Updated on 2026/04/14

写真a

 
HARA MICHIKAZU
 
Organization
Institute of Integrated Research Materials and Structures Laboratory Professor
Title
Professor
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News & Topics

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Degree

  • Doctor of Science ( Tokyo Institute of Technology, Interdisciplinary Graduate School of Science and Engineering )

Research Areas

  • Manufacturing Technology (Mechanical Engineering, Electrical and Electronic Engineering, Chemical Engineering) / Catalyst and resource chemical process

Education

  • Tokyo Institute of Technology

    - 1992

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    Country: Japan

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  • Tokyo Institute of Technology   Graduate School, Division of Integrated Science

    - 1992

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  • Tokyo University of Science

    - 1987

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    Country: Japan

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Research History

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Professional Memberships

Committee Memberships

  • 触媒学会   討論会委員  

    2001   

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    Committee type:Academic society

    触媒学会

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Papers

  • Promotional Effect of Mn On NH3 Synthesis Over Inverse Iron Catalyst

    Yuan Jing, Masashi Hattori, Michikazu Hara

    ChemSusChem   2026.3

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/cssc.202502235

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  • Special Issue Commemorating the Establishment of Institute of Science Tokyo

    Naoto Ohtake, Hiroyuki Kagechika, Michikazu Hara, Masato Sone, Tso-Fu Mark Chang

    ACS Applied Nano Materials   2025.12

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acsanm.5c05322

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  • Topochemical Synthesis and Photocatalytic Activity of Layered K2LaTa2O6N Using CsLaTa2O7 Precursor Prepared by Flux Method

    Hideya Tsuchikado, Yuki Kinoshita, Masashi Hattori, Megumi Okazaki, Takuto Soma, Fumitaka Ishiwari, Michikazu Hara, Akinori Saeki, Kazuhiko Maeda

    Inorganic Chemistry   2025.12

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.inorgchem.5c04858

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  • Significant Enhancement of the Basicity of SrTiO3 Nanoparticles by Alkali Metal Doping: Implication for the Knoevenagel Condensation

    Takeshi Aihara, Wataru Aoki, Satoshi Ishikawa, Soungmin Bae, Shin Kiyohara, Yu Kumagai, Michikazu Hara, Keigo Kamata

    ACS Applied Nano Materials   2025.8

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acsanm.5c02688

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  • Mesoporous Oxyhalide Aggregates Exhibiting Improved Photocatalytic Activity for Visible-Light H2 Evolution and CO2 Reduction

    Hiroto Ueki, Toshiya Tanaka, Shuji Anabuki, Ryuichi Nakada, Megumi Okazaki, Kenta Aihara, Masashi Hattori, Fumitaka Ishiwari, Rie Haruki, Shunsuke Nozawa, Toshiyuki Yokoi, Michikazu Hara, Osamu Ishitani, Akinori Saeki, Akira Yamakata, Kazuhiko Maeda

    ACS Catalysis   15 ( 14 )   12551 - 12562   2025.7

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    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/acscatal.5c02229

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  • Effects of Metal-Cation Doping on Photocatalytic H2 Evolution Activity of Layered Perovskite Oxynitride K2LaTa2O6N

    Hideya Tsuchikado, Shuji Anabuki, Ovidiu Cretu, Yuki Kinoshita, Masashi Hattori, Yuta Shiroma, Dongxiao Fan, Megumi Okazaki, Takuto Soma, Fumitaka Ishiwari, Shunsuke Nozawa, Toshiyuki Yokoi, Michikazu Hara, Koji Kimoto, Akira Yamakata, Akinori Saeki, Kazuhiko Maeda

    ACS Applied Energy Materials   8 ( 6 )   3541 - 3552   2025.3

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    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/acsaem.4c03131

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  • Ammonia Synthesis Over an Iron Catalyst with an Inverse Structure Reviewed International journal

    Masashi Hattori, Kento Miyashita, Yuki Nagasawa, Ryo Suzuki, Michikazu Hara

    Advanced Science   12   2025.1

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    Authorship:Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/advs.202410313

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  • Selective Synthesis of Amines by Heterogeneous Co Catalysts via Borrowing Hydrogen Protocols Reviewed International journal

    Endah Suarsih, Yusuke Kita, Keigo Kamata, Michikazu Hara

    Organic Letters   27   2025.1

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    Authorship:Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.orglett.4c04633

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  • La<inf>1-x</inf>Sr<inf>x</inf>FeO<inf>3−δ</inf> Perovskite Oxide Nanoparticles for Low-Temperature Aerobic Oxidation of Isobutane to tert-Butyl Alcohol Reviewed International journal

    Masanao Yamamoto, Takeshi Aihara, Keiju Wachi, Michikazu Hara, Keigo Kamata

    ACS Applied Materials and Interfaces   16 ( 45 )   62244 - 62253   2024.11

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    Authorship:Last author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acsami.4c15585

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  • Green ammonia production via recycle membrane reactor: Experiment and process simulation Reviewed International journal

    Kotaro Wakimoto, Wei Wei Yan, Masashi Hattori, Michikazu Hara, Norihiro Moriyama, Hiroki Nagasawa, Masakoto Kanezashi, Toshinori Tsuru

    Chemical Engineering Journal   496   2024.9

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    Authorship:Last author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/j.cej.2024.153754

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  • Tuning the Selectivity of Catalytic Nitrile Hydrogenation with Phase-Controlled Co Nanoparticles Prepared by Hydrosilane-Assisted Method Reviewed International journal

    He Jiang, Dian Deng, Yusuke Kita, Masashi Hattori, Keigo Kamata, Michikazu Hara

    Journal of the American Chemical Society   146 ( 30 )   20919 - 20929   2024.7

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    Authorship:Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/jacs.4c04780

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  • Copper Phosphate Nanostructures as Catalysts for the Direct Methane Oxidation Reviewed International journal

    Aoi Matsuda, Takeshi Aihara, Shin Kiyohara, Yu Kumagai, Michikazu Hara, Keigo Kamata

    ACS Applied Nano Materials   7 ( 9 )   10155 - 10167   2024.5

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    Authorship:Last author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acsanm.4c00549

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  • Acid and base catalysis of SrTiO3 nanoparticles for C–C bond-forming reactions

    Takeshi Aihara, Wataru Aoki, Michikazu Hara, Keigo Kamata

    Catalysis Today   428   114448 - 114448   2024.2

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    Publishing type:Research paper (scientific journal)   Publisher:Elsevier BV  

    DOI: 10.1016/j.cattod.2023.114448

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  • Supported Fe catalysts prepared through layered double hydroxides for primary amine synthesis by reductive amination of carbonyl compounds

    Yusuke Kita, Natsuki Yanagisawa, Mayu Arai, Keigo Kamata, Michikazu Hara

    Catalysis Science & Technology   14 ( 18 )   5430 - 5438   2024

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/D4CY00536H

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  • Air-Stable Ni Catalysts Prepared by Liquid-Phase Reduction Using Hydrosilanes for Reactions with Hydrogen

    Yusuke Kita, Kahoko Kato, Shun Takeuchi, Takaaki Oyoshi, Keigo Kamata, Michikazu Hara

    ACS Applied Materials and Interfaces   15 ( 48 )   55659 - 55668   2023.12

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acsami.3c11487

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  • A Career in Catalysis: Kazunari Domen

    Akihiko Kudo, Yoshihisa Sakata, Junko N. Kondo, Michikazu Hara, Jun Kubota, Shigeru Ikeda, Tsuyoshi Takata, Ryu Abe, Atsushi Takagaki, Takashi Hisatomi

    ACS Catalysis   13 ( 10 )   6934 - 6955   2023.5

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    Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/acscatal.3c00951

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  • Low-Temperature Ammonia Synthesis on Iron Catalyst with an Electron Donor

    Masashi Hattori, Natsuo Okuyama, Hiyori Kurosawa, Michikazu Hara

    Journal of the American Chemical Society   145 ( 14 )   7888 - 7897   2023.4

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/jacs.2c13015

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  • Nanosized Ti-Based Perovskite Oxides as Acid–Base Bifunctional Catalysts for Cyanosilylation of Carbonyl Compounds

    Takeshi Aihara, Wataru Aoki, Shin Kiyohara, Yu Kumagai, Keigo Kamata, Michikazu Hara

    ACS Applied Materials &amp; Interfaces   15 ( 14 )   17957 - 17968   2023.4

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    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/acsami.3c01629

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  • Bismuth phosphate nanoparticle catalyst for direct oxidation of methane into formaldehyde

    Aoi Matsuda, Kazuhiko Obara, Atsushi Ishikawa, Meng-Hsuan Tsai, Chia-Hsin Wang, Yu-Chuan Lin, Michikazu Hara, Keigo Kamata

    Catalysis Science & Technology   13 ( 18 )   5180 - 5189   2023

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/D3CY00590A

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  • N-Rich, Polyphenolic Porous Organic Polymer and Its In Vitro Anticancer Activity on Colorectal Cancer

    Sabuj Kanti Das, Snehasis Mishra, Krishna Das Saha, Debraj Chandra, Michikazu Hara, Amany A. Mostafa, Asim Bhaumik

    Molecules   27 ( 21 )   7326 - 7326   2022.10

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    Publishing type:Research paper (scientific journal)   Publisher:MDPI AG  

    DOI: 10.3390/molecules27217326

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  • Stability Enhancement of Iron-based Perovskite Catalysts by A-site Substitution for Oxidative Transposition of α-Bromostyrene to Phenacyl Bromide

    Satomi Shibata, Keigo Kamata, Michikazu Hara

    ChemCatChem   14 ( 18 )   2022.9

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/cctc.202200395

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  • Heterogeneous Low-Valent Mn Catalysts for α-Alkylation of Ketones with Alcohols through Borrowing Hydrogen Methodology Reviewed

    Yusuke Kita, Midori Kuwabara, Keigo Kamata, Michikazu Hara

    ACS Catalysis   12 ( 19 )   11767 - 11775   2022.9

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acscatal.2c03085

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  • β-MnO<inf>2</inf> nanoparticles as heterogenous catalysts for aerobic oxidative transformation of alcohols to carbonyl compounds, nitriles, and amides

    Keigo Kamata, Nanami Kinoshita, Maki Koutani, Ryusei Aono, Eri Hayashi, Michikazu Hara

    Catalysis Science and Technology   12 ( 20 )   6219 - 6230   2022.9

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/d2cy01476a

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  • Synthesis and Aerobic Oxidation Catalysis of Mesoporous Todorokite-Type Manganese Oxide Nanoparticles by Crystallization of Precursors

    Maki Koutani, Eri Hayashi, Keigo Kamata, Michikazu Hara

    Journal of the American Chemical Society   144 ( 31 )   14090 - 14100   2022.8

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/jacs.2c02308

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  • Selective CO2 reduction to methane catalyzed by mesoporous Ru-Fe3O4/CeOx-SiO2 in a fixed bed flow reactor

    Shyamal Roy, Dilip Kumar Mondal, Sauvik Chatterjee, Avik Chowdhury, Tuhin Suvra Khan, M. Ali Haider, Subhash Mandal, Debraj Chandra, Michikazu Hara, Asim Bhaumik

    Molecular Catalysis   528   112486 - 112486   2022.8

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    Publishing type:Research paper (scientific journal)   Publisher:Elsevier BV  

    DOI: 10.1016/j.mcat.2022.112486

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  • Iron to catalyze ammonia synthesis at low temperature

    Michikazu Hara, Masashi Hattori, Natsuo Okuyama, Hiyori Kurosawa

    2022.6

  • A heterogeneous cobalt catalyst for C-C bond formation by a borrowing hydrogen strategy

    Endah Suarsih, Yusuke Kita, Keigo Kamata, Michikazu Hara

    CATALYSIS SCIENCE & TECHNOLOGY   12 ( 13 )   4113 - 4117   2022.5

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/d2cy00724j

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  • Iron to catalyze ammonia synthesis at low temperature

    Michikazu Hara, Masashi Hattori, Natsuo Okuyama, Hiyori Kurosawa

    2022.4

  • Base-Assisted Aerobic C–H Oxidation of Alkylarenes with a Murdochite-Type Oxide Mg6MnO8 Nanoparticle Catalyst

    Eri Hayashi, Takatoshi Tamura, Takeshi Aihara, Keigo Kamata, Michikazu Hara

    ACS Applied Materials &amp; Interfaces   14 ( 5 )   6528 - 6537   2022.2

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    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/acsami.1c20080

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  • Synergistic Effects of Earth-Abundant Metal–Metal Oxide Enable Reductive Amination of Carbonyls at 50 °C

    Manas K. Bhunia, Debraj Chandra, Hitoshi Abe, Yasuhiro Niwa, Michikazu Hara

    ACS Applied Materials and Interfaces   14 ( 3 )   4144 - 4154   2022.1

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acsami.1c21157

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  • Primary amine synthesis by hydrogen-involving reactions over heterogeneous cobalt catalysts

    Kahoko Kato, Dian Deng, Yusuke Kita, Keigo Kamata, Michikazu Hara

    Catalysis Science &amp; Technology   2022

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    Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry (RSC)  

    DOI: 10.1039/d2cy00870j

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  • Preparation of zeolitic bismuth vanadomolybdate using a ball-shaped giant polyoxometalate for olefin epoxidation

    Zhenxin Zhang, Denan Li, Qianqian Zhu, Michikazu Hara, Yanshuo Li, Wataru Ueda

    New Journal of Chemistry   45 ( 46 )   21624 - 21630   2021.12

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/d1nj04019g

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  • Novel Tetradentate Phosphonate Ligand Based Bioinspired Co-Metal–Organic Frameworks: Robust Electrocatalyst for the Hydrogen Evolution Reaction in Different Mediums

    Debabrata Chakraborty, Avik Chowdhury, Moumita Chandra, Rajkumar Jana, Sanjib Shyamal, Manas K. Bhunia, Debraj Chandra, Michikazu Hara, Debabrata Pradhan, Ayan Datta, Asim Bhaumik

    Crystal Growth & Design   21 ( 5 )   2614 - 2623   2021.5

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    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society ({ACS})  

    DOI: 10.1021/acs.cgd.0c01275

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  • CCDC 1922964: Experimental Crystal Structure Determination

    Chakraborty, Debabrata, Chowdhury, Avik, Chandra, Moumita, Jana, Rajkumar, Shyamal, Sanjib, Bhunia, Manas K, Chandra, Debraj, Hara, Michikazu, Pradhan, Debabrata, Datta, Ayan, Bhaumik, Asim

    Cambridge Structural Database   2021

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.5517/CCDC.CSD.CC22K03S

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  • Optical Properties of Chiral Azo-Schiff Base Mn(II) and Zn(II) Complexes with Silver Nanoparticles

    Kazuya Saiga, Tomoyuki Haraguchi, Yasutaka Kitahama, Takuya Hosokai, Hiroyuki Matsuzaki, Dohyun Moon, Mutsumi Sugiyama, Michikazu Hara, Takashiro Akitsu

    Journal of Materials Science and Chemical Engineering   09 ( 04 )   1 - 10   2021

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    Publishing type:Research paper (scientific journal)   Publisher:Scientific Research Publishing, Inc.  

    DOI: 10.4236/msce.2021.94001

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  • Iron phosphate nanoparticle catalyst for direct oxidation of methane into formaldehyde: effect of surface redox and acid–base properties

    Aoi Matsuda, Haruka Tateno, Keigo Kamata, Michikazu Hara

    Catalysis Science & Technology   11 ( 21 )   6987 - 6998   2021

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    Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry ({RSC})  

    DOI: 10.1039/D1CY01265G

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  • Sulfur-containing nitrogen-rich robust hierarchically porous organic polymer for adsorptive removal of mercury: experimental and theoretical insights

    Avik Chowdhury, Sabuj Kanti Das, Saptarsi Mondal, Santu Ruidas, Debabrata Chakraborty, Sauvik Chatterjee, Manas K. Bhunia, Debraj Chandra, Michikazu Hara, Asim Bhaumik

    Environmental Science: Nano   8 ( 9 )   2641 - 2649   2021

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    Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry ({RSC})  

    DOI: 10.1039/D1EN00448D

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  • Aerobic oxidative CC bond cleavage of aromatic alkenes by a high valency iron-containing perovskite catalyst

    Satomi Shibata, Keigo Kamata, Michikazu Hara

    Catalysis Science & Technology   11 ( 7 )   2369 - 2373   2021

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    Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry ({RSC})  

    DOI: 10.1039/D1CY00245G

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  • Solid solution for catalytic ammonia synthesis from nitrogen and hydrogen gases at 50 °C

    Masashi Hattori, Shinya Iijima, Takuya Nakao, Hideo Hosono, Michikazu Hara

    Nature Communications   11 ( 1 )   2020.12

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1038/s41467-020-15868-8

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  • Electronic Effect in a Ruthenium Catalyst Designed in Nanoporous N-Functionalized Carbon for Efficient Hydrogenation of Heteroarenes

    Debraj Chandra, Shikha Saini, Saswata Bhattacharya, Asim Bhaumik, Keigo Kamata, Michikazu Hara

    ACS Applied Materials & Interfaces   12 ( 47 )   52668 - 52677   2020.11

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    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society ({ACS})  

    DOI: 10.1021/acsami.0c15407

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  • Effects of ruthenium hydride species on primary amine synthesis by direct amination of alcohols over a heterogeneous Ru catalyst

    Yusuke Kita, Midori Kuwabara, Satoshi Yamadera, Keigo Kamata, Michikazu Hara

    Chemical Science   11 ( 36 )   9884 - 9890   2020.9

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/d0sc03858j

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  • One-pot reductive amination of carbonyl compounds with nitro compounds over a Ni/NiO composite

    Yusuke Kita, Sayaka Kai, Lesandre Binti Supriadi Rustad, Keigo Kamata, Michikazu Hara

    RSC Advances   10 ( 54 )   32296 - 32300   2020.9

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/d0ra06937j

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  • Template-Free Synthesis of Mesoporous β-MnO<inf>2</inf> Nanoparticles: Structure, Formation Mechanism, and Catalytic Properties

    Yui Yamaguchi, Ryusei Aono, Eri Hayashi, Keigo Kamata, Michikazu Hara

    ACS applied materials &amp; interfaces   12 ( 32 )   36004 - 36013   2020.8

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acsami.0c08043

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  • Folic acid-conjugated magnetic mesoporous silica nanoparticles loaded with quercetin: A theranostic approach for cancer management

    Snehasis Mishra, Krishnendu Manna, Utpal Kayal, Moumita Saha, Sauvik Chatterjee, Debraj Chandra, Michikazu Hara, Sriparna Datta, Asim Bhaumik, Krishna Das Saha

    RSC Advances   10 ( 39 )   23148 - 23164   2020.6

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/d0ra00664e

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  • Ti(IV)-containing aluminophosphate material TAPO-25 for photoelectrochemical water oxidation

    Sauvik Chatterjee, Sanjib Shyamal, Debraj Chandra, Michikazu Hara, Asim Bhaumik

    Molecular Catalysis   486   2020.5

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/j.mcat.2020.110876

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  • Tin oxide-coated transition metal oxide molecular wires for biomass conversion

    Zhenxin Zhang, Haruka Tateno, Michikazu Hara, Wataru Ueda

    New Journal of Chemistry   44 ( 13 )   5147 - 5151   2020.4

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/d0nj00400f

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  • One-pot aerobic oxidative sulfonamidation of aromatic thiols with ammonia by a dual-functional β-MnO<inf>2</inf> nanocatalyst

    Eri Hayashi, Yui Yamaguchi, Yusuke Kita, Keigo Kamata, Michikazu Hara

    Chemical Communications   56 ( 14 )   2095 - 2098   2020.2

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/c9cc09411c

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  • Correction: Effect of MnO<inf>2</inf> Crystal Structure on Aerobic Oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid (Journal of the American Chemical Society (2019) 141 (890-900) DOI: 10.1021/jacs.8b09917) Reviewed

    Eri Hayashi, Yui Yamaguchi, Keigo Kamata, Naoki Tsunoda, Yu Kumagai, Fumiyasu Oba, Michikazu Hara

    Journal of the American Chemical Society   141 ( 46 )   18642 - 18642   2019.11

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    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society ({ACS})  

    DOI: 10.1021/jacs.9b11588

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  • Intramolecular Electron Transfer and Oxygen Transfer of Phosphomolybdate Molecular Wires

    Zhenxin Zhang, Masahiro Sadakane, Michikazu Hara, Yanshuo Li, Wataru Ueda

    Inorganic Chemistry   58 ( 18 )   12272 - 12279   2019.9

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.inorgchem.9b01744

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  • Redox-Active Zeolitic Transition Metal Oxides Based on Îμ -Keggin Units for Selective Oxidation Reviewed

    Zhenxin Zhang, Satoshi Ishikawa, Qianqian Zhu, Toru Murayama, Masahiro Sadakane, Michikazu Hara, Wataru Ueda

    Inorganic Chemistry   58 ( 9 )   6283 - 6293   2019.5

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.inorgchem.9b00502

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  • Low-Temperature Reductive Amination of Carbonyl Compounds over Ru Deposited on Nb <inf>2</inf> O <inf>5</inf> · nH <inf>2</inf> O Reviewed

    Dian Deng, Yusuke Kita, Keigo Kamata, Michikazu Hara

    ACS Sustainable Chemistry and Engineering   7 ( 5 )   4692 - 4698   2019.3

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    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society ({ACS})  

    DOI: 10.1021/acssuschemeng.8b04324

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  • Direct Activation of Cobalt Catalyst by 12CaO·7Al <inf>2</inf> O <inf>3</inf> Electride for Ammonia Synthesis Reviewed

    Yasunori Inoue, Masaaki Kitano, Mai Tokunari, Teppei Taniguchi, Kayato Ooya, Hitoshi Abe, Yasuhiro Niwa, Masato Sasase, Michikazu Hara, Hideo Hosono

    ACS Catalysis   9 ( 3 )   1670 - 1679   2019.3

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    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society ({ACS})  

    DOI: 10.1021/acscatal.8b03650

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  • Effect of MnO<inf>2</inf> Crystal Structure on Aerobic Oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid Reviewed

    Eri Hayashi, Yui Yamaguchi, Keigo Kamata, Naoki Tsunoda, Yu Kumagai, Fumiyasu Oba, Michikazu Hara

    Journal of the American Chemical Society   141 ( 2 )   899 - 900   2019.1

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    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society ({ACS})  

    DOI: 10.1021/jacs.8b09917

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  • Ag nanoparticle-decorated, ordered mesoporous silica as an efficient electrocatalyst for alkaline water oxidation reaction Reviewed

    Utpal Kayal, Bishnupad Mohanty, Piyali Bhanja, Sauvik Chatterjee, Debraj Chandra, Michikazu Hara, Bikash Kumar Jena, Asim Bhaumik

    Dalton Transactions   48 ( 6 )   2220 - 2227   2019

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/c8dt04159h

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  • Ag nanoparticle-decorated, ordered mesoporous silica as an efficient electrocatalyst for alkaline water oxidation reaction Reviewed

    Utpal Kayal, Bishnupad Mohanty, Piyali Bhanja, Sauvik Chatterjee, Debraj Chandra, Michikazu Hara, Bikash Kumar Jena, Asim Bhaumik

    Dalton Transactions   48 ( 6 )   2220 - 2227   2019

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    <p>Ag NPs were decorated on the surface of a functionalized SBA-15 material and the resulting AgNPs@SBA-NH2 material showed excellent OER activity for electrochemical water oxidation under alkaline pH.</p>

    DOI: 10.1039/C8DT04159H

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  • Ambient-temperature oxidative coupling of methane in an electric field by a cerium phosphate nanorod catalyst Reviewed

    Ayaka Sato, Shuhei Ogo, Keigo Kamata, Yuna Takeno, Tomohiro Yabe, Tomokazu Yamamoto, Syo Matsumura, Michikazu Hara, Yasushi Sekine

    Chemical Communications   55 ( 28 )   4019 - 4022   2019

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    DOI: 10.1039/c9cc00174c

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  • Enhanced Catalytic Ammonia Synthesis with Transformed BaO Reviewed

    Masashi Hattori, Taiyo Mori, Tomohiro Arai, Yasunori Inoue, Masato Sasase, Tomofumi Tada, Masaaki Kitano, Toshiharu Yokoyama, Michikazu Hara, Hideo Hosono

    ACS Catalysis   8 ( 12 )   10977 - 10984   2018.12

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    DOI: 10.1021/acscatal.8b02839

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  • A zeolitic vanadotungstate family with structural diversity and ultrahigh porosity for catalysis

    Zhenxin Zhang, Qianqian Zhu, Masahiro Sadakane, Toru Murayama, Norihito Hiyoshi, Akira Yamamoto, Shinichi Hata, Hisao Yoshida, Satoshi Ishikawa, Michikazu Hara, Wataru Ueda

    Nature Communications   9 ( 1 )   2018.12

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    DOI: 10.1038/s41467-018-06274-2

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  • Control of nitrogen activation ability by Co-Mo bimetallic nanoparticle catalysts prepared via sodium naphthalenide-reduction Reviewed

    Yuki Tsuji, Kiya Ogasawara, Masaaki Kitano, Kazuhisa Kishida, Hitoshi Abe, Yasuhiro Niwa, Toshiharu Yokoyama, Michikazu Hara, Hideo Hosono

    Journal of Catalysis   364   31 - 39   2018.8

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    DOI: 10.1016/j.jcat.2018.04.029

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  • Heterogeneously Catalyzed Aerobic Oxidation of Sulfides with a BaRuO<inf>3</inf> Nanoperovskite Reviewed

    Keigo Kamata, Kosei Sugahara, Yuuki Kato, Satoshi Muratsugu, Yu Kumagai, Fumiyasu Oba, Michikazu Hara

    ACS Applied Materials and Interfaces   10 ( 28 )   23792 - 23801   2018.7

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    DOI: 10.1021/acsami.8b05343

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  • Large Oblate Hemispheroidal Ruthenium Particles Supported on Calcium Amide as Efficient Catalysts for Ammonia Decomposition Reviewed

    Kazuhisa Kishida, Masaaki Kitano, Yasunori Inoue, Masato Sasase, Takuya Nakao, Tomofumi Tada, Hitoshi Abe, Yasuhiro Niwa, Toshiharu Yokoyama, Michikazu Hara, Hideo Hosono

    Chemistry - A European Journal   24 ( 31 )   7976 - 7984   2018.6

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    DOI: 10.1002/chem.201800467

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  • Self-organized Ruthenium–Barium Core–Shell Nanoparticles on a Mesoporous Calcium Amide Matrix for Efficient Low-Temperature Ammonia Synthesis Reviewed

    Masaaki Kitano, Yasunori Inoue, Masato Sasase, Kazuhisa Kishida, Yasukazu Kobayashi, Kohei Nishiyama, Tomofumi Tada, Shigeki Kawamura, Toshiharu Yokoyama, Michikazu Hara, Hideo Hosono

    Angewandte Chemie - International Edition   57 ( 10 )   2648 - 2652   2018.3

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    DOI: 10.1002/anie.201712398

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  • Photo-control of adsorption of dye metal complexes incorporating chiral schiff base ligands containing Azo-groups on TiO<inf>2</inf>

    Shinnosuke Tanaka, Hiroki Sato, Yota Ishida, Yanyang Deng, Tomoyuki Haraguchi, Takashiro Akitsu, Mutsumi Sugiyama, Michikazu Hara, Dohyun Moon

    Journal of the Korean Chemical Society   62 ( 4 )   328 - 332   2018

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    DOI: 10.5012/jkcs.2018.62.4.328

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  • Liquid-phase oxidation of alkanes with molecular oxygen catalyzed by high valent iron-based perovskite Reviewed

    Satomi Shibata, Kosei Sugahara, Keigo Kamata, Michikazu Hara

    Chemical Communications   54 ( 50 )   6772 - 6775   2018

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    DOI: 10.1039/c8cc02185f

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  • Ultrathin Anionic Tungstophosphite Molecular Wire with Tunable Hydrophilicity and Catalytic Activity for Selective Epoxidation in Organic Media

    Zhenxin Zhang, Masahiro Sadakane, Michikazu Hara, Wataru Ueda

    Chemistry - A European Journal   23 ( 69 )   17397 - 17503   2017.12

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    DOI: 10.1002/chem.201704762

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  • Structural Characterization of 2D Zirconomolybdate by Atomic Scale HAADF-STEM and XANES and Its Highly Stable Electrochemical Properties as a Li Battery Cathode

    Qianqian Zhu, Zhenxin Zhang, Masahiro Sadakane, Futoshi Matsumoto, Norihito Hiyoshi, Akira Yamamoto, Hisao Yoshida, Akihiro Yoshida, Michikazu Hara, Wataru Ueda

    Inorganic Chemistry   56 ( 22 )   14306 - 14314   2017.11

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    DOI: 10.1021/acs.inorgchem.7b02420

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  • Synthesis and structural characterization of new [CuII-TiO<inf>2</inf>] composites from CuII-salen as precursors

    Minoru Matsuno, Shabana Noor, Takashi Numata, Tomoyuki Haraguchi, Takashiro Akitsu, Michikazu Hara

    Journal of the Indian Chemical Society   94 ( 10 )   1089 - 1098   2017.10

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  • Anchoring Bond between Ru and N Atoms of Ru/Ca<inf>2</inf>NH Catalyst: Crucial for the High Ammonia Synthesis Activity Reviewed

    Hitoshi Abe, Yasuhiro Niwa, Masaaki Kitano, Yasunori Inoue, Masato Sasase, Takuya Nakao, Tomofumi Tada, Toshiharu Yokoyama, Michikazu Hara, Hideo Hosono

    Journal of Physical Chemistry C   121 ( 38 )   20900 - 20904   2017.9

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    DOI: 10.1021/acs.jpcc.7b07268

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  • Electronic Effect of Ruthenium Nanoparticles on Efficient Reductive Amination of Carbonyl Compounds Reviewed

    Tasuku Komanoya, Takashi Kinemura, Yusuke Kita, Keigo Kamata, Michikazu Hara

    Journal of the American Chemical Society   139 ( 33 )   11493 - 11499   2017.8

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    DOI: 10.1021/jacs.7b04481

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  • Ru-Loaded C12A7:e- Electride as a Catalyst for Ammonia Synthesis Reviewed

    Michikazu Hara, Masaaki Kitano, Hideo Hosono

    ACS Catalysis   7 ( 4 )   2313 - 2324   2017.4

  • Back Cover: Heterogeneously‐Catalyzed Aerobic Oxidation of 5‐Hydroxymethylfurfural to 2,5‐Furandicarboxylic Acid with MnO2 (ChemSusChem 4/2017) Reviewed

    Eri Hayashi, Tasuku Komanoya, Keigo Kamata, Michikazu Hara

    ChemSusChem   10 ( 4 )   815   2017.2

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    DOI: 10.1002/cssc.201700221

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  • The Assembly of an All-Inorganic Porous Soft Framework from Metal Oxide Molecular Nanowires

    Zhenxin Zhang, Masahiro Sadakane, Shin Ichiro Noro, Norihito Hiyoshi, Akihiro Yoshida, Michikazu Hara, Wataru Ueda

    Chemistry - A European Journal   23 ( 8 )   1972 - 1980   2017

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    DOI: 10.1002/chem.201605258

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  • Synthesis of crystalline molybdenum oxides based on a 1D molecular structure and their ion-exchange properties Reviewed

    Qianqian Zhu, Zhenxin Zhang, Masahiro Sadakane, Akihiro Yoshida, Michikazu Hara, Wataru Ueda

    New Journal of Chemistry   41 ( 11 )   4503 - 4509   2017

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    DOI: 10.1039/c7nj00334j

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  • Oxidation number estimation of Ca in Ca-N compounds from Ca K-edge XANES spectra Reviewed

    Hitoshi Abe, Yasuhiro Niwa, Masaaki Kitano, Yasunori Inoue, Toshiharu Yokoyama, Michikazu Hara, Hideo Hosono

    Bulletin of the Chemical Society of Japan   90 ( 8 )   963 - 965   2017

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    DOI: 10.1246/bcsj.20170143

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  • A bifunctional cerium phosphate catalyst for chemoselective acetalization Reviewed

    Shunsuke Kanai, Ippei Nagahara, Yusuke Kita, Keigo Kamata, Michikazu Hara

    Chemical Science   8 ( 4 )   3146 - 3153   2017

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    DOI: 10.1039/c6sc05642c

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  • Photoassist-phosphorylated TiO<inf>2</inf> as a catalyst for direct formation of 5-(hydroxymethyl)furfural from glucose Reviewed

    Masashi Hattori, Keigo Kamata, Michikazu Hara

    Physical Chemistry Chemical Physics   19 ( 5 )   3688 - 3693   2017

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    DOI: 10.1039/c6cp06864b

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  • Heterogeneously-Catalyzed Aerobic Oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid with MnO<inf>2</inf> Reviewed

    Eri Hayashi, Tasuku Komanoya, Keigo Kamata, Michikazu Hara

    ChemSusChem   10 ( 4 )   654 - 658   2017

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    DOI: 10.1002/cssc.201601443

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  • Acid properties of protonated titanate nanotubes Reviewed

    Masaaki Kitano, Hisayoshi Kobayashi, Shigenobu Hayashi, Michikazu Hara

    Journal of the Japan Petroleum Institute   60 ( 3 )   113 - 120   2017

  • Nanoscale optical imaging of lithium-ion distribution on a LiCoO2 cathode surface

    Michikazu Hara

    Applied Physics Express   2017

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    DOI: 10.7567/APEX.10.052503

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  • Formation and Structural Changes of 4-Fluorobenzenethiol Self-Assembled Monolayers on Au(111)

    Michikazu Hara

    Journal of Nanoscience and Nanotechnology   2017

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    DOI: 10.1166/JNN.2017.14162

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  • Fungus-derived hydroxyl radicals kill hepatic cells by enhancing nuclear transglutaminase

    Michikazu Hara

    Scientific Reports   2017

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    DOI: 10.1038/S41598-017-04630-8

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  • Raman Imaging Analysis of Local Crystal Structures in LiCoO2 Thin Films Calcined at Different Temperatures

    Michikazu Hara

    Analytical Sciences   2017

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    DOI: 10.2116/ANALSCI.33.853

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  • Standing-Up Phase of Hexanedithiol Self-Assembled Monolayers on Au(111) Induced by Displacement Reaction

    Michikazu Hara

    Journal of Nanoscience and Nanotechnology   2017

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    DOI: 10.1166/JNN.2017.14163

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  • Efficient and Stable Ammonia Synthesis by Self-Organized Flat Ru Nanoparticles on Calcium Amide Reviewed

    Yasunori Inoue, Masaaki Kitano, Kazuhisa Kishida, Hitoshi Abe, Yasuhiro Niwa, Masato Sasase, Yusuke Fujita, Hiroki Ishikawa, Toshiharu Yokoyama, Michikazu Hara, Hideo Hosono

    ACS Catalysis   6 ( 11 )   7577 - 7584   2016.11

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    DOI: 10.1021/acscatal.6b01940

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  • Dioxygen Activation by a Hexagonal SrMnO<inf>3</inf> Perovskite Catalyst for Aerobic Liquid-Phase Oxidation Reviewed

    Shuma Kawasaki, Keigo Kamata, Michikazu Hara

    ChemCatChem   8 ( 20 )   3247 - 3253   2016.10

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    DOI: 10.1002/cctc.201600613

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  • Back Cover: Dioxygen Activation by a Hexagonal SrMnO3 Perovskite Catalyst for Aerobic Liquid-Phase Oxidation (ChemCatChem 20/2016) Reviewed

    Shuma Kawasaki, Keigo Kamata, Michikazu Hara

    ChemCatChem   8 ( 20 )   3302   2016.10

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    DOI: 10.1002/cctc.201601227

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  • ChemInform Abstract: Synthesis of Vanadium-Incorporated, Polyoxometalate-Based Open Frameworks and Their Applications for Cathode-Active Materials. Reviewed

    Zhenxin Zhang, Hirofumi Yoshikawa, Zhongyue Zhang, Toru Murayama, Masahiro Sadakane, Yasunori Inoue, Wataru Ueda, Kunio Awaga, Michikazu Hara

    ChemInform   47 ( 21 )   2016.5

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    DOI: 10.1002/chin.201621017

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  • High Oxidation Tolerance of Ru Nanoparticles on 12CaO·7Al<inf>2</inf>O<inf>3</inf> Electride Reviewed

    Hitoshi Abe, Yasuhiro Niwa, Masaaki Kitano, Yasunori Inoue, Youichi Murakami, Toshiharu Yokoyama, Michikazu Hara, Hideo Hosono

    Journal of Physical Chemistry C   120 ( 16 )   8711 - 8716   2016.4

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    DOI: 10.1021/acs.jpcc.6b00983

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  • A Combined Catalyst of Pt Nanoparticles and TiO<inf>2</inf> with Water-Tolerant Lewis Acid Sites for One-Pot Conversion of Glycerol to Lactic Acid Reviewed

    Tasuku Komanoya, Ayaka Suzuki, Kiyotaka Nakajima, Masaaki Kitano, Keigo Kamata, Michikazu Hara

    ChemCatChem   8 ( 6 )   1094 - 1099   2016.3

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    DOI: 10.1002/cctc.201501197

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  • Synthesis of Vanadium-Incorporated, Polyoxometalate-Based Open Frameworks and Their Applications for Cathode-Active Materials Reviewed

    Zhenxin Zhang, Hirofumi Yoshikawa, Zhongyue Zhang, Toru Murayama, Masahiro Sadakane, Yasunori Inoue, Wataru Ueda, Kunio Awaga, Michikazu Hara

    European Journal of Inorganic Chemistry   2016 ( 8 )   1242 - 1250   2016.3

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    DOI: 10.1002/ejic.201501396

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  • ChemInform Abstract: Recent Progress in the Development of Solid Catalysts for Biomass Conversion into High Value-Added Chemicals Reviewed

    Michikazu Hara, Kiyotaka Nakajima, Keigo Kamata

    ChemInform   47 ( 9 )   no   2016.2

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    DOI: 10.1002/chin.201609248

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  • Essential role of hydride ion in ruthenium-based ammonia synthesis catalysts (vol 7, pg 4036, 2016) Reviewed

    Kitano, M., Inoue, Y., Ishikawa, H., Yamagata, K., Nakao, T., Tada, T., Matsuishi, S., Yokoyama, T., Hara, M., Hosono, H.

    Chemical Science   7 ( 8 )   5596 - 5596   2016

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    DOI: 10.1039/c6sc90039a

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  • Acidic Ultrafine Tungsten Oxide Molecular Wires for Cellulosic Biomass Conversion

    Zhenxin Zhang, Masahiro Sadakane, Norihito Hiyoshi, Akihiro Yoshida, Michikazu Hara, Wataru Ueda

    Angewandte Chemie - International Edition   55 ( 35 )   10234 - 10238   2016

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    DOI: 10.1002/anie.201602770

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  • Ammonia synthesis over Co-Mo alloy nanoparticle catalyst prepared via sodium naphthalenide-driven reduction Reviewed

    Yuki Tsuji, Masaaki Kitano, Kazuhisa Kishida, Masato Sasase, Toshiharu Yokoyama, Michikazu Hara, Hideo Hosono

    Chemical Communications   52 ( 100 )   14369 - 14372   2016

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    DOI: 10.1039/c6cc08566k

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  • Synthesis of niobium-doped titanate nanotubes as solid acid catalysts Reviewed

    Emiko Wada, Masaaki Kitano, Kazuto Yamamoto, Kiyotaka Nakajima, Shigenobu Hayashi, Michikazu Hara

    Catalysis Science and Technology   6 ( 13 )   4832 - 4839   2016

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    DOI: 10.1039/c6cy00044d

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  • Essential role of hydride ion in ruthenium-based ammonia synthesis catalysts Reviewed

    Masaaki Kitano, Yasunori Inoue, Hiroki Ishikawa, Kyosuke Yamagata, Takuya Nakao, Tomofumi Tada, Satoru Matsuishi, Toshiharu Yokoyama, Michikazu Hara, Hideo Hosono

    Chemical Science   7 ( 7 )   4036 - 4043   2016

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    DOI: 10.1039/c6sc00767h

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    Other Link: http://orcid.org/0000-0003-3093-3779

  • Transesterification of Triolein over Hydrophobic Microporous Carbon with SO<inf>3</inf>H Groups Reviewed

    Kiichi Fukuhara, Kiyotaka Nakajima, Masaaki Kitano, Shigenobu Hayashi, Michikazu Hara

    ChemCatChem   7 ( 23 )   3945 - 3950   2015.12

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    DOI: 10.1002/cctc.201500525

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  • Synergistic Catalysis by Lewis Acid and Base Sites on ZrO<inf>2</inf> for Meerwein-Ponndorf-Verley Reduction Reviewed

    Tasuku Komanoya, Kiyotaka Nakajima, Masaaki Kitano, Michikazu Hara

    Journal of Physical Chemistry C   119 ( 47 )   26540 - 26546   2015.11

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    DOI: 10.1021/acs.jpcc.5b08355

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  • Mechanism Switching of Ammonia Synthesis Over Ru-Loaded Electride Catalyst at Metal-Insulator Transition Reviewed

    Shinji Kanbara, Masaaki Kitano, Yasunori Inoue, Toshiharu Yokoyama, Michikazu Hara, Hideo Hosono

    Journal of the American Chemical Society   137 ( 45 )   14517 - 14524   2015.11

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  • Formation of 5-(Hydroxymethyl)furfural by Stepwise Dehydration over TiO<inf>2</inf> with Water-Tolerant Lewis Acid Sites Reviewed

    Ryouhei Noma, Kiyotaka Nakajima, Keigo Kamata, Masaaki Kitano, Shigenobu Hayashi, Michikazu Hara

    Journal of Physical Chemistry C   119 ( 30 )   17117 - 17125   2015.7

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    DOI: 10.1021/acs.jpcc.5b03290

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  • Recent progress in the development of solid catalysts for biomass conversion into high value-added chemicals Invited Reviewed

    Michikazu Hara, Kiyotaka Nakajima, Keigo Kamata

    Science and Technology of Advanced Materials   16 ( 3 )   034903   2015.6

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  • Electron donation enhanced CO oxidation over Ru-loaded 12cao·7Al<inf>2</inf>O<inf>3</inf> electride catalyst Reviewed

    Md Jafar Sharif, Masaaki Kitano, Yasunori Inoue, Yasuhiro Niwa, Hitoshi Abe, Toshiharu Yokoyama, Michikazu Hara, Hideo Hosono

    Journal of Physical Chemistry C   119 ( 21 )   11725 - 11731   2015.5

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    DOI: 10.1021/acs.jpcc.5b02342

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  • 液中レーザーアブレーションによるシリコンナノ粒子の作製と評価 Reviewed

    林 和平, Chewchinda, 井上泰徳, 原亨和, 小田原 修, 和田裕之

    2015.3

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  • Electride support boosts nitrogen dissociation over ruthenium catalyst and shifts the bottleneck in ammonia synthesis Reviewed

    Masaaki Kitano, Shinji Kanbara, Yasunori Inoue, Navaratnarajah Kuganathan, Peter V. Sushko, Toshiharu Yokoyama, Michikazu Hara, Hideo Hosono

    Nature Communications   6   2015.3

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  • Efficient Mukaiyama aldol reaction in water with TiO<inf>4</inf> tetrahedra on a hydrophobic mesoporous silica surface Reviewed

    Hiroshi Shintaku, Kiyotaka Nakajima, Masaaki Kitano, Michikazu Hara

    Chemical Communications   50 ( 88 )   13473 - 13476   2014.10

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    DOI: 10.1039/c4cc05711b

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  • Selective glucose transformation by titania as a heterogeneous Lewis acid catalyst Reviewed

    Kiyotaka Nakajima, Ryouhei Noma, Masaaki Kitano, Michikazu Hara

    Journal of Molecular Catalysis A: Chemical   388-389   100 - 105   2014.7

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    DOI: 10.1016/j.molcata.2013.09.012

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  • Slow reactant-water exchange and high catalytic performance of water-tolerant Lewis acids Reviewed

    Yusuke Koito, Kiyotaka Nakajima, Hisayoshi Kobayashi, Ryota Hasegawa, Masaaki Kitano, Michikazu Hara

    Chemistry - A European Journal   20 ( 26 )   8068 - 8075   2014.6

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    DOI: 10.1002/chem.201400240

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  • Lewis acid properties of some metal salts for lactic acid formation in water: 31P NMR spectroscopy with trimethylphosphine oxide as a molecular probe Reviewed

    Yusuke Koito, Kiyotaka Nakajima, Ryota Hasegawa, Hisayoshi Kobayashi, Masaaki Kitano, Michikazu Hara

    Catalysis Today   226   198 - 203   2014.5

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    DOI: 10.1016/j.cattod.2013.10.071

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  • Surface treatment for conductive 12 CaO7 Al<inf>2</inf>O<inf>3</inf> electride powder by rapid thermal annealing processing and its application to ammonia synthesis Reviewed

    Fumitaka Hayashi, Masaaki Kitano, Toshiharu Yokoyama, Michikazu Hara, Hideo Hosono

    ChemCatChem   6 ( 5 )   1317 - 1323   2014.5

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    DOI: 10.1002/cctc.201301061

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  • Lewis acid catalysis of TiO<inf>4</inf> tetrahedra on mesoporous silica in water Reviewed

    Hiroshi Shintaku, Kiyotaka Nakajima, Masaaki Kitano, Nobuyuki Ichikuni, Michikazu Hara

    ACS Catalysis   4 ( 4 )   1198 - 1204   2014.4

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    DOI: 10.1021/cs401149n

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  • Highly dispersed ru on electride [Ca<inf>24</inf>Al<inf>28</inf>O <inf>64</inf>]4+(e-)<inf>4</inf> as a catalyst for ammonia synthesis Reviewed

    Yasunori Inoue, Masaaki Kitano, Sung Wng Kim, Toshiharu Yokoyama, Michikazu Hara, Hideo Hosono

    ACS Catalysis   4 ( 2 )   674 - 680   2014.2

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    DOI: 10.1021/cs401044a

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  • Photovoltaic properties of Si-based quantum-dot-sensitized solar cells prepared using laser plasma in liquid Reviewed

    Hiroki Kobayashi, Pattarin Chewchinda, Yasunori Inoue, Hiroshi Funakubo, Michikazu Hara, Masaie Fujino, Osamu Odawara, Hiroyuki Wada

    Japanese Journal of Applied Physics   53 ( 1 )   010208   2014.1

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  • Systematical investigation on characteristics of a photocatalyst: Tantalum oxynitrides Reviewed

    Daling Lu, Junko Nomura Kondo, Michikazu Hara, Tsuyoshi Takata, Kazunari Domen

    Microscopy   63 ( 4 )   313 - 324   2014

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  • Photocatalytic activities of Cu<inf>3x</inf>La<inf>1-x</inf>Ta <inf>7</inf>O<inf>19</inf> solid solutions for H<inf>2</inf> evolution under visible light irradiation Reviewed

    Hideki Kato, Arisa Takeda, Makoto Kobayashi, Michikazu Hara, Masato Kakihana

    Catalysis Science and Technology   3 ( 12 )   3147 - 3154   2013.12

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    DOI: 10.1039/c3cy00557g

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  • Effect of preparation conditions on the structural and acid catalytic properties of protonated titanate nanotubes Reviewed

    Emiko Wada, Masaaki Kitano, Kiyotaka Nakajima, Michikazu Hara

    Journal of Materials Chemistry A   1 ( 41 )   12768 - 12774   2013.11

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    DOI: 10.1039/c3ta13015k

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  • Titania as an early transition metal oxide with a high density of lewis acid sites workable in water Reviewed

    Kiyotaka Nakajima, Ryouhei Noma, Masaaki Kitano, Michikazu Hara

    Journal of Physical Chemistry C   117 ( 31 )   16028 - 16033   2013.8

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    DOI: 10.1021/jp404523r

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  • 液中レーザーアブレーションにより得られたシリコンナノ粒子の太陽電池への応用 Reviewed

    林 和平, Chewchinda Pattarin, 原 亨和, 小田原 修, 和田 裕之

    p. 3, 33   2013.8

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  • Ammonia decomposition by ruthenium nanoparticles loaded on inorganic electride C12A7:e- Reviewed

    Fumitaka Hayashi, Yoshitake Toda, Yoshimi Kanie, Masaaki Kitano, Yasunori Inoue, Toshiharu Yokoyama, Michikazu Hara, Hideo Hosono

    Chemical Science   4 ( 8 )   3124 - 3130   2013.8

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    DOI: 10.1039/c3sc50794g

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  • Optical Properties of YAG:Ce Nanoparticles Prepared by Laser Ablation in Water Reviewed

    Noriyuki Tsuruoka, Takao Katagiri, Yasunori Inoue, Takao Sasagawa, Michikazu Hara, Osamu Odawara, Hiroyuki Wada

    Proceedings of the 6th International Congress on Laser Advanced Materials Processing   2013.7

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  • Preparation and Characterization of YAG:Ce Nanoparticles by Laser Ablation in Liquid Reviewed

    Noriyuki Tsuruoka, Takao Katagiri, Yasunori Inoue, Takao Sasagawa, Michikazu Hara, Osamu Odawara, Hiroyuki Wada

    2013.7

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  • Fabrication of SrTiO<inf>3</inf> exposing characteristic facets using molten salt flux and improvement of photocatalytic activity for water splitting Reviewed

    Hideki Kato, Makoto Kobayashi, Michikazu Hara, Masato Kakihana

    Catalysis Science and Technology   3 ( 7 )   1733 - 1738   2013.7

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    DOI: 10.1039/c3cy00014a

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  • Synthesis and acid catalysis of zeolite-templated microporous carbons with SO<inf>3</inf>H groups Reviewed

    Kiichi Fukuhara, Kiyotaka Nakajima, Masaaki Kitano, Shigenobu Hayashi, Michikazu Hara

    Physical Chemistry Chemical Physics   15 ( 23 )   9343 - 9350   2013.6

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    DOI: 10.1039/c3cp43853h

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  • Transformation of cellulosic biomass into high-value-added chemicals for polymers

    Michikazu Hara

    Kobunshi   62 ( 4 )   191 - 196   2013.4

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  • Control of valence band potential and photocatalytic properties of Na <inf>x</inf>La<inf>1-x</inf>TaO<inf>1+2x</inf>N<inf>2-2x</inf> oxynitride solid solutions Reviewed

    Koichiro Ueda, Hideki Kato, Makoto Kobayashi, Michikazu Hara, Masato Kakihana

    Journal of Materials Chemistry A   1 ( 11 )   3667 - 3674   2013.3

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    DOI: 10.1039/c3ta10257b

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  • Protonated titanate nanotubes with Lewis and Brønsted acidity: Relationship between nanotube structure and catalytic activity Reviewed

    Masaaki Kitano, Emiko Wada, Kiyotaka Nakajima, Shigenobu Hayashi, Souichi Miyazaki, Hisayoshi Kobayashi, Michikazu Hara

    Chemistry of Materials   25 ( 3 )   385 - 393   2013.2

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  • Kinetic Study of Glucose Production from Cellobiose through Hydrolysis with Solid Acid Catalyst

    KITANO Makoto, SATO Kenji, Kentaro NARIAI, KANEKO Norimitsu, HARA Michikazu

    Journal of the Fuel Society of Japan   92 ( 7 )   675 - 681   2013

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    Kinetic study of glucose production from cellobiose through hydrolysis has been performed to compare reaction characteristics by using reaction models with β-glucosidase (Trichoderma reesei) and with graphenebased amorphous solid acid catalyst (SAC). The decrease of cellobiose concentration through hydrolysis with β-glucosidase is inhibited by present glucose as reported, resulting in unreacted cellobiose remained for a long time. In contrast cellobiose concentration decreased with SAC obeying 1st reaction rate model, showing relatively rapid reaction rate without such inhibition observed in hydrolysis with β-glucosidase. By using the plug flow reactor with a SAC packing column, an attempt of catalytic aging experiment was carried out about over 4,000 h, succeeding in construction of the 1st order reaction rate model.

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  • 液中レーザーアブレーション法を用いて作製したYAG:Ceナノ蛍光体の光学特性 Reviewed

    鶴岡仙之, 井上泰徳, 淀徳男, 原亨和, 小田原修, 和田裕之

    2013

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  • Solid acid catalysis of Ta-doped titanate nanotubes

    Kitano Masaaki, Morita Ikki, Yamamoto Kazuto, Nakajima Kiyotaka, Hara Michikazu

    Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute   2013   12 - 12   2013

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    DOI: 10.11523/sekiyu.2013.0_12

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  • Lewis acid catalysis of mesoporous titanosilicate in water

    Nakajima Kiyotaka, Shintaku Hiroshi, Kitano Masaaki, Ichikuni Nobuyuki, Hara Michikazu

    Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute   2013   23 - 23   2013

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    DOI: 10.11523/sekiyu.2013.0.23.0

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  • Efficient conversion of pyruvic aldehyde into lactic acid by lewis acid catalyst in water Reviewed

    Yusuke Koito, Kiyotaka Nakajima, Masaaki Kitano, Michikazu Hara

    Chemistry Letters   42 ( 8 )   873 - 875   2013

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    DOI: 10.1246/cl.130319

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  • MoO<inf>3</inf>/ZrO<inf>2</inf> as a stable, reusable, and highly active solid acid catalyst for polyester polyol synthesis Reviewed

    Hironobu Oki, Tsuyoshi Morita, Kiyotaka Nakajima, Michikazu Hara

    Chemistry Letters   42 ( 10 )   1314 - 1316   2013

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    DOI: 10.1246/cl.130635

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  • Electrical properties of amorphous carbon semiconductor prepared using a naphthalene precursor Reviewed

    Yasunori Inoue, Mayo Sugano, Shunsuke Kawakami, Masaaki Kitano, Kiyotaka Nakajima, Hideki Kato, Michikazu Hara

    Bulletin of the Chemical Society of Japan   86 ( 1 )   45 - 50   2013

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    DOI: 10.1246/bcsj.20120201

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  • Ammonia synthesis using a stable electride as an electron donor and reversible hydrogen store Reviewed

    Masaaki Kitano, Yasunori Inoue, Youhei Yamazaki, Fumitaka Hayashi, Shinji Kanbara, Satoru Matsuishi, Toshiharu Yokoyama, Sung Wng Kim, Michikazu Hara, Hideo Hosono

    Nature Chemistry   4 ( 11 )   934 - 940   2012.11

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    DOI: 10.1038/nchem.1476

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  • Sp3-Linked amorphous carbon with sulfonic acid groups as a heterogeneous acid catalyst Reviewed

    Satoshi Suganuma, Kiyotaka Nakajima, Masaaki Kitano, Shigenobu Hayashi, Michikazu Hara

    ChemSusChem   5 ( 9 )   1841 - 1846   2012.9

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    DOI: 10.1002/cssc.201200010

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  • Amorphous carbon with SO<inf>3</inf>H groups as a solid brønsted acid catalyst Reviewed

    Kiyotaka Nakajima, Michikazu Hara

    ACS Catalysis   2 ( 7 )   1296 - 1304   2012.7

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    DOI: 10.1021/cs300103k

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  • Preparation of porous spherical ZrO <inf>2</inf>-SiO <inf>2</inf> composite particles using templating and its solid acidity by H <inf>2</inf>SO <inf>4</inf> treatment Reviewed

    Shuhei Uchiyama, Toshihiro Isobe, Sachiko Matsushita, Kiyotaka Nakajima, Michikazu Hara, Akira Nakajima

    Journal of Materials Science   47 ( 1 )   341 - 349   2012.1

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  • O-203 A new saccharification process of biomass using hydrothcrmal prctrcatmcnt & Carbon-based solid acid catalyst reaction

    Nariai Kentaro, Kaneko Norimitsu, Sato Kenji, Kitano Makoto, Hara Michikazu

    Proceedings of the Conference on Biomass Science   7   18 - 19   2012

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    Carbon-based solid acid catalyst (SAC) is useful material to hydrolyze biomass into monosaccharides for replacing H_2SO_4. To increase the reactivity of biomass & SAC, combined process of hydrothermal (HT) pretreatment & SAC reaction was studied. The oligosaccharides produced by HT pretreatment were easy to hydrolyze into mono-saccharides with SAC. And with changing the HT temperatures, cellulose fraction and from hemicellulose fraction were separated easily. We found new saccharification process of biomass using SAC combined with HT pretreatment.

    DOI: 10.20550/jiebiomassronbun.7.0_18

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  • Production of lactic acid from triose aqueous solution over solid Lewis acid catalysts

    Nakajima Kiyotaka, Kitano Masaaki, Hara Michikazu

    Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute   2012   8 - 8   2012

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    H3PO4-treated titania was found to be effective solid acid catalyst for converting 1,3-dihydroxyacetone (triose sugar) into lactic acid in water. The reaction consists of dehydration of 1,3-dihydroxyacetone into pyruvaldehyde, followed by hydride shift of pyruvaldehyde into lactic acid. Homogeneous and Heterogeneous Br&oslash;nsted acids including H3PO4 mainly produced pyruvaldehyde, indicating that Br&oslash;nsted acids are not active for hydride shift of pyruvaldehyde into lactic acid. FT-IR measurement using pyridine as a basic molecular probe revealed that H3PO4-treated titania has not Br&oslash;nsted acid sites but water-tolerant Lewis acid sites on the surface. High catalytic performance of titania catalyst is therefore attributed to water tolerant Lewis acid sites that proceed effectively on both dehydration and hydride shift reactions.

    DOI: 10.11523/sekiyu.2012.0_8

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  • Solid acid catalysis of protonated titanate nanotubes

    Kitano Masaaki, Nakajima Kiyotaka, Miyazaki Souichi, Kobayashi Hisayoshi, Hayashi Shigenobu, Hara Michikazu

    Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute   2012   89 - 89   2012

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  • Lewis acidity of titania catalyst in water

    Nakajima Kiyotaka, Noma Ryohei, Kitano Masaaki, Hara Michikazu

    Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute   2012   118 - 118   2012

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    H3PO4-treated titania was found to be effective solid acid catalyst for converting 1,3-dihydroxyacetone (triose sugar) into lactic acid and xylose into furfural in water.&nbsp; FT-IR measurement using pyridine as a basic molecular probe revealed that H3PO4-treated titania has not Br&oslash;nsted acid sites but water-tolerant Lewis acid sites on the surface. High catalytic performance of titania catalyst is therefore attributed to water tolerant Lewis acid sites that proceed effectively on&nbsp; dehydration and hydride shift reactions.

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  • SO<inf>3</inf>H-bearing mesoporous carbon with highly selective catalysis Reviewed

    Satoshi Suganuma, Kiyotaka Nakajima, Masaaki Kitano, Hideki Kato, Asako Tamura, Hidesato Kondo, Shinichiro Yanagawa, Shigenobu Hayashi, Michikazu Hara

    Microporous and Mesoporous Materials   143 ( 2-3 )   443 - 450   2011.9

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    DOI: 10.1016/j.micromeso.2011.03.028

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  • Magnetic sponge prepared with an alkanedithiol-bridged network of nanomagnets Reviewed

    Yoshikazu Ito, Akira Miyazaki, Kazuyuki Takai, Vajiravelu Sivamurugan, Takashi Maeno, Takeshi Kadono, Masaaki Kitano, Yoshihiro Ogawa, Naotake Nakamura, Michikazu Hara, Suresh Valiyaveettil, Toshiaki Enoki

    Journal of the American Chemical Society   133 ( 30 )   11470 - 11473   2011.8

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    DOI: 10.1021/ja204617a

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  • Structure and catalysis of cellulose-derived amorphous carbon bearing SO<inf>3</inf>H groups Reviewed

    Kiichi Fukuhara, Kiyotaka Nakajima, Masaaki Kitano, Hideki Kato, Shigenobu Hayashi, Michikazu Hara

    ChemSusChem   4 ( 6 )   778 - 784   2011.6

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    DOI: 10.1002/cssc.201000431

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  • Synthesis and Characterization of Semiconducting Boron-doped Amorphous Carbon Materials Using an Organic Boron Compound as a Precursor Reviewed

    Inoue, Yasunori, Kitano, Masaaki, Nakajima, Kiyotaka, Hara, Michikazu

    Chemistry Letters   40 ( 4 )   410 - 411   2011.4

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    DOI: 10.1246/cl.2011.410

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  • Nb<inf>2</inf>O<inf>5</inf>•nH<inf>2</inf>O as a heterogeneous catalyst with water-tolerant lewis acid sites Reviewed

    Kiyotaka Nakajima, Yusuke Baba, Ryouhei Noma, Masaaki Kitano, Junko N. Kondo, Shigenobu Hayashi, Michikazu Hara

    Journal of the American Chemical Society   133 ( 12 )   4224 - 4227   2011.3

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    DOI: 10.1021/ja110482r

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  • Preparation of N-containing mesoporous organosilica and its catalytic performance

    Tanaka Satoru, Shima Hisashi, Imai Hiroyuki, Yokoi Toshiyuki, Nakajima Kiyotaka, Hara Michikazu, Tatsumi Takashi, Nomura Junko

    Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute   2011   89 - 89   2011

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    Recently, hybrid mesoporous materials containing organicfragments within the silicate framework have been synthesizedfrom bridged organosilane compounds as silica sources inthe presence of a structure-directing agent.Such materialshave the potential to offer a wide range of functionality throughappropriate selection of the organic group in the silicate framework.

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  • HMF production from aqueous glucose solution over solid Lewis acid catalyst

    Nakajima Kiyotaka, Noma Ryouhei, Kitano Masaaki, Hayashi Shigenobu, Hara Michikazu

    Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute   2011   97 - 97   2011

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  • Greatwall Kinase Is an Essential Component of MPF

    Michikazu Hara

    Molecular Biology of the Cell   2011

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  • Mechanical compression induced short-range ordering of nanographene spins

    Katsunori Takahara, Sijia Hao, Hidekazu Tanaka, Takeshi Kadono, Michikazu Hara, Kazuyuki Takai, Toshiaki Enoki

    Physical Review B - Condensed Matter and Materials Physics   82 ( 12 )   2010.9

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    DOI: 10.1103/PhysRevB.82.121417

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  • Biodiesel production by amorphous carbon bearing SO<inf>3</inf>H, COOH and phenolic OH groups, a solid Brønsted acid catalyst Reviewed

    Michikazu Hara

    Topics in Catalysis   53 ( 11-12 )   805 - 810   2010.7

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    DOI: 10.1007/s11244-010-9458-z

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  • Structure and acid catalysis of mesoporous Nb<inf>2</inf>O <inf>5</inf>·n H<inf>2</inf>O Reviewed

    Kiyotaka Nakajima, Tsuyoshi Fukui, Hideki Kato, Masaaki Kitano, Junko N. Kondo, Shigenobu Hayashi, Michikazu Hara

    Chemistry of Materials   22 ( 11 )   3332 - 3339   2010.6

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    DOI: 10.1021/cm100391q

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  • Synthesis and acid catalysis of cellulose-derived carbon-based solid acid Reviewed

    Satoshi Suganuma, Kiyotaka Nakajima, Masaaki Kitano, Daizo Yamaguchi, Hideki Kato, Shigenobu Hayashi, Michikazu Hara

    Solid State Sciences   12 ( 6 )   1029 - 1034   2010.6

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    DOI: 10.1016/j.solidstatesciences.2010.02.038

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  • Starch saccharification by carbon-based solid acid catalyst Reviewed

    Daizo Yamaguchi, Michikazu Hara

    Solid State Sciences   12 ( 6 )   1018 - 1023   2010.6

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    DOI: 10.1016/j.solidstatesciences.2009.12.002

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  • Protonated titanate nanotubes as solid acid catalyst Reviewed

    Masaaki Kitano, Kiyotaka Nakajima, Junko N. Kondo, Shigenobu Hayashi, Michikazu Hara

    Journal of the American Chemical Society   132 ( 19 )   6622 - 6623   2010.5

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    DOI: 10.1021/ja100435w

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  • Automated Analysis of Persistent Organic Pollutants in the Gas Phase by Laser Ionization Mass Spectrometry. Reviewed

    Shinsaku Dobashi, Yoshiki Yamaguchi, Yoshinori Izawa, Akihide Wada, Michikazu Hara

    Journal of the Mass Spectrometry Society of Japan   58 ( 2 )   35 - 46   2010.4

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    Persistent organic pollutants (POPs) are toxic chemicals that adversely affect human health and the environment around the world. The detection and evaluation of small amounts of POPs require methods with both high precision and high chemical selectivity. Conventional methods involve a number of preparatory steps and time-consuming analysis and are not suitable for the abovementioned purposes. Hence, new automated analysis methods are required for on-line detection and rapid analysis of POPs. In this paper, mass spectrometry with resonance-enhanced multi-photon ionization (REMPI) is performed to obtain information about the automated analysis of POPs in the gas-phase with on-line detection. Dynamic trapping time-of-flight mass spectrometry (TOFMS) was performed with sufficient selectivity and sensitivity for rapid analysis of polychlorinated biphenyls (PCBs) in the gas phase. Compared to normal trapping, the use of dynamic trapping enabled ion signal intensity to be increased by a factor of greater than 10. The detection limit at 1 min was <1 ppbV, and the accuracy also correlated well with the results of conventional analysis. Based on these results, an automated monitoring system was developed for automated analysis of PCBs. It was confirmed that this monitoring system was capable of analyzing PCB concentration without being influenced by main gas components or various coexisting substances, even under conditions characterized by exhaust gas and the work environment atmosphere. PCB concentration in PCB waste plants, which is substantially lower than the 0.10 mg/m3N specified in statutory regulations, could be analyzed within 1 min. It was possible to make continuous long-term analysis for over 2,000 h (120,000 points).

    DOI: 10.5702/massspec.58.35

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  • Magnetism of nanographene network influenced by the interaction with acid species

    T. Enoki, S. Tsuge, S. Hao, K. Takai, K. Nakajima, M. Hara, F. Y. Kang

    Journal of Physics and Chemistry of Solids   71 ( 4 )   534 - 538   2010.4

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    DOI: 10.1016/j.jpcs.2009.12.030

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  • Optimization of Hydrolysis of Cellulosic Materials by a Solid Acid Catalyst Reviewed

    Daizo Yamaguchi, Michikazu Hara

    ICEME 2010: INTERNATIONAL CONFERENCE ON ENGINEERING AND META-ENGINEERING (POST-CONFERENCE EDITION)   61 - 66   2010

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  • Biomass conversion by a solid acid catalyst Reviewed

    Michikazu Hara

    Energy and Environmental Science   3 ( 5 )   601 - 607   2010

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    DOI: 10.1039/b922917e

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  • Heterogeneous photocatalytic cleavage of water Reviewed

    Masaaki Kitano, Michikazu Hara

    Journal of Materials Chemistry   20 ( 4 )   627 - 641   2010

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    DOI: 10.1039/b910180b

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  • Nanosheets as highly active solid acid catalysts for green chemical syntheses Reviewed

    Atsushi Takagaki, Caio Tagusagawa, Shigenobu Hayashi, Michikazu Hara, Kazunari Domen

    Energy and Environmental Science   3 ( 1 )   82 - 93   2010

  • Safety management by use of laser mass spectrometry of polychlorinated biphenyls (PCBs) in the processed gas and work environment of a PCB disposal plant

    Shinsaku Dobashi, Yoshiki Yamaguchi, Yoshinori Izawa, Akihide Wada, Michikazu Hara

    Journal of Material Cycles and Waste Management   11 ( 2 )   148 - 154   2009.5

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    DOI: 10.1007/s10163-008-0228-y

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  • Environmental monitoring method of di-, tri-, tetra-, penta-, and hexa-chlorinated biphenyls in the gas phase by use of the picosecond laser ionization

    Shinsaku Dobashi, Yoshiki Yamaguchi, Yoshinori Izawa, Yoshihiro Deguchi, Akihide Wada, Michikazu Hara

    Journal of Chemical Engineering of Japan   40 ( 2 )   191 - 197   2007.2

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    DOI: 10.1252/jcej.40.191

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  • Sulfonated Incompletely Carbonized Glucose as Strong Bronsted Acid Catalyst Reviewed

    Michikazu Hara, Mai Okamura, Masakazu Toda, Junko N. Kondo, Atsushi Takagaki, Kazunari Domen, Takashi Tatsumi, Shigenobu Hayashi

    Studies in Surface Science and Catalysis   172   405 - 408   2007

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  • Laser Mass Spectrometry: Rapid Analysis of Polychlorinated Biphenyls in Exhaust Gas of Disposal Plants. Reviewed

    Shinsaku Dobashi, Yoshiki Yamaguchi, Yoshinori Izawa, Yoshihiro Deguchi, Akihide Wada, Michikazu Hara

    Journal of Environment and Engineering   2 ( 1 )   25 - 34   2007

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    Effective prevention from the leakage of Polychlorinated Biphenyls (PCBs) requires the rapid analysis with on-line detection, but conventional methods require extensive analytical time (several days per sample) and are thus unsuitable. The objective of the research reported here was to develop the Laser Ionization / Ion Trap Storage / Time of Flight Mass Spectrometry (LI-IT-TOFMS) capable of monitoring PCBs within 1 min/sample, as applied to exhaust gas and the atmosphere of the disposal work environment. The achievable PCBs sensitivity for on-line measurement was found to be in the pptV range (< 0.01 mg/m3N) by means of comparison with conventional gas sampling and gas chromatograph - mass spectrometry (GC-MS). A satisfactory proportional relationship was confirmed between laser-based and conventional results for PCBs. We measured the exhaust gas in a PCBs treatment plant (hydrothermal decomposition and container treatment processes) by using the PCBs monitoring system, confirming that PCBs monitoring is possible without interference from either the main gas composition or minor coexisting substances. Accordingly, the LI-IT-TOFMS method is a useful method for the trace analysis of PCBs in exhaust gas.

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  • Ba<inf>1.0</inf>Co<inf>0.7</inf>Fe<inf>0.2</inf>Nb<inf>0.1</inf>O <inf>3-δ</inf> dense ceramic as an oxygen permeable membrane for partial oxidation of methane to synthesis gas Reviewed

    Makoto Harada, Kazunari Domen, Michikazu Hara, Takashi Tatsumi

    Chemistry Letters   35 ( 12 )   1326 - 1327   2006.12

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  • Oxygen-permeable membranes of Ba <inf>1.0</inf>Co <inf>0.7</inf>Fe <inf>0.2</inf>Nb <inf>0.1</inf>O <inf>3-δ</inf> for preparation of synthesis gas from methane by partial oxidation Reviewed

    Makoto Harada, Kazunari Domen, Michikazu Hara, Takashi Tatsumi

    Chemistry Letters   35 ( 8 )   968 - 969   2006.8

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    DOI: 10.1246/cl.2006.968

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  • Esterification of higher fatty acids by a novel strong solid acid Reviewed

    Atsushi Takagaki, Masakazu Toda, Mai Okamura, Junko N. Kondo, Shigenobu Hayashi, Kazunari Domen, Michikazu Hara

    Catalysis Today   116 ( 2 SPEC. ISS. )   157 - 161   2006.8

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    DOI: 10.1016/j.cattod.2006.01.037

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  • Real-time monitoring of monochlorinated benzene and polychlorinated biphenyls in the gas phase with on-line detection: High chemical selectivity of resonance-enhanced two-photon ionization

    Shinsaku Dobashi, Masaharu Kira, Ryuichiro Tanaka, Yoshinori Izawa, Akihide Wada, Michikazu Hara

    Analytical Sciences   22 ( 4 )   603 - 606   2006.4

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    DOI: 10.2116/analsci.22.603

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  • Sulfur-substituted and zinc-doped In(OH)<inf>3</inf>: A new class of catalyst for photocatalytic H<inf>2</inf> production from water under visible light illumination

    Zhibin Lei, Guijun Ma, Meiying Liu, Wansheng You, Hongjian Yan, Guopeng Wu, Tsuyoshi Takata, Michikazu Hara, Kazunari Domen, Can Li

    Journal of Catalysis   237 ( 2 )   322 - 329   2006.1

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    DOI: 10.1016/j.jcat.2005.11.022

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  • Rapid Analysis of Polychlorinated Biphenyls in the Gas Phase with Resonance-enhanced Two-photon Ionization: Optimal Injection of Ions into the Ion-trap Storage/Time-of-flight Mass Spectrometer

    DOBASHI Shinsaku, KIRA Masaharu, TANAKA Ryuichiro, IZAWA Yoshinori, DEGUCHI Yoshihiro, KUBOTA Takahiro, WADA Akihide, HARA Michikazu

    Analytical Sciences   22 ( 5 )   803 - 803   2006

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    DOI: 10.2116/analsci.22.803

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  • Erratum: Synthesis of crystallized mesoporous transition metal oxides by silicone treatment of the oxide precursor (Chemical Communications (2006) DOI: 10.1039/b603115c)

    Nao Shirokura, Kiyotaka Nakajima, Akira Nakabayashi, Daling Lu, Michikazu Hara, Kazunari Domen, Takashi Tatsumi, Junko N. Kondo

    Chemical Communications   ( 20 )   2194   2006

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    DOI: 10.1039/b606115j

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  • Wavelength programmable organic distributed feedback laser using a photoinduced surface relief grating

    Michikazu Hara

    Molecular Crystals and Liquid Crystals   2006

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    DOI: 10.1080/15421400500366704

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  • Fluorescence dynamics of organic laser dyes in azobenzene polymer

    Michikazu Hara

    Molecular Crystals and Liquid Crystals   2006

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    DOI: 10.1080/15421400500379848

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  • Rapid analysis of polychlorinated biphenyls in the gas phase with resonance-enhanced two-photon ionization: Optimal injection of ions into the ion-trap storage/time-of-flight mass spectrometer

    Shinsaku Dobashi, Masaharu Kira, Ryuichiro Tanaka, Yoshinori Izawa, Yoshihiro Deguchi, Takahiro Kubota, Akihide Wada, Michikazu Hara

    Analytical Sciences   21 ( 9 )   1111 - 1115   2005.9

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    DOI: 10.2116/analsci.21.1111

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  • Exfoliated HNb<inf>3</inf>O<inf>8</inf> nanosheets as a strong protonic solid acid Reviewed

    Atsushi Takagaki, Darling Lu, Junko N. Kondo, Michikazu Hara, Shigenobu Hayashi, Kazunari Domen

    Chemistry of Materials   17 ( 10 )   2487 - 2489   2005.5

  • Control of pore size in mesoporous silica by incremental surface modification using tetramethyl orthosilicate

    Ryohei Ishimaru, Yusuke Shibasaki, Michikazu Hara, Mitsuru Ueda, Kazunari Domen, Junko N. Kondo

    Chemistry Letters   34 ( 4 )   596 - 597   2005.4

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    DOI: 10.1246/cl.2005.596

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  • Kinetic study of dehydrogenation between H-siloxane and Ti-OH on TiO <inf>2</inf>

    Akira Nakabayashi, Junko N. Kondo, Michikazu Hara, Kazunari Domen

    Chemistry Letters   34 ( 4 )   460 - 461   2005.4

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    DOI: 10.1246/cl.2005.460

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  • Photoinduced transformation of silicone-modified TiO<inf>2</inf>

    Akira Nakabayashi, Junko N. Kondo, Michikazu Hara, Kazunari Domen

    Chemistry Letters   34 ( 2 )   198 - 199   2005.2

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    DOI: 10.1246/cl.2005.198

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  • Preparation of crack-free, transparent, nanoporous niobium oxide film with crystalline structure by evaporation-induced self-assembly (EISA) process Reviewed

    Kiyotaka Nakajima, Nao Shirokura, Byongjin Lee, Junko N. Kondo, Michikazu Hara, Kazunari Domen

    Studies in Surface Science and Catalysis   156   321 - 326   2005

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    DOI: 10.1016/s0167-2991(05)80224-1

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  • Stable and highly active Ph-SO<inf>3</inf>H functionalized hybrid mesoporous acid catalyst Reviewed

    K. Nakajima, I. Tomita, M. Hara, S. Hayashi, K. Domen, J. N. Kondo

    Studies in Surface Science and Catalysis   158 B   1485 - 1492   2005

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    DOI: 10.1016/s0167-2991(05)80501-4

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  • Synthesis and application of thermally stable mesoporous Ta <inf>2</inf>O<inf>5</inf> photocatalyst for overall water decomposition Reviewed

    K. Nakajima, D. Lu, M. Hara, K. Domen, J. N. Kondo

    Studies in Surface Science and Catalysis   158 B   1477 - 1484   2005

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    DOI: 10.1016/s0167-2991(05)80500-2

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  • Tantalum oxynitride for a novel cathode of PEFC

    Akimitsu Ishihara, Kunchan Lee, Shotaro Doi, Shigenori Mitsushima, Nobuyuki Kamiya, Michikazu Hara, Kazunari Domen, Kenzo Fukuda, Ken Ichiro Ota

    Electrochemical and Solid-State Letters   8 ( 4 )   2005

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    DOI: 10.1149/1.1865612

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  • On-line monitoring method of persistent organic pollutants in gas phase

    Shinsaku Dobashi, Masaharu Kira, Ryuichiro Tanaka, Yoshinori Izawa, Yoshihiro Deguchi, Takahiro Kubota, Akihide Wada, Michikazu Hara

    Proceedings of the SICE Annual Conference   1579 - 1582   2005

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  • Wavelength-programmable organic distributed-feedback laser based on a photoassisted polymer-migration system

    Michikazu Hara

    Advanced Materials   2005

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    DOI: 10.1002/ADMA.200402080

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  • Supermicroporous niobium oxide as an acid catalyst

    Mayako Hiyoshi, Byongjin Lee, Daling Lu, Michikazu Hara, Junko N. Kondo, Kazunari Domen

    Catalysis Letters   98 ( 4 )   181 - 186   2004.12

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    DOI: 10.1007/s10562-004-8678-x

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  • Water reduction and oxidation on Pt-Ru/Y<inf>2</inf>Ta<inf>2</inf>O <inf>5</inf>N<inf>2</inf> catalyst under visible light irradiation

    Meiying Liu, Wansheng You, Zhibin Lei, Guohua Zhou, Jianjun Yang, Guopeng Wu, Guijun Ma, Guoyou Luan, Tuyoshi Takata, Michikazu Hara, Kazunari Domen, Can Li

    Chemical Communications   ( 19 )   2192 - 2193   2004.11

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    DOI: 10.1039/b407892f

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  • Recent progress of visible-light-driven heterogeneous photocatalysts for overall water splitting

    Daisuke Yamasita, Tsuyoshi Takata, Michikazu Hara, Junko N. Kondo, Kazunari Domen

    Solid State Ionics   172 ( 1-4 SPEC. ISS. )   591 - 595   2004.8

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    DOI: 10.1016/j.ssi.2004.04.033

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  • Electrochemical behavior of thin Ta<inf>3</inf>N<inf>5</inf> semiconductor film

    Akio Ishikawa, Tsuyoshi Takata, Junko N. Kondo, Michikazu Hara, Kazunari Domen

    Journal of Physical Chemistry B   108 ( 30 )   11049 - 11053   2004.7

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    DOI: 10.1021/jp048802u

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  • Metal ion and N co-doped TiO<inf>2</inf> as a visible-light photocatalyst

    Yoshiaki Sakatani, Hiroyuki Ando, Kensen Okusako, Hironobu Koike, Jun Nunoshige, Tsuyoshi Takata, Junko N. Kondo, Michikazu Hara, Kazunari Domen

    Journal of Materials Research   19 ( 7 )   2100 - 2108   2004.7

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    DOI: 10.1557/JMR.2004.0269

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  • Porous Single-Crystalline TaON and Ta<inf>3</inf>N<inf>5</inf> Particles

    Daling Lu, Go Hitoki, Emi Katou, Junko N. Kondo, Michikazu Hara, Kazunari Domen

    Chemistry of Materials   16 ( 9 )   1603 - 1605   2004.5

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    DOI: 10.1021/cm0347887

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  • Functionalized self-assembled monolayers and metal nanoparticle devices

    Michikazu Hara

    Abstracts of Papers of the American Chemical Society   2004

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  • Photocatalytic Decomposition of Acetaldehyde under Visible Light Irradiation over La3+ and N Co-doped TiO<inf>2</inf>

    Yoshiaki Sakatani, Jun Nunoshige, Hiroyuki Ando, Kensen Okusako, Hironobu Koike, Tsuyoshi Takata, Junko N. Kondo, Michikazu Hara, Kazunari Domen

    Chemistry Letters   32 ( 12 )   1156 - 1157   2003.12

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    DOI: 10.1246/cl.2003.1156

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  • Ta<inf>3</inf>N<inf>5</inf> and TaON thin films on Ta foil: Surface composition and stability

    Michikazu Hara, Eisuke Chiba, Akio Ishikawa, Tsuyoshi Takata, Junko N. Kondo, Kazunari Domen

    Journal of Physical Chemistry B   107 ( 48 )   13441 - 13445   2003.12

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    DOI: 10.1021/jp036189t

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  • Novel Synthesis and Photocatalytic Activity of Oxysulfide Sm <inf>2</inf>Ti<inf>2</inf>S<inf>2</inf>O<inf>5</inf>

    Akio Ishikawa, Yoko Yamada, Tsuyoshi Takata, Junko N. Kondo, Michikazu Hara, Hisayoshi Kobayashi, Kazunari Domen

    Chemistry of Materials   15 ( 23 )   4442 - 4446   2003.11

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    DOI: 10.1021/cm034540h

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  • Preparation and Catalytic Application of Transition Metal (Fe, V, or Cu) Oxides Homogeneously Dispersed in the Wall of Mesoporous Nb <inf>2</inf>O <inf>5</inf> Reviewed

    Tomohiro Yamashita, Daling Lu, Junko N. Kondo, Michikazu Hara, Kazunari Domen

    Chemistry Letters   32 ( 11 )   1034 - 1035   2003.11

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    DOI: 10.1246/cl.2003.1034

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  • Crystallization of an ordered mesoporous Nb-Ta oxide Reviewed

    Tokumitsu Katou, Byongjin Lee, Daling Lu, Junko N. Kondo, Michikazu Hara, Kazunari Domen

    Angewandte Chemie - International Edition   42 ( 21 )   2382 - 2385   2003.5

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    DOI: 10.1002/anie.200250263

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  • TaON and Ta<inf>3</inf>N<inf>5</inf> as new visible light driven photocatalysts

    Michikazu Hara, Go Hitoki, Tsuyoshi Takata, Junko N. Kondo, Hisayoshi Kobayashi, Kazunari Domen

    Catalysis Today   78 ( 1-4 SPEC. )   555 - 560   2003.2

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    DOI: 10.1016/S0920-5861(02)00354-1

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  • Unusual enhancement of H<inf>2</inf> evolution by Ru on TaON photocatalyst under visible light irradiation

    Michikazu Hara, Jun Nunoshige, Tsuyoshi Takata, Junko N. Kondo, Kazunari Domen

    Chemical Communications   3 ( 24 )   3000 - 3001   2003

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    DOI: 10.1039/b309935k

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  • Photocatalytic water reduction under visible light on a novel ZnIn<inf>2</inf>S<inf>4</inf> catalyst synthesized by hydrothermal method

    Zhibin Lei, Wansheng You, Meiying Liu, Guohua Zhou, Tuyoshi Takata, Michikazu Hara, Kazunari Domen, Can Li

    Chemical Communications   3 ( 17 )   2142 - 2143   2003

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    DOI: 10.1039/b306813g

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  • Surface state analysis of photobrightening in CdSe nanocrystal thin films

    Michikazu Hara

    The Journal of Physical Chemistry B   2003

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    DOI: 10.1021/JP035484A

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  • Ta<inf>3</inf>N<inf>5</inf> as a novel visible light-driven photocatalyst (λ &lt; 600nm)

    Go Hitoki, Akio Ishikawa, Tsuyoshi Takata, Junko N. Kondo, Michikazu Hara, Kazunari Domen

    Chemistry Letters   ( 7 )   736 - 737   2002.7

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    DOI: 10.1246/cl.2002.736

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  • Desorption of aluminum hydride from Al single crystal surfaces

    Michikazu Hara

    Keikinzoku/Journal of Japan Institute of Light Metals   52 ( 5 )   236 - 238   2002

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    DOI: 10.2464/jilm.52.236

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  • New Aspects of Heterogeneous Photocatalysts for Water Decomposition Reviewed

    Kazunari Domen, Michikazu Hara, Junko N. Kondo, Tsuyoshi Takata, Akihiko Kudo, Hisayoshi Kobayashi, Yasunobu Inoue

    Korean Journal of Chemical Engineering   18 ( 6 )   862 - 866   2001.11

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  • Ion-exchangeable thin films derived from a layered titanate, Cs<inf>0.68</inf>Ti<inf>1.83</inf>□<inf>0.17</inf>O<inf>4</inf>(□: Vacancy)

    T. Sumida, Y. Takahara, R. Abe, M. Hara, J. N. Kondo, K. Domen, M. Kakihana, M. Yoshimura

    Physical Chemistry Chemical Physics   3 ( 4 )   640 - 644   2001.2

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    DOI: 10.1039/b007150l

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  • Photocatalytic oxidation of water by silica-supported tris(4,4′-dialkyl-2,2′-bipyridyl)ruthenium polymeric sensitizers and colloidal iridium oxide

    M. Hara, J. T. Lean, T. E. Mallouk

    Chemistry of Materials   13 ( 12 )   4668 - 4675   2001

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    DOI: 10.1021/cm0104811

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  • Mechano-catalytic overall water splitting on some mixed oxides Reviewed

    Go Hitoki, Tsuyosi Takata, Shigeru Ikeda, Michikazu Hara, Junko N. Kondo, Masato Kakihana, Kazunari Domen

    Catalysis Today   63 ( 2-4 )   175 - 181   2000.12

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    DOI: 10.1016/S0920-5861(00)00457-0

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  • Preparation of SiO<inf>2</inf>-pillared layered titanate thin films

    Takeshi Sumida, Ryu Abe, Michikazu Hara, Junko N. Kondo, Kazunari Domen

    Journal of Materials Research   15 ( 12 )   2587 - 2590   2000.12

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    DOI: 10.1557/JMR.2000.0369

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  • Photocatalytic water oxidation by Nafion-stabilized iridium oxide colloids

    M. Hara, T. E. Mallouk

    Chemical Communications   ( 19 )   1903 - 1904   2000.10

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    DOI: 10.1039/b003246h

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  • Synthesis of (H<inf>3</inf>O)TiNbO<inf>5</inf>·0.26H<inf>2</inf>O via hydronium (H<inf>3</inf>O+) ion-exchange reaction and its photocatalytic activity for H<inf>2</inf> evolution from aqueous methanol solution

    H. Takahashi, M. Kakihana, Y. Yamashita, K. Yoshida, S. Ikeda, M. Hara, K. Domen

    Physical Chemistry Chemical Physics   2 ( 19 )   4461 - 4464   2000.10

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    DOI: 10.1039/b003808n

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  • Mechano-catalytic overall water splitting on some oxides (II)

    Tsuyosi Takata, Shigeru Ikeda, Akira Tanaka, Michikazu Hara, Junko N. Kondo, Kazunari Domen

    Applied Catalysis A: General   200 ( 1 )   255 - 262   2000.8

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    DOI: 10.1016/S0926-860X(00)00628-1

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  • A Study of Mechano-Catalysts for Overall Water Splitting

    Michikazu Hara, Mutsuko Komoda, Hironori Hasei, Masaaki Yashima, Sigeru Ikeda, Tsuyoshi Takata, Junko N. Kondo, Kazunari Domen

    Journal of Physical Chemistry B   104 ( 4 )   780 - 785   2000.2

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    DOI: 10.1021/jp993441h

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  • Mechano-catalytic overall water splitting (II) nafion-deposited Cu<inf>2</inf>O

    Michikazu Hara, Hironori Hasei, Masaaki Yashima, Sigeru Ikeda, Tsuyoshi Takata, Junko N. Kondo, Kazunari Domen

    Applied Catalysis A: General   190 ( 1-2 )   35 - 42   2000.1

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    DOI: 10.1016/S0926-860X(99)00284-7

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  • Exfoliation and photocatalytic activities of layered oxides KSr<inf>2</inf>Nb<inf>3</inf>O<inf>10</inf>

    M. Hara, N. Ooto, T. Smida, J. N. Kondo, K. Domen

    Proceedings of the Second International Conference on Processing Materials for Properties   235 - 238   2000

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  • Observation of unstable reaction intermediate by picosecond tunable infrared laser pulses

    K. Domen, K. Kusafuka, A. Bandara, M. Hara, J. N. Kondo, J. Kubota, K. Onda, A. Wada, C. Hirose

    Studies in Surface Science and Catalysis   130 A   365 - 370   2000

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    DOI: 10.1016/s0167-2991(00)80984-2

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  • Unusual isomerization routes of n-butenes on the acidic OH (OD) groups on ferrierite zeolite studied by FT-IR

    Junko N. Kondo, Eisuke Yoda, Michikazu Hara, Fumitaka Wakabayashi, Kazunari Domen

    Studies in Surface Science and Catalysis   130 C   2933 - 2938   2000

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    DOI: 10.1016/s0167-2991(00)80917-9

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  • Photocatalytic water decomposition by layered perovskites

    Tsuyoshi Takata, Akira Tanaka, Michikazu Hara, Junko N. Kondo, Kazunari Domen

    Studies in Surface Science and Catalysis   130 B   1943 - 1948   2000

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    DOI: 10.1016/s0167-2991(00)80486-3

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  • Morphologies of PC12 cells cultured on some polymeric membranes prepared by Langmuir-Blodgett and casting methods

    Michikazu Hara

    Abstracts of Papers of the American Chemical Society   2000

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  • Characterization of Layered Titanate Thin Films

    Takeshi Sumida, Ryu Abe, Michikazu Hara, Junko N. Kondo, Kazunari Domen

    Electrochemistry   67 ( 12 )   1224 - 1226   1999.12

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    DOI: 10.5796/electrochemistry.67.1224

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  • Synthesis of NiO-loaded KTiNbO<inf>5</inf> photocatalysts by a novel polymerizable complex method

    Hiroyuki Takahashi, Masato Kakihana, Yohichi Yamashita, Kiyohide Yoshida, Shigeru Ikeda, Michikazu Hara, Kazunari Domen

    Journal of Alloys and Compounds   285 ( 1-2 Complete )   77 - 81   1999.6

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    DOI: 10.1016/S0925-8388(98)00968-2

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  • Overall Water Splitting on Cu_2O

    HARA Michikazu, DOMEN Kazunari

    J. Surf. Sci. Soc. Jpn.   20 ( 2 )   66 - 72   1999.2

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    Language:Japanese   Publisher:The Surface Science Society of Japan  

    Recently, we have found that Cu2O powder suspended in distilled water by stirring decompose water catalytically into H2 and O2 under visible light irradiation. To our surprise, the experiment revealed that the catalytic decomposion of water by Cu2O is due to the mechanical energy produced in to stirring and the reaction under stirring was enhanced by the irradiation of visible light having photon energies more than the band gap energy of Cu2O(2 eV). The reaction is regarded as "mechano-catalytic overall splitting"; and is distinct from conventional photocatalytic water decomposition.

    DOI: 10.1380/jsssj.20.66

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  • Novel methods for preparation of ion-exchangeable thin films

    Ryu Abe, Shigeru Ikeda, Junko N. Kondo, Michikazu Hara, Kazunari Domen

    Thin Solid Films   343-344 ( 1-2 )   156 - 159   1999

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    DOI: 10.1016/S0040-6090(98)01652-6

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  • Preparation of Ion-Exchangeable Thin Films of Layered Niobate K<inf>4</inf>Nb<inf>6</inf>O<inf>17</inf>

    Ryu Abe, Michikazu Hara, Junko N. Kondo, Kazunari Domen, Kiyoaki Shinohara, Akira Tanaka

    Chemistry of Materials   10 ( 6 )   1647 - 1651   1998.6

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    DOI: 10.1021/cm970825g

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  • Preparation of porous niobium oxide by the exfoliation of K<inf>4</inf>Nb<inf>6</inf>O<inf>17</inf> and its photocatalytic activity

    Ryu Abe, Kiyoaki Shinohara, Akira Tanaka, Michikazu Hara, Junko N. Kondo, Kazunari Domen

    Journal of Materials Research   13 ( 4 )   861 - 865   1998.4

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    DOI: 10.1557/JMR.1998.0115

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  • Preparation of a high active photocatalyst, K<inf>2</inf>La<inf>2</inf>Ti<inf>3</inf>O<inf>10</inf>, by polymerized complex method and its photocatalytic activity of water splitting

    Shigeru Ikeda, Michikazu Hara, Junko N. Kondo, Kazunari Domen, Hiroyuki Takahashi, Toru Okubo, Masato Kakihana

    Journal of Materials Research   13 ( 4 )   852 - 855   1998.4

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    DOI: 10.1557/JMR.1998.0113

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  • Cu<inf>2</inf>O as a photocatalyst for overall water splitting under visible light irradiation

    Michikazu Hara

    Chemical Communications   ( 3 )   357 - 358   1998.2

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/a707440i

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  • Reaction path of methoxy species to isobutene and its dependence on oxide catalysts in CO hydrogenation

    Ken Ichi Maruya, Miyuki Kawamura, Makiko Aikawa, Michikazu Hara, Toru Arai

    Journal of Organometallic Chemistry   551 ( 1-2 )   101 - 105   1998.1

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/S0022-328X(97)00436-1

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  • Preparation of K<inf>2</inf>La<inf>2</inf>Ti<inf>3</inf>O<inf>10</inf> by Polymerized Complex Method and Photocatalytic Decomposition of Water

    Shigeru Ikeda, Michikazu Hara, Junko N. Kondo, Kazunari Domen, Hiroyuki Takahashi, Toru Okubo, Masato Kakihana

    Chemistry of Materials   10 ( 1 )   72 - 77   1998.1

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/cm970221c

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  • Preparation of Thin Films of a Layered Titanate by the Exfoliation of Cs<inf>x</inf>T<inf>i(2-x/4)</inf>□<inf>x/4</inf>O<inf>4</inf>

    Ryu Abe, Kiyoaki Shinohara, Akira Tanaka, Michikazu Hara, Junko N. Kondo, Kazunari Domen

    Chemistry of Materials   10 ( 1 )   329 - 333   1998.1

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/cm970481u

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  • 光で水を分解する(環境問題と触媒化学)

    原 亨和, 堂免 一成

    化学と教育   46 ( 12 )   778 - 781   1998

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    Language:Japanese   Publisher:公益社団法人 日本化学会  

    光触媒による水の分解は太陽光を高効率で水素エネルギーに変換することを目的とした魅力的なテーマである。これが実現した場合, 太陽と水がある限り, クリーンな水素エネルギーを生産することができる。ここでは金属酸化物光触媒による水の光分解を解説し, 研究のブレークスルーポイントに触れる。

    DOI: 10.20665/kakyoshi.46.12_778

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  • Preparation of Porous Niobium Oxides by Soft-Chemical Process and Their Photocatalytic Activity

    Ryu Abe, Kiyoaki Shinohara, Akira Tanaka, Michikazu Hara, Junko N. Kondo, Kazunari Domen

    Chemistry of Materials   9 ( 10 )   2179 - 2184   1997.10

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/cm970284v

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  • Photocatalytic Decomposition of Water on Spontaneously Hydrated Layered Perovskites

    Tsuyoshi Takata, Yoko Furumi, Kiyoaki Shinohara, Akira Tanaka, Michikazu Hara, Junko N. Kondo, Kazunari Domen

    Chemistry of Materials   9 ( 5 )   1063 - 1064   1997.5

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/cm960612b

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  • Effect of the particle size for photocatalytic decomposition of water on Ni-loaded K<inf>4</inf>Nb<inf>6</inf>O<inf>17</inf>

    Shigeru Ikeda, Akira Tanaka, Kiyoaki Shinohara, Michikazu Hara, Junko N. Kondo, Ken Ichi Maruya, Kazunari Domen

    Microporous Materials   9 ( 5-6 )   253 - 258   1997

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/S0927-6513(96)00112-5

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  • Selective isobutene formation in the CO hydrogenation over Cs-doped zrO<inf>2</inf>

    Michikazu Hara, Miyuki Kawamura, Ken Ichi Maruya

    Chemistry Letters   ( 4 )   309 - 310   1997

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1246/cl.1997.309

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  • Ion-exchangeable oxides with layered perovskite structures as photocatalysts for overall water splitting

    T. Takata, K. Shinohara, A. Tanaka, M. Hara, J. N. Kondo, K. Domen

    Materials Research Society Symposium - Proceedings   454   177 - 185   1997

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    Publishing type:Research paper (international conference proceedings)  

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  • Thermal conversion of methoxy species on dimethyl ether adsorbed CeO2 - Comment - Reply

    Hara, M., Kawamura, M., Kondo, JN, Domen, K., Maruya, K.

    Journal of Physical Chemistry B   101 ( 8 )   1997

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/jp963874+

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  • IRAS study of adsorption and transformation of CH<inf>2</inf>I<inf>2</inf> on Al(111) surface

    Junko N. Kondo, Tomoyoshi Higashi, Hiroyoshi Yamamoto, M. Hara, Kazunari Domen, Takaharu Onishi

    Surface Science   349 ( 3 )   294 - 300   1996.4

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/0039-6028(95)01021-1

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  • Key reaction for formation of isobutene over ZrO<inf>2</inf> and isoprene over CeO<inf>2</inf> in CO hydrogenation

    K. Maruya, M. Hara, J. Kondo, K. Domen, T. Onishi

    Studies in Surface Science and Catalysis   101 B   1401 - 1409   1996

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/s0167-2991(96)80352-1

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  • Rechargeable Lithium-ion Cells Using Graphitized Mesophase-Pitch-Based Carbon Fiber Anodes

    Norio Takami, Asako Satoh, Michikazu Hara, Takahisa Ohsaki

    Journal of the Electrochemical Society   142 ( 8 )   2564 - 2571   1995.8

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1149/1.2050054

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  • Surface Structures and Charge-Discharge Characteristics of Mesocarbon Microbeads as the Anodes for Secondary Lithium-Ion Batteries

    Hara Michikazu, Satoh Asako, Takami Norio, Ohsaki Takahisa

    TANSO   1994 ( 165 )   261 - 268   1994

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    Publisher:THE CARBON SOCIETY OF JAPAN  

    The effect of the surface structure of mesocarbon microbeadson charge-discharge characteristics as anodes for secondary lithium-ion batteries was investigated. SEM (Scanning Electron Microscope) and Raman spectroscopy suggested that the mesocarbon microbeads had a more highly graphitized carbon layer on the surface than the inner carbons. The carbon layer caused the small capacity or the short cycle life as the anode. The heat-treatment of the mesocarbon microbeads in air for removing the surface layer gave a good effect on the capacity and the charge-discharge cycle for the anode.

    DOI: 10.7209/tanso.1994.261

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  • DESORPTION OF ALUMINUM-HYDRIDE FROM HYDROGEN ADSORBED ALUMINUM SINGLE-CRYSTAL SURFACES - REMARKABLE ORIENTATION DEPENDENCE

    NOZOYE, H., NISHIHARA, C., KONDOH, H., HARA, M., DOMEN, K.

    Abstracts of Papers of the American Chemical Society   203   1992

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▼display all

Books

  • 第二世代バイオ燃料の開発と応用展開

    CMC出版  2009  ( ISBN:9784781301150

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  • 木質系有機資源の新展開 II

    CMC出版  2009 

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  • Advanced Technologies for Woody Organic Resources II

    2009 

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  • Exploitation of Second Generation Biofuels and its Development

    2009  ( ISBN:9784781301150

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MISC

  • 新しい鉄触媒によるアンモニアの低温・低圧合成 : ヒドリド鉄触媒によるHaber-Boschプロセスの100年を超える課題の克服—Ammonia synthesis over a novel iron catalyst at low temperature and pressure

    原 亨和

    配管技術 = The piping engineering / 「計測技術」編集委員会 編   67 ( 12 )   44 - 49   2025.10

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    Language:Japanese   Publisher:東京 : 日本工業出版  

    CiNii Books

    CiNii Research

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    Other Link: https://ndlsearch.ndl.go.jp/books/R000000004-I034369008

  • 低温・低圧で高いアンモニア合成速度/触媒体積を可能にするメゾスケール鉄触媒の開発

    原 亨和

    クリーンエネルギー / クリーンエネルギー編集委員会 編   34 ( 8 )   37 - 41   2025.8

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    Language:Japanese   Publisher:東京 : 日本工業出版  

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    Other Link: https://ndlsearch.ndl.go.jp/books/R000000004-I034317533

  • 金属ヒドリド種の反応性を利用したアルコール変換—Alcohol Transformation Utilizing the Reactivity Control of Metal Hydride Species—特集 アルコール類の効率的変換を実現する非貴金属触媒の研究動向

    喜多 祐介, 原 亨和

    触媒 = Catalysts & catalysis   67 ( 4 )   158 - 164   2025.8

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    Language:Japanese   Publisher:東京 : 触媒学会  

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    Other Link: https://ndlsearch.ndl.go.jp/books/R000000004-I034411240

  • 鉄触媒による低温アンモニア合成—Low Temperature Ammonia Synthesis Over an Iron Catalyst—特集記事 アンモニアエネルギー利用最前線

    原 亨和

    えねるみくす = Enermix : 日本エネルギー学会機関誌   103 ( 3 )   322 - 327   2024.5

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    Language:Japanese   Publisher:東京 : 日本エネルギー学会  

    CiNii Books

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    Other Link: https://ndlsearch.ndl.go.jp/books/R000000004-I033541064

  • Selective Oxidation of Methane over Supported Iron Phosphate Catalysts Prepared Using Phosphonic Acid

    古谷一眞, 松田蒼依, 原亨和, 鎌田慶吾

    日本化学会春季年会講演予稿集(Web)   104th   2024

  • Selective Oxidation of Methane into Formaldehyde over Copper Phosphate Catalysts

    松田蒼依, 相原健司, 原亨和, 鎌田慶吾

    日本化学会春季年会講演予稿集(Web)   104th   2024

  • リン酸ビスマスナノ粒子触媒を用いたプロパンの直接部分酸化反応

    荘隆行, 鎌田慶吾, 原亨和

    触媒討論会予稿集(CD-ROM)   131st   2023

  • ホスホン酸を用いたリン酸鉄担持触媒によるメタンの直接酸化反応

    古谷一眞, 松田蒼依, 原亨和, 鎌田慶吾

    触媒討論会予稿集(CD-ROM)   132nd   2023

  • Synthesis of Ti-based perovskite nanoparticles with high specific surface areas by sol-gel method and their catalytic application to Knoevenagel condensation reaction

    青木航流, 相原健司, 鎌田慶吾, 原亨和

    日本化学会春季年会講演予稿集(Web)   103rd   2023

  • Direct partial oxidation of propane using bismuth phosphate nanoparticle catalysts

    荘隆行, 鎌田慶吾, 原亨和

    日本化学会春季年会講演予稿集(Web)   103rd   2023

  • Synthesis of Ni Nanoparticles Using Hydrosilanes and their Catalytic Activity

    喜多祐介, 竹内舜, 大吉孝明, 鎌田慶吾, 原亨和

    日本化学会春季年会講演予稿集(Web)   103rd   2023

  • Acid-Base Bifunctionality of Ti-based Perovskite Nanoparticles for Cyanosilylation

    相原健司, 青木航流, 鎌田慶吾, 原亨和

    日本化学会春季年会講演予稿集(Web)   103rd   2023

  • 担持コバルト触媒のニトリル水素化反応特性の解明

    加藤可百子, DENG Dian, 喜多祐介, 鎌田慶吾, 原亨和

    触媒討論会予稿集(CD-ROM)   131st   2023

  • Liquid-phase Oxidation of Light Alkanes Catalyzed by Partially Substituted Iron-based Perovskite

    山本昌尚, 鎌田慶吾, 原亨和

    日本化学会春季年会講演予稿集(Web)   103rd   2023

  • Ti含有ペロブスカイト酸化物の酸・塩基性質の解明とシアノシリル化反応

    相原健司, 青木航流, 鎌田慶吾, 原亨和

    触媒討論会予稿集(CD-ROM)   131st   2023

  • SrTiO3ナノ粒子の酸塩基性質とKnoevenagel縮合反応への応用

    青木航流, 相原健司, 原亨和, 鎌田慶吾

    触媒討論会予稿集(CD-ROM)   132nd   2023

  • アルコールの直接アミノ化に有効な大気安定Ni触媒の開発

    加藤可百子, 喜多祐介, 鎌田慶吾, 原亨和

    触媒討論会予稿集(CD-ROM)   132nd   2023

  • 担持金属触媒によるヒドロキシ基の置換反応におけるMgOの共担持効果

    喜多祐介, 桑原翠, SUARSIH Endah, 山寺哲史, 鎌田慶吾, 原亨和

    触媒討論会予稿集(CD-ROM)   131st   2023

  • 高比表面積Tiペロブスカイトナノ粒子触媒の合成とKnoevenagel縮合反応への応用

    青木航流, 相原健司, 鎌田慶吾, 原亨和

    触媒討論会予稿集(CD-ROM)   131st   2023

  • リン酸ビスマスナノ粒子触媒によるメタンの直接酸化

    松田蒼依, 小原和彦, 石川敦之, TSAI Meng-Hsuan, WANG Chia-Hsin, LIN Yu-Chuan, 原亨和, 鎌田慶吾

    触媒討論会予稿集(CD-ROM)   132nd   2023

  • 高原子価鉄を含むペロブスカイト酸化物触媒を用いた低級アルカンの液相酸化反応

    山本昌尚, 相原健司, 原亨和, 鎌田慶吾

    触媒討論会予稿集(CD-ROM)   132nd   2023

  • LDHから調製したMgO担持Fe触媒による低温還元的アミノ化

    柳澤菜月, 喜多祐介, 鎌田慶吾, 原亨和

    触媒討論会予稿集(CD-ROM)   132nd   2023

  • リン酸銅触媒を用いたメタンからホルムアルデヒドの直接合成と反応機構解明

    松田蒼依, 相原健司, 原亨和, 鎌田慶吾

    触媒討論会予稿集(CD-ROM)   132nd   2023

  • 鉄系ペロブスカイト型酸化物触媒による低級アルカンの液相酸化反応

    山本昌尚, 鎌田慶吾, 原亨和

    触媒討論会予稿集(CD-ROM)   131st   2023

  • 高表面積β-MnO2ナノ粒子触媒によるアルコールからのニトリル合成

    木下七海, 青野竜征, 林愛理, 鎌田慶吾, 原亨和

    触媒討論会講演予稿集(CD-ROM)   129th   2022

  • Synthesis of Murdochite-type Oxide Mg6MnO8 Nanoparticles and the Catalytic Oxidation Properties

    林愛理, 相原健司, 田村高敏, 鎌田慶吾, 原亨和

    日本化学会春季年会講演予稿集(Web)   102nd   2022

  • Synthesis of α-Haloketones from Vinyl Halides with Molecular Oxygen Catalyzed by Iron-based Perovskite

    柴田聡美, 鎌田慶吾, 原亨和

    日本化学会春季年会講演予稿集(Web)   102nd   2022

  • Selective Primary Amine Synthesis by Hydrogenation of Nitriles over Silica Supported Cobalt Catalysts

    加藤可百子, DENG Dian, 喜多祐介, 鎌田慶吾, 原亨和

    日本化学会春季年会講演予稿集(Web)   102nd   2022

  • Synthesis of Nitriles from Alcohols by a High-Surface-Area β-MnO2 Nanoparticle Catalyst

    木下七海, 青野竜征, 林愛理, 鎌田慶吾, 原亨和

    日本化学会春季年会講演予稿集(Web)   102nd   2022

  • Synthesis of High Surface Area Todorokite-type Manganese Oxides Nanoparticles and Their Oxidation Catalysis

    幸谷真芸, 林愛理, 鎌田慶吾, 原亨和

    日本化学会春季年会講演予稿集(Web)   102nd   2022

  • Development of Heterogeneous Manganese Catalysts for Alcohol Transformations through Borrowing Hydrogen Methodology

    喜多祐介, 桑原翠, 鎌田慶吾, 原亨和

    日本化学会春季年会講演予稿集(Web)   102nd   2022

  • 担持Ni触媒を用いたバイオマス由来化合物のアミノ化反応による2,5-ビスアミノメチルフランの合成

    大吉孝明, 喜多祐介, 鎌田慶吾, 原亨和

    触媒討論会討論会A予稿集(CD-ROM)   130th   2022

  • Heterogeneous Co catalyst for the construction of C-C bond by borrowing hydrogen strategy

    SUARSIH Endah, 喜多祐介, 鎌田慶吾, 原亨和

    触媒討論会討論会A予稿集(CD-ROM)   130th   2022

  • Construction of new chemical bonds through borrowing hydrogen strategy over a heterogeneous cobalt catalyst

    ENDAH Suarsih, 喜多祐介, 鎌田慶吾, 原亨和

    有機合成シンポジウム講演予稿集   120th (Web)   2022

  • 不均一系低原子価マンガン触媒によるアルコール変換反応

    喜多祐介, 桑原翠, 鎌田慶吾, 原亨和

    有機合成シンポジウム講演予稿集   120th (Web)   2022

  • ペロブスカイト酸化物の酸塩基性質によるシアノシリル化反応

    相原健司, 青木航流, 鎌田慶吾, 原亨和

    触媒討論会討論会A予稿集(CD-ROM)   130th   2022

  • 前駆体結晶化法によるメソポーラスOMS-1ナノ粒子の合成と酸化触媒作用

    鎌田慶吾, 幸谷真芸, 林愛理, 原亨和

    触媒討論会討論会A予稿集(CD-ROM)   130th   2022

  • リン酸鉄ナノ粒子触媒を用いた直接メタン酸化によるホルムアルデヒド合成

    松田蒼依, 舘野晴香, 鎌田慶吾, 原亨和

    触媒討論会講演予稿集(CD-ROM)   129th   2022

  • トドロカイト型マンガン酸化物ナノ粒子の合成と酸化触媒応用

    幸谷真芸, 林愛理, 鎌田慶吾, 原亨和

    触媒討論会講演予稿集(CD-ROM)   129th   2022

  • 鉄を含むペロブスカイト触媒による分子状酸素を用いたハロゲン化ビニルからα-ハロケトンの合成

    柴田聡美, 鎌田慶吾, 原亨和

    触媒討論会講演予稿集(CD-ROM)   129th   2022

  • Co/SiO2触媒を用いたニトリルの水素化による一級アミン合成

    加藤可百子, 喜多祐介, 鎌田慶吾, 原亨和

    触媒討論会討論会A予稿集(CD-ROM)   128th   2021

  • Oxidative Cleavage Reaction of Alkenes with Molecular Oxygen Catalyzed by High-valent Iron-containing Perovskite-type Oxides

    柴田聡美, 鎌田慶吾, 原亨和

    日本化学会春季年会講演予稿集(Web)   101st   2021

  • Synthesis of Murdochite-type Oxide Mg6MnO8 Nanoparticles and Their Catalytic Oxidation Properties

    林愛理, 田村高敏, 鎌田慶吾, 原亨和

    日本化学会春季年会講演予稿集(Web)   101st   2021

  • Effects of MgO on Direct Amination of Alcohols over Ru Catalysts

    喜多祐介, 桑原翠, 鎌田慶吾, 原亨和

    日本化学会春季年会講演予稿集(Web)   101st   2021

  • ヒドロシランを用いた液相還元法による大気安定性Ni触媒の調製

    竹内舜, 喜多祐介, 鎌田慶吾, 原亨和

    触媒討論会討論会A予稿集(CD-ROM)   128th   2021

  • 担持鉄触媒を用いたカルボニル化合物の還元的アミノ化反応による一級アミン合成

    新井麻友, 喜多祐介, 鎌田慶吾, 原亨和

    触媒討論会討論会A予稿集(CD-ROM)   128th   2021

  • Primary Amine Synthesis by Hydrogenation of Nitriles over Supported Cobalt Catalysts

    加藤可百子, 喜多祐介, 鎌田慶吾, 原亨和

    日本化学会春季年会講演予稿集(Web)   101st   2021

  • Borrowing Hydrogen法を用いた変換反応を可能とする不均一系マンガン触媒の開発

    桑原翠, 喜多祐介, 鎌田慶吾, 原亨和

    触媒討論会討論会A予稿集(CD-ROM)   128th   2021

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  • Effect of Iron phosphate Catalysts on Direct Synthesis of Formaldehyde from Methane

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    青野竜征, 山口ゆい, 林愛理, 鎌田慶吾, 原亨和

    日本化学会春季年会講演予稿集(CD-ROM)   100th   2020

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  • Synthesis of Bismuth Phosphate Catalysts for Direct Synthesis of Formaldehyde from Methane

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  • リン酸鉄触媒を用いたメタンからホルムアルデヒドの直接合成と反応機構解明

    松田蒼依, 舘野晴香, 鎌田慶吾, 原亨和

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  • 高表面積β-MnO2触媒によるアルコール酸化反応

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  • リン酸ビスマス触媒によるメタンからホルムアルデヒドへの直接合成

    小原和彦, 鎌田慶吾, 鎌田慶吾, 原亨和

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    松田蒼依, 舘野晴香, 鎌田慶吾, 原亨和

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  • Direct Synthesis of Formaldehyde from Methane by an Iron Phosphate Catalyst and Reaction Mechanism

    松田蒼依, 舘野晴香, 鎌田慶吾, 原亨和

    日本化学会春季年会講演予稿集(CD-ROM)   100th   2020

  • Benzylic C–H fluorination over supported silver catalyst Reviewed

    Yusuke Kita, Shunsuke Shigetani, Keigo Kamata, Michikazu Hara

    Molecular Catalysis   475   2019.10

  • Structure-Function Relationships in Fructose Dehydration to 5-Hydroxymethylfurfural under Mild Conditions by Porous Ionic Crystals Constructed with Analogous Building Blocks

    Takumi Yamada, Keigo Kamata, Eri Hayashi, Michikazu Hara, Sayaka Uchida

    ChemCatChem   11 ( 16 )   3745 - 3749   2019.8

  • トクシュウ CO ₂ フリー スイソ サプライチェーン ニ カカワル ショクバイ カイハツ ドウコウ

    61 ( 2 )   72 - 77   2019.4

  • 貴金属触媒を使わずバイオマスから合成できるプラスチック原料

    鎌田慶吾, 原亨和

    コンバーテック   47 ( 5 )   2019

  • 高原子価鉄を含むペロブスカイト型酸化物触媒による分子状酸素を用いたアルカン類の選択酸化反応

    柴田聡美, 鎌田慶吾, 鎌田慶吾, 原亨和, 原亨和

    日本化学会春季年会講演予稿集(CD-ROM)   99th   2019

  • 5-ヒドロキシメチルフルフラールの酸化反応に有効な高表面積β-MnO2の合成とキャラクタリゼーション

    山口ゆい, 林愛理, 鎌田慶吾, 原亨和

    日本化学会春季年会講演予稿集(CD-ROM)   99th   2019

  • 高原子価鉄を含むペロブスカイト型酸化物を触媒とした分子状酸素を用いたアルカン類の選択酸化反応

    柴田聡美, 鎌田慶吾, 原亨和

    酸化反応討論会講演要旨集   52nd   2019

  • 種々の結晶構造をもつ二酸化マンガン触媒による5-ヒドロキシメチルフルフラールから2,5-フランジカルボン酸への酸化反応

    林愛理, 山口ゆい, 鎌田慶吾, 角田直樹, 熊谷悠, 大場史康, 原亨和

    日本化学会春季年会講演予稿集(CD-ROM)   99th   2019

  • 高表面積β-MnO2触媒の合成と酸化反応への応用

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  • アミノ酸法によるムルドカイト型酸化物Mg6MnO8ナノ粒子の合成とその触媒特性

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    酸化反応討論会講演要旨集   52nd   2019

  • 中高生会員ライジング

    原 亨和, 宮本 一弘

    化学と教育   66 ( 10 )   506 - 507   2018.10

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  • 水素エネルギーキャリアの現状と展望 電子化物または水素化物を利用したアンモニア合成

    北野政明, 原亨和, 細野秀雄

    太陽エネルギー   44 ( 4 )   23‐30   2018.7

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  • 水中で機能する固体ルイス酸とその応用—Heterogeneous Lewis Acid Workable in Water—特集 固体酸触媒の最新の研究動向

    原 亨和

    触媒 = Catalysts & catalysis   60 ( 1 )   27 - 32   2018.1

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  • 高原子価鉄を含むペロブスカイト型触媒による分子状酸素を用いたアルカン類の選択酸化反応

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    触媒討論会討論会A予稿集   122nd   2018

  • 金属リン酸塩触媒による分子状酸素を用いたメタンの選択酸化反応

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  • A high performance catalyst of shape-specific ruthenium nanoparticles for production of primary amines by reductive amination of carbonyl compounds

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    Chemical Science   9 ( 27 )   5949 - 5956   2018

  • 種々の結晶構造をもつ二酸化マンガン触媒による5-ヒドロキシメチルフルフラールの酸化反応

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  • BaRuO3ペロブスカイト触媒による分子状酸素を酸化剤としたスルフィドの酸化反応

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  • Reductive Amination of Carbonyl Compounds Catalyzed by Ruthenium Nanoparticles on Nb2O5

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  • Ce酸化物系触媒を用いた低温電場印加反応場におけるメタン酸化カップリング

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  • Ce-P-O系触媒を用いた低温電場中でのメタン酸化カップリング

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  • Acetalization of Carbonyl Compounds by a Bifunctional Cerium Phosphate Catalyst

    68 ( 8 )   580 - 585   2017.8

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  • カルシウムアミド上にフラットな形状で自己組織化したRuナノ粒子によるアンモニア合成

    井上泰徳, 北野政明, 岸田和久, 阿部仁, 阿部仁, 阿部仁, 丹羽尉博, 笹瀬雅人, 横山壽治, 原亨和, 原亨和, 細野秀雄, 細野秀雄, 細野秀雄

    Photon Factory News   35 ( 1 )   23‐27   2017.5

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  • Amino Acid-Aided Synthesis of a Hexagonal SrMnO<inf>3</inf> Nanoperovskite Catalyst for Aerobic Oxidation Reviewed

    Kosei Sugahara, Keigo Kamata, Satoshi Muratsugu, Michikazu Hara

    ACS Omega   2 ( 4 )   1608 - 1616   2017.4

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  • 二酸化マンガンによる5-ヒドロキシメチルフルフラールからの2,5-フランジカルボン酸合成

    林愛理, 駒野谷将, 鎌田慶吾, 原亨和

    触媒討論会講演予稿集   119th   2017

  • 高比表面積SrMnO3ペロブスカイト型酸化物触媒の合成と分子状酸素を酸化剤とした酸化触媒作用

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  • 水素化カルシウム担持ルテニウム触媒を用いたアンモニア合成

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    触媒討論会討論会A予稿集   120th   2017

  • 高密度リン酸修飾二酸化チタンによるグルコースからのヒドロキシルメチルフルフラールの高効率合成

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    日本化学会春季年会講演予稿集(CD-ROM)   97th   2017

  • 二酸化マンガン触媒による5-ヒドロキシメチルフルフラールの酸化反応機構の検討

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    日本化学会春季年会講演予稿集(CD-ROM)   97th   2017

  • 担持金属触媒を用いたベンゼンとアンモニアからの直接アニリン合成

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    触媒討論会討論会A予稿集   120th   2017

  • 高比表面積SrMnO3ペロブスカイト型酸化物触媒による分子状酸素を酸化剤とした酸化触媒作用

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    触媒討論会討論会A予稿集   120th   2017

  • 高密度リン酸修飾二酸化チタンによるグルコースからのヒドロキシルメチルフルフラールの高効率合成

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    触媒討論会講演予稿集   119th   2017

  • ベンゼンとアンモニアからアニリン直接合成を可能とする触媒の構築

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    触媒討論会講演予稿集   119th   2017

  • 二元機能リン酸セリウム触媒による官能基選択的アセタール化反応

    鎌田慶吾, 鎌田慶吾, 金井俊祐, 長原一平, 喜多祐介, 原亨和, 原亨和

    触媒討論会討論会A予稿集   120th   2017

  • Synthesis of a hexagonal SrMnO3 perovskite catalyst and its oxidation catalysis with dioxygen as an oxidant Title

    鎌田慶吾, 鎌田慶吾, 川崎周馬, 菅原紘成, 原亨和, 原亨和

    触媒討論会講演予稿集   119th   2017

  • カルボニル化合物の還元的アミノ化反応による一級アミン合成

    駒野谷将, 杵村峻志, 喜多祐介, 鎌田慶吾, 原亨和

    日本化学会春季年会講演予稿集(CD-ROM)   97th   2017

  • 二元機能リン酸セリウム触媒を用いた5-ヒドロキシメチルフルフラールのアセタール化反応

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    日本化学会春季年会講演予稿集(CD-ROM)   97th   2017

  • Ru触媒によるカルボニル化合物の還元的アミノ化反応

    駒野谷将, 杵村峻志, 喜多祐介, 鎌田慶吾, 原亨和

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  • 二元機能リン酸セリウム触媒による5-ヒドロキシメチルフルフラールのアセタール化反応

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    触媒討論会講演予稿集   119th   2017

  • エレクトライドアンモニア合成触媒—Electride for Catalytic Ammonia Synthesis—特集 アンモニア合成の最新動向

    原 亨和

    ファインケミカル : 調査・資料・報道・抄録   45 ( 3 )   19 - 26   2016.3

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  • アンモニアから電気をつくる 新触媒でアンモニアをつくる 03 100年不変のアンモニア合成法を大きく変えるか?新触媒の開発

    細野秀雄, 細野秀雄, 原亨和, 北野政明

    JST News   2016 ( Feb )   8 - 11   2016.2

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  • エレクトライドを利用した新規なアンモニア合成触媒

    北野政明, 細野秀雄, 細野秀雄, 原亨和

    ペトロテック   39 ( 2 )   127‐132   2016.2

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  • 担持金属触媒を用いたフルフラールの還元的アミノ化反応

    杵村峻志, 駒野谷将, 鎌田慶吾, 原亨和

    触媒討論会討論会A予稿集   118th   2016

  • 二酸化マンガンによる5-ヒドロキシメチルフルフラールから2,5-フランジカルボン酸への酸化反応

    林愛理, 駒野谷将, 鎌田慶吾, 原亨和

    触媒討論会討論会A予稿集   118th   2016

  • 六方晶BaRuO3の合成と分子状酸素を用いた酸化触媒作用

    加藤裕希, 鎌田慶吾, 原亨和

    触媒討論会討論会A予稿集   118th   2016

  • 希土類リン酸塩触媒による5-ヒドロキシメチルフルフラールのアセタール化反応

    金井俊祐, 長原一平, 鎌田慶吾, 原亨和

    触媒討論会討論会A予稿集   118th   2016

  • リン酸修飾二酸化チタンを用いたグルコースからのヒドロキシルメチルフルフラールの高効率合成

    服部真史, 鎌田慶吾, 原亨和

    触媒討論会討論会A予稿集   118th   2016

  • 担持金属触媒によるアルデヒド類の還元的アミノ化反応

    杵村峻志, 駒野谷将, 鎌田慶吾, 原亨和

    日本化学会春季年会講演予稿集(CD-ROM)   96th   2016

  • 水熱法により合成したリン酸ランタンの酸塩基触媒作用

    長原一平, 鎌田慶吾, 原亨和

    日本化学会春季年会講演予稿集(CD-ROM)   96th   2016

  • 遷移金属酸化物触媒による5-ヒドロキシメチルフルフラールの酸化反応

    林愛理, 駒野谷将, 鎌田慶吾, 原亨和

    日本化学会春季年会講演予稿集(CD-ROM)   96th   2016

  • 六方晶マンガン酸ストロンチウム触媒による選択酸化反応

    川崎周馬, 鎌田慶吾, 原亨和

    日本化学会春季年会講演予稿集(CD-ROM)   96th   2016

  • 水熱合成法によるリン酸ランタンの合成とその酸塩基触媒作用

    長原一平, 鎌田慶吾, 原亨和

    触媒討論会講演予稿集   117th   2016

  • 担持金属触媒を用いたアルデヒド類の還元的アミノ化反応

    杵村峻志, 駒野谷将, 鎌田慶吾, 原亨和

    触媒討論会講演予稿集   117th   2016

  • 遷移金属酸化物触媒による5-ヒドロキシメチルフルフラールから2,5-フランジカルボン酸への酸化反応

    林愛理, 駒野谷将, 鎌田慶吾, 原亨和

    触媒討論会講演予稿集   117th   2016

  • 二酸化マンガンによる5-ヒドロキシメチルフルフラールの酸化反応

    林愛理, 駒野谷将, 鎌田慶吾, 原亨和

    酸化反応討論会講演要旨集   49th   2016

  • 異なるアニオン種を有する12CaO・7Al2O3の塩基触媒特性

    木村温, 井上泰徳, 北野政明, 鎌田慶吾, 原亨和

    触媒討論会講演予稿集   117th   2016

  • 六方晶ペロブスカイト型BaRuO3触媒を用いた芳香族炭化水素の酸化反応

    加藤裕希, 鎌田慶吾, 原亨和

    日本化学会春季年会講演予稿集(CD-ROM)   96th   2016

  • 希土類リン酸塩触媒の合成とその酸塩基触媒作用

    長原一平, 金井俊祐, 喜多祐介, 鎌田慶吾, 原亨和

    触媒討論会討論会A予稿集   118th   2016

  • Ptナノ粒子-TiO2複合触媒を用いたグリセリンからの乳酸合成

    駒野谷将, 中島清隆, 北野政明, 鎌田慶吾, 原亨和, 原亨和

    日本化学会春季年会講演予稿集(CD-ROM)   96th   2016

  • 六方晶ペロブスカイト型BaRuO3の合成とその酸化触媒作用

    加藤裕希, 鎌田慶吾, 原亨和

    触媒討論会講演予稿集   117th   2016

  • 各種アニオンを内包した12CaO・7Al2O3の骨格構造に起因する塩基触媒特性

    木村温, 井上泰徳, 北野政明, 鎌田慶吾, 原亨和

    日本化学会春季年会講演予稿集(CD-ROM)   96th   2016

  • The effect of electrolyte concentration on silicon nanoparticles prepared by laser ablation in liquid Reviewed

    Pattarin Chewchinda, Yoshitaka Kitamoto, Hiroshi Funakubo, Michikazu Hara, Osamu Odawara, Hiroyuki Wada

    2015.5

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  • 六方晶SrMnO3触媒による分子状酸素を用いた選択酸化反応

    川崎周馬, 鎌田慶吾, 原亨和

    触媒討論会討論会A予稿集   116th   2015

  • リン酸処理チタン触媒を用いた水溶液中での糖からのフラン類合成

    野間遼平, 野間遼平, 中島清隆, 中島清隆, 鎌田慶吾, 北野政明, 林繁信, 原亨和, 原亨和

    触媒討論会討論会A予稿集   116th   2015

  • 水の存在下でも働く不均一系ルイス酸触媒

    原 亨和

    現代化学 = Chemistry today   ( 520 )   30 - 33   2014.7

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  • Surface modification of Y2O3:Er,Yb upconversion nanoparticles prepared by laser ablation in water

    Kobayashi Hiroki, P. CHEWCHINDA, Chewchinda Pattarin, inoue yasunori, FUNAKUBO HIROSHI, HARA MICHIKAZU, ODAWARA OSAMU, Wada Hiroyuki

    Japanese Journal of Applied Physics   53 ( 5 )   2014.5

  • Heterogeneous Lewis acid catalysts workable in water

    Michikazu Hara

    Bulletin of the Chemical Society of Japan   87 ( 9 )   931 - 941   2014

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  • Reaction mechanism on glucose to HMF transformation over titania catalyst

    Noma Ryouhei, Kitano Masaaki, Nakajima Kiyotaka, Hara Michikazu

    Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute   2014f   175   2014

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    DOI: 10.11523/sekiyu.2014f.0_175

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  • Effect of preparation conditions on the acid catalytic properties of protonated titanate nanotubes

    Kitano Masaaki, Nakajima Kiyotaka, Kobayashi Hisayoshi, Hara Michikazu

    Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute   2014   10   2014

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    The effect of hydrothermal treatment on the morphological and acid catalytic properties of titanate nanotubes was examined. Anatase nanoparticles were converted into titanate nanotubes and layered titanate nanorods according to the heating temperature used durign hydrothermal treatment. FT-IR measurement revealed that both Lewis and Bronsted acid sites are formed after hydrothermal treatment at temperatures higher than 323 K. Titanate nanotubes prepared at 423 K exhibited the highest catalytic activity for alkylation reaction.

    DOI: 10.11523/sekiyu.2014.0_10

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  • Acid catalysis of titanium-immobilized mesoporous silica for the Mukaiyama-aldol reastion in water

    Nakajima Kiyotaka, Shintaku Hiroshi, Kitano Masaaki, Hara Michikazu

    Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute   2014   34   2014

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    DOI: 10.11523/sekiyu.2014.0_34

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  • 電子化物を利用したアンモニア合成用触媒材料の開発

    北野政明, 原亨和, 細野秀雄

    スマートプロセス学会誌   2 ( 6 )   293 - 298   2013.11

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  • Catalytic Ammonia Synthesis over Ruthenium-loaded 12CaO 7Al2O3 Electride.

    北野政明, 原亨和, 細野秀雄

    触媒   55 ( 4 )   239 - 245   2013.8

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  • 私の自慢 師曰く, : 言葉の魅力

    原 亨和

    化学と工業 = Chemistry & chemical industry   66 ( 6 )   457 - 459   2013.6

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  • 高分子科学最近の進歩 草や木からポリマー原料を生産する

    原 亨和

    高分子 = High polymers, Japan : polymers   62 ( 4 )   191 - 196   2013.4

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  • エレクトライドによる新規アンモニア合成触媒の開発 : ハーバー-ボッシュ法を超える反応を目指して

    原 亨和

    現代化学 = Chemistry today   ( 505 )   32 - 36   2013.4

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  • 高活性アンモニア合成触媒の開発

    北野政明, 原亨和, 細野秀雄

    化学経済   60 ( 2 )   73 - 77   2013.2

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  • Ammonia synthesis using an electride as a catalyst

    Kitano Masaaki, Inoue Yasunori, Kanbara Shinji, Hara Michikazu, Hosono Hideo

    Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute   2013f   125   2013

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    12CaO·7Al2O3 electride (C12A7:e-)with alow work function was synthesized under a reducing atmosphere by utilizing a stable inorganic oxide, 12CaO·7Al2O3 which is a commercial alumina cement with a mayenite structure. Ru-loaded C12A7:e- exhibited a remarkable catalytic activity for ammonia synthesis and the activation energy was about one-half of that of conventional catalysts. Such high catalytic performance of Ru/C12A7:e- is attributed to efficient electron donation from C12A7:e- to antibonding orbitals of N2 through Ru nanoparticle.

    DOI: 10.11523/sekiyu.2013f.0.125.0

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  • Lewis acid catalysis of WOx/ZrO2 in water

    Nakajima Kiyotaka, Takeda Daiki, Kitano Masaaki, Hara Michikazu

    Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute   2013f   95   2013

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    DOI: 10.11523/sekiyu.2013f.0.95.0

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  • 東京工業大学応用セラミックス研究所

    原 亨和

    觸媒 = Catalyst   54 ( 6 )   422   2012.10

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  • バイオプラ最前線 セルロースバイオマスからの化学資源の生産

    原 亨和

    バイオプラジャーナル = Biopla journal / 企画調査委員会 編   12 ( 2 )   11 - 18   2012.8

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  • セルロース糖化技術および糖の高効率転換技術の確立—Cellulosic Biomass Saccharification and Saccharide Conversion by Heterogeneous Acid Catalysts—特集 バイオリファイナリー最前線

    原 亨和

    Bio industry = バイオインダストリー / シーエムシー出版 編   29 ( 5 )   22 - 31   2012.5

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  • Solid Acid Catalysis of Protonated Titanate Nanotubes

    KITANO MASAAKI, HARA MICHIKAZU

    53 ( 6 )   340 - 345   2011.10

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  • でん粉利用に有用な新しい固体酸触媒

    原 亨和

    でん粉情報 = Starch information / 農畜産業振興機構調査情報部 編   ( 48 )   15 - 18   2011.9

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  • CVD法を用いた窒素含有アモルファスカーボン薄膜の作製

    森 琢麻, 井上 泰徳, 北野 政明, 中島 清隆, 原 亨和

    応用物理学会学術講演会講演予稿集   2011.2   853 - 853   2011.8

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    DOI: 10.11470/jsapmeeting.2011.2.0_853

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  • 技術と産業を創出するKASTの研究成果(第2回)原「エコ固体酸触媒」プロジェクト

    原 亨和

    工業材料 = Engineering materials   59 ( 7 )   67 - 71   2011.7

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  • 固体触媒を用いた環境低負荷セルロース糖化—特集 次世代省エネ・省資源プロセスの開発

    原 亨和

    ケミカルエンジニヤリング = Chemical engineering   56 ( 6 )   451 - 457   2011.6

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  • Do What We Think Right

    HARA Michikazu

    53 ( 3 )   149   2011.4

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  • Processing and solid acidity of zirconia porous sphere particles using organic monolith templates

    Isobe Toshihiro, Uchiyama Shuhei, Matsushita Sachiko, Nakajima Akira, Hara Michikazu, Nakajima Kiyotaka

    Preprints of Annual Meeting of The Ceramic Society of Japan<br> Preprints of Fall Meeting of The Ceramic Society of Japan   2011S   180 - 180   2011

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    DOI: 10.14853/pcersj.2011s.0.180.0

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  • ナフタレンを前駆体にしたアモルファスカーボン半導体材料の合成とその電気特性評価

    菅野 真代, 中島 清隆, 原 亨和, 北野 政明

    応用物理学会学術講演会講演予稿集   2010.2   3568 - 3568   2010.8

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    DOI: 10.11470/jsapmeeting.2010.2.0_3568

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  • ホウ素含有有機化合物を前駆体としたホウ素ドープカーボン半導体の合成と評価

    原 亨和, 北野 政明, 井上 泰徳, 中島 清隆

    応用物理学会学術講演会講演予稿集   2010.2   3570 - 3570   2010.8

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    DOI: 10.11470/jsapmeeting.2010.2.0_3570

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  • ノボラック樹脂の熱分解により調製したアモルファスカーボン薄膜の光起電力特性

    安達 大悟, 井上 泰徳, 北野 政明, 原 亨和, 平野 栄樹

    応用物理学会学術講演会講演予稿集   2010.2   2731 - 2731   2010.8

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    DOI: 10.11470/jsapmeeting.2010.2.0_2731

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  • 環境低負荷なバイオディーゼル製造—Environmentally benign biodiesel production—特集 固体触媒設計でバイオマスをフル活用する!

    原 亨和

    ファインケミカル : 調査・資料・報道・抄録   39 ( 6 )   20 - 27   2010.6

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  • Solid acid catalysis of protonated titanate nanotube Reviewed

    Shokubai   52   366 - 368   2010.3

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  • Needlelike Crystal Growth and Anisotropic Photochemical Reactivity of Ta3N5 Synthesized in Vacuo

    Daling Lu, Michikazu Hara, Takashi Hisatomi, Tsuyoshi Takata, Kazunari Domen

    JOURNAL OF PHYSICAL CHEMISTRY C   113 ( 39 )   17151 - 17155   2009.10

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  • Preparation of a Sulfonated Porous Carbon Catalyst with High Specific Surface Area

    Masaaki Kitano, Keisuke Arai, Atsushi Kodama, Tsutomu Kousaka, Kiyotaka Nakajima, Shigenobu Hayashi, Michikazu Hara

    CATALYSIS LETTERS   131 ( 1-2 )   242 - 249   2009.8

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  • Preparation of a sulfonated porous carbon catalyst with high specific surface area

    Masaaki Kitano, Keisuke Arai, Atsushi Kodama, Tsutomu Kousaka, Kiyotaka Nakajima, Shigenobu Hayashi, Michikazu Hara

    Catalysis Letters   131 ( 1-2 )   242 - 249   2009.8

  • Preparation of solid acid carbon coating on the surface of TiO2 by photo-CVD of gaseous aromatic hydrocarbons

    Akira Nakajima, Katsuhiro Horie, Michikazu Hara, Masaaki Kitano, Toshihiro Isobe, Yoshikazu Kameshima, Kiyoshi Okada

    Catalysis Communications   10 ( 13 )   1670 - 1673   2009.7

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  • Preparation of solid acid carbon coating on the surface of TiO<inf>2</inf> by photo-CVD of gaseous aromatic hydrocarbons

    Akira Nakajima, Katsuhiro Horie, Michikazu Hara, Masaaki Kitano, Toshihiro Isobe, Yoshikazu Kameshima, Kiyoshi Okada

    Catalysis Communications   10 ( 13 )   1670 - 1673   2009.7

  • Preparation of solid acid carbon coating on the surface of TiO2 by photo-CVD of gaseous aromatic hydrocarbons

    Akira Nakajima, Katsuhiro Horie, Michikazu Hara, Masaaki Kitano, Toshihiro Isobe, Yoshikazu Kameshima, Kiyoshi Okada

    CATALYSIS COMMUNICATIONS   10 ( 13 )   1670 - 1673   2009.7

  • Adsorption-enhanced hydrolysis of /?-1,4-glucan on graphene-based amorphous carbon bearing so<inf>3</inf>H, COOH, and OH groups

    Masaaki Kitano, Daizo Yamaguchi, Satoshi Suganuma, Kiyotaka Nakajima, Hideki Kato, Shigenobu Hayashi, Michikazu Hara

    Langmuir   25 ( 9 )   5068 - 5075   2009.5

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  • Adsorption-Enhanced Hydrolysis of beta-1,4-Glucan on Graphene-Based Amorphous Carbon Bearing SO3H, COOH, and OH Groups

    Masaaki Kitano, Daizo Yamaguchi, Satoshi Suganuma, Kiyotaka Nakajima, Hideki Kato, Shigenobu Hayashi, Michikazu Hara

    LANGMUIR   25 ( 9 )   5068 - 5075   2009.5

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  • 環境低負荷を目指した固体触媒による化学資源の生産—Environmentally benign production of chemical resources by a heterogeneous catalyst—特集 元素戦略を推進するセラミックス材料技術

    原 亨和

    Ceramics Japan = セラミックス : bulletin of the Ceramic Society of Japan   44 ( 5 )   354 - 359   2009.5

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  • Hydrolysis of cellulose by a solid acid catalyst under optimal reaction conditions

    Daizo Yamaguchi, Masaaki Kitano, Satoshi Suganuma, Kiyotaka Nakajima, Hideki Kato, Michikazu Hara

    Journal of Physical Chemistry C   113 ( 8 )   3181 - 3188   2009.2

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  • Hydrolysis of cellulose by a solid acid catalyst under optimal reaction conditions

    Daizo Yamaguchi, Masaaki Kitano, Satoshi Suganuma, Kiyotaka Nakajima, Hideki Kato, Michikazu Hara

    Journal of Physical Chemistry C   113 ( 8 )   3181 - 3188   2009.2

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    DOI: 10.1021/jp808676d

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  • Environmentally benign production of biodiesel using heterogeneous catalysts

    Michikazu Hara

    ChemSusChem   2 ( 2 )   129 - 135   2009.2

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    DOI: 10.1002/cssc.200800222

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  • Environmentally benign production of biodiesel using heterogeneous catalysts

    Michikazu Hara

    ChemSusChem   2 ( 2 )   129 - 135   2009.2

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    DOI: 10.1002/cssc.200800222

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  • Hydrolysis of Cellulose by a Solid Acid Catalyst under Optimal Reaction Conditions

    Daizo Yamaguchi, Masaaki Kitano, Satoshi Suganuma, Kiyotaka Nakajima, Hideki Kato, Michikazu Hara

    JOURNAL OF PHYSICAL CHEMISTRY C   113 ( 8 )   3181 - 3188   2009.2

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  • Amorphous carbon bearing sulfonic acid groups in mesoporous silica as a selective catalyst

    Kiyotaka Nakajima, Mai Okamura, Junko N. Kondo, Kazunari Domen, Takashi Tatsumi, Shigenobu Hayashi, Michikazu Hara

    Chemistry of Materials   21 ( 1 )   186 - 193   2009.1

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    DOI: 10.1021/cm801441c

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  • Amorphous carbon bearing sulfonic acid groups in mesoporous silica as a selective catalyst

    Kiyotaka Nakajima, Mai Okamura, Junko N. Kondo, Kazunari Domen, Takashi Tatsumi, Shigenobu Hayashi, Michikazu Hara

    Chemistry of Materials   21 ( 1 )   186 - 193   2009.1

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  • Amorphous Carbon Bearing Sulfonic Acid Groups in Mesoporous Silica as a Selective Catalyst

    Kiyotaka Nakajima, Mai Okamura, Junko N. Kondo, Kazunari Domen, Takashi Tatsumi, Shigenobu Hayashi, Michikazu Hara

    CHEMISTRY OF MATERIALS   21 ( 1 )   186 - 193   2009.1

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  • ナノグラフェン固体酸触媒—Nanographen solid acid catalyst—特集 炭素材料--熱い注目を集める材料

    原 亨和

    触媒 = Catalysts & catalysis   51 ( 1 )   39 - 44   2009.1

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  • Preparation of solid acid carbon coating on the surface of TiO2 by photo-CVD

    Akira Nakajima, Katsuhiro Horie, MICHIKAZU HARA, Masaaki Kitano, Toshihiro Isobe, YOSHIKAZU KAMESHIMA, KIYOSHI OKADA

    Catalysis Communications   10   1670窶骭€1673   2009

  • Hydrolysis of Cellulose by a Solid Acid Catalyst under Optimal Reaction Conditions

    Daizo Yamaguchi, Masaaki Kitano, satoshi suganuma, Kiyotaka Nakajima, Hideki Kato, MICHIKAZU HARA

    Journal of Physical Chemistry C   113   3181 - 3188   2009

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  • Needlelike crystal growth and anisotropic photochemical reactivity of Ta<inf>3</inf>N<inf>5</inf> synthesized in vacuo

    Daling Lu, Michikazu Hara, Takashi Hisatomi, Tsuyoshi Takata, Kazunari Domen

    Journal of Physical Chemistry C   113 ( 39 )   17151 - 17155   2009

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  • Preparation of solid acid carbon coating by photo-polymerization of gaseous aromatic hydrocarbon

    Horie Katsuhiro, Nakazima Akira, Isobe Toshihiro, Kameshima Yoshikazu, Kitano Masaaki, Hara Michiazu, Okada kiyoshi

    Preprints of Annual Meeting of The Ceramic Society of Japan<br> Preprints of Fall Meeting of The Ceramic Society of Japan   2009S   557 - 557   2009

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    DOI: 10.14853/pcersj.2009s.0.557.0

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  • Hydrolysis of cellulose by amorphous carbon bearing SO<inf>3</inf>H, COOH, and OH groups

    Satoshi Suganuma, Kiyotaka Nakajima, Masaaki Kitano, Daizo Yamaguchi, Hideki Kato, Shigenobu Hayashi, Michikazu Hara

    Journal of the American Chemical Society   130 ( 38 )   12787 - 12793   2008.9

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  • Hydrolysis of cellulose by amorphous carbon bearing SO3H, COOH, and OH groups

    Satoshi Suganuma, Kiyotaka Nakajima, Masaaki Kitano, Daizo Yamaguchi, Hideki Kato, Shigenobu Hayashi, Michikazu Hara

    Journal of the American Chemical Society   130 ( 38 )   12787 - 12793   2008.9

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    DOI: 10.1021/ja803983h

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  • Hydrolysis of cellooligosaccharide using carbon-based solid acid catalyst

    KITANO Masaaki, YAMAGUCHI Daizo, SUGANUMA Satoshi, NAKAJIMA Kiyotaka, KATO Hideki, HAYASHI Shigenobu, HARA Michikazu

    触媒   50 ( 6 )   468 - 470   2008.9

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  • Hydrolysis of cellulose by amorphous carbon bearing SO3H, COOH, and OH groups

    Satoshi Suganuma, Kiyotaka Nakajima, Masaaki Kitano, Daizo Yamaguchi, Hideki Kato, Shigenobu Hayashi, Michikazu Hara

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   130 ( 38 )   12787 - 12793   2008.9

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  • 茂木健一郎と愉しむ科学のクオリア(28)夢の固体触媒を作る

    茂木 健一郎, 原 亨和

    日経サイエンス   38 ( 11 )   100 - 105   2008.9

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  • 液体の反応場を固体の反応場に変換(ヘッドライン:さまざまな反応場の世界)

    原 亨和

    化学と教育   56 ( 11 )   548 - 549   2008

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    硫酸は工業的に重要な化学資源を製造するのに必要不可欠な触媒である一方,反応後の製品との分離,回収,廃棄等に多くのエネルギーを要する。可能な限り環境に与える負荷を低減した生産が求められる現在,硫酸触媒に依存する化成品製造の低環境負荷化が重要である。本稿では硫酸触媒の代替となる新しいタイプの固体酸触媒を概説する。

    DOI: 10.20665/kakyoshi.56.11_548

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  • Environmentally benign production of chemicals and energy using a carbon-based strong solid acid

    Kiyotaka Nakajima, Michikazu Hara, Shigenobu Hayashi

    Journal of the American Ceramic Society   90 ( 12 )   3725 - 3734   2007.12

  • Lanthanum-indium oxysulfide as a visible light driven photocatalyst for water splitting

    Kiyonori Ogisu, Akio Ishikawa, Kentaro Teramura, Kenji Toda, Michikazu Hara, Kazunari Domen

    Chemistry Letters   36 ( 7 )   854 - 855   2007.7

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  • Lanthanum-indium oxysulfide as a visible light driven photocatalyst for water splitting

    Kiyonori Ogisu, Akio Ishikawa, Kentaro Teramura, Kenji Toda, Michikazu Hara, Kazunari Domen

    CHEMISTRY LETTERS   36 ( 7 )   854 - 855   2007.7

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  • Zinc and titanium spinel oxynitride (Zn<inf>x</inf>TiO<inf>y</inf>N <inf>z</inf>) as a d0-d10 complex photocatalyst with visible light activity

    Takashi Hisatomi, Kazuya Hasegawa, Kentaro Teramura, Tsuyoshi Takata, Michikazu Hara, Kazunari Domen

    Chemistry Letters   36 ( 4 )   558 - 559   2007.4

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  • Modification of (Zn1+xGe)(N2Ox) solid solution as a visible light driven photocatalyst for overall water splitting

    Yungi Lee, Kentaro Teramura, Michikazu Hara, Kazunari Domen

    CHEMISTRY OF MATERIALS   19 ( 8 )   2120 - 2127   2007.4

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  • Modification of (Zn<inf>1+x</inf>Ge)(N<inf>2</inf>O<inf>x</inf>) solid solution as a visible light driven photocatalyst for overall water splitting

    Yungi Lee, Kentaro Teramura, Michikazu Hara, Kazunari Domen

    Chemistry of Materials   19 ( 8 )   2120 - 2127   2007.4

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  • Zinc and titanium spinel oxynitride (ZnxTiOyNz) as a d(0)-d(10) complex photocatalyst with visible light activity

    Takashi Hisatomi, Kazuya Hasegawa, Kentaro Teramura, Tsuyoshi Takata, Michikazu Hara, Kazunari Domen

    CHEMISTRY LETTERS   36 ( 4 )   558 - 559   2007.4

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  • Hydrothermal synthesis of fine NaTaO3 powder as a highly efficient photocatalyst for overall water splitting

    Yungi Lee, Tomoaki Watanabe, Tsuyoshi Takata, Michikazu Hara, Masahiro Yoshimura, Kazunari Domen

    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN   80 ( 2 )   423 - 428   2007.2

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  • Zinc germanium oxynitride as a photocatalyst for overall water splitting under visible light

    Yungi Lee, Hiroaki Terashima, Yoshiki Shimodaira, Kentaro Teramura, Michikazu Hara, Hisayoshi Kobayashi, Kazunari Domen, Masatomo Yashima

    Journal of Physical Chemistry C   111 ( 2 )   1042 - 1048   2007.1

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  • Zinc germanium oxynitride as a photocatalyst for overall water splitting under visible light

    Yungi Lee, Hiroaki Terashima, Yoshiki Shimodaira, Kentaro Teramura, Michikazu Hara, Hisayoshi Kobayashi, Kazunari Domen, Masatomo Yashima

    JOURNAL OF PHYSICAL CHEMISTRY C   111 ( 2 )   1042 - 1048   2007.1

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  • Environmentally benign production of chemicals and energy using a carbon-based strong solid acid

    KIYOTAKA NAKAJIMA, HAYASHI SHIGENOBU, MICHIKAZU HARA

    Journal of the American Ceramics Society   90 ( 12 )   3725   2007

  • Visible-light-driven photocatalytic behavior of tantalum-oxynitride and nitride

    T. Takata, G. Hitoki, J. N. Kondo, M. Hara, H. Kobayashi, K. Domen

    RESEARCH ON CHEMICAL INTERMEDIATES   33 ( 1-2 )   13 - 25   2007

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  • Hydrothermal synthesis of fine NaTaO<inf>3</inf> powder as a highly efficient photocatalyst for overall water splitting

    Yungi Lee, Tomoaki Watanabe, Tsuyoshi Takata, Michikazu Hara, Masahiro Yoshimura, Kazunari Domen

    Bulletin of the Chemical Society of Japan   80 ( 2 )   423 - 428   2007

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  • Visible-light-driven photocatalytic behavior of tantalum-oxynitride and nitride

    T. Takata, G. Hitoki, J. N. Kondo, M. Hara, H. Kobayashi, K. Domen

    Research on Chemical Intermediates   33 ( 1-2 )   13 - 25   2007

  • kagaku

    hara m

    Abstract of annual meeting of the Surface Science of Japan   27   10 - 10   2007

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    DOI: 10.14886/sssj.27.0.10.0

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  • 特別寄稿 環境・エネルギー問題の解決を目指した固体酸触媒の開発—化学品特集号

    原 亨和

    ENEOS technical review   48 ( 4 )   142 - 146   2006.12

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  • Effect of high-pressure ammonia treatment on the activity of Ge <inf>3</inf>N<inf>4</inf> photocatalyst for overall water splitting

    Yungi Lee, Tomoaki Watanabe, Tsuyoshi Takata, Michikazu Hara, Masahiro Yoshimura, Kazunari Domen

    Journal of Physical Chemistry B   110 ( 35 )   17563 - 17569   2006.9

  • Development of highly active SO<inf>3</inf>H-modified hybrid mesoporous catalyst

    Kiyotaka Nakajima, Ikuyoshi Tomita, Michikazu Hara, Shigenobu Hayashi, Kazunari Domen, Junko N. Kondo

    Catalysis Today   116 ( 2 SPEC. ISS. )   151 - 156   2006.8

  • Acid-catalyzed reactions on flexible polycyclic aromatic carbon in amorphous carbon

    Mai Okamura, Atsushi Takagaki, Masakazu Toda, Junko N. Kondo, Kazunari Domen, Takashi Tatsumi, Michikazu Hara, Shigenobu Hayashi

    Chemistry of Materials   18 ( 13 )   3039 - 3045   2006.6

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  • Acid-catalyzed reactions on flexible polycyclic aromatic carbon in amorphous carbon

    M Okamura, A Takagaki, M Toda, JN Kondo, K Domen, T Tatsumi, M Hara, S Hayashi

    CHEMISTRY OF MATERIALS   18 ( 13 )   3039 - 3045   2006.6

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  • Synthesis of crystallized mesoporous transition metal oxides by silicone treatment of the oxide precursor

    N Shirokura, K Nakajima, A Nakabayashi, DL Lu, M Hara, K Domen, T Tatsumi, JN Kondo

    CHEMICAL COMMUNICATIONS   Vol. ( 20 )   2188 - 2190   2006.5

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  • 砂糖からつくるエコロジー触媒--硫酸に代わる新しい固体酸

    原 亨和

    化学 = Chemistry   61 ( 5 )   30 - 33   2006.5

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  • Effect of 10 MPa ammonia treatment on the activity of visible light responsive Ta<inf>3</inf>N<inf>5</inf> photocatalyst

    Yungi Lee, Kota Nukumizu, Tomoaki Watanabe, Tsuyoshi Takata, Michikazu Hara, Masahiro Yoshimura, Kazunari Domen

    Chemistry Letters   35 ( 4 )   352 - 353   2006.4

  • バイオディーゼル触媒を糖からつくる--液体硫酸をしのぐカーボン系固体硫酸—特集 バイオマスとバイオエネルギー

    原 亨和

    Bionics   3 ( 2 )   34 - 38   2006.2

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  • 新しい固体酸 -カーボン系固体酸- Invited

    高垣敦, 原亨和

    ペトロテック   29 ( 6 )   411 - 416   2006

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  • Synthesis of crystallized mesoporous transition metal oxides by silicone treatment of the oxide precursor

    Nao Shirokura, Kiyotaka Nakajima, Akira Nakabayashi, Daling Lu, Michikazu Hara, Kazunari Domen, Takashi Tatsumi, Junko N. Kondo

    Chemical Communications   Vol. ( 20 )   2188 - 2190   2006

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  • Development of highly active SO3H-modified hybrid mesoporous catalyst

    KIYOTAKA NAKAJIMA, IKUYOSHI TOMITA, MICHIKAZU HARA, Shigenobu Hayashi, KAZUNARI DOMEN, JUNKO NOMURA

    Catalysis Today   116   151   2006

  • Carbon-based protonic solid as a replacement for sulfuric acid

    Hara Michikazu

    Preprints of Annual Meeting of The Ceramic Society of Japan<br> Preprints of Fall Meeting of The Ceramic Society of Japan   2006F   463 - 463   2006

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    The chemical industry is currently searching for a stable, strong solid acid for PEFC and the eco-friendly production of chemicals. However, satisfactory solid acid has never been devised to date.
    Carbon-based solid acid -a novel strong solid acid - functions as a replacement catalyst for sulfuric acid, exhibiting remarkable catalytic performance.

    DOI: 10.14853/pcersj.2006f.0.463.0

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  • Green chemistry: Biodiesel made with sugar catalyst

    Masakazu Toda, Atsushi Takagaki, Mai Okamura, Junko N. Kondo, Shigenobu Hayashi, Kazunari Domen, Michikazu Hara

    Nature   438 ( 7065 )   178 - 178   2005.11

  • Overall water splitting on (Ga<inf>1-x</inf>Zn<inf>x</inf>)(N <inf>1-x</inf>O<inf>x</inf>) solid solution photocatalyst: Relationship between physical properties and photocatalytic activity

    Kazuhiko Maeda, Kentaro Teramura, Tsuyoshi Takata, Michikazu Hara, Nobuo Saito, Kenji Toda, Yasunobu Inoue, Hisayoshi Kobayashi, Kazunari Domen

    Journal of Physical Chemistry B   109 ( 43 )   20504 - 20510   2005.11

  • Green chemistry - Biodiesel made with sugar catalyst

    M Toda, A Takagaki, M Okamura, JN Kondo, S Hayashi, K Domen, M Hara

    NATURE   438 ( 7065 )   178 - 178   2005.11

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  • A stable and highly active hybrid mesoporous solid acid catalyst

    Kiyotaka Nakajima, Ikuyoshi Tomita, Michikazu Hara, Shigenobu Hayashi, Kazunari Domen, Junko N. Kondo

    Advanced Materials   17 ( 15 )   1839 - 1842   2005.8

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  • Triblock copolymer-assisted synthesis of a hybrid mesoporous ethenylene-silica with 2D hexagonal structure and large pores

    Kiyotaka Nakajima, Ikuyoshi Tomita, Michikazu Hara, Shigenobu Hayashi, Kazunari Domen, Junko N. Kondo

    Journal of Materials Chemistry   15 ( 24 )   2362 - 2368   2005.6

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    DOI: 10.1039/b501170a

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  • GaN:ZnO solid solution as a photocatalyst for visible-light-driven overall water splitting

    Kazuhiko Maeda, Tsuyoshi Takata, Michikazu Hara, Nobuo Saito, Yasunobu Inoue, Hisayoshi Kobayashi, Kazunari Domen

    Journal of the American Chemical Society   127 ( 23 )   8286 - 8287   2005.6

  • Water Cleavage by (Oxy)nitride Photocatalysts

    HARA MICHIKAZU, INOUE YASUNOBU, DOMEN KAZUNARI

    47 ( 4 )   261 - 266   2005.6

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  • Preparation and crystallization characteristics of mesoporous TiO <inf>2</inf> and mixed oxides

    Junko N. Kondo, Tomohiro Yamashita, Kiyotaka Nakajima, Dating Lu, Michikazu Hara, Kazunari Domen

    Journal of Materials Chemistry   15 ( 20 )   2035 - 2040   2005.5

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  • Preparation and characterization of sodium tantalate thin films by hydrothermal-electrochemical synthesis

    Yungi Lee, Tomoaki Watanabe, Tsuyoshi Takata, Junko N. Kondo, Michikazu Hara, Masahiro Yoshimura, Kazunari Domen

    Chemistry of Materials   17 ( 9 )   2422 - 2426   2005.5

  • RuO<inf>2</inf>-loaded β-Ge<inf>3</inf>N<inf>4</inf> as a non-oxide photocatalyst for overall water splitting

    Junya Sato, Nobuo Saito, Yoko Yamada, Kazuhiko Maeda, Tsuyoshi Takata, Junko N. Kondo, Michikazu Hara, Hisayoshi Kobayashi, Kazunari Domen, Yasunobu Inoue

    Journal of the American Chemical Society   127 ( 12 )   4150 - 4151   2005.3

  • Synthesis of highly ordered mesoporous tantalum oxide

    Kiyotaka Nakajima, Michikazu Hara, Kazunari Domen, Junko N. Kondo

    Chemistry Letters   34 ( 3 )   394 - 395   2005.3

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  • Synthesis of highly ordered mesoporous tantalum oxide

    Kiyotaka Nakajima, Michikazu Hara, Kazunari Domen, Junko N. Kondo

    Chemistry Letters   34 ( 3 )   394 - 395   2005.3

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  • スルホン酸基を導入した新規ハイブリッド型メソポーラス材料の調製と酸触媒能

    中島 清隆, 冨田 育義, 原 亨和, 堂免 一成, 林 繁信, 野村 淳子

    触媒 = Catalysts & Catalysis   47 ( 2 )   165 - 167   2005.3

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  • A stable and highly active mesoporous solid acid catalyst

    Kiyotaka Nakajima, IKUYOSHI TOMITA, MICHIKAZU HARA, SHIGENOBU HAYASHI, KAZUNARI DOMEN, JUNKO NOMURA

    Advanced Materials   17 ( 15 )   1839   2005

  • Preparation and crystallization characteristics of mesoporous TiO2 and mixed oxides

    JUNKO NOMURA, Tomohiro Yamashita, kiyotaka nakajima, daling ru, MICHIKAZU HARA, KAZUNARI DOMEN

    Journal of Materials Chemistry   15 ( No. )   2035   2005

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  • Triblock copolymer-assisted synthesis of a hybrid mesoporous ethenylene-silica with 2D hexagonal structure and large pores

    Nakajima, K., Tomita, I., Hara, M., Hayashi, S., Domen, K., Kondo, JN

    Journal of Materials Chemistry   15 ( 24 )   2362   2005

  • okishi

    Hara Michikazu, Nomura Junko, Domen Kazunari

    Abstract of annual meeting of the Surface Science of Japan   25   93 - 93   2005

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    DOI: 10.14886/sssj.25.0.93.0

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  • Comment on "a study of mechano-catalysis for overall water splitting"

    David S. Ross, Michikazu Hara, Kazunari Domen

    Journal of Physical Chemistry B   108 ( 49 )   19076 - 19078   2004.12

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    Publishing type:Rapid communication, short report, research note, etc. (scientific journal)  

    DOI: 10.1021/jp0403361

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  • Synthesis, mesostructure, and photocatalysis of a highly ordered and thermally stable mesoporous Mg and Ta mixed oxide

    Junko N. Kondo, Miwa Uchida, Kiyotaka Nakajima, Lu Daling, Michikazu Hara, Kazunari Domen

    Chemistry of Materials   16 ( 22 )   4304 - 4310   2004.11

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  • Synthesis, mesostructure, and photocatalysis of a highly ordered and thermally stable mesoporous Mg and Ta mixed oxide

    JN Kondo, M Uchida, K Nakajima, DL Lu, M Hara, K Domen

    CHEMISTRY OF MATERIALS   16 ( 22 )   4304 - 4310   2004.11

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  • Polyanion-nanosheets as solid acid catalysts

    TAKAGAKI Atsushi, N.(KONDO) Junko, HARA Michikazu, KOBAYASHI Hisayoshi, HAYASHI Shigenobu, DOMEN Kazunari

    46 ( 6 )   513 - 515   2004.9

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  • Titanium niobate and titanium tantalate nanosheets as strong solid acid catalysts

    Atsushi Takagaki, Takemi Yoshida, Darling Lu, Junko N. Kondo, Michikazu Hara, Kazunari Domen, Shigenobu Hayashi

    Journal of Physical Chemistry B   108 ( 31 )   11549 - 11555   2004.8

  • Photocatalytic reduction of water by TaON under visible light irradiation

    Michikazu Hara, Tsuyoshi Takata, Junko N. Kondo, Kazunari Domen

    Catalysis Today   90 ( 3-4 )   313 - 317   2004.7

  • A carbon material as a strong protonic acid

    Michikazu Hara, Takemi Yoshida, Atsushi Takagaki, Tsuyoshi Takata, Junko N. Kondo, Shigenobu Hayashi, Kazunari Domen

    Angewandte Chemie - International Edition   43 ( 22 )   2955 - 2958   2004.5

  • Mechanocatalytic Overall Water Splitting

    TAKATA TSUYOSHI, HARA MICHIKAZU, DOMEN KAZUNARI

    46 ( 3 )   237 - 241   2004.4

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  • Oxysulfides Ln<inf>2</inf>Ti<inf>2</inf>S<inf>2</inf>O<inf>5</inf> as stable photocatalysts for water oxidation and reduction under visible-light irradiation

    Akio Ishikawa, Tsuyoshi Takata, Tadaaki Matsumura, Junko N. Kondo, Michikazu Hara, Hisayoshi Kobayashi, Kazunari Domen

    Journal of Physical Chemistry B   108 ( 8 )   2637 - 2642   2004.2

  • Layered titanate thin film as an electrode material

    Akio Ishikawa, Tsuyoshi Takata, Junko N. Kondo, Michikazu Hara, Yasumichi Matsumoto, Kazunari Domen

    Journal of Materials Research   19 ( 2 )   661 - 666   2004.2

  • Photocatalytic Water Splitting under Visible-Light Irradiation

    46 ( 1 )   51 - 51   2004.1

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  • A carbon material as a strong protonic acid

    M Hara, T Yoshida, A Takagaki, T Takata, JN Kondo, S Hayashi, K Domen

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   43 ( 22 )   2955 - 2958   2004

  • Crystallization of highly ordered mesoporous niobium and tantalum mixed oxide

    J. N. Kondo, T. Katou, D. Lu, M. Hara, K. Domen

    Studies in Surface Science and Catalysis   154 A   951 - 957   2004

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  • Synthesis of Highly Ordered Hybrid Mesoporous Material Containing Etenylene (-CH=CH-) within the Silicate Framework

    Kiyotaka Nakajima, Daling Lu, Junko N. Kondo, Ikuyoshi Tomita, Shinji Inagaki, Michikazu Hara, Shigenobu Hayashi, Kazunari Domen

    Chemistry Letters   32 ( 10 )   950 - 951   2003.10

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  • Synthesis of Highly Ordered Hybrid Mesoporous Material Containing Etenylene (-CH=CH-) within the Silicate Framework

    Kiyotaka Nakajima, Daling Lu, Junko N. Kondo, Ikuyoshi Tomita, Shinji Inagaki, Michikazu Hara, Shigenobu Hayashi, Kazunari Domen

    Chemistry Letters   32 ( 10 )   950 - 951   2003.10

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  • Exfoliated nanosheets as a new strong solid acid catalyst

    Atsushi Takagaki, Mariko Sugisawa, Darling Lu, Junko N. Kondo, Michikazu Hara, Kazunari Domen, Shigenobu Hayashi

    Journal of the American Chemical Society   125 ( 18 )   5479 - 5485   2003.5

  • Exfoliated nanosheets as a new strong solid acid catalyst

    A Takagaki, M Sugisawa, DL Lu, JN Kondo, M Hara, K Domen, S Hayashi

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   125 ( 18 )   5479 - 5485   2003.5

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  • Conduction and valence band positions of Ta<inf>2</inf>O<inf>5</inf>, TaOn, and Ta<inf>3</inf>N<inf>5</inf> by UPS and electrochemical methods

    Wang Jae Chun, Akio Ishikawa, Hideki Fujisawa, Tsuyoshi Takata, Junko N. Kondo, Michikazu Hara, Maki Kawai, Yasumichi Matsumoto, Kazunari Domen

    Journal of Physical Chemistry B   107 ( 8 )   1798 - 1803   2003.2

  • TiN<inf>x</inf>O<inf>y</inf>F<inf>z</inf> as a stable photocatalyst for water oxidation in visible light (&lt;570 nm)

    Kohta Nukumizu, Jun Nunoshige, Tsuyoshi Takata, Junko N. Kondo, Michikazu Hara, Hisayoshi Kobayashi, Kazunari Domen

    Chemistry Letters   32 ( 2 )   196 - 197   2003.2

  • LaTiO<inf>2</inf>N as a visible-light (≤600 nm)-driven photocatalyst (2)

    Asako Kasahara, Kohta Nukumizu, Tsuyoshi Takata, Junko N. Kondo, Michikazu Hara, Hisayoshi Kobayashi, Kazunari Domen

    Journal of Physical Chemistry B   107 ( 3 )   791 - 797   2003.1

  • Preparation of ordered mesoporous NbTa mixed oxide with crystallized wall

    T. Katou, B. Lee, D. Lu, J. N. Kondo, M. Hara, K. Domen

    Studies in Surface Science and Catalysis   146   251 - 254   2003

  • Ta3N5 and TaON as novel photocatalysts responding to visible light

    Michikazu Hara, Go Hitoki, Tsuyoshi Takata, Junko N. Kondo, Hisayoshi Kobayashi, Kazunari Domen

    Studies in Surface Science and Catalysis   145   169 - 172   2003

  • 太陽光からクリーンなエネルギーを創る(レーダー)

    原 亨和

    化学と教育   51 ( 8 )   478 - 479   2003

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    DOI: 10.20665/kakyoshi.51.8_478

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  • Oxysulfide Sm<inf>2</inf>Ti<inf>2</inf>S<inf>2</inf>O<inf>5</inf> as a stable photocatalyst for water oxidation and reduction under visible light irradiation (λ ≤ 650 nm)

    Akio Ishikawa, Tsuyoshi Takata, Junko N. Kondo, Michikazu Hara, Hisayoshi Kobayashi, Kazunari Domen

    Journal of the American Chemical Society   124 ( 45 )   13547 - 13553   2002.11

  • An oxynitride, TaON, as an efficient water oxidation photocatalyst under visible light irradiation (lambda &lt;= 500 nm)

    G Hitoki, T Takata, JN Kondo, M Hara, H Kobayashi, K Domen

    CHEMICAL COMMUNICATIONS   2 ( 16 )   1698 - 1699   2002.8

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  • Photoreactions on LaTiO<inf>2</inf>N under visible light irradiation

    Asako Kasahara, Kota Nukumizu, Go Hitoki, Tsuyoshi Takata, Junko N. Kondo, Michikazu Hara, Hisayoshi Kobayashi, Kazunari Domen

    Journal of Physical Chemistry A   106 ( 29 )   6750 - 6753   2002.7

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  • Photoreactions on LaTiO2N under visible light irradiation

    A Kasahara, K Nukumizu, G Hitoki, T Takata, JN Kondo, M Hara, H Kobayashi, K Domen

    JOURNAL OF PHYSICAL CHEMISTRY A   106 ( 29 )   6750 - 6753   2002.7

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  • Metal Oxide Nanosheets as Solid Acids

    HARA Michikazu, DOMEN Kazunari, HAYASHI Shigenobu

    44 ( 4 )   240 - 245   2002.6

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  • (Oxy)nitrides as New Photocatalysis for Water Splitting under Visible Light Irradiation

    HITOKI Go, TAKATA Tsuyoshi, KONDO Junko N., HARA Michikazu, KOBAYASHI Hisayoshi, DOMEN Kazunari

    Electrochemistry   70 ( 6 )   460 - 462   2002.6

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  • (Oxy)nitrides as new photocatalysts for water splitting under visible light irradiation

    Go Hitoki, Tsuyoshi Takata, Junko N. Kondo, Michikazu Hara, Hisayoshi Kobayashi, Kazunari Domen

    Electrochemistry   70 ( 6 )   463 - 465   2002.6

  • 可視光による水分解新触媒の開発 (先端環境技術特集 水から水素を造る--光による水分解技術)

    原 亨和, 堂免 一成

    マテリアルステージ   2 ( 2 )   33 - 38   2002.5

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  • Material Report R&D オキシナイトライド・ナイトライド--新しい可視光応答光触媒

    原 亨和, 堂免 一成

    機能材料   22 ( 3 )   25 - 30   2002.3

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  • Single crystal particles of mesoporous (Nb, Ta)<inf>2</inf>O<inf>5</inf>

    Junko N. Kondo, Tomohiro Yamashita, Tokumitsu Katou, Byongjin Lee, Daling Lu, Michikazu Hara, Kazunari Domen

    Studies in Surface Science and Catalysis   141   265 - 272   2002

  • An oxynitride, TaON, as an efficient water oxidation photocatalyst under visible light irradiation (λ ≤ 500 nm)

    Go Hitoki, Tsuyoshi Takata, Junko N. Kondo, Michikazu Hara, Hisayoshi Kobayashi, Kazunari Domen

    Chemical Communications   2 ( 16 )   1698 - 1699   2002

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  • 水の可視光分解を目的とした遷移金属オキシナイトライド型光触媒

    高田 剛, 一木 豪, 笠原 麻子, 魯 大凌, 野村 淳子, 原 亨和, 堂免 一成, 小林 芳久

    触媒   43 ( 6 )   499 - 501   2001.9

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  • 水から水素をつくる 光触媒とメカノキャタリシス

    原 亨和, 堂免 一成

    ペトロテック = Petrotech   24 ( 2 )   90 - 94   2001.2

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  • 光触媒によるエネルギー変換 (特集 光触媒反応とその応用)

    原 亨和, 堂免 一成

    マテリアルインテグレ-ション   14 ( 2 )   7 - 11   2001.2

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  • Mechano-catalytic overall water-splitting into hydrogen and oxygen on some metal oxides

    Kazunari Domen, Shigeru Ikeda, Tsuyoshi Takata, Akira Tanaka, Michikazu Hara, Junko N. Kondo

    Applied Energy   67 ( 1-2 )   159 - 179   2000.9

  • Photocatalytic water oxidation in a buffered tris(2,2′-bipyridyl)ruthenium complex-colloidal IrO<inf>2</inf> system

    Michikazu Hara, Chad C. Waraksa, John T. Lean, Bradley A. Lewis, Thomas E. Mallouk

    Journal of Physical Chemistry A   104 ( 22 )   5275 - 5280   2000.6

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  • Photocatalytic water oxidation in a buffered tris(2,2 '-bipyridyl)ruthenium complex-colloidal IrO2 system

    M Hara, CC Waraksa, JT Lean, BA Lewis, TE Mallouk

    JOURNAL OF PHYSICAL CHEMISTRY A   104 ( 22 )   5275 - 5280   2000.6

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  • Photo- and mechano-catalytic overall water splitting reactions to form hydrogen and oxygen on heterogeneous catalysts

    Kazunari Domen, Junko N. Kondo, Michikazu Hara, Tsuyoshi Takata

    Bulletin of the Chemical Society of Japan   73 ( 6 )   1307 - 1331   2000.6

  • ファイル処理問題におけるクラス設計の自動化システムEOS/Pの開発—ソフトウェア工学 研究報告

    南 旭瑞, 山内 亨和, 原田 実

    情報処理学会研究報告 = IPSJ SIG technical reports   2000 ( 25 )   81 - 88   2000.3

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    Other Link: https://ndlsearch.ndl.go.jp/books/R000000004-I5339994

  • A study of mechano-catalysts for overall water splitting

    M Hara, M Komoda, H Hasei, M Yashima, S Ikeda, T Takata, JN Kondo, K Domen

    JOURNAL OF PHYSICAL CHEMISTRY B   104 ( 4 )   780 - 785   2000.2

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  • A study of mechano-catalysts for overall water splitting

    M Hara, M Komoda, H Hasei, M Yashima, S Ikeda, T Takata, JN Kondo, K Domen

    JOURNAL OF PHYSICAL CHEMISTRY B   104 ( 4 )   780 - 785   2000.2

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  • Photocatalytic water oxidation byNafion-stabilized IrO2 colloid-tris(2,2’-bipyridyl)ruthenium Complex photosystem

    M. Hara, T. E. Mallouk

    Journal of Chemical Society Chemical Communication   1903   2000

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  • Effect of chromium addition for photocatalytic overall water splitting on Ni-K<inf>2</inf>La<inf>2</inf>Ti<inf>3</inf>O<inf>10</inf>

    C. T.K. Thaminimulla, T. Takata, M. Hara, J. N. Kondo, K. Domen

    Journal of Catalysis   196 ( 2 )   362 - 365   2000

  • Photocatalytic water oxidation byNafion-stabilized IrO2 colloid-tris(2,2’-bipyridyl)ruthenium Complex photosystem

    M. Hara, T. E. Mallouk

    Journal of Chemical Society Chemical Communication   1903   2000

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  • 遠吠えの中で

    原 亨和

    触媒   41 ( 8 )   624   1999.12

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  • 遷移金属酸化物を用いるメカノキャタリシスによる水の分解反応—特集 異分野に学ぶメカノケミストリー

    高田 剛, 原 亨和, 野村 淳子

    金属   69 ( 12 )   1066 - 1071   1999.12

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    Language:Japanese   Publisher:東京 : アグネ技術センター  

    資料形態 : テキストデータ プレーンテキスト
    コレクション : 国立国会図書館デジタルコレクション > デジタル化資料 > 雑誌

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    Other Link: https://ndlsearch.ndl.go.jp/books/R000000004-I4923182

  • Mechano-catalysis - A novel method for overall water splitting

    Shigeru Ikeda, Tsuyoshi Takata, Mutsuko Komoda, Michikazu Hara, Junko N. Kondo, Kazunari Domen, Akira Tanaka, Hideo Hosono, Hiroshi Kawazoe

    Physical Chemistry Chemical Physics   1 ( 18 )   4485 - 4491   1999.9

  • 層状構造の光触媒の設計と水の光分解 (高次機能触媒の設計--環境調和型触媒の開発を目指した新展開) -- (特殊反応場と触媒設計--触媒機能の複合化と新機能発現機構)

    原 亨和, 堂免 一成

    季刊化学総説   ( 41 )   155 - 161   1999.7

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  • 図書紹介,Studies in Surface Science and Catalysis, Vol. 117. "Mesoporous Molecular Sieves 1998"

    原 亨和

    触媒   41 ( 1 )   65 - 65   1999.1

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  • Overall water splitting on Cu(I)-containing ternary oxides, CuMO2(M=Fe, Ga, Al) with delafossite structure

    Ikeda, S., Tanaka, A., Hosono, H., Kawazoe, H., Hara, M., Kondo, JN, Domen, K., Hattori, H., Otsuka, K.

    Science and Technology in Catalysis 1998   121   301 - 304   1999

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  • Mechano-catalytic overall water splitting

    Shigeru Ikeda, Tsuyoshi Takata, Takeshi Kondo, Go Hitoki, Michikazu Hara, Junko N. Kondo, Kazunari Domen, Hideo Hosono, Hiroshi Kawazoe, Akira Tanaka

    Chemical Communications   ( 20 )   2185 - 2186   1998.10

  • Recent progress of photocatalysts for overall water splitting

    Tsuyoshi Takata, Akira Tanaka, Michikazu Hara, Junko N. Kondo, Kazunari Domen

    Catalysis Today   44 ( 1-4 )   17 - 26   1998.9

  • Mechano-catalytic overall water splitting

    IKEDA Shigeru, TAKATA Tsuyoshi, KOMODA Mutsuko, TANAKA Akira, HOSONO Hideo, KAWAZOE Hiroshi, HARA Michikazu, KONDO Junko N., DOMEN Kazunari

    Chem. Commun.   40 ( 6 )   482 - 485   1998.9

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  • Dependence of catalytic activity in CO hydrogenation on strong basic sites of ZrO<inf>2</inf> surface

    Lianhai Lu, Tomoki Hayakawa, Tetsuji Ueda, Michikazu Hara, Kazunari Domen, Ken Ichi Maruya

    Chemistry Letters   ( 1 )   65 - 66   1998

  • Microporous structure of a thin film made of an ion-exchangeable layered compound

    R. Abe, J. N. Kondo, M. Hara, K. Domen

    Supramolecular Science   5 ( 3-4 )   229 - 233   1998

  • 発光分光法を用いた光触媒のキャラクタリゼーション

    原 亨和

    触媒   39 ( 8 )   665 - 666   1997.12

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  • Visible Light Induced Water Decomposition on Cu(I)Metal oxides

    HARA M., IKEDA S., KONDO T., SHINOHARA K., TANAKA A., HOSONO H., KAWAZOE H., DOMEN K.

    39 ( 6 )   394 - 397   1997.9

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  • A highly active photocatalyst for overall water splitting with a hydrated layered perovskite structure

    T. Takata, K. Shinohara, A. Tanaka, M. Hara, J. N. Kondo, K. Domen

    Journal of Photochemistry and Photobiology A: Chemistry   106 ( 1-3 )   45 - 49   1997.6

  • Reply to comment on "Thermal conversion of methoxy species on dimethyl ether adsorbed CeO2"

    BINET C, LAVALLEY J‐C, HARA M, KAWAMURA M, KONDO J N, DOMEN K, MARUYA K

    The Journal of Physical Chemistry B   101 ( 8 )   1484 - 1487   1997

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  • Desorption of dimethyl ether from a methoxy species formed on a CeO<inf>2</inf> surface

    Michikazu Hara, Miyuki Kawamura, Junko N. Kondo, Kazunari Domen, Ken Ichi Maruya

    Langmuir   12 ( 26 )   6712 - 6713   1996.12

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  • Thermal conversion of methoxy species on dimethyl ether adsorbed CeO<inf>2</inf>

    Michikazu Hara, Miyuki Kawamura, Junko N. Kondo, Kazunari Domen, Ken Ichi Maruya

    Journal of Physical Chemistry   100 ( 34 )   14462 - 14467   1996.8

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  • 酸化セリウム表面に形成されたメトキシ種からのジメチルエーテルの脱離

    原亨和

    12 ( 26 )   6712   1996

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  • ジメチルエーテルを吸着した酸化セリウム表面でのメトキシ種の熱分解

    原亨和

    100 ( 34 )   14462   1996

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  • STRUCTURAL AND ELECTROCHEMICAL PROPERTIES OF LITHIATED POLYMERIZED AROMATICS - ANODES FOR LITHIUM-ION CELLS

    M HARA, A SATOH, N TAKAMI, T OHSAKI

    JOURNAL OF PHYSICAL CHEMISTRY   99 ( 44 )   16338 - 16343   1995.11

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  • STRUCTURAL AND KINETIC CHARACTERIZATION OF LITHIUM INTERCALATION INTO CARBON ANODES FOR SECONDARY LITHIUM BATTERIES

    N TAKAMI, A SATOH, M HARA, OHSAKI, I

    JOURNAL OF THE ELECTROCHEMICAL SOCIETY   142 ( 2 )   371 - 379   1995.2

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  • Structural and Kinetic Characterization of Lithium Intercalation into Carbon Anodes for Secondary Lithium Batteries

    Norio Takami, Asako Satoh, Michikazu Hara, Takahisa Ohsaki

    Journal of the Electrochemical Society   142 ( 2 )   371 - 379   1995.2

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  • Structural and electrochemical properties of lithiated polymerized aromatics. Anodes for lithium-ion cells

    Michikazu Hara, Asako Satoh, Norio Takami, Takahisa Ohsaki

    Journal of Physical Chemistry   99 ( 44 )   16338 - 16343   1995

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  • Adsorption of hydrogen on Al(111) and Al(110): coverage and temperature dependence of adsorption states

    H. Kondoh, M. Hara, K. Domen, H. Nozoye

    Surface Science   287-288 ( PART 1 )   74 - 78   1993.5

  • Adsorption of Hydrogen on Al (111) and Al (110)

    MICHIKAZU HARA

    Surface Science   287 ( 288 )   74   1993

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  • A Survey on the Fire-Protection Performance of Through-Penetrate Assembly : on the thermal characteristics of cables

    Chung Hyung-wha

    Summaries of technical papers of Annual Meeting Architectural Institute of Japan. A, Materials and construction, fire safety, off-shore engineering and architecture, information systems technology   ( 1992 )   1359 - 1360   1992.8

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  • Surface reaction of CH<inf>2</inf>I<inf>2</inf> with an Al(111) surface

    M. Hara, K. Domen, M. Kato, T. Onishi, H. Nozoye

    Journal of Physical Chemistry   96 ( 6 )   2637 - 2641   1992

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  • Hydrogen adsorption on Al(110): strong orientation-dependence of aluminum hydride desorption

    H. Kondoh, M. Hara, K. Domen, H. Nozoye

    Surface Science   268 ( 1-3 )   L287 - L292   1992

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  • Erratum: Surface reaction of CH<inf>2</inf>I<inf>2</inf> with an Al(111) surface (Journal of Physical Chemistry (1992) 96, (2639))

    M. Hara, K. Domen, M. Kato, T. Onishi, H. Nozoye

    Journal of Physical Chemistry   96 ( 15 )   6514   1992

  • Hydrogen adsorption on Al(110): strong orientation-dependence of aluminum hydride desorption

    H. Kondoh, M. Hara, K. Domen, H. Nozoye

    Surface Science   268 ( 1-3 )   L287 - L292   1992

  • HREELS study on hydrogen adsorbed Al(111) surface

    H. Kondoh, C. Nishihara, H. Nozoye, M. Hara, K. Domen

    Chemical Physics Letters   187 ( 5 )   466 - 470   1991.12

  • HREELS STUDY ON HYDROGEN ADSORBED AL(111) SURFACE

    H KONDOH, C NISHIHARA, H NOZOYE, M HARA, K DOMEN

    CHEMICAL PHYSICS LETTERS   187 ( 5 )   466 - 470   1991.12

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  • ETCHING OF ALUMINUM FILM BY HYDROGEN-ATOMS

    M HARA, K DOMEN, T ONISHI, H NOZOYE

    APPLIED PHYSICS LETTERS   59 ( 14 )   1793 - 1795   1991.9

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  • A Study on the Fire Resistance of Gypsum-board Panel : in Case of Dry-wall Joint

    JEE Nam Yong

    Summaries of technical papers of Annual Meeting Architectural Institute of Japan. A, Materials and construction, fire safety, off-shore engineering and architecture, information systems technology   ( 1991 )   1055 - 1056   1991.8

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  • Formation and desorption of aluminum hydride from hydrogen adsorbed aluminum surfaces

    M. Hara, K. Domen, T. Onishi, H. Nozoye, C. Nishihara, Y. Kaise, H. Shindo

    Surface Science   242 ( 1-3 )   459 - 463   1991.2

  • FORMATION AND DESORPTION OF ALUMINUM-HYDRIDE FROM HYDROGEN ADSORBED ALUMINUM SURFACES

    M HARA, K DOMEN, T ONISHI, H NOZOYE, C NISHIHARA, Y KAISE, H SHINDO

    SURFACE SCIENCE   242 ( 1-3 )   459 - 463   1991.2

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  • DESORPTION OF ALUMINUM-HYDRIDE FROM HYDROGEN ADSORBED AL(111) SURFACE

    M HARA, K DOMEN, T ONISHI, H NOZOYE

    JOURNAL OF PHYSICAL CHEMISTRY   95 ( 1 )   6 - 7   1991.1

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    Language:English   Publishing type:Rapid communication, short report, research note, etc. (scientific journal)  

    DOI: 10.1021/j100154a003

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  • Desorption of Aluminum Hydride from Al (111) Surface

    MICHIKAZU HARA

    The Journal of Physical Chemistry   95   7   1991

  • Desorption of aluminum hydride from hydrogen adsorbed Al(111) surface

    M. Hara, K. Domen, T. Onishi, H. Nozoye

    Journal of Physical Chemistry   95 ( 1 )   6 - 7   1991

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  • Etching of aluminum film by hydrogen atoms

    M. Hara, K. Domen, T. Onishi, H. Nozoye

    Applied Physics Letters   59 ( 14 )   1793 - 1795   1991

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  • Evaluation for Fire Resitance of Plaster Boards(Part 2)

    JEE Nam Yong

    Summaries of technical papers of Annual Meeting Architectural Institute of Japan. A, Materials and construction, fire safety, off-shore engineering and architecture, information systems technology   ( 1990 )   1017 - 1018   1990.9

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  • Observation of an alkyl aluminium complex formed by reaction of CH <inf>2</inf>I<inf>2</inf> with an Al(111) surface

    M. Hara, K. Domen, M. Kato, T. Onishi, H. Nozoye

    Journal of the Chemical Society, Chemical Communications   33 ( 23 )   1717 - 1718   1990

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  • Observation of an Alkyl Aluminum Complex formed by Reaction of CH┣D22┫D2I┣D22┫D2 with an Al (111) Surface.

    MICHIKAZU HARA

    Journal of Chemical Society Chemical Comunicaiton   33   1717   1990

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Presentations

  • Hydrolysis of Cellulose by a Solid Catalyst. Acid Catalyzed Reaction at Solid-Solid Interface

    6th World Congress on Catalysis by Acids and Bases  2009 

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  • カーボン系固体酸を用いたセロオリゴ糖の加水分解

    触媒  2008 

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  • “Preparation of Solid Acid Carbon Coating by Photo-polymerization of Gaseous Aromatic Hydrocarbon”

    2nd China-Japan Symposium on Advanced Photocatalytic Materials,  2009 

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  • Hydrolysis of Cellulose by a Solid Catalyst. Acid Catalyzed Reaction at Solid-Solid Interface

    6th World Congress on Catalysis by Acids and Bases  2009 

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  • “Preparation of Solid Acid Carbon Coating by Photo-polymerization of Gaseous Aromatic Hydrocarbon”

    2nd China-Japan Symposium on Advanced Photocatalytic Materials,  2009 

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  • 「芳香族炭化水素の光重合による炭素系固体強酸の作製と評価」

    日本セラミックス協会2009年年会  2009 

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  • Cellulose Saccharification by a Carbon-Based Solid Acid

    1st Annual Chemical Sciences and Society Symposium (CS3)  2010 

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  • Cellulose Saccharification by a Carbon-Based Solid Acid

    1st Annual Chemical Sciences and Society Symposium (CS3)  2010 

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  • Stable and Highly Active Ph-SO3H Functionalized Hybrid Mesoporous Acid Catalyst

    3rd FEZA conference  2005 

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  • Synthesis and Application of Thermally Stable Mesoporous Ta2O5 Photocatalyst for Overall Water Decomposition

    3rd FEZA conference  2005 

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  • Stable and Highly Active Ph-SO3H Functionalized Hybrid Mesoporous Acid Catalyst

    3rd FEZA conference  2005 

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  • Preparation of crack-free, transparent, nanoporous niobium oxide film with crystalline structure by evaporation-induced self-assembly (EISA) process

    Nanoporous Materials IV  2005 

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  • Synthesis and Application of Thermally Stable Mesoporous Ta2O5 Photocatalyst for Overall Water Decomposition

    3rd FEZA conference  2005 

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  • Preparation of crack-free, transparent, nanoporous niobium oxide film with crystalline structure by evaporation-induced self-assembly (EISA) process

    Nanoporous Materials IV  2005 

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Awards

  • 5th Scientific American 50

    2006  

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  • 5th Scientific American 50

    2006  

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  • 東京工業大学挑戦的研究賞

    2003  

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    Country:Japan

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Research Projects

  • Development of iron catalyst combined with group 13 metal nitrides for low temperature ammonia synthesis

    Grant number:23H00245  2023.4 - 2026.3

    Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research  Grant-in-Aid for Scientific Research (A)

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    Grant amount:\47060000 ( Direct Cost: \36200000 、 Indirect Cost:\10860000 )

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  • Process intensification for green NH3 via advanced membrane separation and catalysts

    Grant number:21H04630  2021.4 - 2025.3

    Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research  Grant-in-Aid for Scientific Research (A)

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    Grant amount:\41860000 ( Direct Cost: \32200000 、 Indirect Cost:\9660000 )

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  • Low temperature ammonia synthesis by heterogeneous catalysts enhancing electron-donating power

    Grant number:18H05251  2018.6 - 2023.3

    Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research  Grant-in-Aid for Scientific Research (S)

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    Grant amount:\190580000 ( Direct Cost: \146600000 、 Indirect Cost:\43980000 )

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  • Synthesis of highly active and multi-functional carbon-based solid acid

    Grant number:18206081  2006 - 2008

    Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research  Grant-in-Aid for Scientific Research (A)

    HARA Michikazu, TATSUMI Takashi, NOMURA Junko

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    Grant amount:\47190000 ( Direct Cost: \36300000 、 Indirect Cost:\10890000 )

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  • バイオフューエルの高効率製造のための固体触媒の創生

    2004

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    Grant type:Competitive

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  • Solid catalyst for efficient biofuel production

    2004

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    Grant type:Competitive

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  • Development of novel solid acid catalyst based on polyanion nanosheets

    Grant number:15360427  2003 - 2005

    Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research  Grant-in-Aid for Scientific Research (B)

    HARA Michikazu, KONDO Junko N.

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    Grant amount:\14900000 ( Direct Cost: \14900000 )

    Two-dimensional metal oxide sheets in cation-exchangeable layered metal oxides such as HTiNbO_5 and HNb_3O_8 were examined as solid-acid catalysts. Exfoliation of HTiNbO_5 and HNb_3O_8 in aqueous solutions formed colloidal single-crystal TiNbO_5 and Nb_3O_8 nanosheets, precipitating under an acidic condition to form aggregates of the nanosheets. Although esterification of acetic acid, cracking of cumene and dehydration of 2-propanol were not catalyzed by original layered metal oxides because of the narrow interlayer distance, which prevents the insertion of organic molecules, the nanosheet aggregates functioned as strong solid acid catalysts for the reactions. NH_3 temperature-programmed desorption and ^1H magic-angle spinning nuclear magnetic resonance spectroscopy revealed that these nanosheet aggregates have strong Bronsted acid sites due to Nb^<5+> (or Ti^<4+>)-(OH)-Nb^<5+>.
    We also found that amorphous carbon composed of small graphen sheets with high density of sulfonic acid groups function as a replacement for sulfuric acid catalyst. The material prepared from inexpensive starting materials has high thermal and chemical stability.

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  • カーボン太陽電池

    2003

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    Grant type:Competitive

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  • Carbon solar cell

    2003

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    Grant type:Competitive

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  • マクロポリアニオンシートの応用展開

    Grant number:14655299  2002 - 2003

    日本学術振興会  科学研究費助成事業  萌芽研究

    原 亨和, 野村 淳子

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    Grant amount:\1700000 ( Direct Cost: \1700000 )

    本研究はカチオン交換性層状金属酸化物から得られる厚さ数nm未満のポリアニオンナノシートを高性能な光触媒、固体酸触媒、部分酸化触媒、あるいは新材料として展開することを念頭に置き、光触媒反応、酸触媒反応、部分酸化反応に最適な2次元マクロポリアニオンシートの探索を行うと同時に、ポリアニオンシートの構造を解明することを目的としている。
    十数種類のカチオン交換性層状金属酸化物の単結晶ポリアニオンナノシートを液相で剥離し、これを凝集させることによって得た高表面積の粉末材料を触媒として様々な反応が研究された。HTiNbO_5、HTi_2NbO_7、及びH_<1.15>Ti_<1.15>Nb_<0.85>O_5ナノシート凝集体はエステル化等の液相酸触媒反応において非常に強い固体酸触媒として働くことが既に明らかになっているが、これらはエポキシ化等の部分酸化反応に対しても非常に高い触媒活性をもつことがはじめて見出された。
    従来の手法、及び分光学的手法によってこれらのシート凝集体の部分酸化触媒能はNb^<5+>に起因することが確認された。Nb^<5+>が部分酸化触媒反応で高活性な活性点として働くことはこれまで知られておらず、上記の材料は全く新しいタイプの部分酸化触媒といえる。
    以上の結果はポリアニオンナノシートが固体酸触媒として機能するだけでなく、部分酸化触媒として応用展開できることを示している。

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  • 新規エネルギー変換材料による水素製造

    Grant number:11874096  1999 - 2000

    日本学術振興会  科学研究費助成事業  萌芽的研究

    原 亨和, 野村 淳子

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    Grant amount:\1700000 ( Direct Cost: \1700000 )

    これまでの研究から、数多くの単純な金属酸化物の中でNiO、Co_3O_4、Cu_2O、Fe_3O_4、RuO_2、IrO_2のみがメカノキャタリシスによる水の全分解反応の触媒となることが明らかになった。同じ反応条件ではでNiO、Co_3O_4が高い触媒活性を示す一方、RuO_2、IrO_2は低活性であった。この触媒反応は前述のように反応容器底面とその上で回転する回転体の間に挟まれた触媒粒子に力学的エネルギーが加えられて進行するが、その水の分解活性は触媒の粒径、回転体の形状、回転体と反応容器底面の間にかかる圧力に大きく依存した。触媒粒経がサブミクロンオーダーの場合、反応容器底面と回転する攪拌子の間にある小さな触媒粒子に充分な力学的エネルギーが与えられないために水分解活性は非常に小さい。平らな反応容器底面に回転体を線接触した時の活性は面接触の場合より高く、回転体を反応容器底面に押し付ける力に比例して水の分解速度が大きくなった。これらの結果は触媒粒子に加えられる圧力が高いほど触媒に与えられる力学的エネルギーが大きくなり、水の全分解速度が速くなることを示している。各々の反応条件下、これらの金属酸化物触媒の中でNiOが最も高い水の分解活性をもち、力学的エネルギーの変換効率は4-10%に達した。一方、RuO_2、IrO_2は最適条件下においても低い活性しか示さなかった。
    また、NiO、Co_3O_4、Cu_2Oを用いて反応メカニズムの解明が試みた結果、反応条件下でこれらの金属酸化物表面の一部は金属まで還元され、再び元の酸化物に戻ることが明らかになった。このことは触媒表面でレドックス反応が進行していることを示している。分光学的な解析も行われ、水がない状態でCu_2Oに力学的エネルギーを回転体によって与えると波長600nm未満(>2.1eV)の発光が検出された。Cu_2Oのバンドギャップエネルギーが2.1eVであることを考慮すると、力学的エネルギーを与えられたCu_2Oでは電子のバンドギャップ遷移が起きていることが考えられる。他の触媒の分光学的実験は現在継続中であるが、Cu_2Oのメカノキャタリシスでは力学的エネルギーがバンドギャップ遷移を起し、これが触媒表面でのレドックス反応のドライビングフォースとなっていることが予想された。

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  • 層状金属酸化物と用いた新規光機能性薄膜の創出

    Grant number:11118227  1999

    日本学術振興会  科学研究費助成事業  特定領域研究(A)

    堂免 一成, 原 *和, 野村 淳子

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    Grant amount:\2000000 ( Direct Cost: \2000000 )

    本研究で用いる薄膜の評価はバルク構造、表面構造、電子構造、物性等から行い、層状金属酸化物薄膜の新機能の発現を探るだけでなく、これまでわかっていない層間現象の解明を試みてた。ウロコ鉄鋼型Ti系層状金属酸化物Cs_xTi_<(2-x/4)>_<x/4>O_4薄膜、及びNb系層状金属酸化物K_4Nb_6O_<17>薄膜は、層構造を維持した状態で金属カチオンなど種々カチオンの層間へのインターカレートを行えることが確認された。また、アルキルアミンにより層間修飾を行うと、層間距離が広がることをXRDにより確認でた。更に、SNO電極上に形成させた薄膜は、同処理を行うことにより電気伝導性の向上を図れることがCVにより示唆された。また、層間距離を広げることにより、有機金属錯体(Ru(bpy)_3^<2+>等)のインターカレートも可能となった。薄膜自体は可視光領域に吸収帯を持っていないが、可視光照射下で光機能性を持つ有機金属錯体を層間にインターカレートした薄膜は、可視域に吸収帯を持たせることができた。現時点で調べた錯体Ru(bpy)_3^<2+>やメチルビオロゲンは、他種カチオンが多量に存在している条件においても層間に固定化させておくことができ、さらには電気化学的手法により可逆的に酸化還元反応を行えることが明らかになった。可視域に吸収を持たせ、さらには層間にインターカレートした錯体を安定にレドックスさせることができるという結果を得たことにより、光機能性薄膜構築に向けて重要な指針が得られた。

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  • 光機能性層状酸化物薄膜の創成と物性

    Grant number:09237225  1997

    日本学術振興会  科学研究費助成事業  重点領域研究

    堂免 一成, 原 亨和

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    Grant amount:\2000000 ( Direct Cost: \2000000 )

    本研究では層状金属酸化物をソフトケミカル的手法によって薄膜化し、その物性、構造を評価することによって従来の限界を超えた新規光機能性デバイスの可能性を模索することを目的としている。層状チタン酸の1種であるCs_xTi(2_<-2>/4)□_x/_4O_4のプロトン交換体は、水酸化テトラブチルアンモニウムやエチルアミンの水溶液の中においてチタン酸シートの剥離が可能である。この剥離したシートを基板上にスピンコートすると二次元に配列した層状の薄膜が非常に容易に得られる。この薄膜は層間に有機物であるアミンを含むため熱的安定性に乏しく、それ以上の修飾方法が限定されていたが、水溶液中でイオン交換を行うことにより耐熱性を持たせることに成功した。交換前の薄膜においては、250°C以上の加熱により層間の縮合が起こり、そのイオン交換能が失われる。しかしながら薄膜をCsCl水溶液中で処理することで、層間のアミンがCsイオンに置き換わり、この薄膜は450°Cの加熱後においても層構造を失うことなく、安定であることが確認された。またCs以外にも多種のイオンへの交換が可能であることが確認され、特にNi等においては層間において還元が可能であり、チタン酸シートとNi微粒子を交互に包括した薄膜が得られた。
    層状ニオブ酸K_4Nb_6O_<17>はその層間が容易に水和するため、湿式粉砕を行うと超微粒子を含む懸濁液が得られ、この懸濁液を基板上にスピンコートし高温で焼成すると結晶成長が起こり、非常に結晶性の良い層状の薄膜が得られる。この薄膜は前者に比較して結晶性、熱安定性の両者で勝っており、イオン交換能においても種々の金属イオンを始め錯体のインターカレーションも可能であることが分かった。また長鎖のアルキルアミンを層間に挿入することで自由に層間距離が変えられることが確認され、この層間距離を広げた薄膜を前駆体として用いることで、Ru(bpy)_3色素などの大きな分子への交換も可能となった。

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  • DESIGN OF NEW PHOTOFUNCTIONAL MATERIALS BASED ON EXFOLIATED TWO DIMENSIONAL OXIDES

    Grant number:08554028  1996 - 1997

    Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research  Grant-in-Aid for Scientific Research (A)

    DOMEN Kazunari, HARA Michikazu, KONDO Junko N., TANAKA Akira

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    Grant amount:\3900000 ( Direct Cost: \3900000 )

    Photocatalysts recently attract a great attention from the view point of eco-friendliness. However, already found photocatalysts do not avail the visible light which dominates the solar light. Although several materials such as CdS were found to utilize the visible light, the eco-harm nature of them is the great disadvantage. We have found that the ion-exchangeable transition metal oxides are promising catalysts which have the photoresponse in visible light region. The serious problem of those materials are that their high interlayr electron density inhibit the intercalation of reactants and that the interlayr spase has not been efficiently utilized. On the other hand, the use of intercalation of organic ions such as tri-butyl-ammonium ion (TBA+) enabled the exfoliation of the layr to produce macropolyanion sheets highly dispersed in water. Furthermore, the dispersed two dimensional inorganic sheets were found to be starting materials of microporous materials and inorganic thin films. These novel materials demonstrated higher photoactivity than the original transition metal oxide and showed different chemical nature. The new types of layred materials were synthesized and are expected to be utilized as functional materials.

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