Updated on 2026/03/10

写真a

 
ISHIUCHI SHUN-ICHI
 
Organization
School of Science Professor
Title
Professor
External link

Degree

  • Master of Science ( Waseda University )

  • Doctor of Science ( The Graduate University for Advanced Studies )

Research Interests

  • Molecular spectra

  • 分子スペクトル

Research Areas

  • Nanotechnology/Materials / Fundamental physical chemistry

Education

  • The Graduate University for Advanced Studies   Graduate School, Division of Mathematical and Physical Science

    - 2001

      More details

    Country: Japan

    researchmap

  • Waseda University   School of Science and Engineering

    - 1996

      More details

    Country: Japan

    researchmap

Research History

  • Institute of Science Tokyo   School of Science, Department of Chemistry   Professor

    2020.5

      More details

    Country:Japan

    researchmap

  • Tokyo Institute of Technology   Associate Professor

    2017.4 - 2020.4

      More details

    Country:Japan

    researchmap

  • Tokyo Institute of Technology   Specially Appointed Associate Professor

    2016.4 - 2017.3

      More details

    Country:Japan

    researchmap

  • Tokyo Institute of Technology   Chemical Resources Laboratory   Assistant Professor

    2004.4 - 2016.3

      More details

    Country:Japan

    researchmap

  • Japan Science and Technology Agency   Precursory Research for Embryonic Science and Technology

    2002 - 2006

      More details

  • Keio University   Faculty of Science and Technology   Research Associat

    2001 - 2003

      More details

  • Japan Society for the Promotion of Science   Special Researcher

    1998 - 2001

      More details

▼display all

Professional Memberships

Papers

  • Infrared and Ultraviolet Spectra of the Monohydrated N -Methyl-Dopamine–Methylation Effect on Structure and Excited State Dynamics

    Keisuke Hirata, Ken-ichi Kasai, Masaaki Fujii, Gilles Grégoire, Shun-ichi Ishiuchi

    The Journal of Physical Chemistry A   2025.12

     More details

    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/acs.jpca.5c06307

    researchmap

  • Probing the Triplet State by Cryogenic Ion Trap IR Spectroscopy─Application to Protonated Lumiflavin

    Sotaro Ohara, Keisuke Hirata, Gilles Grégoire, Masaaki Fujii, Otto Dopfer, Shun-ichi Ishiuchi

    The Journal of Physical Chemistry Letters   12514 - 12519   2025.11

     More details

    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/acs.jpclett.5c02372

    researchmap

  • The Deprotonation Sites of Gas Phase Uridine and Pseudouridine: Implications for mRNA Vaccines

    Yuika Okura, Garrett D. Santis, Xiao-Fei Gao, Wenjin Cao, Keisuke Hirata, Shun-ichi Ishiuchi, Masaaki Fujii, Xue-Bin Wang, Sotiris S. Xantheas

    The Journal of Physical Chemistry Letters   10945 - 10951   2025.10

     More details

    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/acs.jpclett.5c02616

    researchmap

  • The Path from Sequestration to Hydration: Why Na+ Takes a Unique Route with the Ionophore, Beauvericin

    Kien X. Vo, Keisuke Hirata, James M. Lisy, Masaaki Fujii, Shun-ichi Ishiuchi

    The Journal of Physical Chemistry A   129 ( 35 )   8101 - 8109   2025.8

     More details

    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/acs.jpca.5c03824

    researchmap

  • Is Tl+ an Analogue of K+? IR Spectroscopy of Tl+ and a Key Peptide of the Selectivity Filter in K+ Channels

    Satoru Tanabe, Keisuke Hirata, Koichi Tsukiyama, James M. Lisy, Masaaki Fujii, Shun-ichi Ishiuchi

    The Journal of Physical Chemistry Letters   16 ( 33 )   8621 - 8626   2025.8

     More details

    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/acs.jpclett.5c01660

    researchmap

  • Optical and Infrared Spectroscopy of Lumiflavin Protomers in a Cryogenic Ion Trap

    Sotaro Ohara, Keisuke Hirata, Gilles Grégoire, Masaaki Fujii, Otto Dopfer, Shun-ichi Ishiuchi

    The Journal of Physical Chemistry A   129 ( 24 )   5245 - 5250   2025.6

     More details

    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/acs.jpca.5c01350

    researchmap

  • The Nicotine–Tryptophan Dimer: Probing the Principal Interaction of Nicotine with the Nicotinic Acetylcholine Receptor (nAChR), the Binding Pocket in the Human Brain

    Yuika Okura, Madisen N. Hallsten, Garrett D. Santis, Keisuke Hirata, Masaaki Fujii, Shun-Ichi Ishiuchi, Sotiris S. Xantheas

    Journal of the American Chemical Society   147 ( 17 )   14043 - 14047   2025.4

     More details

    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/jacs.5c00880

    researchmap

  • i-Motif DNA in isolated hemiprotonated cytosine dimers, studied using IR spectroscopy and theoretical calculations

    Ana D. Parejo Vidal, Yuika Okura, Keisuke Hirata, Vijay Madhav Miriyala, Pavel Hobza, Shun-ichi Ishiuchi, Masaaki Fujii, Mattanjah S. de Vries

    Physical Chemistry Chemical Physics   27 ( 19 )   9980 - 9990   2025

     More details

    Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry (RSC)  

    This study provides a comprehensive investigation of the structural properties of cytosine monomers and dimers, highlighting how tautomer stability shifts under varying conditions.

    DOI: 10.1039/d5cp00657k

    researchmap

  • Unbuckling the 18-Crown-6 Ether Belt Around Metal Ions: Forging the Connection to the Condensed Phase

    Ryu Sakuma, Keisuke Hirata, James M. Lisy, Masaaki Fujii, Shun-ichi Ishiuchi

    Journal of the American Chemical Society   2024.11

     More details

    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/jacs.4c12036

    researchmap

  • Enantioselective complexation of protonated tyrosine by a chiral crown‐ether: the nature of the Hydrogen bonds makes the difference.

    Anne Zehnacker, Kien Xuan Vo, Keisuke Hirata, Bruno Martínez-Haya, Jos Oomens, Shun-ichi Ishiuchi, Masaaki Fujii

    ChemPhysChem   2024.11

     More details

    Publishing type:Research paper (scientific journal)   Publisher:Wiley  

    The complexes formed between (18‐crown‐6)‐tetracarboxylic acid, denoted as 18C6TA, and the two enantiomers of protonated tyrosine, L‐ and D‐Tyr, are studied in a cryogenic ion trap by combining mass spectrometry, laser spectroscopy, and DFT calculations. Both UV and IR photodissociation spectra indicate the formation of multiple isomers for each complex, some of them interconverting upon IR irradiation. Conformer‐selective vibrational spectroscopy reveals that all structures involve an internally hydrogen‐bonded folded structure of the crown ether. The complexes formed with L‐Tyr involve two NH…O interactions with the ether oxygen atoms,and two hydrogen bonds to the crown ether carboxylic function, one from the NH group and the other from the COOH group of tyrosine. The   D‐Tyr complexesshow more conformational mobility: two out of the three lowest energy conformers observed are tripodal, with three NH…O interactions between the amino acid ammonium and the crown ether oxygens. An additional conformer shows only one NH…O interaction, but has two interactions involving one of the cavity COOH moieties, one with the NH and one with the phenol OH. The increased calculated stability of the complex made from (‐) 18C6TA and L‐Tyr parallels its higher abundance in the mass spectrum of an isotopically labelled racemic mixture.

    DOI: 10.1002/cphc.202400880

    researchmap

  • Releasing Preferentially Sequestered Na+ from Its Confinement by Beauvericin: A Single Water Molecule is the Accomplice

    Kien X. Vo, Keisuke Hirata, James M. Lisy, Masaaki Fujii, Shun-ichi Ishiuchi

    The Journal of Physical Chemistry A   2024.10

     More details

    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/acs.jpca.4c04515

    researchmap

  • Water-Induced Dissociative Mechanism of Carboxylate and Divalent Calcium Ions Revealed by IR Laser Spectroscopy

    Jean-Xavier Bardaud, Yurika Hayakawa, Hikaru Takayanagi, Keisuke Hirata, Shun-ichi Ishiuchi, Masaaki Fujii, Eric Gloaguen

    The Journal of Physical Chemistry Letters   9295 - 9300   2024.9

     More details

    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/acs.jpclett.4c01803

    researchmap

  • Micro Solvation Effect of Methanol on Excited-State Dynamics of Protonated Tryptophan and Dopamine

    Hideo Toma, Jun-ichi Tabata, Keisuke Hirata, Gilles Gregoire, Masaaki Fujii, Shun-ichi Ishiuchi

    The Journal of Physical Chemistry A   2024.7

     More details

    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/acs.jpca.4c03178

    researchmap

  • The Gas Phase Protonation Sites of Six Naturally Occurring Nicotinoids

    Yuika Okura, Garrett D. Santis, Keisuke Hirata, Sotiris S. Xantheas, Masaaki Fujii, Shun-Ichi Ishiuchi

    The Journal of Physical Chemistry Letters   6966 - 6973   2024.6

     More details

    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/acs.jpclett.4c01206

    researchmap

  • Affinity of Nicotinoids to a Model Nicotinic Acetylcholine Receptor (nAChR) Binding Pocket in the Human Brain

    Garrett D. Santis, Yuika Okura, Keisuke Hirata, Shun-Ichi Ishiuchi, Masaaki Fujii, Sotiris S. Xantheas

    The Journal of Physical Chemistry B   2024.5

     More details

    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/acs.jpcb.3c07919

    researchmap

  • Switching of Protonation Sites in Hydrated Nicotine via a Grotthuss Mechanism

    Yuika Okura, Garrett D. Santis, Keisuke Hirata, Vasilios S. Melissas, Shun-ichi Ishiuchi, Masaaki Fujii, Sotiris S. Xantheas

    Journal of the American Chemical Society   2024.1

     More details

    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/jacs.3c08922

    researchmap

  • Conformational preference of 2-(4-methoxyphenyl)ethanol studied by supersonic jet spectroscopy: Intramolecular OH/π interaction

    Hironari Nagasawa, Sakuya Ogawa, Wataru Kashihara, Tasuku Isozaki, Keisuke Hirata, Shun-ichi Ishiuchi, Masaaki Fujii, Tadashi Suzuki

    The Journal of Chemical Physics   160 ( 2 )   2024.1

     More details

    Publishing type:Research paper (scientific journal)   Publisher:AIP Publishing  

    A π-type hydrogen bonding between the OH group and the π electron is a crucial factor for the conformational preference of the molecular structure with a flexible group. However, the information on the effect of the substituent on the OH/π interaction is insufficient. The laser-induced fluorescence (LIF) excitation, the dispersed fluorescence (DF), the IR–UV hole-burning, and the IR dip spectra of jet-cooled 2-(4-methoxyphenyl)ethanol were measured for the first time. Almost all bands observed in the spectral region of 35 550–36 500 cm−1 in the LIF excitation spectrum were successfully assigned with the DF and the IR–UV hole-burning spectra coupled with the quantum chemical calculation at M06-2x/6-311G and MP2/6-311G levels. Five conformers were found in the LIF excitation spectrum. The most stable conformer was Ggπ, and the second most stable conformer was Ggπ′ (the trans rotamer of the methoxy group for Ggπ). Ggπ and Ggπ′ had the OH group directed toward the π electron system of the benzene ring. The OH stretching frequency of Ggπ/Ggπ′ of MPE in the IR dip spectra was red-shifted against that of Ggπ of phenylethanol, indicating that the introduction of the methoxy group would enhance the intramolecular OH/π interaction. In addition, the torsional vibration between the benzene ring and the side chain (−CH2CH2OH) (mode 63) was observed in the DF spectra of the Ggπ–00 and Ggπ′–00 band excitation, but their intensities were rather different, resulting from the different orientation of the OH group for each conformer toward the π electron system. The methoxy group would increase the negative charge on the benzene ring and would enhance the intramolecular OH/π interaction through the electrostatic interaction.

    DOI: 10.1063/5.0184664

    researchmap

  • Transition from vehicle to Grotthuss proton transfer in a nanosized flask: Cryogenic ion spectroscopy of protonated p-aminobenzoic acid solvated with D2O

    Keisuke Hirata, Kyota Akasaka, Otto Dopfer, Shun-ichi Ishiuchi, Masaaki Fujii

    Chemical Science   2024

     More details

    Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry (RSC)  

    Proton transfer (PT) is one of the most ubiquitous reactions in chemistry and life science. The unique nature of PT has been rationalized not by a transport of a solvated...

    DOI: 10.1039/d3sc05455a

    researchmap

  • Infrared Spectra of Beauvericin-Alkaline Earth Metal Ion Complexes─Ion Preference to Physiological Ions

    Kien X. Vo, Keisuke Hirata, James M. Lisy, Shun-ichi Ishiuchi, Masaaki Fujii

    The Journal of Physical Chemistry A   2023.8

     More details

    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/acs.jpca.3c02783

    researchmap

  • Does Chiral Sensitivity of a Structure Depend on the Metal Core? Alkali Ion Complexes of Cyclo(Tyr‐Tyr)

    Koki Yoshizawa, Keisuke Hirata, Shun-ichi Ishiuchi, Masaaki Fujii, Anne Zehnacker

    ChemPhysChem   2023.7

     More details

    Publishing type:Research paper (scientific journal)   Publisher:Wiley  

    DOI: 10.1002/cphc.202300172

    researchmap

  • Ion Recognition beyond Size Matching: Cooperative Hydration Effect on the K+ Selectivity of Valinomycin over Na+ Revealed by Cryogenic Double Ion Trap Infrared Spectroscopy

    Keisuke Hirata, Eiko Sato, James M. Lisy, Shun-ichi Ishiuchi, Masaaki Fujii

    The Journal of Physical Chemistry Letters   14 ( 24 )   5567 - 5572   2023.6

     More details

    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/acs.jpclett.3c01030

    researchmap

  • Can Ag+ Permeate through a Potassium Ion Channel? A Bottom-Up Approach by Infrared Spectroscopy of the Ag+ Complex with the Partial Peptide of a Selectivity Filter

    Satoru Tanabe, Keisuke Hirata, Koichi Tsukiyama, James M. Lisy, Shun-ichi Ishiuchi, Masaaki Fujii

    The Journal of Physical Chemistry Letters   2886 - 2890   2023.3

     More details

    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/acs.jpclett.2c03366

    researchmap

  • Thermodynamics and kinetics of a partial peptide of K+ channels: DFT transition state calculations coupled with temperature-controlled gas phase laser spectroscopy

    Yukina Suzuki, Keisuke Hirata, James M. Lisy, Shun-ichi Ishiuchi, Masaaki Fujii

    Bulletin of the Chemical Society of Japan   2023.2

     More details

    Publishing type:Research paper (scientific journal)   Publisher:The Chemical Society of Japan  

    DOI: 10.1246/bcsj.20220345

    researchmap

  • Similarity scores of vibrational spectra reveal the atomistic structure of pentapeptides in multiple basins

    Hiroki Otaki, Shun-ichi Ishiuchi, Masaaki Fujii, Yuji Sugita, Kiyoshi Yagi

    ChemRxiv   10.26434/chemrxiv-2023-qn9rc   2023.2

     More details

  • Stepwise hydration of [CH3COOMg]+ studied by cold ion trap infrared spectroscopy: insights into interactions in the magnesium channel selection filters

    Hikaru Takayanagi, jean-xavier bardaud, Keisuke Hirata, Valerie Brenner, Eric Gloaguen, Shun-ichi Ishiuchi, Masaaki Fujii

    Physical Chemistry Chemical Physics   2023

     More details

    Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry (RSC)  

    The magnesium channel controls Mg2+ concentration in the cell and plays an indispensable role in biological functions. The crystal structure of the Magnesium Transport E channel suggested that Mg2+ hydrated...

    DOI: 10.1039/d3cp00992k

    researchmap

  • Na+ Selective Binding by Beauvericin and Its Mechanism Studied by Mass-Coupled Cold Ion Trap Infrared Spectroscopy

    Kien X. Vo, Keisuke Hirata, James M. Lisy, Shun-ichi Ishiuchi, Masaaki Fujii

    The Journal of Physical Chemistry Letters   11330 - 11334   2022.12

     More details

    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/acs.jpclett.2c02814

    researchmap

  • Ultraviolet and infrared spectra of mono-, di- and tri-hydrated clusters of protonated noradrenaline – Solvation and conformational variations

    Keisuke Yamaguchi, Keisuke Hirata, Shun-ichi Ishiuchi, Masaaki Fujii

    Chemical Physics Letters   806   140014 - 140014   2022.11

     More details

    Publishing type:Research paper (scientific journal)   Publisher:Elsevier BV  

    DOI: 10.1016/j.cplett.2022.140014

    researchmap

  • Conformer‐selective Photodynamics of TrpH+‐H2O

    Franco Molina, Jordan Dezalay, Jun-ichi Tabata, Satchin Soorkia, Michel Broquier, Keisuke Hirata, Shun-Ichi Ishiuchi, Masaaki Fujii, Gilles Grégoire

    ChemPhysChem   2022.9

     More details

    Publishing type:Research paper (scientific journal)   Publisher:Wiley  

    DOI: 10.1002/cphc.202200561

    researchmap

  • Do Stereochemical Effects Overcome a Charge-Induced Perturbation in Isolated Protonated Cyclo(Tyr-Tyr)?

    Koki Yoshizawa, Keisuke Hirata, Shun-Ichi Ishiuchi, Masaaki Fujii, Anne Zehnacker

    The Journal of Physical Chemistry A   126 ( 37 )   6387 - 6394   2022.9

     More details

    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/acs.jpca.2c03789

    researchmap

  • Structure of Gas Phase Monohydrated Nicotine: Implications for Nicotine’s Native Structure in the Acetylcholine Binding Protein

    Garrett D. Santis, Naoya Takeda, Keisuke Hirata, Kazuya Tsuruta, Shun-ichi Ishiuchi, Sotiris S. Xantheas, Masaaki Fujii

    Journal of the American Chemical Society   2022.8

     More details

    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/jacs.2c04064

    researchmap

  • Excited state dynamics of protonated dopamine: Hydration and conformation effects Reviewed

    Keisuke Hirata, Ken-ichi Kasai, Koki Yoshizawa, Gilles Gregoire, Shun-ichi Ishiuchi, Masaaki Fujii

    Physical Chemistry Chemical Physics   24 ( 18 )   10737 - 10744   2022.5

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/D2CP00543C

    researchmap

  • A Bottom-up approach to the ion recognition mechanism of K+ channels from the laser spectroscopy of hydrated partial peptide - alkali metal ion complexes

    Yukina Suzuki, Keisuke Hirata, James M. Lisy, Shun-ichi Ishiuchi, Masaaki Fujii

    Physical Chemistry Chemical Physics   2022

     More details

    Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry (RSC)  

    K+ channels allow selective permeation of K+, but not physiologically abundant Na+, at almost diffusion limit rates. The conduction mechanism of K+ channels is still controversial, with experimental and computation...

    DOI: 10.1039/d2cp01667b

    researchmap

  • Collision-assisted stripping for determination of microsolvation-dependent protonation sites in hydrated clusters by cryogenic ion trap infrared spectroscopy: the case of benzocaineH+(H2O)n

    Keisuke Hirata, Fuad Haddad, Otto Dopfer, Shun-ichi Ishiuchi, Masaaki Fujii

    Physical Chemistry Chemical Physics   24 ( 10 )   5774 - 5779   2022

     More details

    Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry (RSC)  

    Protonation sites in hydrated clusters can be clearly determined by CAS-IRPD (collision-assisted stripping infrared photodissociation) spectroscopy as shown for the example of hydrated protonated benzocaine.

    DOI: 10.1039/d1cp05762f

    researchmap

  • Cation-responsive cavity expansion of valinomycin revealed by cryogenic ion trap infrared spectroscopy

    Keisuke Hirata, Eiko Sato, James M. Lisy, Shun-ichi Ishiuchi, Masaaki Fujii

    Physical Chemistry Chemical Physics   2022

     More details

    Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry (RSC)  

    Valinomycin (VM) is a natural K+-selective ionophore that transports K+ through the cell membrane. VM captures K+ in its central cavity with a C3-symmetric β-turn-like backbone. Although the binding affinity...

    DOI: 10.1039/d2cp04570b

    researchmap

  • Hydration-induced protomer switching in p-aminobenzoic acid studied by cold double ion trap infrared spectroscopy

    Kyota Akasaka, Keisuke Hirata, Fuad Haddad, Otto Dopfer, Shun-ichi Ishiuchi, Masaaki Fujii

    Physical Chemistry Chemical Physics   2022

     More details

    Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry (RSC)  

    Para-aminobenzoic acid (PABA) is a benchmark molecule to study solvent-induced proton site switching. Protonation of the carboxy and amino groups of PABA generates O- and N-protomers of PABAH+, respectively. Ion...

    DOI: 10.1039/d2cp04497h

    researchmap

  • Gas phase protonated nicotine is a mixture of pyridine- and pyrrolidine-protonated conformers: implications for its native structure in the nicotinic acetylcholine receptor

    Naoya Takeda, Keisuke Hirata, Kazuya Tsuruta, Garrett D. Santis, Sotiris S. Xantheas, Shun-ichi Ishiuchi, Masaaki Fujii

    Physical Chemistry Chemical Physics   24 ( 10 )   5786 - 5793   2022

     More details

    Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry (RSC)  

    The infrared (IR) spectra of gas phase protonated nicotine has been measured in the never-before probed N–H “fingerprint region” (3200–3500 cm−1).

    DOI: 10.1039/d1cp05175j

    researchmap

  • Hydration-controlled excited-state relaxation in protonated dopamine studied by cryogenic ion spectroscopy

    Keisuke Hirata, Ken-ichi Kasai, Gilles Grégoire, Shun-ichi Ishiuchi, Masaaki Fujii

    The Journal of Chemical Physics   155 ( 15 )   151101 - 151101   2021.10

     More details

    Publishing type:Research paper (scientific journal)   Publisher:AIP Publishing  

    DOI: 10.1063/5.0066919

    researchmap

  • Double Ion Trap Laser Spectroscopy of Alkali Metal Ion Complexes with a Partial Peptide of the Selectivity Filter in K+ Channels—Temperature Effect and Barrier for Conformational Conversions

    Yukina Suzuki, Keisuke Hirata, James M. Lisy, Shun-ichi Ishiuchi, Masaaki Fujii

    The Journal of Physical Chemistry A   2021.10

     More details

    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/acs.jpca.1c06440

    researchmap

  • Rethinking Ion Transport by Ionophores: Experimental and Computational Investigation of Single Water Hydration in Valinomycin-K+ Complexes

    Eiko Sato, Keisuke Hirata, James M. Lisy, Shun-ichi Ishiuchi, Masaaki Fujii

    The Journal of Physical Chemistry Letters   1754 - 1758   2021.2

     More details

    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/acs.jpclett.0c03372

    researchmap

  • Potassium and Sodium Ions Complexes with a Partial Peptide of the Selectivity Filter in K+ Channels Studied by Cold Ion Trap Infrared Spectroscopy: Effect of Hydration

    Takumi Negoro, Keisuke Hirata, James M. Lisy, Shun-ichi Ishiuchi, Masaaki Fujii

    Physical Chemistry Chemical Physics   2021

     More details

    Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry (RSC)  

    <p>Potassium channels allow K+ to rapidly diffuse, while the selectivity filter (SF) actively blocks Na+. The presence of water in the SF during ion translocation remains under debate due the...</p>

    DOI: 10.1039/d1cp00936b

    researchmap

  • Cryogenic Ion Spectroscopy of a Singly Protonated Peptide DYYVVR: Locating Phosphorylation Sites of a Kinase Domain

    Jang Han Kwon, Min Ji Lee, Gyeongok Song, Kazuya Tsuruta, Shun-Ichi Ishiuchi, Masaaki Fujii, Hyuk Kang

    Journal of Physical Chemistry Letters   11 ( 17 )   7103 - 7108   2020.9

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society  

    DOI: 10.1021/acs.jpclett.0c01802

    Scopus

    PubMed

    researchmap

  • Excited-state proton transfer in protonated adrenaline revealed by cryogenic UV photodissociation spectroscopy Reviewed

    Jordan Dezalay, Michel Broquier, Satchin Soorkia, Keisuke Hirata, Shun-ichi Ishiuchi, Masaaki Fujii, Gilles Grégoire

    Physical Chemistry Chemical Physics   22 ( 20 )   11498 - 11507   2020.4

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry (RSC)  

    <p>Excited state proton transfer is the main non radiative deactivation process in protonated adrenaline.</p>

    DOI: 10.1039/d0cp01127d

    researchmap

  • Alkali and Alkaline Earth Metal Ions Complexes with a Partial Peptide of the Selectivity Filter in K+ Channels Studied by a Cold Ion Trap Infrared Spectroscopy

    Remina Otsuka, Keisuke Hirata, Yuta Sasaki, James M. Lisy, Shun-ichi Ishiuchi, Masaaki Fujii

    ChemPhysChem   21 ( 8 )   712 - 724   2020.4

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Wiley-VCH Verlag  

    DOI: 10.1002/cphc.202000033

    Scopus

    PubMed

    researchmap

  • Alkali and Alkaline Earth Metal Ions Complexes with a Partial Peptide of the Selectivity Filter in K+ Channels Studied by a Cold Ion Trap Infrared Spectroscopy

    Remina Otsuka, Keisuke Hirata, Yuta Sasaki, James M. Lisy, Shun-Ichi Ishiuchi, Masaaki Fujii

    Chemphyschem : a European journal of chemical physics and physical chemistry   21 ( 8 )   687   2020.4

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:NLM (Medline)  

    DOI: 10.1002/cphc.202000246

    Scopus

    PubMed

    researchmap

  • Excited state hydrogen transfer dynamics in phenol–(NH3)2 studied by picosecond UV-near IR-UV time-resolved spectroscopy

    Shun-ichi Ishiuchi, Junko Kamizori, Norihiro Tsuji, Makoto Sakai, Mitsuhiko Miyazaki, Claude Dedonder, Christophe Jouvet, Masaaki Fujii

    Physical Chemistry Chemical Physics   22 ( 10 )   5740 - 5748   2020

     More details

    Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry (RSC)  

    <p>Intersystem crossing from 1πσ* to 3πσ* states traps excited state hydrogen transfer reaction in a bound state formed by 3ππ* and 3πσ* states.</p>

    DOI: 10.1039/c9cp06369b

    researchmap

  • Chiral discrimination between tyrosine and β-cyclodextrin revealed by cryogenic ion trap infrared spectroscopy

    Keisuke Hirata, Yuta Mori, Shun-ichi Ishiuchi, Masaaki Fujii, Anne Zehnacker

    Physical Chemistry Chemical Physics   2020

     More details

    Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry (RSC)  

    <p>Cryogenic ion trap infrared spectroscopy reveals that different binding motifs between the two enantiomers of protonated tyrosine and permethylated β-cyclodextrin result in chiral discrimination.</p>

    DOI: 10.1039/d0cp02968h

    researchmap

  • Ionization-Induced π→H Site Switching in Resorcinol?Arn?(N = 1 and 2) Clusters Probed by Infrared Spectroscopy Reviewed

    Mitsuhiko Miyazaki, Kuntal Chatterjee, Kaori Hattori, Remina Otsuka, Shun-ichi Ishiuchi, Otto Dopfer, Masaaki Fujii

    The Journal of Physical Chemistry A   123 ( 32 )   6828 - 6839   2019.8

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.jpca.9b04460

    researchmap

  • Probing the selectivity of Li+ and Na+ cations on noradrenaline at the molecular level Reviewed

    Shun-ichi Ishiuchi, Hiromichi Wako, Sotiris S. Xantheas, Masaaki Fujii

    Faraday Discussions   217   396 - 413   2019.7

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/C8FD00186C

    researchmap

  • Can the Partial Peptide SIVSF of the β2-Adrenergic Receptor Recognize Chirality of the Epinephrine Neurotransmitter? Reviewed

    Masato Tamura, Tsubasa Sekiguchi, Shun-ichi Ishiuchi, Anne Zehnacker-Rentien, Masaaki Fujii

    The Journal of Physical Chemistry Letters   10 ( 10 )   2470 - 2474   2019.5

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.jpclett.9b00184

    researchmap

  • Ion-peptide interactions between alkali metal ions and a termini-protected dipeptide; Modeling a portion of the selectivity filter in K+ channels Reviewed

    Shun-ichi Ishiuchi, Yuta Sasaki, James M. Lisy, Masaaki Fujii

    Physical Chemistry Chemical Physics   21 ( 2 )   561 - 571   2019.1

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/C8CP05839C

    researchmap

  • Probing chirality recognition of protonated glutamic acid dimers by gas-phase vibrational spectroscopy and first-principles simulations Reviewed

    Johanna Klyne, Aude Bouchet, Shun-ichi Ishiuchi, Masaaki Fujii, Markus Schneider, Carsten Baldauf, Otto Dopfer

    Physical Chemistry Chemical Physics   20 ( 45 )   28452 - 28464   2018.12

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/C8CP05855E

    researchmap

  • Entropic effects make a more tightly folded conformer of a β-amino acid less stable: UV-UV hole burning and IR dip spectroscopy of L-β3-homotryptophan using a laser desorption supersonic jet technique Reviewed

    Woon Yong Sohn, Jeong Jin Kim, Myeongwon Jeon, Takuma Aoki, Shun-ichi Ishiuchi, Masaaki Fujii, Hyuk Kang

    Physical Chemistry Chemical Physics   20 ( 30 )   19979 - 19986   2018.8

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/C8CP02106F

    researchmap

  • Molecular Recognition by a Short Partial Peptide of the Adrenergic Receptor: A Bottom-Up Approach Reviewed

    Tsubasa Sekiguchi, Masato Tamura, Hikari Oba, Pierre ?ar?arbal, Rolando Rafael Lozada-Garcia, Anne Zehnacker-Rentien, Gilles Gr?goire, Shun-ichi Ishiuchi, Masaaki Fujii

    Angewandte Chemie International Edition   57 ( 20 )   5626 - 5629   2018.5

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/anie.201712976

    researchmap

  • Cation-Size-Dependent Conformational Locking of Glutamic Acid by Alkali Ions: Infrared Photodissociation Spectroscopy of Cryogenic Ions Reviewed

    Johanna Klyne, Aude Bouchet, Shun-ichi Ishiuchi, Masaaki Fujii, Otto Dopfer

    The Journal of Physical Chemistry B   122 ( 8 )   2295 - 2306   2018.3

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.jpcb.7b12601

    researchmap

  • Stereochemistry-dependent structure of hydrogen-bonded protonated dimers: The case of 1-amino-2-indanol Reviewed

    Aude Bouchet, Johanna Klyne, Shun-Ichi Ishiuchi, Otto Dopfer, Masaaki Fujii, Anne Zehnacker

    Physical Chemistry Chemical Physics   20 ( 18 )   12430 - 12443   2018

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry  

    DOI: 10.1039/c8cp00787j

    Scopus

    researchmap

  • Conformation of protonated glutamic acid at room and cryogenic temperatures Reviewed

    Aude Bouchet, Johanna Klyne, Shun-ichi Ishiuchi, Masaaki Fujii, Otto Dopfer

    PHYSICAL CHEMISTRY CHEMICAL PHYSICS   19 ( 17 )   10767 - 10776   2017.5

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/c6cp08553a

    Web of Science

    researchmap

  • A conformational study of protonated noradrenaline by UV-UV and IR dip double resonance laser spectroscopy combined with an electrospray and a cold ion trap method Reviewed

    Hiromichi Wako, Shun-ichi Ishiuchi, Daichi Kato, Geraldine Feraud, Claude Dedonder-Lardeux, Christophe Jouvet, Masaaki Fujii

    PHYSICAL CHEMISTRY CHEMICAL PHYSICS   19 ( 17 )   10777 - 10785   2017.5

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/c6cp08426e

    Web of Science

    researchmap

  • High-cooling-efficiency cryogenic quadrupole ion trap and UV-UV hole burning spectroscopy of protonated tyrosine Reviewed

    Shun-ichi Ishiuchi, Hiromichi Wako, Daichi Kato, Masaaki Fujii

    JOURNAL OF MOLECULAR SPECTROSCOPY   332   45 - 51   2017.2

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/j.jms.2016.10.011

    Web of Science

    researchmap

  • Anharmonic Vibrational Analyses of Pentapeptide Conformations Explored with Enhanced Sampling Simulations Reviewed

    Otaki Hiroki, Yagi Kiyoshi, Ishiuchi Shun-ichi, Fujii Masaaki, Sugita Yuji

    JOURNAL OF PHYSICAL CHEMISTRY B   120 ( 39 )   10199 - 10213   2016.10

  • Gas phase ultraviolet and infrared spectroscopy on a partial peptide of β2-adrenoceptor SIVSF-NH2 by a laser desorption supersonic jet technique Reviewed

    Shun-ichi Ishiuchi, Kohei Yamada, Hikari Oba, Hiromichi Wako, Masaaki Fujii

    Physical Chemistry Chemical Physics   18 ( 33 )   23277 - 23284   2016.9

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.chemrev.5b00610

    researchmap

  • Effective Strategy for Conformer-Selective Detection of Short-Lived Excited State Species: Application to the IR Spectroscopy of the N1H Keto Tautomer of Guanine Reviewed

    Hiroya Asami, Munefumi Tokugawa, Yoshiaki Masaki, Shun-ichi Ishiuchi, Eric Gloaguen, Kohji Seio, Hiroyuki Saigusa, Masaaki Fujii, Mitsuo Sekine, Michel Mons

    The Journal of Physical Chemistry A   120 ( 14 )   2179 - 2184   2016.4

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.jpca.6b01194

    researchmap

  • Structural motifs of 2-(2-fluoro-phenyl)-ethylamine conformers Reviewed

    Nitzan Mayorkas, Hanan Sachs, Markus Sch?tz, Shun-ichi Ishiuchi, Masaaki Fujii, Otto Dopfer, Ilana Bar

    Physical Chemistry Chemical Physics   18 ( 2 )   1191 - 1201   2016.1

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/C5CP06131H

    researchmap

  • Spectroscopic study of jet-cooled indole-3-carbinol by laser desorption technique: Franck?Condon simulations and anharmonic calculations Reviewed

    Ahreum Ahn, Ahreum Min, Cheol Joo Moon, Ji Hoon Lee, Seung Jun Lee, Taichi Warashina, Shun-ichi Ishiuchi, Masaaki Fujii, Myong Yong Choi

    Chemical Physics Letters   638   237 - 243   2015.10

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/j.cplett.2015.08.063

    researchmap

  • Mass analyzed threshold ionization detected infrared spectroscopy: isomerization activity of the phenol?Ar cluster near the ionization threshold Reviewed

    Mitsuhiko Miyazaki, Shunpei Yoshikawa, Fran?ois Michels, Kentaro Misawa, Shun-ichi Ishiuchi, Makoto Sakai, Otto Dopfer, Klaus M?ller-Dethlefs, Masaaki Fujii

    Physical Chemistry Chemical Physics   17 ( 4 )   2949 - 2503   2015.1

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/C4CP04584J

    Scopus

    researchmap

  • UV-UV hole burning and IR dip spectroscopy of homophenylalanine by laser desorption supersonic jet technique Reviewed

    Woon Yong Sohn, Shun-ichi Ishiuchi, Pierre ?ar?abal, Hikari Oba, Masaaki Fujii

    Chemical Physics   445   21 - 30   2014.12

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/j.chemphys.2014.10.012

    researchmap

  • Fast Nonradiative Decay in o-Aminophenol Reviewed

    Marcela C. Capello, Michel Broquier, Shun-Ichi Ishiuchi, Woon Y. Sohn, Masaaki Fujii, Claude Dedonder-Lardeux, Christophe Jouvet, Gustavo A. Pino

    The Journal of Physical Chemistry A   118 ( 11 )   2056 - 2062   2014.4

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/jp411457v

    researchmap

  • Solvent Migration in Microhydrated Aromatic Aggregates: Ionization‐Induced Site Switching in the 4‐Aminobenzonitrile?Water Cluster Reviewed

    Takashi Nakamura, Matthias Schmies, Alexander Patzer, Mitsuhiko Miyazaki, Shun-ichi Ishiuchi, Martin Weiler, Otto Dopfer, Masaaki Fujii

    Chemistry - A European Journal   20 ( 7 )   7月23日 - 7月31日   2014.2

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/chem.201303321

    researchmap

  • Ionization-induced π→H site-switching in phenol?CH4 complexes studied using IR dip spectroscopy Reviewed

    Mitsuhiko Miyazaki, Akihiro Takeda, Matthias Schmies, Makoto Sakai, Kentaro Misawa, Shun-ichi Ishiuchi, Fran?ois Michels, Klaus M?ller-Dethlefs, Otto Dopfer, Masaaki Fujii

    Physical Chemistry Chemical Physics   16 ( 1 )   110 - 116   2014.1

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/C3CP53533A

    Scopus

    PubMed

    researchmap

  • Unusual Behavior in the First Excited State Lifetime of Catechol Reviewed

    Martin Weiler, Mitsuhiko Miyazaki, G?raldine F?raud, Shun-ichi Ishiuchi, Claude Dedonder, Christophe Jouvet, Masaaki Fujii

    The Journal of Physical Chemistry Letters   4 ( 22 )   3819 - 3823   2013.11

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/jz402089m

    researchmap

  • Laser Desorption Supersonic Jet Spectroscopy of Octopamine by Its Hydrochloride Salt Reviewed

    Shun-ichi Ishiuchi, Hirokazu Sone, Masaaki Fujii

    Chemistry Letters   42 ( 10 )   1166 - 1167   2013.10

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:The Chemical Society of Japan  

    Octopamine is a phenol analog of noradrenaline and acts as a neurotransmitter in invertebrates such as octopus. It is available as a hydrochloride salt to avoid air oxidation. We applied laser desorption supersonic jet technique to octopamine hydrochloride without any chemical preparations and found that molecular ion of octopamine, not salt, is observed. Resonance-enhanced 2-photon ionization and ultraviolet–ultraviolet hole-burning spectra of octopamine were measured, and four conformers were identified. This number of conformations is rationalized by conformations of ethanolamine chain and orientations of phenolic OH.

    DOI: 10.1246/cl.130431

    CiNii Books

    researchmap

  • Gas-Phase Spectroscopy of Laser-Desorbed Acedan and Proline-Acedan Reviewed

    Hae Jun Jung, Woon Yong Sohn, Cheol Ho Heo, Hwan Myung Kim, Shun-ichi Ishiuchi, Masaaki Fujii, Hyuk Kang

    Bulletin of the Korean Chemical Society   34 ( 8 )   2241 - 2242   2013.8

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.5012/bkcs.2013.34.8.2241

    researchmap

  • Gas-phase spectroscopy and anharmonic vibrational analysis of the 3-residue peptide Z-Pro-Leu-Gly-NH2 by the laser desorption supersonic jet technique Reviewed

    Ishiuchi Shun-ichi, Yamada Kohei, Chakraborty Shamik, Yagi Kiyoshi, Fujii Masaaki

    CHEMICAL PHYSICS   419   145 - 152   2013.6

  • Revised conformational assignments and conformational evolution of tyrosine by laser desorption supersonic jet laser spectroscopy Reviewed

    Yoko Shimozono, Kohei Yamada, Shun-ichi Ishiuchi, Koichi Tsukiyama, Masaaki Fujii

    Physical Chemistry Chemical Physics   15 ( 14 )   5163 - 5175   2013.4

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/C3CP43573C

    researchmap

  • Microsolvation of the 4-Aminobenzonitrile Cation (ABN+) in a Nonpolar Solvent: IR Spectra of ABN+-Ln (L=Ar and N2, n≦4) Reviewed

    Matthias Schmies, Alexander Patzer, Sarah Kruppe, Mitsuhiko Miyazaki, Shun-ichi Ishiuchi, Masaaki Fujii, Otto Dopfer

    ChemPhysChem   14 ( 4 )   728 - 740   2013.3

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/cphc.201200790

    researchmap

  • IR Spectroscopy of the 4-Aminobenzonitrile-Ar Cluster in the S0, S1 Neutral and D0 Cationic States Reviewed

    Takashi Nakamura, Mitsuhiko Miyazaki, Shun-ichi Ishiuchi, Martin Weiler, Matthias Schmies, Otto Dopfer, Masaaki Fujii

    ChemPhysChem   14 ( 4 )   741 - 745   2013.3

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/cphc.201200821

    researchmap

  • Imaging of Polycyclic Aromatic Hydrocarbons by Means of Sputtered Neutral Mass Spectrometry Using a Diode-pumped Solid-State Laser Reviewed

    Kenji OHISHI, Tetsuo SAKAMOTO, Jiro SAIKAWA, Naoya ISHIGAKI, Koji TOJO, Yutaka IDO, Shun-ichi ISHIUCHI, Kentaro MISAWA, Masaaki FUJII

    Analytical Sciences   29 ( 3 )   291 - 295   2013.3

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:The Japan Society for Analytical Chemistry  

    Laser post-ionization of sputtered molecules by pulsed Ga focused ion-beam (Ga-FIB) bombardment was examined for the detection and imaging of polycyclic aromatic hydrocarbons (PAHs) on particles. As model samples, pyrene and pelyrene adsorbed on TiO2, blended regents of pyrene and n-heneicosan were used. The TiO2 particle size was selected to be several micro-meters. Laser light and Ga-FIB were synchronized with each other. The repetition rate synchronized with Ga-FIB was 1 kHz for pyrene analysis and 2 kHz for perylene, respectively. The laser wavelength was set to 266 nm. The wavelength was a generated fourth harmonic of a Nd:YAG DPSS (diode-pumped solid-state) micro-chip laser (UV microchip laser). By using a UV microchip laser, laser-SNMS (laser post-ionized sputtered neutral mass spectrometry) analysis and imaging were performed. The imaging of pyrene (m/z = 202, C16H10) and perylene (m/z = 252, C20H12) has been successful. Both the scanning ion microscopy image of TiO2 and the PAHs image in laser-SNMS analysis were well-fitted with each other.

    DOI: 10.2116/analsci.29.291

    CiNii Books

    researchmap

    Other Link: https://jlc.jst.go.jp/DN/JALC/10015807082?from=CiNii

  • Ground State Proton Transfer in Phenol-(NH3)n (n?11) Clusters Studied by Mid-IR Spectroscopy in 3-10 μm Range Reviewed

    Mitsuhiko Miyazaki, Ayako Kawanishi, Iben Nielsen, Ivan Alata, Shun-ichi Ishiuchi, Claude Dedonder, Christophe Jouvet, Masaaki Fujii

    The Journal of Physical Chemistry A   117 ( 7 )   1522 - 1530   2013.2

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/jp312074m

    researchmap

  • Structure of 1-naphthol?water clusters in the S1 state studied by UV?IR fluorescence dip spectroscopy and ab initio molecular orbital calculations Reviewed

    Toshihiko Shimizu, Ruriko Yoshino, Shun-ichi Ishiuchi, Kenro Hashimoto, Mitsuhiko Miyazaki, Masaaki Fujii

    Chemical Physics Letters   557   19 - 25   2013.2

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/j.cplett.2012.11.030

    researchmap

  • Conformationally resolved spectra of Acetaminophen by UV-UV hole burning and IR dip spectroscopy in gas phase Reviewed

    Woon Yong Sohn, Shun-ichi Ishiuchi, Mitsuhiko Miyazaki, Jeong Seok Kang, So Young Lee, Ahreum Min, Myong Yong Choi, Hyuk Kang, Masaaki Fujii

    Physical Chemistry Chemical Physics   15 ( 3 )   957 - 964   2013.1

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/C2CP43552G

    researchmap

  • Gas phase IR spectra of tri-peptide Z-Pro-Leu-Gly: Effect of C-terminal amide capping on secondary structure Reviewed

    Shamik Chakraborty, Kohei Yamada, Shun-ichi Ishiuchi, Masaaki Fujii

    Chemical Physics Letters   531   41 - 45   2012.4

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/j.cplett.2012.01.086

    researchmap

  • A two-color tunable infrared/vacuum ultraviolet spectrometer for high-resolution spectroscopy of molecules in molecular beams Reviewed

    Jonathan R. Woodward, Hirokazu Watanabe, Shun-ichi Ishiuchi, Masaaki Fujii

    Review of Scientific Instruments   83 ( 1 )   014102-1 - 014102-9   2012.1

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1063/1.3673639

    Web of Science

    researchmap

  • Gas-phase Infrared Spectroscopy of Monopeptides from 10 to 3 ?m Reviewed

    Mitsuhiko Miyazaki, Koji Makara, Shun-ichi Ishiuchi, Masaaki Fujii

    Chemistry Letters   40 ( 10 )   1157 - 1158   2011.10

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:The Chemical Society of Japan  

    Infrared spectra of protected amino acids, N-benzoxycarbonyl-<small>L</small>-proline and N-benzoxycarbonyl-<small>L</small>-isoleucine were measured in the gas phase from 10 to 3 µm. 4 and 3 conformers were found, respectively. The spectra in the 3 µm region reveal the carboxylic OH and amide NH bonds do not participate in hydrogen bonding with neighboring amide groups despite the highest acidity in the molecule. The spectra in the 10–5 µm region imply the main chain structure is the same among the conformers.

    DOI: 10.1246/cl.2011.1157

    CiNii Books

    researchmap

  • Gas-Phase Spectroscopy of Synephrine by Laser Desorption Supersonic Jet Technique Reviewed

    Shun-ichi Ishiuchi, Toshiro Asakawa, Haruhiko Mitsuda, Mitsuhiko Miyazaki, Shamik Chakraborty, Masaaki Fujii

    The Journal of Physical Chemistry A   115 ( 37 )   10363 - 10369   2011.9

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/jp205267c

    researchmap

  • Isomerization reaction in high-n Rydberg states of phenol-Ar/Kr clusters measured by autoionization detected infrared spectroscopy Reviewed

    Mitsuhiko Miyazaki, Shinya Tanaka, Shun-ichi Ishiuchi, Otto Dopfer, Masaaki Fujii

    Chemical Physics Letters   513 ( 4-6 )   208 - 211   2011.9

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/j.cplett.2011.08.001

    researchmap

  • Hole-Burning Spectra of m-Fluorophenol/Ammonia (1:3) Clusters and Their Excited State Hydrogen Transfer Dynamics Reviewed

    Norihiro Tsuji, Shun-ichi Ishiuchi, Christophe Jouvet, Claude Dedonder-Lardeux, Mitsuhiko Miyazaki, Makoto Sakai, Masaaki Fujii

    ChemPhysChem   12 ( 10 )   1928 - 1934   2011.7

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/cphc.201100102

    researchmap

  • Conformational reduction of DOPA in the gas phase studied by laser desorption supersonic jet laser spectroscopy Reviewed

    Shun-ichi Ishiuchi, Haruhiko Mitsuda, Toshiro Asakawa, Mitsuhiko Miyazaki, Masaaki Fujii

    Physical Chemistry Chemical Physics   13 ( 17 )   7812 - 7820   2011.5

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/C0CP02695F

    researchmap

  • Photoionization-induced large-amplitude pendular motion in phenol+-Kr Reviewed

    Mitsuhiko Miyazaki, Akihiro Takeda, Shun-ichi Ishiuchi, Makoto Sakai, Otto Dopfer, Masaaki Fujii

    Physical Chemistry Chemical Physics   13 ( 7 )   2744 - 2747   2011.2

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/C0CP01961E

    researchmap

  • Ionization-induced π → H site switching dynamics in phenol-Ar3 Reviewed

    Shun-ichi Ishiuchi, Mitsuhiko Miyazaki, Makoto Sakai, Masaaki Fujii, Matthias Schmies, Otto Dopfer

    Physical Chemistry Chemical Physics   13 ( 6 )   2409 - 2416   2011.2

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/C0CP01926G

    researchmap

  • Structural Evolution of (1-NpOH)(n) Clusters Studied by R2PI and IR Dip Spectroscopies Reviewed

    Saeki Morihisa, Ishiuchi Shun-ichi, Sakai Makoto, Hashimoto Kenro, Fujii Masaaki

    JOURNAL OF PHYSICAL CHEMISTRY A   114 ( 42 )   11210 - 11215   2010.10

  • Dissociation energetics of the phenol+…Ar2 cluster ion: The role of π→H isomerization Reviewed

    Xin Tong, Antonio Armentano, Mikko Riese, Med Ben Yezzar, Simon M. Pimblott, Klaus M?ller-Dethlefs, Shun-ichi Ishiuchi, Makoto Sakai, Akihiro Takeda, Masaaki Fujii, Otto Dopfer

    The Journal of Chemical Physics   133 ( 15 )   154308-1 - 154308-5   2010.10

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1063/1.3482733

    researchmap

  • Evidence for Catechol Ring- Induced Conformational Restriction in Neurotransmitters Reviewed

    Haruhiko Mitsuda, Mitsuhiko Miyazaki, Iben B. Nielsen, Pierre ?ar?abal, Claude Dedonder, Cristophe Jouvet, Shun-ichi Ishiuchi, Masaaki Fujii

    The Journal of Physical Chemistry Letters   1 ( 7 )   1130 - 1133   2010.4

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/jz100186h

    researchmap

  • Measurement of adiabatic ionization energies of the rotational isomers of n-propylbenzene and m-fluorophenol by direct VUV laser photoionization Reviewed

    Hirokazu Watanabe, Shun-ichi Ishiuchi, Kentaro Misawa, Mitsuhiko Miyazaki, Jonathan, R. Woodward, Masaaki Fujii

    Chemical Physics Letters   485 ( 1-3 )   31 - 35   2010.1

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/j.cplett.2009.12.023

    Scopus

    researchmap

  • Real-time Analysis of Benzene in Exhaust Gas from Driving Automobiles Using Jet-REMPI Method Reviewed

    Kentaro Misawa, Shun-ichi Ishiuchi, Masaaki Fujii, Jun Matsumoto, Koichi Tanaka, Jun Nakagawa, Katsumi Endo, Shunichi Hayashi, Kotaro Tanaka, Hiroyuki Yamada, Yuichi Goto

    SAE Technical papers   2009-01-2740   2009.11

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.4271/2009-01-2740

    Scopus

    researchmap

  • レーザーイオン化法による自動車排出ガスのリアルタイム質量分析(第2報) ―モード走行時の排出傾向― // Real-time Mass Spectrometry of Exhaust Gas from Automobiles Utilizing Laser Ionization (Second Report) ―Emission Trends in Driving Mode― Reviewed

    田中 光太郎, 三澤 健太郎, 田中 康一, 松本 淳, 石内 俊一, 齊川 次郎, 藤井 正明, 林 俊一, 柏木 隆宏, 中川 潤, 遠藤 克己, 渡辺 敬太郎, 山田 裕之, 後藤 雄一, Kotaro Tanaka, Kentaro Misawa, Koichi Tanaka, Jun Matsumoto, Shun-ichi Ishiuchi, Jiro Saikawa, Masaaki Fujii, Shun-ichi Hayashi, Takahiro Kashiwagi, Jun Nakagawa, Katsumi Endo, Keitaro Watanabe, Hiroyuki Yamada, Yuichi Goto

    自動車技術会論文集   40 ( 5 )   1339 - 1344   2009.9

     More details

    Publishing type:Research paper (scientific journal)  

    researchmap

  • レーザーイオン化 法による自動車排出ガスのリアルタイム質量分析(第1報) ―多成分同時分析装置の開発― // Real-time Mass Spectrometry of Exhaust Gas from Automobiles Utilizing Laser Ionization (First Report) ―Development of Simultaneous Analyzer of Multicomponents― Reviewed

    三澤 健太郎, 田中 光太郎, 田中 康一, 松本 淳, 石内 俊一, 齊川 次郎, 林 俊一, 藤井 正明, 柏木 隆宏, 中川 潤, 遠藤 克己, 渡辺 敬太郎, 山田 裕之, 後藤 雄一, Kentaro Misawa, Kotaro Tanaka, Koichi Tanaka, Jun Matsumoto, Shun-ichi Ishiuchi, Jiro Saikawa, Shun-ichi Hayashi, Masaaki Fujii, Takahiro Kashiwagi, Jun Nakagawa, Katsumi Endo, Keitaro Watanabe, Hiroyuki Yamada, Yuichi Goto

    自動車技術会論文集   40 ( 5 )   1333 - 1338   2009.9

     More details

    Publishing type:Research paper (scientific journal)  

    researchmap

  • Simultaneous Measurements for Multicomponents of VOCs and PAHs in Diesel Exhaust Gas using a Laser Ionization Method Reviewed

    Kotaro Suzaki, Hiroyuki Yamada, Yuichi Goto, Kentaro Misawa, Jun Matsumoto, Masaaki Fujii, Koichi Tanaka, Keitaro Watanabe, Shun-ichi Ishiuchi, Jun Nakagawa, Katsumi Endo, Shunichi Hayashi

    SAE Technical papers   2009-01-1842   2009.6

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.4271/2009-01-1842

    Scopus

    researchmap

  • Time-resolved measurements of low concentration aromatic hydrocarbons in diesel exhaust using a resonance enhanced multi-photon ionization method Reviewed

    Kentaro Misawa, Koichi Tanaka, Hiroyuki Yamada, Yuichi Goto, Jun Matsumoto, Yohei Yamato, Shun-ichi Ishiuchi, Masaaki Fujii, Katsumi Endo, Shun-ichi Hayashi

    Internatinal Journal of Engine research   10 ( 6 )   409 - 417   2009.6

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1243/14680874JER03909

    Scopus

    researchmap

  • IR spectra of resorcinol+-Arn cluster cations (n = 1, 2): Evidence for photoionization-induced π → H isomerization Reviewed

    Alexander Patzer, Judith Langer, Harald Knorke, Helge Neitsch, Otto Dopfer, Mitsuhiko Miyazaki, Kaori Hattori, Akihiro Takeda, Shun-ichi Ishiuchi, Masaaki Fujii

    Chemical Physics Letters   474 ( 1-3 )   7 - 12   2009.5

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/j.cplett.2009.04.030

    researchmap

  • The most stable conformer of benzyl alcohol Reviewed

    Benjamin J. Miller, Henrik G. Kjaergaard, Kaori Hattori, Shun-ichi Ishiuchi, Masaaki Fujii

    Chemical Physics Letters   466 ( 1-3 )   21 - 26   2008.11

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/j.cplett.2008.10.028

    researchmap

  • Development of Supercritical Fluid Jet Spectroscopy and Its Application for Spectroscopy of Supra Functional Systems Reviewed

    ISHIUCHI Shun-ichi, Fujii Masaaki

    Bunko Kenkyu   57 ( 4 )   158 - 167   2008.8

     More details

    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:The Spectroscopical Society of Japan  

    We developed a supercritical fluid jet technique, which enables the vaporization and the jet-cooling of non-vola-tile molecules by supersonic expansion of their supercritical solutions to vacuum directly. For its purpose, a new high-pressure pulsed valve was developed. By using this pulsed valve, we could introduce the high-pressure fluid. over 25MPa into vacuum as a short gaseous pulse, and confirmed that we can obtain an enough jet-cooling condi-tion. In this review, we will introduce a detail of the high-pressure pulsed valve and its application for the super-critical fluid jet spectroscopy.

    DOI: 10.5111/bunkou.57.158

    researchmap

  • Real-Time and Direct Measurement of Pollutants in Exhaust Gas Utilizing Supersonic Jet/Resonance Enhanced Multi-Photon Ionization Reviewed

    Kentaro Misawa, Jun Matsumoto, Yohei Yamato, Saori Mae, Shun-ichi Ishiuchi, Masaaki Fujii, Koichi Tanaka, Tetsuya Suzuki, Shun-ichi Hayashi, Hiroyuki Yamada, Yuichi Goto

    SAE Technical Papers   2008-01-0761   2008.4

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.4271/2008-01-0761

    Scopus

    researchmap

  • Development of high sensitive on-line laser ionization mass spectrometer for environmental hazardous organic compounds Reviewed

    Shun-ichi Fiayashi, Tetsuya Suzuki, Shun-ichi Ishiuchi, Masaaki Fujii

    BUNSEKI KAGAKU   57 ( 4 )   227 - 237   2008.4

     More details

    Language:Japanese   Publishing type:Research paper (scientific journal)  

    Web of Science

    researchmap

  • 環境負荷物質分析のための高感度オンラインレーザーイオン化質量分析装置の開発 Reviewed

    林 俊一, 鈴木 哲也, 石内 俊一, 藤井 正明

    分析化学   57 ( 4 )   227 - 237   2008.4

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.2116/bunsekikagaku.57.227

    researchmap

  • 超高感度レーザー分析の最前線=分子選択的リアルタイム高感度分析= Reviewed

    三澤 健太郎, 松本 淳, 石内 俊一, 藤井 正明, 林 俊一

    光アライアンス   19 ( 3 )   48 - 52   2008.3

     More details

    Publishing type:Research paper (scientific journal)  

    researchmap

  • 超音速分子ジェット多光子共鳴イオン化質量分析装置を用いる石炭加熱時のナフタレン発生挙動の観察 Reviewed

    相本 道宏, 西藤 将之, 林 俊一, 鈴木 哲也, 石内 俊一, 藤井 正明

    分析化学   56 ( 12 )   1133 - 1139   2007.12

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.2116/bunsekikagaku.56.1133

    researchmap

  • Thermal emission monitoring of naphthalene from coals by supersonic jet resonance enhanced multi-photon ionization time-of-flight mass spectrometry technique Reviewed

    Michiro Aimoto, Masayuki Nishifuji, Shun-ichi Hayashi, Tetsuya Suzuki, Shun-ichi Ishiuchi, Masaaki Fujii

    BUNSEKI KAGAKU   56 ( 12 )   1133 - 1139   2007.12

     More details

    Language:Japanese   Publishing type:Research paper (scientific journal)  

    Web of Science

    researchmap

  • 共鳴多光子イオン化法を用いたオンサイト・リアルタイム質量分析 // On-site and Real-time Mass Spectrometer Utilizing the Resonance Enhanced Multi-photon Ionization Technique Reviewed

    松本 淳, 三澤 健太郎, 石内 俊一, 鈴木 哲也, 林 俊一, 藤井 正明

    真空 Journal of the Vacuum Society of Japan   50 ( 4 )   241 - 245   2007.4

     More details

    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:The Vacuum Society of Japan  

    DOI: 10.3131/jvsj.50.241

    CiNii Books

    researchmap

    Other Link: https://jlc.jst.go.jp/DN/JALC/00293460697?from=CiNii

  • Vibrational Overtone Spectroscopy of Phenol and Its Deuterated Isotopomers Reviewed

    Shun-ichi Ishiuchi, Masaaki Fujii, Timothy W. Robinson, Benjamin J. Miller, Henrik G. Kjaergaard

    The Journal of Physical Chemistry A   110 ( 23 )   7345 - 7354   2006.6

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/jp060723q

    researchmap

  • 超音速分子ジェット多光分子吸収イオン化質量分析法を基本とする環境負荷物質リアルタイムモニタリング装置の開発 // Development of Real Time Monitoring Apparatus Based on Jet-REMPI Technique for the Determination of Hazardous Organic Compounds Reviewed

    林 俊一, 鈴木 哲也, 石内 俊一, 藤井 正明

    鉄と鋼   92 ( 4 )   262 - 267   2006.4

     More details

    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:The Iron and Steel Institute of Japan (ISIJ)  

    For monitoring of hazardous organic compounds, we have been developing an on-line analytical instrument based on a supersonic jet resonance enhanced multi-photon laser ionization (Jet-REMPI) mass spectrometry. We have attempted to apply this technique to monitor transient attitudes of hazardous organic compounds, e.g. in the exhaust gas. It becomes possible that the real time monitoring of the gaseous compounds in atmosphere by our instrument with a continuous sample introduction. We demonstrated that the signals of mono-chlorinated benzene in the air could be detected with 150s interval through a 23m stainless steel pipe, which kept 200 degree of centigrade. Our instrument has a very high vacuum pumping system to keep the difference of the vacuum level between in atmosphere and in ionization chamber. It has been proved that monitored molecules were well cooled as the result of REMPI spectra. It is strongly advantageous for the selective detection of a specific molecular species. The emission mechanism of chlorinated aromatic compounds is discussed by monitoring 2 different kinds of compounds, simultaneously.

    DOI: 10.2355/tetsutohagane1955.92.4_262

    CiNii Books

    researchmap

  • レーザーイオン化質量分析による超微量物質検出 Reviewed

    林 俊一, 鈴木 哲也, 石内 俊一, 藤井 正明

    レーザー研究   34 ( 4 )   283 - 288   2006.4

     More details

    Publishing type:Research paper (scientific journal)  

    researchmap

  • Analysis of a fluorescence depletion process of Rhodamine 6G in a PMMA matrix induced by nano- and picosecond lasers Reviewed

    Takeshi Watanabe, Yoshinori Iketaki, Makoto Sakai, Tsutom Ohmori, Tadashi Ueda, Takaya Yamanaka, Shun-ichi Ishiuchi, Masaaki Fujii

    Chemical Physics Letters   420 ( 4-6 )   410 - 415   2006.3

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/j.cplett.2005.12.020

    researchmap

  • A New, Highly Sensitive Time-of-Flight Mass Spectrometer Consisting of a Flangeon-type Conical Ion Lens System and a Proto-type Daly Detector for Exhaust Gas Analysis Based on the Jet-REMPI Technique Reviewed

    Tetsuya SUZUKI, Shun-ichi HAYASHI, Shun-ichi ISHIUCHI, Morihisa SAEKI, Masaaki FUJII

    Analytical Sciences   21 ( 8 )   991 - 996   2005.8

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    CiNii Books

    researchmap

  • Pulsed field ionisation - ZEKE photoelectron spectrum of o-, m- and p-tolunitrile Reviewed

    K Suzuki, S Ishiuchi, M Sakai, M Fujii

    JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA   142 ( 3 )   215 - 221   2005.3

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/j.elspec.2004.09.020

    Web of Science

    researchmap

  • Vibrational overtone spectroscopy of jet-cooled aminophenols as a probe for rotational isomers Reviewed

    Timothy W. Robinson, Henrik G. Kjaergaard, Shun-Ichi Ishiuchi, Minako Shinozaki, Masaaki Fujii

    Journal of Physical Chemistry A   108 ( 20 )   4420 - 4427   2004.5

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/jp037577y

    Scopus

    researchmap

  • Formation of a doughnut laser beam for super-resolving microscopy using a phase spatial light modulator Reviewed

    T Watanabe, Y Igasaki, N Fukuchi, M Sakai, S Ishiuchi, M Fujii, T Omatsu, K Yamamoto, Y Iketaki

    OPTICAL ENGINEERING   43 ( 5 )   1136 - 1143   2004.5

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1117/1.1690767

    Web of Science

    researchmap

  • Predicted Spatial Resolution of Super-Resolving Fluorescence Microscopy Using Two-Color Fluorescence Dip Spectroscopy Reviewed

    Yoshinori Iketaki, Takeshi Watanabe, Shun-Ichi Ishiuchi, Makoto Sakai, Takashige Omatsu, Kimihisa Yamamoto, Masaaki Fujii

    Applied Spectroscopy   57 ( 10 )   1312 - 1316   2003.10

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1366/000370203769699234

    Scopus

    PubMed

    researchmap

  • Two-color far-field super-resolution microscope using a doughnut beam Reviewed

    Watanabe T, Iketaki Y, Omatsu T, Yamamoto K, Ishiuchi S, Sakai M, Fujii M

    CHEMICAL PHYSICS LETTERS   371 ( 5-6 )   634 - 639   2003.4

  • Photochemistry of Phenol-(NH3)n Clusters: Solvent Effect of a Radical Cleavage of an OH bond in an Electronically Excited State and Intracluster reactions of the Product NH4(NH3)n-1 (n ?5) Reviewed

    Kota Daigoku, Shun'ichi Ishiuchi, Makoto Sakai, Masaaki Fujii, Kenro Hashimoto

    J. Chem. Phys.   119 ( 10 )   5149 - 5158   2003

     More details

  • Far-field super-resolution scanning fluorescence microscope by using up-conversion-depletion technique

    Takeshi Watanabe, Makoto Sakai, Shun-Ichi Ishiuchi, Masaaki Fujii, Yoshinori Iketaki, Takashige Omatsu, Kimihisa Yamamoto

    OSA Trends in Optics and Photonics Series   88   750 - 752   2003

     More details

    Language:English   Publishing type:Research paper (international conference proceedings)   Publisher:Optical Society of American (OSA)  

    Scopus

    researchmap

  • The PFI-ZEKE photoelectron spectrum of m-fluorophenol and its aqueous complexes: Comparing intermolecular vibrations in rotational isomers Reviewed

    Keigo Yosida, Kazunari Suzuki, Shun-ichi Ishiuchi, Makoto Sakai, Masaaki Fujii, Caroline E, H. Dessent, Klaus M?ller-Dethlefs

    Physical Chemistry Chemical Physics   4 ( 12 )   2534 - 2538   2002.6

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/B201107G

    researchmap

  • Structure of 1-naphthol/alcohol clusters studied by IR dip spectroscopy and ab initio molecular orbital calculations Reviewed

    Saeki M, Ishiuchi S, Sakai M, Fujii M

    JOURNAL OF PHYSICAL CHEMISTRY A   105 ( 44 )   10045 - 10053   2001.11

  • Structures of carbazole-(H2O)(n) (n=1-3) clusters studied by IR dip spectroscopy and a quantum chemical calculation Reviewed

    Sakai M, Daigoku K, Ishiuchi S, Saeki M, Hashimoto K, Fujii M

    JOURNAL OF PHYSICAL CHEMISTRY A   105 ( 38 )   8651 - 8657   2001.9

  • Electronic and infrared spectra of jet-cooled 4-aminobenzonitrile-H2O. Change of NH from proton acceptor to proton donor by CN substitution Reviewed

    Kenji Sakota, Norifumi Yamamoto, Kazuhiko Ohashi, Hiroshi Sekiya, Morihisa Saeki, Shun-ichi Ishiuchi, Makoto Sakai, Masaaki Fujii

    Chemical Physics Letters   341   70-76   2001

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/S0009-2614(01)00463-8

    researchmap

  • Pico-second time-resolved infrared spectra of photo-excited phenol-(NH3)3 cluster Reviewed

    Shun-ichi Ishiuchi, Makoto Sakai, Kota Daigoku, Tadashi Ueda, Takaya Yamanaka, Kenro Hashimoto, Masaaki Fujii

    Chem. Phys. Lett.   347   87 - 92   2001

     More details

  • Structure and dynamics of 9(10H)-acridone and its hydrated clusters. II. Structural characterization of hydrogen-bonding networks

    M Mitsui, Y Ohshima, S Ishiuchi, M Sakai, M Fujii

    JOURNAL OF PHYSICAL CHEMISTRY A   104 ( 38 )   8649 - 8659   2000.9

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/jp0010482

    Web of Science

    researchmap

  • Infrared dip spectra of photochemical reaction products in a phenol/ammonia cluster: examination of intracluster hydrogen transfer Reviewed

    Ishiuchi S, Saeki M, Sakai M, Fujii M

    CHEMICAL PHYSICS LETTERS   322 ( 1-2 )   27 - 32   2000.5

  • Structural characterization of the acridine-(H2O)n (n=1-3) clusters by fluorescence-detected infrared spectroscopy

    M Mitsui, Y Ohshima, S Ishiuchi, M Sakai, M Fujii

    CHEMICAL PHYSICS LETTERS   317 ( 3-5 )   211 - 219   2000.2

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/S0009-2614(99)01386-X

    Web of Science

    researchmap

  • Structure of 1-Naphthol-Water Clusters as Studied by IR Dip Spectroscopy and Ab Initio Molecular Orbital Calculation Reviewed

    R. Yoshino, K. Hashimoto, T. Omi, S. Ishiuchi, M. Fujii

    J. Phys. Chem. A   102   6227 - 6223   1998

     More details

    Language:English  

    DOI: 10.1021/jp9815006

    researchmap

  • Overtone spectroscopy of jet-cooled phenol studied by nonresonant ionization detected IR spectroscopy Reviewed

    S Ishiuchi, M Fujii

    RESONANCE IONIZATION SPECTROSCOPY   454   137 - 142   1998

     More details

    Language:English   Publishing type:Research paper (international conference proceedings)  

    Web of Science

    researchmap

▼display all

MISC

  • Static and Dynamic Structures of Phenol/Ar Clusters Studied by Multiresonance Laser Spectroscopy

    Shun-ichi Ishiuchi

    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN   84 ( 11 )   1151 - 1168   2011.11

     More details

    Language:English   Publishing type:Book review, literature introduction, etc.  

    DOI: 10.1246/bcsj.20110167

    Web of Science

    researchmap

  • Real-time monitoring of individual pollutants and evaluation of OH reactivity in exhaust gas of a mode-driving vehicle utilizing the laser multi-photon ionization technique

    MATSUMOTO Jun, MISAWA Kentaro, ISHIUCHI Shun-ichi, FUJII Masaaki, HAYASHI Shun-ichi, TANAKA Kotaro, YAMADA Hiroyuki, GOTO Yuichi

    Journal of Japan Society for Atmospheric Environment   45 ( 5 )   205 - 211   2010.8

     More details

    Language:Japanese  

    CiNii Books

    researchmap

  • Real time observation of excited state hydrogen transfer reaction in phenol-(NH3)(n) (n=4, 5) clusters by ps time resolved infrared spectroscopy

    Mitsuhiko Miyazaki, Shun-ichi Ishiuchi, Makoto Sakai, Masaaki Fujii

    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY   238   2009.8

     More details

    Language:English   Publishing type:Research paper, summary (international conference)  

    Web of Science

    researchmap

  • In Situ, Fast-response, Molecular-selective Methods for Measuring Emission Factors of Volatile Organic Compounds (VOCs) into the Atmosphere

    Jun Matsumoto, Kentaro Misawa, Shun-ichi Ishiuchi, Masaaki Fujii

    CHEMISTRY LETTERS   38 ( 1 )   74 - 75   2009.1

     More details

  • Vibrational Signature of the Conformers in Tyramine Studied by IR Dip and Dispersed Fluorescence Spectroscopies

    Koji Makara, Kentaro Misawa, Mitsuhiko Miyazaki, Haruhiko Mitsuda, Shun-ichi Ishiuchi, Masaaki Fujii

    JOURNAL OF PHYSICAL CHEMISTRY A   112 ( 51 )   13463 - 13469   2008.12

     More details

  • Electronic spectra of 7-azaindole/ammonia clusters and their photochemical reactivity

    Yuna Koizumi, Christophe Jouvet, Tsuji Norihiro, Shun-ichi Ishiuchi, Claude Dedonder-Lardeux, Masaaki Fujii

    JOURNAL OF CHEMICAL PHYSICS   129 ( 10 )   2008.9

     More details

  • Electronic spectra of 7-azaindole/ammonia clusters and their photochemical reactivity

    Yuna Koizumi, Christophe Jouvet, Tsuji Norihiro, Shun-ichi Ishiuchi, Claude Dedonder-Lardeux, Masaaki Fujii

    JOURNAL OF CHEMICAL PHYSICS   129 ( 10 )   104311   2008.9

     More details

  • EM2-2: Time-Resolved Measurements of Aromatic Hydrocarbon in Exhaust Gas Using Resonance Enhanced Multi-Photon Ionization Method(EM: Exhaust Emission Control and Measurement,General Session Papers)

    SUZAKI Kotaro, YAMADA Hiroyuki, GOTO Yuichi, MISAWA Kentaro, MATSUMOTO Jun, YAMATO Yohei, ISHIUCHI Shunichi, FUJII Masaaki, TANAKA Koichi, ENDO Katsumi, HAYASHI Shunichi

    The ... international symposium on diagnostics and modeling of combustion in internal combustion engines   2008 ( 7 )   725 - 730   2008.7

     More details

    Language:English   Publisher:The Japan Society of Mechanical Engineers  

    Time-resolved measurements of volatile organic compounds (VOC) and poly aromatic hydrocarbon (PAH) in exhaust gas from automobiles in a driving mode have been performed using Supersonic Jet / resonance enhanced multi-photon ionization (Jet-REMPI) method with 10 ppb sensitivity. Benzene, naphthalene and phenol were measured before and after catalyst treatment in the diesel cars. At the same time total hydrocarbon (THC) was detected by FID through a CVS instrument, which is the normal method for real-time measurement of hydrocarbon without distinction of hydrocarbon species in exhaust gas. The changes in concentration of benzene and other PAH corresponding to the changes in the driving mode were successfully measured every 1 second. As a result of real-time monitoring of exhaust gas from diesel engine, benzene, naphthalene and phenol were quantified at JE05 mode. Compared a real-time PAH and VOC signals with a total hydrocarbon signal detected by FID, it was found that each tendency of benzene and naphthalene was almost same as that of THC, while the tendency of phenol is different from that of THC.

    CiNii Books

    researchmap

  • Real-time and Direct Analysis of Pollutants in Exhaust Gas Utilizing Resonance Enhanced multi-photon ionization (1) 窶骭€ Monitoring System for Realgas Sample 窶骭

    Jun Matsumoto, Kentaro Misawa, Yohei Yamato, Saori Mae, Shun-ichi Ishiuchi, Masaaki Fujii, Koichi Tanaka, Tetsuya Suzuki, Shun-ichi Hayashi, Hiroyuki Yamada, Yuichi Goto

    Review of Automotive Engineering.   29   119 - 121   2008

     More details

  • Real-time and Direct Analysis of Pollutants in Exhaust Gas Utilizing Resonance Enhanced Multi-photon Ionization (2) : Variations of Emissions Under Test Driving Modes

    MISAWA Kentaro, MATSUMOTO Jun, YAMATO Yohei, MAE Saori, ISHIUCHI Shun-ichi, FUJII Masaaki, TANAKA Koichi, SUZUKI Tetsuya, HAYASHI Shun-ichi, YAMADA Hiroyuki, GOTO Yuichi

    Review of Automotive Engineering   29 ( 1 )   123 - 125   2008

     More details

    Language:English  

    CiNii Books

    researchmap

  • Real-time and Direct Analysis of Pollutants in Exhaust Gas Utilizing Resonance Enhanced Multi-photon Ionization (1) : Monitoring System for Real Gas Sample

    MATSUMOTO Jun, MISAWA Kentaro, YAMATO Yohei, MAE Saori, ISHIUCHI Shun-ichi, FUJII Masaaki, TANAKA Koichi, SUZUKI Tetsuya, HAYASHI Shun-ichi, YAMADA Hiroyuki, GOTO Yuichi

    Review of Automotive Engineering   29 ( 1 )   119 - 121   2008

     More details

    Language:English  

    CiNii Books

    researchmap

  • Real-time and Direct Analysis of Pollutants in Exhaust Gas Utilizing Resonance Enhanced multi-photon ionization (2) 窶天ariations of Emissions Under Test Driving Modes窶骭

    Kentaro Misawa, Jun Matsumoto, Yohei Yamato, Saori Mae, Shun-ichi Ishiuchi, Masaaki Fujii, Koichi Tanaka, Tetsuya Suzuki, Shun-ichi Hayashi, Hiroyuki Yamada, Yuichi Goto

    Review of Automotive Engineering   29 ( 1 )   123 - 125   2008

     More details

    Language:English  

    CiNii Books

    researchmap

  • Hydrogen transfer dynamics in a photoexcited phenol/ammonia (1 : 3) cluster studied by picosecond time-resolved UV-IR-UV ion dip spectroscopy

    Shun-ichi Ishiuchi, Makoto Sakai, Kota Daigoku, Kenro Hashimoto, Masaaki Fujii

    JOURNAL OF CHEMICAL PHYSICS   127 ( 23 )   234304   2007.12

     More details

  • IR signature of the photoionization-induced hydrophobic -&gt; hydrophilic site switching in phenol-Ar-n clusters

    Shun-ichi Ishiuchi, Makoto Sakai, Yuji Tsuchida, Akihiro Takeda, Yasutake Kawashima, Otto Dopfer, Klaus Mueller-Dethlefs, Masaaki Fujii

    JOURNAL OF CHEMICAL PHYSICS   127 ( 11 )   114307   2007.9

     More details

  • IR signature of the photoionization-induced hydrophobic -&gt; hydrophilic site switching in phenol-Ar-n clusters

    Shun-ichi Ishiuchi, Makoto Sakai, Yuji Tsuchida, Akihiro Takeda, Yasutake Kawashima, Otto Dopfer, Klaus Mueller-Dethlefs, Masaaki Fujii

    JOURNAL OF CHEMICAL PHYSICS   127 ( 11 )   114307   2007.9

     More details

  • IR spectra of phenol(+)-Kr-n cluster cations (n=1,2): Evidence for photoionization-induced pi -&gt; H isomerization

    Akihiro Takeda, Horia-Sorin Andrei, Mitsuhiko Miyazaki, Shun-ichi Ishiuchi, Makoto Sakai, Masaaki Fujii, Otto Dopfer

    CHEMICAL PHYSICS LETTERS   443 ( 4-6 )   227 - 231   2007.8

     More details

  • Hole-burning spectra of Phenol-Ar-n (n=1,2) clusters: Resolution of the isomer issue

    Shun-Ichi Ishiuchi, Yuji Tsuchida, Otto Dopfer, Klaus Mueller-Dethlefs, Masaaki Fujii

    JOURNAL OF PHYSICAL CHEMISTRY A   111 ( 31 )   7569 - 7575   2007.8

     More details

  • Vibrational OH-stretching overtone spectroscopy of jet-cooled resorcinol and hydroquinone rotamers

    Kaori Hattori, Shun-ichi Ishiuchi, Masaaki Fujii, Daryl L. Howard, Henrik G. Kjaergaard

    JOURNAL OF PHYSICAL CHEMISTRY A   111 ( 27 )   6028 - 6033   2007.7

     More details

  • Structure of the jet-cooled 1-naphthol dimer studied by IR dip spectroscopy: Cooperation between the π-π interaction and the hydrogen bonding

    Morihisa Saeki, Shun-Ichi Ishiuchi, Makoto Sakai, Masaaki Fujii

    Journal of Physical Chemistry A   111 ( 6 )   1001 - 1005   2007.2

     More details

  • Structure of the jet-cooled 1-naphthol dimer studied by IR dip spectroscopy: Cooperation between the pi-pi interaction and the hydrogen bonding

    Morihisa Saeki, Shun-ichi Ishiuchi, Makoto Sakai, Masaaki Fujii

    JOURNAL OF PHYSICAL CHEMISTRY A   111 ( 6 )   1001 - 1005   2007.2

     More details

  • Hydrogen transfer dynamics in a photoexcited phenol/ammonia (1:3) cluster studied by picosecond time-resolved UV-IR-UV ion dip spectroscopy

    Shun-Ichi Ishiuchi, Makoto Sakai, Kota Daigoku, Kenro Hashimoto, Masaaki Fujii

    Journal of Chemical Physics   127 ( 23 )   234304   2007

     More details

  • IR signature of the photoionization-induced hydrophobic R hydrophilic site switching in phenol-Arn clusters

    Shun-ichi Ishiuchi, Makoto Sakai, Yuji Tsuchida, Akihiro Takeda, Yasutake Kawashima, Otto Dopfer, Klaus Muller-Dethlefs, Masaaki Fujii

    Virtual Journal of Nanoscale Science & Technology   16 ( 14 )   2007

     More details

  • IR signature of the photoionization-induced hydrophobic R hydrophilic site switching in phenol-Arn clusters

    Shun-ichi Ishiuchi, Makoto Sakai, Yuji Tsuchida, Akihiro Takeda, Yasutake Kawashima, Otto Dopfer, Klaus Muller-Dethlefs, Masaaki Fujii

    Virtual Journal of Nanoscale Science & Technology   16 ( 14 )   2007

     More details

  • Development of a supercritical fluid jet technique for supersonic jet laser spectroscopy of nonvolatile and pyrolytic molecules

    Shun-Ichi Ishiuchi, Masaaki Fujii

    Chemistry Letters   35 ( 9 )   1044 - 1045   2006.9

     More details

  • Development of a supercritical fluid jet technique for supersonic jet laser Spectroscopy of nonvolatile and pyrolytic molecules

    Shun-ichi Ishiuchi, Masaaki Fujii

    CHEMISTRY LETTERS   35 ( 9 )   1044 - 1045   2006.9

     More details

  • Excited state hydrogen transfer in fluorphenol center dot ammonia clusters studied by two-color REMPI spectroscopy

    N Tsuji, S Ishiuchi, M Sakai, M Fujii, T Ebata, C Jouvet, C Dedonder-Lardeux

    PHYSICAL CHEMISTRY CHEMICAL PHYSICS   8 ( 1 )   114 - 121   2006

     More details

  • Excited state hydrogen transfer in fluorphenol center dot ammonia clusters studied by two-color REMPI spectroscopy

    N Tsuji, S Ishiuchi, M Sakai, M Fujii, T Ebata, C Jouvet, C Dedonder-Lardeux

    PHYSICAL CHEMISTRY CHEMICAL PHYSICS   8 ( 1 )   114 - 121   2006

     More details

  • Development of Real Time Monitoring Instrument for Trace Gas Analysis based on Jet-REMPI Technique : Development of High Sensitive Daly detector

    HAYASHI Shun-ichi

    18 ( 3 )   653 - 653   2005.3

     More details

    Language:Japanese  

    CiNii Books

    researchmap

  • Theoretical investigation of the point-spread function given by super-resolving fluorescence microscopy using two-color fluorescence dip spectroscopy

    Y Iketaki, T Watanabe, M Sakai, S Ishiuchi, M Fujii, T Watanabe

    OPTICAL ENGINEERING   44 ( 3 )   2005.3

     More details

  • Real-time observation of ionization-induced hydrophobic -&gt; hydrophilic switching

    S Ishiuchi, M Sakai, Y Tsuchida, A Takeda, Y Kawashima, M Fujii, O Dopfer, K Muller-Dethlefs

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   44 ( 38 )   6149 - 6151   2005

     More details

  • Real-time observation of ionization-induced hydrophobic -&gt; hydrophilic switching

    S Ishiuchi, M Sakai, Y Tsuchida, A Takeda, Y Kawashima, M Fujii, O Dopfer, K Muller-Dethlefs

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   44 ( 38 )   6149 - 6151   2005

     More details

  • Development of Real Time Monitoring Instrument for Trace Gas Analysis based on Jet-REMPI Technique

    HAYASHI Shun-ichi

    17 ( 6 )   1491 - 1491   2004.9

     More details

    Language:Japanese  

    CiNii Books

    researchmap

  • Four-color hole burning spectra of phenol/ammonia 1 : 3 and 1 : 4 clusters

    S Ishiuchi, K Daigoku, K Hashimoto, M Fujii

    JOURNAL OF CHEMICAL PHYSICS   120 ( 7 )   3215 - 3220   2004.2

     More details

  • Photo-excitation : Intact Ionization of Molecules by Resonant Enhanced Multiuphoton Ionization Spectroscopy

    FUJII Masaaki, ISHIUCHI Shun-ichi, HAYASHI Shun-ichi

    Journal of the Vacuum Society of Japan   47 ( 8 )   612 - 617   2004

     More details

    Language:Japanese   Publisher:The Vacuum Society of Japan  

    DOI: 10.3131/jvsj.47.612

    CiNii Books

    researchmap

    Other Link: https://jlc.jst.go.jp/DN/JALC/00242164317?from=CiNii

  • Investigation of the fluorescence depletion process in the condensed phase; application to a tryptophan aqueous solution

    Y Iketaki, T Watanabe, S Ishiuchi, M Sakai, T Omatsu, K Yamamoto, M Fujii, T Watanabe

    CHEMICAL PHYSICS LETTERS   372 ( 5-6 )   773 - 778   2003.5

     More details

  • Development of Trace Gas Analysis in High Temperature Furnace Based on Jet-REMPI Instrument

    HAYASHI Shun-ichi

    16 ( 3 )   708 - 708   2003.3

     More details

    Language:Japanese  

    CiNii Books

    researchmap

  • The enhancement of the two-pint resolution of the far-field super-resolution microscopy by using two color fluorescence dip spectroscopy

    Takeshi Watanabe, Makoto Sakai, Shun-ichi Ishiuchi, Masaaki Fujii, Yoshinori Iketaki Takashige, Omatsu Kimihisa Yamamoto

    Opt. Express   11   3271   2003

     More details

  • Pulsed field ionization-ZEKE spectroscopy of 4-aminobenzonitrile-H2O. Hydrogen-bonding interaction in the amino site

    K Sakota, N Yamamoto, K Ohashi, M Saeki, S Ishiuchi, M Sakai, M Fujii, H Sekiya

    PHYSICAL CHEMISTRY CHEMICAL PHYSICS   5 ( 9 )   1775 - 1779   2003

     More details

  • The investigation for the fluorescence depletion process of the Rhodamine-6G molecule

    Takeshi Watanabe, Makoto Sakai, Shun-ichi Ishiuchi, Masaaki Fujii, Yoshinori Iketaki Takashige, Omatsu Kimihisa Yamamoto

    Chem. Phys. Lett   372   773 - 778   2003

     More details

  • Super-resolution Fluorescence Microscopy in Nano-meter Scale Region Using Two-color Laser Beams

    IKETAKI Yoshinori, WATANABE Takeshi, SAKAI Makoto, ISHIUCHI Shun-ichi, OMATSU Takashige, YAMAMOTO Kimihisa, FUJII Masaaki

    J. Surf. Sci. Soc. Jpn.   24 ( 7 )   2 - 9   2003

     More details

    Language:Japanese   Publisher:The Surface Science Society of Japan  

    A super-resolution fluorescence microscopy using two-color laser beams was proposed. The microscopy is based on the combination of two-color fluorescence dip spectroscopy and a phase modulation technique for the laser beam. By applying the proposed technique to a laser-scanning microscope, a fluorescence image of a sample can be observed with a spatial resolution overcoming the optical diffraction limit. To demonstrate validity of the microscopy, we constructed a scanning microscope system using commercial nano-second pulse lasers. An image of micro beads containing dye molecules was observed by the microscopy. We succeeded in obtaining the image with a resolution overcoming the diffraction limit in nano-meter scale region. The experimental data showed that the resolution was improved three times at least. The microscopy is expected to be an appropriate analysis method for the samples with nano-meter scale structures.

    DOI: 10.1380/jsssj.24.392

    CiNii Books

    researchmap

    Other Link: https://jlc.jst.go.jp/DN/JALC/00230543018?from=CiNii

  • Hydrogen transfer in photo-excited phenol/ammonia clusters by UV-IR-UV ion dip spectroscopy and ab initio molecular orbital calculations. II. Vibrational transitions

    Shun-Ichi Ishiuchi, Kota Daigoku, Morihisa Saeki, Makoto Sakai, Kenro Hashimoto, Masaaki Fujii

    Journal of Chemical Physics   117 ( 15 )   7083 - 7093   2002.10

     More details

    Language:English  

    DOI: 10.1063/1.1508104

    Scopus

    researchmap

  • Hydrogen transfer in photo-excited phenol/ammonia clusters by UV-IR-UV ion dip spectroscopy and ab initio molecular orbital calculations. II. Vibrational transitions

    S Ishiuchi, K Daigoku, M Saeki, M Sakai, K Hashimoto, M Fujii

    JOURNAL OF CHEMICAL PHYSICS   117 ( 15 )   7083 - 7093   2002.10

     More details

  • IR-dip and IR-UV hole-burning spectra of jet-cooled 4-aminobenzonitrile-(H2O)(1). Observation of pi-type and sigma-type hydrogen-bonded conformers in the CN site

    K Sakota, N Yamamoto, K Ohashi, M Saeki, S Ishiuchi, M Sakai, M Fujii, H Sekiya

    CHEMICAL PHYSICS   283 ( 1-2 )   209 - 219   2002.10

     More details

  • Hydrogen transfer in photoexcited phenol/ammonia clusters by UV-IR-UV ion dip spectroscopy and ab initio molecular orbital calculations. I. Electronic transitions

    S Ishiuchi, K Daigoku, M Saeki, M Sakai, K Hashimoto, M Fujii

    JOURNAL OF CHEMICAL PHYSICS   117 ( 15 )   7077 - 7082   2002.10

     More details

  • Structure of hydrogen-bonded clusters of 7-azaindole studied by IR dip spectroscopy and ab initio molecular orbital calculation (vol 105A, pg 9371, 2001)

    H Yokoyama, H Wantanabe, T Omi, S Ishiuchi, M Fujii

    JOURNAL OF PHYSICAL CHEMISTRY A   106 ( 5 )   854 - 854   2002.2

     More details

  • Pulsed Field Ionization Zero Kinetic Energy Photoelectron Study on Methylanisole Molecules in a Supersonic Jet

    Keigo Yosida, Kazunari Suzuki, Shun-ichi Ishiuchi, Makoto Sakai, Masaaki Fujii, Caroline E, H. Dessent, Klaus Muller-Dethlefs

    Phys. Chem. Chem. Phys.   4   2534 - 2538   2002

     More details

  • OH- and CH-Stretching Overtone Spectra of Catechol

    Henrik G. Kjaergaard Daryl L. Howar, Daniel P. Schofield Timothy, W. Robinson, Shun-ichi Ishiuchi, Masaaki Fujii

    J. Phys. Chem. A   106   258   2002

     More details

  • Pulsed Field Ionization Zero Kinetic Energy Photoelectron Study on Methylanisole Molecules in a Supersonic Jet

    Keigo Yosida, Kazunari Suzuki, Shun-ichi Ishiuchi, Makoto Sakai, Masaaki Fujii, Caroline E, H. Dessent, Klaus Muller-Dethlefs

    Phys. Chem. Chem. Phys.   4   2534 - 2538   2002

     More details

  • Picosecond Time-Resolved Nonresonant Ionization Detected IR Spectroscopy on 7-Azaindole Dimer

    Makoto Sakai, Shun-ichi Ishiuchi, Masaaki Fujii

    Eur. J. Phys. D.   20   399   2002

  • Hydrogen Transfer in Photoexcited Phenol/ammonia Clusters by UV-IR-UV Ion Dip Spectroscopy and ab initio Molecular Orbital Calculations. I. Electronic Transitions

    Shun-ichi Ishiuchi, Kota Daigoku, Morihisa Saeki, Makoto Sakai, Kenro Hashimoto, Masaaki Fujii

    J. Chem. Phys.   117 ( 15 )   7077 - 7082   2002

     More details

  • Hydrogen transfer in photoexcited phenol/ammonia clusters by UV-IR-UV ion dip spectroscopy and ab initio molecular orbital calculations. I. Electronic transitions

    S. Ishiuchi, K. Daigoku, M, Saeki, M. Sakai, K. Hashimoto, M. Fujii

    Journal of Chemical Physics   117 ( 15 )   7077 - 7082   2002

     More details

  • Hydrogen Transfer in Photoexcited Phenol/ammonia Clusters by UV-IR-UV Ion Dip Spectroscopy and ab initio Molecular Orbital Calculations. I. Electronic Transitions

    Shun-ichi Ishiuchi, Kota Daigoku, Morihisa Saeki, Makoto Sakai, Kenro Hashimoto, Masaaki Fujii

    J. Chem. Phys.   117 ( 15 )   7077 - 7082   2002

     More details

  • Structure of Hydrogen-bonded Clusters of 7-Azaindole Studied by IR dip Spectroscopy and Ab Initio Molecular Orbital Calculation

    Hiroshi Yokoyama, Hidekazu Watanabe Takuichiro Omi, Shun-ichi Ishiuchi, Masaaki Fujii

    J. Phys. Chem. A   105   9366   2001

     More details

  • Internal Methyl Group Rotation in o-Cresol Studied by Pulsed Field Ionization - ZEKE Photoelectron Spectroscopy

    Kazunari Suzuki, Yuji Emura, Shun-ichi Ishiuchi, Masaaki Fujii

    J. Electron Spectrosc.   108   13   2000

  • Pulsed Field Ionization - ZEKE Spectroscopy of Cresoles and Their Aqueous Complex:Internal Rotation of Methyl Group and Intermolecular Vibrations

    Kazunari Suzuki, Shun-ichi Ishiuchi, Masaaki Fujii

    Faraday Discuss.   115   229   2000

     More details

  • Nonresonant ionization detected IR spectrum of jet-cooled phenol. Ionization mechanism and its application to overtone spectroscopy

    S Ishiuchi, H Shitomi, K Takazawa, M Fujii

    CHEMICAL PHYSICS LETTERS   283 ( 3-4 )   243 - 250   1998.2

     More details

  • Nonresonant ionization detected IR spectrum of jet-cooled phenol. Ionization mechanism and its application to overtone spectroscopy

    S Ishiuchi, H Shitomi, K Takazawa, M Fujii

    CHEMICAL PHYSICS LETTERS   283 ( 3-4 )   243 - 250   1998.2

     More details

  • Higher Vibrational States of Jet-cooled Phenol Studied by Nonresonant Ionization Detected IR Spectroscopy.

    石内俊一, 蔀洋司, 高沢健, 藤井正明

    化学反応討論会講演要旨集   12th   1996

  • IR-UV Double Resonance Spectrum of Phenol-Water Cluster-OH Stretching Overtone.

    石内俊一, 蔀洋司, 藤井正明, 岩崎純史, 江幡孝之, 三上直彦

    分子構造総合討論会講演要旨集   1996   1996

  • Rotational Isomers in Fluorophenols studied by IR-UV Double Resonance spectroscopy-Overtone spectroscopy of Water Cluster.

    蔀洋司, 石内俊一, 藤井正明

    分子構造総合討論会講演要旨集   1996   1996

▼display all

Presentations

  • Hydrogen transfer in photo-excited phenol / ammonia clusters by UV-IR-UV ion dip spectroscopy and ab initio MO calculations II : Vibrational Transitions

    J. Chem. Phys.  2002 

     More details

  • Hydrogen transfer in photo-excited phenol / ammonia clusters by UV-IR-UV ion dip spectroscopy and ab initio MO calculations I : Electronic Transitions

    J. Chem. Phys.  2002 

     More details

  • Structure of 1-Naphthol-Water Clusters Studied by IR Dip Spectroscopy and Ab Initio Molecular Orbital Calculation

    J. Phys. Chem. A,  1998 

     More details

  • Structure of 1-Naphthol-Water Clusters Studied by IR Dip Spectroscopy and Ab Initio Molecular Orbital Calculation

    J. Phys. Chem. A,  1998 

     More details

  • Hydrogen transfer in photo-excited phenol / ammonia clusters by UV-IR-UV ion dip spectroscopy and ab initio MO calculations II : Vibrational Transitions

    J. Chem. Phys.  2002 

     More details

  • Hydrogen transfer in photo-excited phenol / ammonia clusters by UV-IR-UV ion dip spectroscopy and ab initio MO calculations I : Electronic Transitions

    J. Chem. Phys.  2002 

     More details

▼display all

Research Projects

  • 蛍光分子の焼き付けと蛍光回復を利用したATP合成反応における酵素の回転の測定

    Grant number:21K19210  2021.7 - 2023.3

    日本学術振興会  科学研究費助成事業  挑戦的研究(萌芽)

    久堀 徹, 石内 俊一

      More details

    Grant amount:\6500000 ( Direct Cost: \5000000 、 Indirect Cost:\1500000 )

    researchmap

  • 冷却イオン分光によるイオン選択性分子に対する微視的水和効果の解明

    Grant number:21H04674  2021.4 - 2025.3

    日本学術振興会  科学研究費助成事業  基盤研究(A)

    石内 俊一, 平田 圭祐

      More details

    Grant amount:\42380000 ( Direct Cost: \32600000 、 Indirect Cost:\9780000 )

    researchmap

  • Molecular recognition mechanism of adrenaline receptors studied by ESI- ion trap spectroscopy

    Grant number:20H00372  2020.4 - 2024.3

    Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research  Grant-in-Aid for Scientific Research (A)

      More details

    Grant amount:\44720000 ( Direct Cost: \34400000 、 Indirect Cost:\10320000 )

    researchmap

  • 冷却イオントラップ分光による天然変性タンパク質複合体へのボトムアップアプローチ

    Grant number:20K20446  2020.4 - 2023.3

    日本学術振興会  科学研究費助成事業  挑戦的研究(開拓)

    藤井 正明, 石内 俊一, 平田 圭祐, 宮崎 充彦

      More details

    Grant amount:\26000000 ( Direct Cost: \20000000 、 Indirect Cost:\6000000 )

    1)YEMPS-ドーパおよびノルアドレナリン複合体のの冷却イオントラップ赤外分光
    天然変性タンパク質であるα-シヌクレインのドーパミン結合部位にはドーパミン誘導体であるドーパやノルアドレナリンも結合することが分かっている。そこで,YEMPS配列の部分ペプチドAc-YEMPS-NHMe(以降YEMPS)とプロトン付加ドーパおよびプロトン付加ノルアドレナリンの複合体をエレクトロスプレーで気相中に取り出し,冷却イオントラップ中の極低温下で赤外スペクトルを測定した。ドーパミン複合体の場合と同様に,プロトン化アミノ基がYEMPSと優先的に結合するのを阻害するために,18C6クラウンエーテルでプロトン化アミノ基を包接保護した。その結果,これら2つの複合体でも,YEMPSとカテコールOH基が結合した構造を形成させることができた。YEMPSの2 次構造を明らかにするために,ペプチド結合のC=O伸縮振動(amide-I)を測定したところ,1650 cm-1にバンドが観測され,α-ヘリックス構造が形成されていることが確認された。従って,ドーパミンと同様に,ドーパやノルアドレナリンも複合体形成によりYEMPSにヘリックス構造を誘起することが分かった。
    <BR>
    2)異性体分離したスペクトル測定法の検討
    クラウンエーテルを付加した複合体ではUVスペクトルの測定が困難なため,UVスペクトルを用いた異性体分離ができない。そこで,IRスペクトルのみを用いて異性体分離したスペクトルを測定する方法であるIR-IR dip分光法を用いる必要があるが,これを実現するためには,1本目のIR照射と2本目のIR照射の間で質量分析する必要があり,現有装置では困難である。そのため,冷却イオントラップの後の線形飛行時間方質量分析器を2段の質量分析器に改造する必要があり,最適な方法をイオン軌道シミュレーションを用いて確立した。

    researchmap

  • DESI・冷却イオン分光によるコンフォメーションイメージング法の確立

    Grant number:19K22163  2019.6 - 2023.3

    日本学術振興会  科学研究費助成事業  挑戦的研究(萌芽)

    石内 俊一

      More details

    Grant amount:\6370000 ( Direct Cost: \4900000 、 Indirect Cost:\1470000 )

    1)質量分析装置の改造
    昨年度納品が遅れていたRF電源が納入されたため,当該装置を用いてRFイオンガイドの改造を行った。その結果,予想された様なイオン損失の低下は見られなかった。再度,電極形状の変更やイオン軌道シミュレーションを行ったところ,イオントラップにイオンを導入するところで,イオンの収束が悪いことが分かり,種々の検討の結果,先が徐々に細くなるRFイオンガイドを用いてイオン軌道を強制的に収束させることが最善策であると結論した。それに従い,RFイオンガイドを再設計し製作した。
    <BR>
    2)DESI試料作成法の検討
    種々の基板にチロシンなどのモデル試料を均一に塗布する方法を確立した。基本的にはエアーブラシを用いて塗布を行うが,最適な試料濃度や溶媒を検討した。

    researchmap

  • Hydration effect on ion-selectivity of ion channels studied by cold ion trap spectroscopy

    Grant number:18H01938  2018.4 - 2021.3

    Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research  Grant-in-Aid for Scientific Research (B)

    Ishiuchi Shun-ichi

      More details

    Grant amount:\17550000 ( Direct Cost: \13500000 、 Indirect Cost:\4050000 )

    To elucidate hydration effects on the ion selectivity of ion channels at molecular level, structural changes of metal ion complexes of a partial peptide which constitutes selectivity filter of the ion channel by hydration were investigated by using infrared spectroscopy measured under ultra cold isolated condition. So far, hydration effects upon the ion selectivity have been argued from the point of view of simple thermo dynamics; which is more stable, binding with the selectivity filter or hydration. In this work, however, it was revealed that the hydration effect affects the ion selectivity more directly and plays a crucial role for it in some case.

    researchmap

  • Structural diversity and hydration dynamics of hydrogen bonding system studied by gas-phase spectroscopy

    Grant number:25104008  2013.6 - 2018.3

    Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research  Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

    Fujii Masaaki

      More details

    Grant amount:\89180000 ( Direct Cost: \68600000 、 Indirect Cost:\20580000 )

    Electrospray cryogenic ion trap spectrometer was developed, and applied to complexes of partial sequence of receptor proteins and several ligands to reveal their interactions at molecular level. In addition, hydration effects on their structures were clarified by using hydrated clusters in which number of water molecules and their orientation can be rigorously determined. Furthermore, Structures of alkali metal ion complexes of biomolecules were investigated by using isomer-selected infrared spectroscopy, and conformational specificity depending on the alkali metal ions was revealed. Through these results, we successfully demonstrated that precise spectroscopic studies on the interaction centers cut out from biomolecules, i.e., "bottom-up approach" is useful.

    researchmap

  • Excited state dynamics of peptides by gas phase spectroscopy - photo protecting mechanism of protein

    Grant number:25708001  2013.4 - 2016.3

    Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research  Grant-in-Aid for Young Scientists (A)

    Ishiuchi Shun-ichi

      More details

    Grant amount:\19630000 ( Direct Cost: \15100000 、 Indirect Cost:\4530000 )

    Laser desorption supersonic jet laser spectroscopy was applied to several peptides including aromatic amino-acids to measure conformer-selected electronic and infrared spectra. By comparing them with theoretical calculations, structure of each conformer was determined, and the correlation between the structure and shape of the electronic spectrum (whether broadened or not) was discussed. In the case of the peptides including tyrosine, significant difference of excited state lifetime was not found among different conformers. On the other hand, in the tryptophan-inculded peptides, broadened electronic spectra were observed when the peptides form strong cyclic hydrogen bond between NH and CO and the tryptophan residue is included in that circle. From this result, it was suggested that such structures accelerate excited state relaxation process.

    researchmap

  • Surface-assisted laser desorption/ionization mass analysis system with nano-scale surface modified sample substrate

    Grant number:21310072  2009 - 2011

    Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research  Grant-in-Aid for Scientific Research (B)

    YONEZAWA Tetsu, FUJII Masaaki, ISHIUCHI Shun-ichi, ARAKAWA Ryuichi, KAWASAKI Hideya

      More details

    Grant amount:\18460000 ( Direct Cost: \14200000 、 Indirect Cost:\4260000 )

    Development of surface assisted LDI (SALDI) system used for analyses of low molecular compounds has been carried out. Dealloy process with electrochemical etching could successfully provide nanoporous platinum plate. The structure of nanopores strongly varied with the alloy composition. These plates were applied as SALDI-MS sample plate, desorption/ionization of organic compounds could not be detected. On the other hand, aggregated sample plate of semiconductor nanoparticles effectively

    researchmap

  • Elementary process of molecular recognition from cluster to cell

    Grant number:19056002  2007 - 2011

    Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research  Grant-in-Aid for Scientific Research on Priority Areas

    FUJII Masaaki, SAKAI Makoto, ISHIUCHI Shun-ichi, HASHIMOTO Kenro, MISAWA Kentaro, MIYAZAKI Mitsuhiko

      More details

    Grant amount:\83300000 ( Direct Cost: \83300000 )

    Various materials to increase the efficiency of laser desorption of nonvolatile biomolecules were explored. Gold nano particle and carbon black were concluded as the best materials. The development enables us to determine structures of catecholamines and related molecules systematically by their UV and IR spectra. Picosecond time-resolved IR spectroscopy was applied to ionization triggered water migration dynamics in acetanilide-water system. This revealed details of the dynamics of single water molecule from the molecular point of view for the first time. Vibrational sum-frequency generation and optical microscope were combined to develop an IR super-resolution microscopy. 14 times higher spatial resolution than the IR diffraction limit was achieved and internal structures of cells were successfully visualized.

    researchmap

  • Development of super critical fluid jet technique and its application to elucidate the mechanism of the molecular recognition

    2002 - 2005

    JST Basic Research Programs (Precursory Research for Embryonic Science and Technology :PRESTO) 

      More details

    Grant type:Competitive

    researchmap

  • イオン化検出赤外分光法による孤立分子の高振動状態の研究

    Grant number:98J06622  1998 - 2000

    日本学術振興会  科学研究費助成事業  特別研究員奨励費

    石内 俊一

      More details

    Grant amount:\2700000 ( Direct Cost: \2700000 )

    researchmap

▼display all