱

    塚本 孝政

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  • 若い世代の特別講演会賞

    2021.3   日本化学会   アトムハイブリッド法と超周期表:量子サイズ物質の合成技術と設計理論の開発

    塚本 孝政

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  • 大隅良典基礎研究支援

    2020.1   東京工業大学   球を超える対称性を持つ「超縮退物質」の実験的実証

    塚本 孝政

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  • 学術振興基金賞

    2013.9   日本粘土学会  

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  • MIP (Most Impressive Presenter) 賞

    2013.3   首都大学東京  

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  • 優秀ポスター賞

    2011.9   日本化学会新領域研究グループ、低次元無機-有機複合系の光化学  

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Research Projects

  • 力学的対称性を発現する四面体型クラスター「超縮退物質」の実験実証

    Grant number:24K21707  2024.6 - 2027.3

    日本学術振興会  科学研究費助成事業  挑戦的研究(萌芽)

    塚本 孝政

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    Authorship:Principal investigator 

    Grant amount:\6500000 ( Direct Cost: \5000000 、 Indirect Cost:\1500000 )

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  • 安価に合成可能な原子クラスター材料の触媒展開に向けた研究開発

    2024.5 - 2027.3

    新エネルギー・産業技術総合開発機構  先導研究プログラム (未踏) 

    塚本 孝政

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  • サブナノ物質元素ライブラリの構築

    Grant number:22H01904  2022.4 - 2026.3

    日本学術振興会  科学研究費助成事業  基盤研究(B)

    塚本 孝政

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    Authorship:Principal investigator 

    Grant amount:\17420000 ( Direct Cost: \13400000 、 Indirect Cost:\4020000 )

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  • サブナノ物質元素ライブラリの構築

    Grant number:23K23172  2022.4 - 2026.3

    日本学術振興会  科学研究費助成事業  基盤研究(B)

    塚本 孝政

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    Grant amount:\17420000 ( Direct Cost: \13400000 、 Indirect Cost:\4020000 )

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  • 特異的原子配列が創るエキゾチッククラスターの開拓

    2020.12 - 2025.3

    科学技術振興機構  戦略的創造研究推進事業 さきがけ研究 (1年追加支援採択) 

    塚本 孝政

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  • 球を超える対称性を持つ「超縮退物質」の実験的実証

    2020.1 - 2020.12

    大隅良典記念基金  大隅良典基礎研究支援 

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  • 異種元素配合サブナノ粒子の物性・機能に関わる組成効果の解明

    2019.10 - 2020.9

    新世代研究所  ATI研究助成 

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    Authorship:Principal investigator 

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  • Creation of cell-like nanomaterials based on dendrimer and development of concerted functions of their assembly

    Grant number:19K15583  2019.4 - 2021.3

    Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research Grant-in-Aid for Early-Career Scientists  Grant-in-Aid for Early-Career Scientists

    Tsukamoto Takamasa

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    Grant amount:\4290000 ( Direct Cost: \3300000 、 Indirect Cost:\990000 )

    In this study, by using a 4th generation dendrimer with multiple Lewis basic imine units as a host material, multimetallic multinuclear complexes accumulating various Lewis acidic metal salts as guest materials were utilized as a model of "cell-type nanomaterial". The basicity of imines was designed to be stronger for inner imines in the dendrimer molecule, and the acidity of metal salts was modified by controlling oxidation number or counter anions. As a result, multiple metal elements were co-accumulated and formed multimetallic multinuclear complexes with various types of conformations such as normal, inverted, nested, and inverted-nested types in the dendrimer. In conclusion, a new technique for self-assemling and organizing a desired guest molecule at a desired position in a host material has been developed successfully.

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  • 光捕集機能を有するナノシート型人工光合成系の構築

    Grant number:14J03441  2014.4 - 2016.3

    日本学術振興会  科学研究費助成事業 特別研究員奨励費  特別研究員奨励費

    塚本 孝政

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    Grant amount:\2170000 ( Direct Cost: \1900000 、 Indirect Cost:\270000 )

    アニオン性の粘土ナノシートをホスト、独自に開発したカチオン性の光捕集色素と光触媒色素をゲスト分子として、光捕集機能を有するナノシート型光物質変換系の構築を行った。この光捕集色素と光触媒色素を共吸着させ、吸着量・吸着比の制御により、最大で100%のエネルギー移動効率を達成した。この色素-ナノシート複合体を用いて光触媒性能を検討した。光捕集色素を選択的光励起した際の反応活性の比較検討により、両者が共存した系でのみ光触媒反応が進行した。これにより光捕集機能を付与した光物質変換系の構築に成功した。またこの系においては特異的に光捕集色素が効率100%の活性種メディエータとなり、光触媒色素を保護・分解抑制する新たな機能も発現した。結果、光捕集と光物質変換の両機能を合わせ持った『次世代型人工光合成系』の構築を達成した。
    一方新たなアプローチでのナノシート型人工光合成系の構築を目指し、発光性金属錯体ナノシートの開発を行った。3叉テルピリジン配位子と亜鉛イオンを用い、有機-水の液液界面において新規亜鉛-テルピリジンナノシートの合成に成功した。このナノシートは発光性能を有し、青色発光を示した。計算によりナノシートの発光は分子内電荷移動(ICT)遷移に由来することが示された。そこで配位子の構造改変によるICTの制御を試みた。配位子の骨格を高電子密度のものに変更した結果ナノシートは橙色発光を示し、光化学性能の制御に成功した。更にテルピリジン錯体ユニットのカチオン性に着目し、アニオン性色素ゲスト導入によるナノシートへの光化学性能の付与を試みた。キサンテン色素溶液へのナノシート浸漬により色素ゲストの導入に成功した。このナノシート中では、シートからゲストへのエネルギー移動が起こり、エネルギー移動効率は90%以上に達した。このようにゲスト導入によるナノシートへの光捕集能の付与に成功した。

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